Adhesives

Purpose: The aim of this in vitro study was to investigate the adhesive bond strength of glass fiber posts when cemented with universal resin cement in two different adhesion modes: adhesive and self-adhesive. Methods: A total of 20 extracted single-root teeth were endodontically treated, decoronated and prepared to receive glass fiber posts (GFPs) with a diameter of 1.6 mm (RelyX fiber post 3D). Specimens were randomly divided into two groups: (G1) GFPs were cemented using RelyX Universal cement in self-adhesive mode, and (G2) GFPs were cemented using Scotch Bond Universal Plus and RelyX Universal cement (adhesive mode). Afterwards, the specimens were sliced at three root levels: coronal, middle and apical. Bond strength was measured using a push-out test. Data were analyzed with a two-way analysis of variance (ANOVA) test and independent sample T-test. Results: Bond strength was significantly influenced by the adhesive strategy (p < 0.025) and the position of the root third (p < 0.007). Microscopic analysis of failure mode revealed a higher prevalence of adhesive failures (cement–dentine). Conclusions: Glass fiber posts cemented with universal resin cement applied in adhesive mode showed significantly higher push-out bond strength than when applied in self-adhesive mode. In both study groups, the apical root regions exhibited the highest retention values, followed by the middle and coronal regions. Full article

Tapes are widely utilized across various industries, offering versatile solutions for bonding, sealing, and packaging applications. Their ease of use, strength, and adaptability make them essential in manufacturing, construction, and consumer markets. However, the effectiveness of tapes depends heavily on their adhesive performance, which is influenced by factors such as the adhesive layer composition, material compatibility, environmental conditions, and contact parameters. Quantifying adhesive performance through standardized testing is critical to ensuring reliability, optimizing functionality, and meeting industry-specific requirements. Traditional methods, such as peel and shear tests, are commonly used to evaluate the adhesive and shear strength of tapes. However, these methods typically operate at macro-load scales and often use complex sample geometries and significant material quantities. Recently, precision indentation–retraction testing has emerged as a promising technique for accurately quantifying the adhesion and cohesion forces of viscoelastic fluids. This study adapts this method to evaluate and compare the adhesive strength of various commercially available adhesive tapes. The adhesion force and separation energy of five commercial tapes, namely paper masking tape, high-temperature tape, insulation tape, duct tape, box wrapping tape, and double-sided tape, were measured using a Falex Tackiness Adhesion Analyser (TAA) tester, under controlled conditions (approach speed: 0.01 mm/s, retraction speed: 0.1 mm/s, and load: 50 mN). The results indicated that the adhesion force and separation energy varied significantly among the tapes, whereas a different pattern in the indentation–retraction curves was obtained for these tapes. In addition, the significance of difference among the adhesive properties of the tapes was assessed with the use of analysis of variance (ANOVA). This innovative approach not only enhances the precision of adhesive strength measurements but also provides valuable insights into adhesive layer properties, offering a novel tool for research, development, and quality control in tape production. Full article

The classical approach for the preparation of an endodontically treated molar with a post and core involves widening the anatomically complex system of canals, which may be narrow or curved with variable angulation. The aforementioned along with the fact that restorative dentistry stands against the wastage of tooth tissue make endocrowns an appealing alternative. Bindl and Mörmann first described an all-ceramic crown anchored to the internal portion of the pulp chamber and on the cavity margins, thus obtaining macromechanical retention provided by the axial opposing pulpal walls and microretention attained with the use of adhesive cementation. The purpose of this report is to describe the protocol for the treatment plan selection, preparation, impression, and adhesive cementation of an endocrown with a follow-up of 5 years. A 56-year-old male patient presented to the Postgraduate Clinic of Prosthodontics seeking rehabilitation for tooth No. #36. A clinical examination revealed multiple immediate composite resin restorations with unacceptable morphology and adaptation to the remaining tooth as well as a lack of a contact point but, rather, a large, concave contact area facilitating food entrapment. Since the tooth was endodontically treated, the proposed treatment plan included the fabrication of an all-ceramic endocrown. The steps of preparation, attribution of the correct shape, impression, and adhesive luting under rubber dam isolation are thoroughly described. The final functional and aesthetic result, patient’s satisfaction, and the 5-year follow-up render restorations such as endocrowns, which draw their retention from adhesive luting, a viable alternative to conventional approaches. Full article

Additive manufacturing enables new design solutions across various engineering fields. This work presents a method to enhance the sustainability of adhesive joints by designing joints that can be disassembled and repaired multiple times. The approach involves the use of a Multi-Material Additive Manufacturing process to produce substrates with integrated circuits and electrical resistance, printed using a conductive filament. This resistance can be used to heat the thermoplastic adhesive layer up to 110 °C, allowing for reversibility in the assembly process and enabling joint re-use and repair without constraints on the component’s materials and thicknesses. The joints tested after successive assembly/disassembly operations reach maximum strength during the first iteration, which decreases by around 50% after five repair iterations. The focus of the work is on the feasibility of this process, but it is expected that performance can be improved after process optimization. This result could be highly valuable for enabling component in-service healing and the design for demanufacturing and remanufacturing. Full article

This study investigated the impact of natural compound enrichment, specifically quercetin and trans, trans-farnesol (tt-farnesol), on the physicochemical properties of a universal adhesive system. A preliminary DPPH assay was conducted to determine the optimal concentrations of quercetin (0.24 mg/mL) and tt-farnesol (1.43 mg/mL) based on their radical scavenging abilities. These compounds were then incorporated into the adhesive system. Specimens (n = 5; 7 mm × 1 mm) of the adhesive system, both with and without the added compounds, were prepared and tested for water sorption, solubility, Knoop hardness, and softening percentage. Water sorption and solubility were measured after immersion in deionized water for 7 days, and Knoop hardness was measured before and after immersion in 75% ethanol. Softening percentage was calculated based on changes in hardness. Data on water sorption, solubility, and percentage of softening were submitted to the Student’s t-test (α = 5%) while Knoop hardness values were submitted to the Mann–Whitney test (α = 5%). Both quercetin and tt-farnesol exhibited important antioxidant activity (85.5% and 82%, respectively). Water sorption was similar for both groups (p > 0.05) but the experimental adhesive had a significantly higher solubility, lower hardness, and higher softening. The incorporation of quercetin and tt-farnesol into a universal adhesive system detrimentally affects its essential physicochemical properties, compromising its performance. Full article

Water-based lubricants have become increasingly prevalent across various fields due to their accessibility, cooling properties, and environmentally friendly characteristics. This study investigated the non-Newtonian properties of polyoxyethylene oxide (PEO) aqueous solutions. The rheological behaviors of 1%, 2%, and 3% PEO aqueous solutions were assessed using a flat plate rheometer. Shear strain responses were comprehensively analyzed, resulting in the derivation of the corresponding power law functions. The total loads of 1%, 2%, and 3% PEO aqueous solutions can be obtained by the numerical integration of Reynolds equations. Results indicate that at high shear strain rates, load-carrying capacity increased; however, the rate of increase gradually diminished as the shear strain rate rose. In practical applications, shear stress is subject to fluctuations; negative viscosity occurs resulting in reduced hydrodynamic pressure and potential lubrication failure. Full viscosity and incremental viscosity are introduced, with the latter being identified as a crucial factor that provides a more direct characterization of the relationship between shear stress and shear strain rate. This factor significantly influences the load-bearing capacity of the lubrication film in non-Newtonian fluids. Full article

Cyanoacrylates, known for their rapid polymerization and strong bonding capabilities, are widely used in industrial and medical applications. This study investigates the impacts of different process atmospheres with varying water and oxygen contents—air, argon, and argon/silane—on the curing and adhesion mechanisms of cyanoacrylate adhesives on oxidized copper substrates. Raman spectroscopy indicated that the curing process in argon and argon/silane atmospheres was slower compared to ambient air, likely due to the reduced moisture content of the atmosphere. However, the degree of curing and the inter- and intramolecular interactions within the adhesive volume showed no significant differences across atmospheres. X-ray photoelectron spectroscopy (XPS) and infrared reflection absorption spectroscopy (IRRAS) revealed that strong ionic interactions between cyanoacrylate and the copper surface oxide were absent in the low-moisture argon atmosphere. The introduction of silane resulted in the formation of silicon oxides and other silane-derived compounds, which probably contributed to the formation of these ionic interactions, similar to those observed in air. This study highlights the critical influence of the surrounding atmosphere on the adhesive properties of cyanoacrylates, with implications for optimizing bonding processes in various environments. Full article