Photo/Electrocatalytic Performance of Novel Transition-Metal Oxide Based Electrocatalysts

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Electrocatalysis".

Deadline for manuscript submissions: closed (15 February 2023) | Viewed by 2227

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Chemistry Department, Science College, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia
Interests: electrocatalysis; energy; photoelectrochemistry
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Battery Research Center of Green Energy, Ming Chi University of Technology, New Taipei City 24301, Taiwan
Interests: nanocomposite materials; non-precious metal catalysts; bifunctional electrocatalysts; electrochemistry; electrochemical sensors and biosensors; electrocatalysis; energy conversion application; supercapacitor; Li-ion battery and LiO2 battery; water splitting; photocatalysis; corrosion
Special Issues, Collections and Topics in MDPI journals
PG & Research Department of Chemistry, DKM College for Women, Vellore, Tamil Nadu, India
Interests: polymers; nanotechnology; adsorption; catalysis; tissue engineering
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Special Issue Information

Dear Colleagues, 

Due to industrial growth in emerging economies, the extensive utilization of fossil fuels has been the major source of environmental pollution and the energy crisis. Thus, transforming solar energy into chemicals through photosynthesis has been considered the favorable approach to tackle the situation. Material selection for photo/electrochemical applications is critical, provided that photoelectrodes absorb incident photons and generate the charge carriers, and that they are economical for practical applications. In recent decades, transition metal oxides, especially TiO2-, WO3-, BiVO4-, and Fe2O3-based catalyst materials, have been widely studied in many research fields, such as catalysis, photocatalysis, electrocatalysis, water splitting, electrochemical CO2 conversion, etc. In recent decades, oxynitrides-based photoanodes have been demonstrated as alternatives for oxide-based electrodes to grasp visible-light photons to produce solar fuels from water at the stoichiometric ratio. These materials have usually been synthesized through simple and cost-effective methods such as hydro/solvothermal methods, co-precipitation methods, sonochemical methods, combustion methods, sol-gel methods, and solid-state methods. Due to their unique features, including physicochemical properties, stable crystal structure, high photostability, good catalytic convertor ability, and high electronic conductivity, transition metal oxides-based catalytic materials have been extensively investigated in photo/electrochemical applications.

This Special Issue aims to cover all types of transition metal oxides and oxynitrides used in photo/electrochemical applications. This includes their synthesis, characterization, property evaluation, composite material synthesis, CO2 conversion to value-added products, pharmaceutical pollutant degradation and degradation through photo/electrocatalytic oxidations and reductions, and photodegradation applications. The Issue also concerns experimental and theoretical evaluations to understand the photo/electrocatalytic reaction kinetics of potential catalysts. Original research papers, short communications, and review articles are invited for submission.

Dr. Prabhakarn Arunachalam
Dr. Chelladurai Karuppiah
Dr. P.N. Sudha
Guest Editors

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Keywords

  • oxygen evolution reactions
  • hydrogen evolution reactions
  • supercapacitors and batteries
  • photoelectrochemical CO2 conversion
  • photoelectrochemical degradation of pollutants
  • photoelectrochemical water splitting
  • bifunctional electrochemical reactions
  • electrochemical sensors
  • transition metal oxide electrocatalysts

Published Papers (1 paper)

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Research

18 pages, 5383 KiB  
Article
SrMnO3/Functionalized h-BN Composite Modified Disposable Sensor for the Voltammetric Determination of Furaltadone Antibiotic Drug
by Krishnan Venkatesh, Ramachandran Rajakumaran, Shen-Ming Chen, Periyakaruppan Karuppasamy, Artur Banach, Wedad A. Al-Onazi, Selvam Sonadevi, Nattamai Perumal Krishnan, Chun-Chen Yang, Chelladurai Karuppiah and Sayee Kannan Ramaraj
Catalysts 2022, 12(12), 1494; https://doi.org/10.3390/catal12121494 - 22 Nov 2022
Cited by 7 | Viewed by 1935
Abstract
Improper disposal of pharmaceutical drugs, including antibiotics, can affect the ecological system and generate serious health problems for living organisms. In this work, we have developed an electrochemical sensor based on a strontium manganese oxide/functionalized hexagonal boron nitride (SrMnO3/f-BN) [...] Read more.
Improper disposal of pharmaceutical drugs, including antibiotics, can affect the ecological system and generate serious health problems for living organisms. In this work, we have developed an electrochemical sensor based on a strontium manganese oxide/functionalized hexagonal boron nitride (SrMnO3/f-BN) electrocatalyst for the detection of the antibiotic drug furaltadone (FLD). Various analytical techniques were used to characterize the physicochemical properties of the as-prepared SrMnO3/f-BN composite. The as-fabricated SrMnO3/f-BN composite electrode showed excellent sensing activity towards FLD, with a wide linear range (0.01–152.11 µM) and low detection limit (2.0 nM). The sensor exhibited good selectivity towards FLD for detection in the presence of various interfering species (nitro compounds, metal ions, and biological compounds). Interestingly, real-time analysis using the proposed SrMnO3/f-BN composite was able to determine the FLD content in human urine and wastewater samples with good recovery. Hence, the as-developed SrMnO3/f-BN modified sensor could be viable in practical applications to target the antibiotic drug FLD in both human fluids and environmental samples. Full article
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