Sustainable Precursors, Additives and Approaches for Carbon Fibers

A special issue of Fibers (ISSN 2079-6439).

Deadline for manuscript submissions: closed (27 August 2021) | Viewed by 20612

Special Issue Editors


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Guest Editor
1. School of Agriculture and Food Sustainability, The University of Queensland, Brisbane, QLD 4072, Australia
2. Centre for Future Materials, University of Southern Queensland, Toowoomba, QLD 4350, Australia
Interests: cellulose; natural fibers; sustainable building blocks; nanomaterials; biomass-derived carbon
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Guest Editor
The University of Queensland, Australian Institute Bioengineering and Nanotechnology (AIBN), Brisbane, Qld 4072, Australia
Interests: nanocellulose; fiber engineering; smart textiles; elastomers

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Guest Editor
The University of Queensland, Australian Institute Bioengineering and Nanotechnology (AIBN), Brisbane, Qld 4072, Australia
Interests: carbon materials; energy storage materials; sustainable carbon precursors
Special Issues, Collections and Topics in MDPI journals

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Guest Editor
The University of Queensland, Australian Institute Bioengineering and Nanotechnology (AIBN), Brisbane, Qld 4072, Australia
Interests: polymer nanocomposites, sustainable and safe nanomaterials

Special Issue Information

Dear Colleagues,

Lightweight materials and carbon fiber-reinforced composites have recently found considerable use in the automotive and aerospace sectors, allowing to address issues related to environmental regulations, fuel price, and industrial demand. The industrial uptake of carbon fibers in other industries is still severely limited by the cost associated with the petroleum-derived polyacrylonitrile (PAN) precursor and the high energy requirements for the conversion of precursor fibers into high-quality (stiff and strong) carbon fibers. In order to reduce the production costs, there is currently a great demand for new approaches and methods to manufacture carbon fibers with high mechanical properties, while consuming less energy.

In the recent decades, there has been a renewed research interest in the use of bio-based or renewable precursors such as rayon, bio-acrylonitrile, and lignin, and of low-cost synthetic precursors such as polyethylene. On the other hand, significant research efforts have also been addressed towards reducing the energy costs or production costs in a number of ways, including the optimization of fiber processing conditions, the tailoring of PAN comonomer compositions, and the synthesis of high-molecular-weight PAN by reversible addition–fragmentation chain-transfer (RAFT) polymerization.

This Special Issue of Fibers intends to cover recent advances in renewable or sustainable precursors for carbon fibers and solicits contributions from researchers active in reducing the energy requirements in the stabilization and carbonization stages and in optimizing alternative, cost-effective precursors and the use of nanoadditives in carbon fiber manufacturing.

Dr. Pratheep Kumar Annamalai
Dr. Nasim Amiralian
Dr. Ashok Kumar Nanjundan
Prof. Darren James Martin
Guest Editors

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Keywords

  • Renewable
  • Lignin
  • Cellulose
  • Carbon fiber
  • Mechanical properties
  • Electrospinning
  • Wet spinning
  • Stabilization
  • Carbonization
  • Polyacrylonitrile

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Published Papers (3 papers)

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Research

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15 pages, 3113 KiB  
Article
The Effect of Alcohol Precipitants on Structural and Morphological Features and Thermal Properties of Lyocell Fibers
by Igor S. Makarov, Lyudmila K. Golova, Markel I. Vinogradov, Ivan S. Levin, Georgiy A. Shandryuk, Natalia A. Arkharova, Yaroslav V. Golubev, Anna K. Berkovich, Timofei V. Eremin and Elena D. Obraztsova
Fibers 2020, 8(6), 43; https://doi.org/10.3390/fib8060043 - 26 Jun 2020
Cited by 8 | Viewed by 5414
Abstract
This research examines the possibilities of regulating the structure of cellulose precursor fibers spun from solutions in N-methylmorpholine-N-oxide when replacing aqueous coagulation baths with thermodynamically softer alcohol baths at different temperatures. The fibers were spun by the dry jet–wet method [...] Read more.
This research examines the possibilities of regulating the structure of cellulose precursor fibers spun from solutions in N-methylmorpholine-N-oxide when replacing aqueous coagulation baths with thermodynamically softer alcohol baths at different temperatures. The fibers were spun by the dry jet–wet method in isobutanol coagulation baths with a temperature of 25 °C and 70 °C. The study of the phase state of the solvent–coagulant system using viscometry and point cloud methods revealed the temperature-concentration regions of the single-phase and two-phase states of the system. Using elemental analysis, DSC (differential scanning calorimetry) and XRD (X-ray diffraction) methods, it was shown that just spun fibers, due to the presence of a residual amount of solvent and coagulant in them, regardless of the temperature of the precipitator, have an amorphous structure. Additional washing with water completely washed away the solvent and coagulant as well, however, the structure of cellulose changes slightly, turning into a defective amorphous-crystalline one. A relationship was found between the phase composition, structure, and properties of just spun fibers and precursors washed with water. Thus, the loss of structural ordering of both just spun and washed cellulose fibers leads to a decrease in strength characteristics and an increase in deformation. The thermal behavior of the fibers is determined by their phase composition. Fibers just spun into hot alcohol containing a coagulant and traces of solvent acquire thermal stability up to 330 °C. During the pyrolysis of the obtained precursors up to 1000 °C, the value of the carbon yield doubles. The amorphized structure of the obtained fibers allows us to consider it as a model when analyzing the transformation of the structure of precursors during thermolysis. Full article
(This article belongs to the Special Issue Sustainable Precursors, Additives and Approaches for Carbon Fibers)
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12 pages, 3326 KiB  
Article
Improvement in Carbonization Efficiency of Cellulosic Fibres Using Silylated Acetylene and Alkoxysilanes
by Maria Mironova, Igor Makarov, Lyudmila Golova, Markel Vinogradov, Georgy Shandryuk and Ivan Levin
Fibers 2019, 7(10), 84; https://doi.org/10.3390/fib7100084 - 28 Sep 2019
Cited by 18 | Viewed by 6773
Abstract
Comparative studies of the structure and thermal behavior of cellulose and composite precursors with additives of silyl-substituted acetylene and alkoxysilanes were carried out. It is shown that the introduction of silicon-containing additives into the cellulose matrix influenced the thermal behavior of the composite [...] Read more.
Comparative studies of the structure and thermal behavior of cellulose and composite precursors with additives of silyl-substituted acetylene and alkoxysilanes were carried out. It is shown that the introduction of silicon-containing additives into the cellulose matrix influenced the thermal behavior of the composite fibers and the carbon yield after carbonization. Comparison of the activation energies of the thermal decomposition reaction renders it possible to determine the type of additive and its concentration, which reduces the energy necessary for pyrolysis. It is shown that the C/O ratio in the additive and the presence of the Si–C bond affected the activation energy and the temperature of the beginning and the end of the pyrolysis reaction. Full article
(This article belongs to the Special Issue Sustainable Precursors, Additives and Approaches for Carbon Fibers)
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Review

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25 pages, 4845 KiB  
Review
Impact of Alternative Stabilization Strategies for the Production of PAN-Based Carbon Fibers with High Performance
by Spyridon Soulis, George Konstantopoulos, Elias P. Koumoulos and Costas A. Charitidis
Fibers 2020, 8(6), 33; https://doi.org/10.3390/fib8060033 - 26 May 2020
Cited by 23 | Viewed by 7502
Abstract
The aim of this work is to review a possible correlation of composition, thermal processing, and recent alternative stabilization technologies to the mechanical properties. The chemical microstructure of polyacrylonitrile (PAN) is discussed in detail to understand the influence in thermomechanical properties during stabilization [...] Read more.
The aim of this work is to review a possible correlation of composition, thermal processing, and recent alternative stabilization technologies to the mechanical properties. The chemical microstructure of polyacrylonitrile (PAN) is discussed in detail to understand the influence in thermomechanical properties during stabilization by observing transformation from thermoplastic to ladder polymer. In addition, relevant literature data are used to understand the comonomer composition effect on mechanical properties. Technologies of direct fiber heating by irradiation have been recently involved and hold promise to enhance performance, reduce processing time and energy consumption. Carbon fiber manufacturing can provide benefits by using higher comonomer ratios, similar to textile grade or melt-spun PAN, in order to cut costs derived from an acrylonitrile precursor, without suffering in regard to mechanical properties. Energy intensive processes of stabilization and carbonization remain a challenging field of research in order to reduce both environmental impact and cost of the wide commercialization of carbon fibers (CFs) to enable their broad application. Full article
(This article belongs to the Special Issue Sustainable Precursors, Additives and Approaches for Carbon Fibers)
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