Search Results (33)

Surface optical losses represent one of the critical factors limiting the photogenerated current density and power conversion efficiency (PCE) of perovskite solar cells (PSCs). To address this issue, this paper introduces a pyramid/porous composite structure on the light-facing surface of PSCs. The pyramids and porous structures are obtained on silicon surfaces via alkaline wet etching and metal-assisted chemical etching, respectively, and then replicated onto the cell surface using nanoimprint technology. The research findings indicate that the micrometer-scale pyramids induce multiple refractions of incident light, enhancing the probability of photons entering the interior of the cell. Moreover, the nanoscale porous structures on the pyramid mitigate the refractive index difference between air and the pyramid material, thereby reducing reflection losses for single-incident light. For the optimized pyramid/porous structure, a reduction in surface reflectivity from 40.3% to 5.1% is observed on silicon. Benefiting from the suppression of surface reflection losses by the pyramid/porous structure, the response spectrum of the PSCs is significantly improved. Consequently, the photogenerated current density of the device increases from 21.62 to 23.86 mA cm⁻², with a relative enhancement in PCE by 9.5%. Full article

SiN_x:H film deposition via plasma-enhanced chemical vapor deposition has been widely used in semiconductor devices. However, the relationship between the chemical bonds and the physical and chemical properties has rarely been studied for films deposited using tools in terms of the actual volume production. In this study, we investigated the effects of the deposition conditions on the H-related chemical bonding, physical and chemical properties, yield, and quality of SiN_x:H films used as passivation layers at the 28 nm technology node. The radiofrequency (RF) power, electrode plate spacing, temperature, chamber pressure, and SiH₄:NH₃ gas flow ratio were selected as the deposition parameters. The results show a clear relationship between the H-related chemical bonds and the examined film properties. The difference in the refractive index (RI) and breakdown field (E_B) of the SiN_x:H films is mainly attributed to the change in the Si–H:N–H ratio. As the Si–H:N–H ratio increased, the RI and E_B showed linear growth and exponential downward trends, respectively. In addition, compared with the Si–H:N–H ratio, the total Si–H and N–H contents had a greater impact on the wet etching rates of the SiN_x:H films, but the stress was not entirely dependent on the total Si–H and N–H contents. Notably, excessive electrode plate spacing can lead to a significant undesired increase in the non-uniformity and surface roughness of SiN_x:H films. This study provides industry-level processing guidance for the development of advanced silicon nitride film deposition technology. Full article

Wet milling is a fractionation process widely used in the corn industry, which allows the separation of its main chemical components (starch, proteins, fiber and lipids) with high efficiency and purity compared to dry milling. The first stage of this process consists of maceration; after softening the grain, the actual milling is carried out, and the germ is separated by flotation because of its high lipid content. The chemical composition of pseudocereals is similar to that of cereals, hence their name, so they could be processed in the same way. In this way, the traditional corn wet milling process was adapted to quinoa. The objective of this work is to isolate the germ of red Bolivian Royal quinoa using wet milling, and evaluate its efficiency and physicochemical characteristics due to its large size and nutrient concentration. By cold pressing the red quinoa germ, crude oil was obtained and characterized in terms of: Acid Index, Iodine Index, Saponification Index, K Index, Refractive Index (20 °C) and fatty acid composition, determined by gas chromatography coupled to a mass detector (GC-MS). This profile was compared with the fatty acid profile of the solvent-extracted quinoa oil, and it was observed that there were no significant differences between the two oil samples. In addition, the sample obtained via cold pressing showed similar characteristics to corn oil, except for a higher Saponification Index and proportion of linolenic acid (omega-3). Full article

Sample homogeneity dictates whether analyzing a test portion of an entire sample can provide representative information about incurred mycotoxins. In this study, we evaluated particle-size-distribution-based homogeneity of laboratory mycotoxin samples using laser diffraction particle size analysis and International Organization for Standardization (ISO) Guide 35: 2017. Incurred whole corn, compound feed, peanut butter, and wheat flour (500 g each) were comminuted using wet, cryogenic, or dry milling. We used a sample dividing (riffling) device to obtain representative subsamples (25 g each) and developed a laser diffraction particle size analysis procedure by optimizing key parameters such as the refractive index, absorption, and stirring rate. The homogeneity of the particle size distribution within laboratory subsamples was characterized using the optimized laser diffraction procedure. An assessment of homogeneity was also performed for individual mycotoxins in each incurred matrix sample following the procedure described in ISO Guide 35. The concentrations of the incurred mycotoxins were determined using liquid chromatography–mass spectrometry (LC-MS). Within- and between-subsample variances of incurred aflatoxin B1 in peanut butter; deoxynivalenol in corn, compound feed, and wheat flour; and fumonisins in compound feed corroborated that when the particle size measurements were less than 850 µm, mycotoxins concentrations were consistent across independent test portions, which was confirmed using an analysis of variance (F-test). This study highlights the benefits of laser diffraction particle size analysis and suggests its use as a test procedure to evaluate homogeneity in new sample commodities. Full article

A distributed optical fiber refractive index sensor based on etched Ge-doped SMF in optical frequency domain reflection (OFDR) was proposed and demonstrated. The etched Ge-doped SMF was obtained by only using wet-etching, i.e., hydrofluoric acid solution. The distributed refractive index sensing is achieved by measuring the spectral shift of the local RBS spectra using OFDR. The sensing length of 10 cm and the spatial resolution of 5.25 mm are achieved in the experiment. The refractive index sensing range is as wide as 1.33–1.44 refractive index units (RIU), where the average sensitivity was about 757 GHz/RIU. Moreover, the maximum sensitivity of 2396.9 GHZ/RIU is obtained between 1.43 and 1.44 RIU. Full article

A series of poly(vinyl acetate-co-2-hydroxyethylmethacrylate)/acyclovir drug carrier systems (HEMAVAC) containing different acyclovir contents was prepared through bulk free radical polymerization of 2-hydroxyethyl methacrylate with vinyl acetate (VAc) in presence of acyclovir (ACVR) as the drug using a LED lamp in presence of camphorquinone as the photoinitiator. The structure of the drug carrier system was confirmed by FTIR and ¹HNMR analysis, and the uniform dispersion of the drug particles in the carrier was proved by DSC and XRD analysis. The study of the physico-chemical properties of the prepared materials, such as the transparency, swelling capacity, wettability and optical refraction, was carried out by UV–visible analysis, a swelling test and measurement of the contact angle and the refractive index, respectively. The elastic modulus and the yield strength of the wet prepared materials were examined by dynamic mechanical analysis. The cytotoxicity of the prepared materials and cell adhesion on these systems were studied by LDH assay and the MTT test, respectively. The results obtained were comparable to those of standard lenses with a transparency of 76.90–89.51%, a swelling capacity of 42.23–81.80% by weight, a wettability of 75.95–89.04°, a refractive index of 1.4301–1.4526 and a modulus of elasticity of 0.67–1.50 MPa, depending on the ACVR content. It was also shown that these materials exhibit no significant cytotoxicity; on the other hand, they show significant cell adhesion. The in vitro dynamic release of ACVR in water revealed that the HEMAVAC drug carrier can consistently deliver uniformly adequate amounts of ACVR (5.04–36 wt%) over a long period (7 days) in two steps. It was also found that the solubility of ACVR obtained from the release process was improved by 1.4 times that obtained by direct solubility of the drug in powder form at the same temperature. Full article

Constructing accurate models that provide information about water vapor content in the troposphere improves the reliability of numerical weather forecasts and the position accuracy of low-cost Global Navigation Satellite System (GNSS) receivers. However, developing models with high spatial-temporal resolution demands compact observational datasets in the regions of interest. Empirical models, such as the Global Pressure and Temperature 3 (GPT3w), have been constructed based on the monthly averaged outputs of numerical weather models. These models are based on the assimilation of existing measurements to provide estimations of atmospheric parameters. Therefore, their accuracy may be reduced over regions with a low resolution of radiosonde or continuous GNSS stations. By emerging and increasing the Low-Earth-Orbiting (LEO) satellites that measure atmospheric parameter profiles using the Radio Occultation (RO) technique, new opportunities have appeared to acquire high-resolution atmospheric observations at different altitudes. This study aims to apply these RO observations to improve the accuracy of the GPT3w model over Iran, which is sparse in terms of long-term GNSS and radiosonde measurements. The temperature, pressure, and water vapor pressure parameters from the GPT3w model have been used as the input layers of the Extremely Learning Machine (ELM) technique. The wet refractivity indices from the RO technique are considered target parameters in the output layer to train the ELM. The RO observations of 2007–2020 are applied for training, and those of 2020–2022 for evaluating the performance of the developed ELM. Our numerical results indicate that the developed ELM decreases the Root-Mean-Square Error (RMSE) values of the wet refractivity indices by about 17 percent, compared to the original GPT3w RMSE values. Additionally, the wet refractivity indices from ELM have revealed correlation coefficients of about 0.64, which is about 1.9 times those related to the original GPT3w model. The performance of ELM has also been examined by comparison with the data of six located radiosonde stations covering the year 2020. This comparison shows an improvement of about 14 percent in the average RMSE values of the estimated wet refractivity indices. Full article

Port fuel injection is an important technical route in methanol engines. To obtain a theoretical basis for injector arrangement and injection strategy development in methanol engines, an optimal experimental platform based on diffuse back-illumination and the refractive index matching method (RIM) was designed and built in this study. The experiments on the behavior of low-pressure methanol spray-wall impingement and wall film were carried out and the influence of the three boundary conditions of spray distance (D_imp), wall temperature (T_wall), and injection pressure (P_inj) were analyzed comprehensively. Results showed that with the increase of D_imp, the overall shape of spray before impinging the wall changed from conical to cylindrical. The impinging spray height H_i and impinging spray width W_i increased with the decrease of D_imp and the increase of P_inj. Adhesive fuel film mass M_f increased with the increase of D_imp due to the decrease of kinetic energy during wall impact. In addition, the increase of the wall temperature T_wall reduced M_f due to evaporation, but when T_wall reached 423 K, M_f rebounded due to the Leidenfrost effect. The results of this study are helpful to improve the accuracy of the numerical methanol engine model. Full article

Time-series interferometric synthetic aperture radar (TS-InSAR) is often affected by tropospheric artifacts caused by temporal and spatial variability in the atmospheric refractive index. Conventional temporal and spatial filtering cannot effectively distinguish topography-related stratified delays, leading to biased estimates of the deformation phases. Here, we propose a TS-InSAR atmospheric delay correction method based on ERA-5; the robustness and accuracy of ERA-5 data under the influence of different atmospheric delays were explored. Notably, (1) wet delay was the main factor affecting tropospheric delay within the interferogram; the higher spatial and temporal resolution of ERA-5 can capture the wet delay signal better than MERRA-2. (2) The proposed method can mitigate the atmospheric delay component in the interferogram; the average standard deviation (STD) reduction for the Radarsat-2 and Sentinel-1A interferograms were 19.68 and 14.75%, respectively. (3) Compared to the empirical linear model, the correlation between the stratified delays estimated by the two methods reached 0.73. We applied this method for the first time to a ground subsidence study in the Yuxi Basin and successfully detected three subsidence centers. We analyzed and discussed ground deformation causes based on rainfall and fault zones. Finally, we verified the accuracy of the proposed method by using leveling monitoring data. Full article

In the past few decades, several methods concerning optical thin films have been established to facilitate the development of integrated optics. This paper provides a brief depiction of different techniques for implementing optical waveguide thin films that involve chemical, physical, and refractive index modification methods. Recent advances in these fabrication methods are also been presented. Most of the methods developed for the realization of the thin-films are quite efficient, but they are expensive and require sophisticated equipment. The major interest of the scientists is to develop simple and cost-effective methods for mass production of optical thin films resulting in the effective commercialization of the waveguide technology. Our research group is focused on developing a silica-titania optical waveguide platform via the sol-gel dip-coating method and implementing active and passive optical elements via the wet etching method. We are also exploring the possibility of using nanoimprint lithography (NIL) for patterning these films so that the fabrication process is efficient and economical. The recent developments of this platform are discussed. We believe that silica-titania waveguide technology developed via the sol-gel dip-coating method is highly attractive and economical, such that it can be commercialized for applications such as sensing and optical interconnects. Full article

Titanium dioxide (TiO₂) is commonly used in food, cosmetic, and pharmaceutical industries as a white pigment due to its extraordinary light scattering properties and high refractive index. However, as evidenced from recent reports, there are overriding concerns about the safety of nanoparticles of TiO₂. As an alternative to TiO₂, Mg-Al layered double hydroxide (LDH) and their composite containing casein and carboxymethyl cellulose (CMC) were synthesized using wet chemistry and compared with currently used materials (food grade TiO₂ (E171), rice starch, and silicon dioxide (E551)) for its potential application as a white pigment. These particles were characterized for their size and shape (Transmission Electron Microscopy), crystallographic structure (X-Ray Diffraction), agglomeration behavior and surface charge (Dynamic Light Scattering), surface chemistry (Fourier Transform Infrared Spectroscopy), transmittance (UV–VIS spectroscopy), masking power, and cytotoxicity. Our results showed the formation of typical layered double hydroxide with flower-like morphology which was restructured into pseudo-spheres after casein intercalation. Transmittance measurement showed that LDH composites had better performance than pristine LDH, and the aqueous suspension was heat and pH resistant. While its masking power was not on a par with E171, the composite of LDH was superior to current alternatives such as rice starch and E551. Sustainability score obtained by MATLAB^® based comparison for price, safety, and performance showed that LDH composite was better than any of the compared materials, highlighting its potential as a white pigment for applications in food. Full article

Atmospheric radio refractivity has an obvious influence on the signal transmission path and communication group delay effect. The uncertainty of water vapor distribution is the main reason for the large error of tropospheric refractive index modeling. According to the distribution and characteristics of water vapor pressure, temperature, and pressure, which are the basic components of the refractive index, a method for retrieving atmospheric refractivity profile based on GNSS (Global Navigation Satellite System) and meteorological sensor measurement is introduced and investigated in this study. The variation of the correlation between zenith wet delay and water vapor pressure is investigated and analyzed in detail. The partial pressure profiles of water vapor are retrieved with relevance vector machine method based on tropospheric zenith wet delay calculated by single ground-based GPS (Global Positioning System) receiver. The atmospheric temperature and pressure is calculated with the least square method, which is used to fit the coefficients of the polynomial model based on a large number of historical meteorological radiosonde data of local stations. By combining the water vapor pressure profile retrieving from single ground-based GPS and temperature and pressure profile from reference model, the refractivity profile can be obtained, which is compared to radiosonde measurements. The comparison results show that results of the proposed method are consistent with the results of radiosonde. By using over ten years’ (through 2008 to 2017) historical radiosonde meteorological data of different months at China Big-Triangle Points, i.e., Qingdao, Sanya, Kashi, and Jiamusi radiosonde stations, tropospheric radio refractivity profiles are retrieved and modeled. The comparison results present that the accuracies of refractivity profile of the proposed method at Qingdao, Sanya, Kashi, and Jiamusi are about 5.48, 5.63, 3.58, and 3.78 N-unit, respectively, and the annual average relative RMSE of refractivity at these stations are about 1.66, 1.53, 1.49, and 1.23%, respectively. Full article

In this study, thin composite films of a sol–gel Nb₂O₅ matrix doped with coal fly ash Na-X zeolites were deposited by the spin-coating method. Fly ash of lignite coal collected from the electrostatic precipitators of one of the biggest TPPs in Bulgaria was used as a raw material for obtaining zeolites. Zeolite Na-X was synthesized by ultrasonic-assisted double stage fusion-hydrothermal alkaline conversion of coal fly ash. In order to improve the optical quality and sensing properties of the deposited thin films, synthesized zeolites were wet-milled for 60, 120, and 540 s prior to film deposition. The surface morphology of zeolite powders was studied both by scanning electron microscopy and transmission electron microscopy, while their porosity was investigated by N₂-physisorption. Refractive index, extinction coefficient, and thickness of the films were determined through fitting of their reflectance spectra. The sensing ability of thin films towards acetone vapors was tested by measuring the reflectance spectra prior to and during exposure to the analyte, and the change in the reflection coefficient ∆R of the films was calculated. The influence of milling time of zeolites on the sensing and optical properties of the films was assumed and confirmed. Full article

Black silicon (BSi) fabrication via surface texturization of Si-wafer in recent times has become an attractive concept regarding photon trapping and improved light absorption properties for photovoltaic applications. In this study, surface texturization has been conducted on mono-crystalline Si(100) wafer using a wet chemical anisotropic etching process with IPA:KOH solution to form micro-pyramidal surface structures. Moreover, the optimized properties of the fabricated BSi wafers are used for numerical simulation using PC1D software to analyze the performance of the solar cell and establish the correlation among relevant parameters. Effects such as doping concentration, texturization, passivation, and anti-reflection coating of BSi on the solar cell performance have numerically been investigated. Results show that textured surface obtained from the wet chemical anisotropic etching process has successfully reduced the reflectance of the BSi wafer and surpassed the solar cell efficiency by 2%, which is mainly attributed to the optical confinement of the textured pyramids on the surface with a height of 1–2 μm and angles of 70 degrees. Furthermore, the doping concentration of the p-type wafer and n-type emitter were optimized to be 1 × 10¹⁶ cm⁻³ and 1 × 10¹⁸ cm⁻³, respectively. In the case of device optimization, the SiO₂ passivation layer with a refractive index of 1.48 and the Si₃N₄ ARC layer with a refractive index of 2.015 has been identified as the best combination for the solar cell performance. These optimized parameters eventually result in 23.14% conversion efficiency from numerical simulation for solar cells that use black silicon wafers as fabricated in this study. Full article

We have studied the parallel and perpendicular electric field effects on the system of SiGe prolate and oblate quantum dots numerically, taking into account the wetting layer and quantum dot size effects. Using the effective-mass approximation in the two bands model, we computationally calculated the extensive variation of dipole matrix (DM) elements, bandgap and non-linear optical properties, including absorption coefficients, refractive index changes, second harmonic generation and third harmonic generation as a function of the electric field, wetting layer size and the size of the quantum dot. The redshift is observed for the non-linear optical properties with the increasing electric field and an increase in wetting layer thickness. The sensitivity to the electric field toward the shape of the quantum dot is also observed. This study is resourceful for all the researchers as it provides a pragmatic model by considering oblate and prolate shaped quantum dots by explaining the optical and electronic properties precisely, as a consequence of the confined stark shift and wetting layer. Full article