Nanoporous Microtubes via Oxidation and Reduction of Cu–Ni Commercial Wires
Abstract
:1. Introduction
2. Materials and Methods
3. Results
3.1. Oxidation
3.2. Etching
3.3. Reduction
4. Discussion
5. Conclusions
Author Contributions
Conflicts of Interest
References
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Sample | Kp′ (g2·cm−4·s−1) | Kp′′ (g2·cm−4·s−1) |
---|---|---|
Ni | 1.62 × 10−9 | n.a. |
Cu-65Ni | 3.32 × 10−8 | 6.40 × 10−7 |
Cu-44Ni | 1.64 × 10−7 | - |
Cu-23Ni | 2.00 × 10−6 | 9.56 × 10−6 |
Cu | 2.83 × 10−6 | n.a. |
Sample | Process Step | Quantitative Phase Analysis (wt. %) | Lattice Parameters |
---|---|---|---|
Cu-65Ni | Oxidation (300 min) | CuO: 42% | a = 0.47045 nm, b = 0.34077 nm, c = 0.51340 nm, β = 99.6° |
NiO: 47% | a = 0.41923 nm | ||
f.c.c.-(Cu,Ni): 11% | a = 0.35565 nm | ||
Etching | CuO: 29% | a = 0.47043 nm, b = 0.34047 nm, c = 0.51234 nm, β = 99.6° | |
NiO: 71% | a = 0.41914 nm | ||
Reduction | f.c.c.-(Cu rich): 37% | a = 0.36108 nm | |
f.c.c.-(Ni rich): 63% | a = 0.35436 nm | ||
Cu-44Ni | Oxidation (160 min) | Cu2O: 7% | a = 0.42696 nm |
CuO: 58% | a = 0.46980 nm, b = 0.34110 nm, c = 0.51332 nm, β = 99.4° | ||
NiO: 35% | a = 0.41920 nm | ||
Etching | Cu2O: 3% | a = 0.42696 nm | |
CuO: 43% | a = 0.46884 nm, b = 0.34202 nm, c = 0.51307 nm, β = 99.4° | ||
NiO: 54% | a = 0.41913 nm | ||
Reduction | f.c.c.-(Cu rich): 52% | a = 0.36102 nm | |
f.c.c.-(Ni rich): 48% | a = 0.35538 nm | ||
Cu-23Ni | Oxidation (30 min) | Cu2O: 43% | a = 0.42722 nm |
CuO: 48% | a = 0.46824 nm, b = 0.34181 nm, c = 0.51274 nm, β = 99.4° | ||
NiO: 9% | a = 0.41841 nm | ||
Etching | CuO: 25% | a = 0.46846 nm, b = 0.34214 nm, c = 0.51289 nm, β = 99.5° | |
NiO: 75% | a = 0.41839 nm | ||
Reduction | f.c.c.-(Cu rich): 31% | a = 0.36131 nm | |
f.c.c.-(Ni rich): 69% | a = 0.35328 nm | ||
Cu | Oxidation (1440 min) | Cu2O: 8% | a = 0.42685 nm |
CuO: 92% | a = 0.46835 nm, b = 0.34235 nm, c = 0.51293 nm, β = 99.5° | ||
Etching | CuO: 100% | a = 0.46848 nm, b = 0.34390 nm, c = 0.51308 nm, β = 99.5° |
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Marano, E.F.; Castellero, A.; Baricco, M. Nanoporous Microtubes via Oxidation and Reduction of Cu–Ni Commercial Wires. Metals 2017, 7, 46. https://doi.org/10.3390/met7020046
Marano EF, Castellero A, Baricco M. Nanoporous Microtubes via Oxidation and Reduction of Cu–Ni Commercial Wires. Metals. 2017; 7(2):46. https://doi.org/10.3390/met7020046
Chicago/Turabian StyleMarano, Emanuele Francesco, Alberto Castellero, and Marcello Baricco. 2017. "Nanoporous Microtubes via Oxidation and Reduction of Cu–Ni Commercial Wires" Metals 7, no. 2: 46. https://doi.org/10.3390/met7020046