Crystal Structures and Magnetic Interactions of Magnetic Materials

A special issue of Crystals (ISSN 2073-4352). This special issue belongs to the section "Inorganic Crystalline Materials".

Deadline for manuscript submissions: 15 February 2025 | Viewed by 990

Special Issue Editor


E-Mail Website
Guest Editor
National Institute for Materials Physics, 077125 Magurele, Romania
Interests: thermal analysis; material characterization; DSC TGA; X-ray diffraction; nanomaterials; XRD analysis; powder X-ray diffraction; material characteristics; TEM image analysis

Special Issue Information

Dear Colleagues,

Rare earth free permanent magnets are being actively studied for their potential as a future class of magnetic materials, capable of operating at higher temperatures and in challenging corrosion environments, such as renewable energy applications. Of these classes, novel magnets without rare earth components show promise, as they are cost-effective and have interesting magnetic properties. Sustained efforts are being made nowadays in the search for new classes of magnets, motivated by the continuous depletion of rare earth oxide resources and the need for improved magnetic parameters, especially for high-temperature applications. Indeed, rare-earth-free magnets can operate under extreme conditions such as high temperatures and corrosive media, which are the milieu of the operation of motors in wind turbines subjected to strong variations in temperature and humidity. Various possible rare-earth-free magnets have been proposed and largely investigated, using compounds derived from the binary systems FePt, MnAl, MnBi, MnGa, etc. What is common for all these different systems is the fact that they all may exhibit, under certain conditions, the formation of the tetragonal L10 phase, which has been shown to present large magnetocrystalline anisotropy and high coercivity.

The aim of this Special Issue is to investigate the crystal structures responsible for the enhanced magnetic performances of rare-earth-free magnetic materials.

This Special Issue will address all the challenges involved in developing optimized crystal structures in novel rare-earth-free nanocomposite magnets, including, but not limited to, the following topics:

  • Theory and modelling;
  • Synthesis challenges and microstructure optimization;
  • Magnetic phase coexistence and phase stability with temperature;
  • Hard–soft exchange coupling in multiphase magnetic nanocomposites;
  • Optimization of magnetic performances in rare-earth-free nanocomposite magnets;
  • Magnetic performances in extreme conditions of operation.

Dr. Alina Crisan
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Crystals is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2100 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • RE-free nanocomposite magnets
  • hard–soft exchange coupling
  • magnetic stability
  • structural phase transformation
  • L10 phase
  • ferromagnetism
  • antiferromagnetism
  • soft magnetic materials
  • hard magnets
  • magnetocaloric materials
  • functional magnetic materials
  • magnetocaloric, magnetoelastic
  • multiferroic materials

Benefits of Publishing in a Special Issue

  • Ease of navigation: Grouping papers by topic helps scholars navigate broad scope journals more efficiently.
  • Greater discoverability: Special Issues support the reach and impact of scientific research. Articles in Special Issues are more discoverable and cited more frequently.
  • Expansion of research network: Special Issues facilitate connections among authors, fostering scientific collaborations.
  • External promotion: Articles in Special Issues are often promoted through the journal's social media, increasing their visibility.
  • e-Book format: Special Issues with more than 10 articles can be published as dedicated e-books, ensuring wide and rapid dissemination.

Further information on MDPI's Special Issue polices can be found here.

Published Papers (1 paper)

Order results
Result details
Select all
Export citation of selected articles as:

Research

24 pages, 6021 KiB  
Article
Structural, Optical, Magnetic, and Dielectric Investigations of Pure and Co-Doped La0.67Sr0.33Mn1-x-yZnxCoyO3 Manganites with (0.00 < x + y < 0.20)
by Mansour Mohamed, A. Sedky, Abdullah S. Alshammari, Z. R. Khan, M. Bouzidi and Marzook S. Alshammari
Crystals 2024, 14(11), 981; https://doi.org/10.3390/cryst14110981 - 14 Nov 2024
Viewed by 668
Abstract
Here, we report the structural, optical, magnetic, and dielectric properties of La0.67Sr0.33Mn1-x-yZnxCoyO3 manganite with various x and y values (0.025 < x + y < 0.20). The pure and co-doped samples are [...] Read more.
Here, we report the structural, optical, magnetic, and dielectric properties of La0.67Sr0.33Mn1-x-yZnxCoyO3 manganite with various x and y values (0.025 < x + y < 0.20). The pure and co-doped samples are called S1, S2, S3, S4, and S5, with (x + y) = 0.00, 0.025, 0.05, 0.10, and 0.20, respectively. The XRD confirmed a monoclinic structure for all the samples, such that the unit cell volume and the size of the crystallite and grain were generally decreased by increasing the co-doping content (x + y). The opposite was true for the behaviors of the porosity, the Debye temperature, and the elastic modulus. The energy gap Eg was 3.85 eV for S1, but it decreased to 3.82, 3.75, and 3.65 eV for S2, S5, and S3. Meanwhile, it increased and went to its maximum value of 3.95 eV for S4. The values of the single and dispersion energies (Eo, Ed) were 9.55 and 41.88 eV for S1, but they were decreased by co-doping. The samples exhibited paramagnetic behaviors at 300 K, but they showed ferromagnetic behaviors at 10 K. For both temperatures, the saturated magnetizations (Ms) were increased by increasing the co-doping content and they reached their maximum values of 1.27 and 15.08 (emu/g) for S4. At 300 K, the co-doping changed the magnetic material from hard to soft, but it changed from soft to hard at 10 K. In field cooling (FC), the samples showed diamagnetic regime behavior (M < 0) below 80 K, but this behavior was completely absent for zero field cooling (ZFC). In parallel, co-doping of up to 0.10 (S4) decreased the dielectric constant, AC conductivity, and effective capacitance, whereas the electric modulus, impedance, and bulk resistance were increased. The analysis of the electric modulus showed the presence of relaxation peaks for all the samples. These outcomes show a good correlation between the different properties and indicate that co-doping of up to 0.10 of Zn and Co in place of Mn in La:113 compounds is beneficial for elastic deformation, optoelectronics, Li-batteries, and spintronic devices. Full article
(This article belongs to the Special Issue Crystal Structures and Magnetic Interactions of Magnetic Materials)
Show Figures

Figure 1

Back to TopTop