Highly Active Catalysts for Selective Hydrogenation

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Catalytic Materials".

Deadline for manuscript submissions: closed (24 December 2023) | Viewed by 1069

Special Issue Editors


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Guest Editor
Institute of Industrial Catalysis, Zhejiang University of Technology, Hangzhou 310014, China
Interests: alkyne hydrogenation; CO2 reduction; nitrogen reduction
School of Chemical Engineering, Northeast Electric Power University, Jilin 132012, China
Interests: acetylene hydrochlorination; industrial catalysis; ionic liquids
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Special Issue Information

Dear Colleagues,

Selective hydrogenation is one of the most dazzling jewels in the crown of catalytic transformations, and is among the central themes of the petrochemical, coal chemical, fine chemical, and environmental industries. It is estimated that 25% of chemical transformations include at least one hydrogenation step, and it is thus not surprising that the hydrogenation reaction is one of the most intensively investigated topics in catalysis. The key to selective hydrogenation relies on the fabrication of efficient and selective catalysts. Unfortunately, improvements in selectivity are usually at the expense of catalytic activity; therefore, it remains a challenge to achieve high chemoselectivity without compromising activity. One prerequisite to the rational design of chemoselective catalysts is the understanding of the reaction mechanism that governs chemoselectivity. So far, a consensus has been reached that selectivity, to a large degree, depends on the adsorption strength and configuration of the reactants/intermediates on the surfaces of catalysts, which in turn are determined by the electronic and geometric structures of active sites. These issues should be further presented and appraised.

This Special Issue, entitled “Highly Active Catalysts for Selective Hydrogenation”, will focus on the state of the art and outlooks of selective hydrogenation catalysis. Submissions in the form of original research articles and comprehensive reviews in the areas of designing excellent hydrogenation catalysts, developing new synthetic methods, and finding new mechanisms for selective hydrogenation catalysts are all welcomed. The scope of this Special Issue covers all applications of selective hydrogenation catalysis, including, but not limited to, alkyne hydrogenation, the hydrogenation of functionalized nitroarenes, CO2 reduction, ammonia synthesis, the hydrogenation of α,β-unsaturated aldehydes/ketones, etc.

Dr. Yuxue Yue
Dr. Bolin Wang
Guest Editors

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Keywords

  • selective hydrogenation
  • alkyne hydrogenation
  • CO2 reduction
  • N2/nitrate reduction
  • diastereo- and enantioselective hydrogenation
  • stereoselective hydrogenation
  • mild hydrogenation
  • nanostructured catalysts
  • hydrogenation of α,β-unsaturated aldehydes/ketones
  • advanced materials and characterization

Published Papers (1 paper)

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Research

7 pages, 1204 KiB  
Communication
Pd/C-Based Sensor for Gas Sensing in Transformer Oil
by Haidan Lin, Jiachang Guo, Daiyong Yang, Shouxue Li, Dan Liu, Changyan Liu, Zilong Zhang, Bolin Wang and Haifeng Zhang
Catalysts 2023, 13(7), 1113; https://doi.org/10.3390/catal13071113 - 17 Jul 2023
Cited by 1 | Viewed by 810
Abstract
The detection of dissolved gas in transformer oil is of vital importance to diagnose the early fault and monitor the security and stability of power systems. In this work, distinct Pd/C, Pd/C-R and Pd/NC were synthesized and evaluated. XRD and XPS characterizations show [...] Read more.
The detection of dissolved gas in transformer oil is of vital importance to diagnose the early fault and monitor the security and stability of power systems. In this work, distinct Pd/C, Pd/C-R and Pd/NC were synthesized and evaluated. XRD and XPS characterizations show that both Pd0 and PdII are presented over the surface of carbon host for Pd/C, while poor gas-sensitive properties were presented for Pd0 in H2-reduced Pd/C-R sample. High content of cationic PdII species are synthesized by nitrogen doping of the carbon surface for Pd/NC. The experimental results showed that the gas-sensitive performances of H2/CO/C2H2 gases is facilitated over the developed Pd/NC material. This study can provide reference for the rapid detection and fault diagnosis of faulty gases in transformers. Full article
(This article belongs to the Special Issue Highly Active Catalysts for Selective Hydrogenation)
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