Emerging Perovskite Materials and Applications

A special issue of Crystals (ISSN 2073-4352). This special issue belongs to the section "Inorganic Crystalline Materials".

Deadline for manuscript submissions: 25 October 2025 | Viewed by 314

Special Issue Editors


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Guest Editor
School of Materials Science and Engineering, Shenyang Jianzhu University, Shenyang 110168, China
Interests: perovskite materials; fluorescence; pressure; phase transition; rare earth

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Guest Editor
Department of Industrial Engineering, University of Salerno, 84084 Fisciano, Italy
Interests: photovoltaic material; polymer based nanocomposites; perovskite; silicon
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Special Issue Information

Dear Colleagues,

Perovskite materials have shown good application prospects in optoelectronics and photovoltaics due to their unique structural advantages. How to control the local structure of perovskite materials based on the original structure and performance advantages, to explore potential high performance and new properties, is of great significance to further expanding the application prospects of such materials. In recent years, with the deepening of research, its conversion efficiency in the field of photovoltaics has continued to rise, from the initial single digits to more than 25 %, and has gradually become a research hotspot of energy materials. The common preparation methods of perovskite materials include the high temperature solid phase method, sol–gel method, hydrothermal synthesis method, and vapor deposition method. Doping is an important means to regulate the physical properties of halide perovskites and even induce them to produce new properties. In view of the structural characteristics of the vacancy configuration of the double perovskite Cs2BX6, different ions can be easily doped, especially the 6-coordinated tetravalent cation B position. After ion doping, due to the different ionic radii, local distortion of the octahedral structural unit is caused, the symmetry of the local structure is reduced, a local potential well is generated, and the transition from free exciton to self-trapped exciton is induced. It is expected to break the odd–even forbidden transition and provide additional emission centers to excite the novel photoelectric properties of perovskite. Therefore, it can be foreseen that regulating the local behavior of double perovskite octahedral units is expected to optimize their physical properties.

Prof. Dr. Tingting Yan
Dr. Heinz Christoph Neitzert
Guest Editors

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Keywords

  • perovskite materials
  • fluorescence
  • efficiency
  • solar cells
  • ion doping
  • pressure effects
  • phase transition
  • optical properties
  • vibrational spectroscopy
  • electronic state calculations
  • theoretical models

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Published Papers (1 paper)

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Research

11 pages, 1557 KiB  
Article
Synthesis and High-Pressure Stability Study of Energetic Molecular Perovskite DAI-X1
by Tingting Yan, Han Li, Dongyang Xi, Linan Liu, Lei Sun and Dinghan Jin
Crystals 2025, 15(6), 530; https://doi.org/10.3390/cryst15060530 - 1 Jun 2025
Viewed by 193
Abstract
In the pursuit of advancing the knowledge of energetic materials, we successfully formulated the energetic perovskite DAI-X1 with the chemical formula (C12H50I6N3Na2O36). Energetic perovskites hold great promise in various applications, including [...] Read more.
In the pursuit of advancing the knowledge of energetic materials, we successfully formulated the energetic perovskite DAI-X1 with the chemical formula (C12H50I6N3Na2O36). Energetic perovskites hold great promise in various applications, including high-energy storage and propulsion systems, due to their unique combination of high energy density and structural versatility. DAI-X1, in particular, has attracted our attention because of its potential for optimized performance in these areas. We conducted an in-depth investigation into the high-pressure stability of DAI-X1 using in situ high-pressure Raman spectroscopy analysis. DAI-X1 possesses a cubic ABX3 perovskite structure, and notable modifications in its Raman spectroscopic characteristics were noted within the pressure interval of 2.5–7.8 GPa, indicating structural instability under high pressure and suggesting a possible phase transition. Upon pressure release following compression to 12.5 GPa, the Raman spectra exhibit partial reversibility of the phase transition, as certain characteristic peaks return to their original positions while others retain irreversible shifts. This study establishes fundamental understanding for investigating high-pressure responses in DAI-X1 and analogous energetic materials. Full article
(This article belongs to the Special Issue Emerging Perovskite Materials and Applications)
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