Engineering of Nanostructured Catalytic Materials for Selective Hydrogenation Reactions

A special issue of Catalysts (ISSN 2073-4344). This special issue belongs to the section "Catalytic Materials".

Deadline for manuscript submissions: 31 March 2026 | Viewed by 806

Special Issue Editor


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Guest Editor
Key Laboratory of Green Chemical Process of Ministry of Education, Hubei Key Laboratory of Novel Chemical Reactor and Green Chemical Technology, School of Chemical Engineering & Pharmacy, Wuhan Institute of Technology, Wuhan 430073, China
Interests: engineering of nanostructured catalysts, selective hydrogenation; heterogeneous catalysis; reaction kinetics

Special Issue Information

Dear Colleagues,

Selective hydrogenation is a key step in many industrial fields—such as pharmaceuticals, fine chemicals, and petrochemicals—because of its ability to selectively reduce unsaturated bonds and valorize various chemicals. Consequently, the development of efficient and selective catalysts for hydrogenation reactions has long been a prominent area of research. Traditional precious metal catalysts, such as platinum and palladium, exhibit excellent catalytic activity but often face challenges including poor selectivity, catalyst deactivation, and high cost.

With advances in base metal, single-atom, and bimetallic catalytic systems, new avenues have emerged enhancing the selectivity and activity of hydrogenation reactions. These innovations enable better control over the reaction pathway, thereby improving the yield and the selectivity of the target product. Moreover, factors such as metal–support interaction, nanoparticle morphology, and reaction conditions also play a crucial role in determining catalytic performance.

This Special Issue of Catalysts will focus on the latest progress in selective hydrogenation catalysts. We invite original research articles and reviews that explore innovative catalytic materials, mechanistic insights, and practical applications. Topics of interest include, but are not limited to, the following:

  • Engineering of heterogeneous catalytic systems for selective hydrogenation reactions;
  • Advances in precious- and base-metal catalysts for selective hydrogenation;
  • Design and applications of bimetallic and trimetallic catalysts;
  • Effects of metal–support interactions, morphology, and other factors on catalytic performance;
  • Reaction mechanism and structure–activity relationship of selective hydrogenation;
  • Study on stability, recyclability, and deactivation mechanism of catalysts;
  • Applications of selective hydrogenation in the production of fine chemicals, pharmaceuticals, and fuels.

If you wish to submit a paper for publication in this Special Issue or have any questions, please contact the in-house Editor, Ms. Georgie Guan (georgie.guan@mdpi.com).

Prof. Dr. Xingmao Jiang
Guest Editor

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Keywords

  • catalyst design and engineering
  • selective hydrogenation
  • heterogeneous catalysis
  • single-atom catalysts
  • bimetallic catalysts
  • reaction mechanisms
  • kinetics
  • metal–support interactions

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Published Papers (1 paper)

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Research

18 pages, 8437 KB  
Article
Palladium as a Molecular Architect: Control of Hydrocarbon Chain Growth and Branching in Zeolite Catalysts for Fischer–Tropsch Synthesis
by Roman Yakovenko, Anastasia Chemes, Andrey Volik, Danila Ponomarev, Evgeniya Yakovenko, Alexander Astakhov, Victoria Marchenko, Andrey Nikolaev, Evgeniy Sadyrin, Roman Svetogorov and Marat Agliullin
Catalysts 2026, 16(2), 179; https://doi.org/10.3390/catal16020179 - 11 Feb 2026
Viewed by 509
Abstract
The effect of palladium addition to a hybrid Co/SiO2 + HZSM-5 + Al2O3 catalyst on the combined Fischer–Tropsch (FT) synthesis and hydrocarbon hydroconversion process was studied. Catalysts with a Pd content of 0.075–0.3 wt.% were characterized by a complex [...] Read more.
The effect of palladium addition to a hybrid Co/SiO2 + HZSM-5 + Al2O3 catalyst on the combined Fischer–Tropsch (FT) synthesis and hydrocarbon hydroconversion process was studied. Catalysts with a Pd content of 0.075–0.3 wt.% were characterized by a complex of physicochemical methods, including synchrotron radiation X-ray diffraction (SR-XRD), temperature-programmed reduction with hydrogen (H2-TPR), temperature-programmed desorption of hydrogen with oxygen titration (H2-TPD/O2 titration), IR spectroscopy of adsorbed pyridine, and STEM-EDX analysis. It was found that the addition of palladium decreases the cobalt oxide reduction temperature due to interphase hydrogen transfer. Tests in hydrocarbon synthesis at 240–250 °C, a pressure of 2 MPa, and an H2/CO ratio of 2 showed that the sample with 0.15% Pd exhibits the highest selectivity for C5+ hydrocarbons (66.8% at 240 °C) and stability for 150 h. Analysis of the synthesis products revealed a fivefold decrease in the proportion of alkenes and an increase in isoalkanes with increasing Pd concentration. This effect enables the in situ hydroprocessing of primary FT products in a single reactor. The results demonstrate that the targeted introduction of palladium into the hybrid system is an effective strategy for regulating its functionality, allowing for the one-stage production of high-quality fuels with a controlled hydrocarbon composition from syngas. Full article
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