Documenting a Graffiti Tag by Muelle, a Pioneer of Graffiti Art in Spain
Abstract
1. Introduction
2. Materials and Methods
2.1. The Location of the Signature and the Environmental Context
2.2. The Techniques Used to Document and Characterize the Materials
- A micromorphological analysis of the polished transverse sections of the samples with an optical microscope (OM) ZEISS Axioscope 5/7KMAT (Carl Zeiss Meditec Iberia S.A.U., Madrid, Spain). The specimens were first embedded in epoxy resin (EpoThin 2 Epoxy Resin and EpoThin 2 Epoxy Hardener) and then cut and polished to a mirror shine.
- A micromorphological and chemical analysis of the polished transverse sections the of samples by scanning electron microscopy (SEM) (with a JEOL JSM 6010L, JEOL Ltd., Tokyo, Japan) with energy-dispersive X-ray spectroscopy (EDS) in both secondary (SE) and backscattered electron (BSE) detection modes. The observation conditions included a working distance of around 10 mm, an accelerating potential of 20 kV, and a specimen current of ~60 mA.
- An X-ray diffraction (XRD) analysis (with a SIEMENS D5000 Siemens S.A., Madrid, Spain). The samples were ground to less than 50 µm and analyzed by the crystalline powder method. Analyses were conducted using Cu-Kα radiation, an Ni filter, a voltage of 40 kV, and a 40 mA intensity, applying the random powder method. The exploration range was 3° to 60° 2θ and the goniometer speed was 0.01° 2θ/s. The minerals were identified with Xpert Highscore 2.0 software (Malvern Panalytical B.V.).
- Fourier transform infrared spectroscopy (FTIR) (with a Thermo Nicolet 6700 spectrometer, Thermo Fisher Scientific, Waltham, MA, USA). Spectra were recorded in the mid (400–4000 cm−1) infrared spectral region at a spectral resolution of 4 cm−1, for 32 sample scans and a 38.17 s collection time. Spectra were collected using an infrared microscope (Nicolet Continuum, Thermo Fisher Scientific, USA), first analyzing the sample surface using reflection mode and then on the bulk sample using attenuated total reflectance (ATR) mode (with the Smart Orbit Diamond II accessory).
3. Results and Discussion
3.1. Description and Attribution
3.2. Characterization and Diagnosis of the Conservation Status
- Scaling: Detachment of the pictorial layer along with the substrate material. This is the most severe type of alteration and has strongly affected the integrity of the tag, causing the loss of large portions of the paintwork (in the order of centimetres) (Figure 3b–d). Scaling has affected the underlying substrate (the white mortar and grey paint) as well as the pictorial layer of the signature. In the most severely affected areas, the granite surface of the wall is exposed.
- Peeling: Loss of the pictorial layer. The black paint layer has peeled at some points, leaving the underlying substrate exposed (Figure 3d). This type of alteration affects much smaller areas than scaling, in the order of millimetres.
- (1)
- Two samples of the wall coating (which, in turn, consist of a white layer of mortar and an overlying layer of grey paint): sample S1 is from the coating on the wall in the area with the graffiti tags (Figure 5a) and sample S2 (Figure 5b) is from the coating on another part of the wall (further along the alley, on the other side of the metal door, see Figure 3b) where there are no tags or other graffiti. These samples were examined to determine whether the signatures were painted directly on the wall, without prior preparation of the surface. Given that the samples were micro-samples, it was necessary to optimize the analytical protocol. To this end, an aliquot of each sample was first analyzed by FTIR (reflection mode), followed by XRD (random powder), and subsequently by FTIR (ATR mode). Another aliquot was studied under an OM and by SEM after being prepared as a cross-section.
- (2)
- A third sample of the coating that forms the substrate for Muelle’s tag, which is of a lighter grey colour than the rest of the wall (S3, Figure 3d and Figure 7). This sample was obtained with the aim of determining whether there was a layer of lighter grey paint under Muelle’s tag, as suggested by visual observations made in situ. The whole sample was prepared as cross-section and analyzed by an OM and SEM-EDS and the observations were compared with those of sample S1.
- (3)
- Two samples of black paint from the lines forming the signature: one in an apparently good state of conservation (PN1) and another affected by peeling (PN2); an aliquot of each sample was first analyzed by FTIR (reflection mode) and subsequently by FTIR (ATR mode). Another aliquot was studied under an OM and by SEM after being prepared as a cross-section.
- A white base layer (bl in Figure 5c) of variable thickness (90–200 µm) formed, in turn, by different sublayers (bl-1, bl-2, and bl-3). The deepest sublayer is rich in S and Ca (forming gypsum, according to the XRD analysis) and the other two layers are richer in Ca, C, and O (forming calcium carbonate, according to the XRD analysis). This deep layer may correspond to plaster made from air lime and gypsum.
- Covering the aforementioned white base layer, there is a layer of thickness 270–110 µm (cm, Figure 5c), formed by angular-shape grains of sizes between 90 and 10 µm agglomerated by a cementing matrix. SEM-EDS (Figure 5e) confirmed that the grains are calcium carbonate and that the matrix is formed by two phases: one of very fine grains rich in C, Ca, and O (forming calcium carbonate) and another formed by grains of mixed composition, formed by Si- and Ca-rich phases intermixed with Al- and Ca-rich phases; these grains correspond to the typical calcium silicates and calcium aluminate hydrated mineral phases of early Portland cement (manufactured between 1820 and 1890; [56]). The mixed composition (cemented aggregates) suggest that this layer is a mortar made from lime and Portland cement.
- This layer of mortar is covered by a thin coat (25–150 µm) of grey paint (grey paint, gp, Figure 5c,e). This grey paint is composed of a C-rich matrix (of low contrast under BSE detector, Figure 5e) that agglomerates subangular fragments of size 2–12 µm, rich in Ca, C, and O (probably calcium carbonate), S and Ca (probably gypsum), and also bright microparticles (<2 µm) rich in S and Ba (present in an atomic ratio equivalent to that of barium sulphate) (Figure 5e). Calcium carbonate, gypsum, and barite, which were detected by XDR, are typical mineral phases used as fillers in modern paints [57,58].
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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| Name | Area (%) | Classification Accuracy (%) |
|---|---|---|
| Muelle’s tag | 4.01 | 93.3 |
| Granite substrate | 53.46 | 95.4 |
| Grey paintwork underneath the tag | 33.79 | 95.17 |
| Blue tag | 1.69 | 94.07 |
| Wios’ tag | 2.32 | 92.55 |
| Unclassified | 4.73 | 100 |
| Name | Description | Location | Analyses |
|---|---|---|---|
| S1 | Wall coating | Graffiti painting area | FTIR, XRD (bulk sample) OM and SEM (cross-section) |
| S2 | Wall coating | Inaccessible area of the alley | FTIR, XRD (bulk sample) OM and SEM (cross-section) |
| S3 | Wall coating | Substrate of Muelle’s tag | OM and SEM (cross section) |
| PN1 | Black paint in good condition | Muelle’s tag | FTIR (bulk sample) OM and SEM (cross-section) |
| PN2 | Black paint affected by peeling | Muelle’s tag | FTIR (bulk sample) OM and SEM (cross-section) |
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Rivas, T.; Santos-Hermo, A.; Andrés-Herguedas, L.; Pozo-Antonio, J.S. Documenting a Graffiti Tag by Muelle, a Pioneer of Graffiti Art in Spain. Heritage 2026, 9, 23. https://doi.org/10.3390/heritage9010023
Rivas T, Santos-Hermo A, Andrés-Herguedas L, Pozo-Antonio JS. Documenting a Graffiti Tag by Muelle, a Pioneer of Graffiti Art in Spain. Heritage. 2026; 9(1):23. https://doi.org/10.3390/heritage9010023
Chicago/Turabian StyleRivas, Teresa, Alberto Santos-Hermo, Laura Andrés-Herguedas, and Jose Santiago Pozo-Antonio. 2026. "Documenting a Graffiti Tag by Muelle, a Pioneer of Graffiti Art in Spain" Heritage 9, no. 1: 23. https://doi.org/10.3390/heritage9010023
APA StyleRivas, T., Santos-Hermo, A., Andrés-Herguedas, L., & Pozo-Antonio, J. S. (2026). Documenting a Graffiti Tag by Muelle, a Pioneer of Graffiti Art in Spain. Heritage, 9(1), 23. https://doi.org/10.3390/heritage9010023

