Search Results (13,680)

The cosmetic industry is growing at an impressive rate worldwide. In the cosmetic field, natural-origin ingredients represent the new frontier in this industry. Among the main components of cosmetics, lipids, emulsifiers, rheological modifiers, preservatives, colorants, and antioxidants can be found. These compounds form emulsions, which are among the main cosmetic formulations. An important aspect in this regard is the evaluation of emulsions’ stability over time and emulsions’ production methodology. In this paper, a comparison is made between two emulsion production technologies, the Standard and the “One-Pot” methods, through the characterization of the raw material ABWAX^® Revomul, a multifunctional wax for cosmetic use which consists of a low-melting structuring wax of vegetal origin (Rhus wax) and a natural emulsifier (Polyglyceril-3 Stearate). First, we evaluated the affinity between the wax raw materials and emollients of different chemical nature; then, we analyzed the impact of the production method on the emulsions to identify similarities and differences. ABWAX^® Revomul demonstrated a high level of effectiveness in regard to stabilizing water-in-oil emulsions. This study suggests that from an industrial point of view, the application of the two procedures allows products with different characteristics to be obtained, consequently allowing a specific method to be chosen to obtain the desired product. Full article

With the increasing awareness of energy consumption issues, there has been a growing emphasis on energy-saving retrofits for central air-conditioning systems that constitute a significant proportion of energy consumption in buildings. Efficient energy utilization can be achieved by optimizing the modeling of the equipment within the chiller plants of central air-conditioning systems. Traditional modeling approaches have been static and have focused on modeling within narrow time frames when a certain amount of equipment operating data has accumulated, thus prioritizing the precision of the model itself while overlooking the fact that energy-saving retrofits are a long-term process. This study proposes a modeling scheme for the equipment within chiller plants throughout the energy-saving retrofit process. Based on the differences in the amount of available operating data for the equipment and the progress of retrofit implementation, the retrofit process was divided into three stages, each employing different modeling techniques and ensuring smooth transitions between the stages. The equipment within the chiller plants is categorized into two types based on the clarity of their operating characteristics, and two modeling schemes are proposed accordingly. Based on the proposed modeling scheme, chillers and chilled-water pumps were selected to represent the two types of equipment. Real operating data from actual retrofit projects was used to model the equipment and evaluate the accuracy of the model predictions. The results indicate that the models established by the proposed modeling scheme exhibit good accuracy at each stage of the retrofit, with the coefficients of variation (CV) remaining below 6.88%. Furthermore, the prediction accuracy improved as the retrofitting process progressed. The modeling scheme performs better on equipment with simpler and clearer operating characteristics, with a CV as low as 0.67% during normal operation stages. This underscores the potential application of the proposed modeling scheme throughout the energy-saving retrofit process and provides a model foundation for the subsequent optimization of the refrigeration system. Full article

While acetic acid has proven effective as a mild acidic treatment for removing adhered mortar from recycled concrete aggregate (RCA) surfaces, its potential for dissolving damage to the surface of the original natural coarse aggregate (NCA) within the RCA and its impact on the resultant concrete properties require careful consideration. This investigation systematically evaluates the effects of varying concentrations of dilute acetic acid solutions, commonly used in RCA treatment protocols, through a multi-methodological approach that includes comprehensive physical characterization, stylus and 3D optical profilometry, scanning electron microscopy (SEM), and nanoindentation analysis. The results show that even dilute acid solutions have an upper concentration limit, as excessive acid concentration, specifically 0.4 M, induces significant textural dislocations on NCA surfaces, creating millimeter-scale erosion pits that increase aggregate water absorption by 18.5%. These morphological changes significantly impair concrete workability and reduce compressive strength performance. Furthermore, microstructural analysis reveals a 45.24% expansion in interfacial transition zone (ITZ) thickness, accompanied by notable reductions in elastic modulus and microhardness characteristics. In practical RCA treatment applications, for RCA containing limestone-based NCA, it is recommended to use acetic acid concentrations between 0.1 and 0.3 M to avoid substantial physical and microstructural degradation of aggregates and concrete. Full article

High-performance waterproof and breathable nanofiber membranes (WBNMs) are in great demand for various advanced applications. However, the fabrication of such membranes often relies on fluorinated materials or involves complex preparation processes, limiting their practical use. In this study, we present an innovative approach by utilizing silicon-containing polyurethane (SiPU) as a single-component, fluorine-free raw material to prepare high-performance WBNMs via a simple one-step electrospinning process. The electrospinning technique enables the formation of SiPU nanofibrous membranes with a small maximum pore size (d_max) and high porosity, while the intrinsic hydrophobicity of SiPU imparts excellent water-repellent characteristics to the membranes. As a result, the single-component SiPU WBNM exhibits superior waterproofness and breathability, with a hydrostatic pressure of 52 kPa and a water vapor transmission rate (WVTR) of 5798 g m⁻² d⁻¹. Moreover, the optimized SiPU-14 WBNM demonstrates outstanding mechanical properties, including a tensile strength of 6.15 MPa and an elongation at break of 98.80%. These findings indicate that the single-component SiPU-14 WBNMs not only achieve excellent waterproof and breathable performance but also possess robust mechanical strength, thereby enhancing the comfort and expanding the potential applications of protective textiles, such as outdoor apparel and car seats. Full article

The spatial variation of forest ecosystem services at regional scales remains poorly understood, and few studies have explicitly analyzed how ecosystem services are distributed across different forest management types. This study assessed the spatial overlap between forest management types and ecosystem service hotspots in the Southeastern United States (SEUS) and the Pacific Northwest (PNW) forests. We used the InVEST suite of tools and GIS to quantify carbon storage and water yield. Carbon storage was estimated, stratified by forest group and age class, and literature-based biomass pool values were applied. Average annual water yield and its temporal changes (2001–2020) were modeled using the annual water yield model, incorporating precipitation, potential evapotranspiration, vegetation type, and soil characteristics. Ecosystem service outputs were classified to identify hotspot zones (top 20%) and to evaluate the synergies and tradeoffs between these services. Hotspots were then overlaid with forest management maps to examine their distribution across management types. We found that only 2% of the SEUS and 11% of the PNW region were simultaneous hotspots for both services. In the SEUS, ecological and preservation forest management types showed higher efficiency in hotspot allocation, while in PNW, production forestry contributed relatively more to hotspot areas. These findings offer valuable insights for decision-makers and forest managers seeking to preserve the multiple benefits that forests provide at regional scales. Full article

The efficiency of electric motors is highly dependent on their operating temperature, with lower temperatures contributing to enhanced performance, reliability, and extended service life. This study presents a comprehensive review of state-of-the-art cooling technologies and evaluates their impact on the thermal behavior of a commercial motor–generator system in high-demand applications. A baseline model of a permanent magnet synchronous motor (PMSM) was developed using MotorCAD 2023^® software, which was supported by reverse engineering techniques to accurately replicate the motor’s physical and thermal characteristics. Subsequently, multiple cooling strategies were simulated under consistent operating conditions to assess their effectiveness. These strategies include conventional axial water jackets as well as advanced oil-based methods such as shaft cooling and direct oil spray to the windings. The integration of these systems in hybrid configurations was also explored to maximize thermal efficiency. Simulation results reveal that hybrid cooling significantly reduces the temperature of critical components such as stator windings and permanent magnets. This reduction in thermal stress improves current efficiency, power output, and torque capacity, enabling reliable motor operation across a broader range of speeds and under sustained high-load conditions. The findings highlight the effectiveness of hybrid cooling systems in optimizing both thermal management and operational performance of electric machines. Full article

The spatiotemporal evolution of the regional water use structure holds significant theoretical value for optimizing regional water resource allocation, adjusting industrial structures, and achieving sustainable water resource development. Shandong Province, located at the lowest reach of the Yellow River Basin in China, is a major economic, agricultural, and populous province, as well as a region with one of the most prominent water supply–demand imbalances in the country. As a result, exploring how water use patterns change over time and space in this region has become crucial. Using analytical methods like the Lorenz curve, Gini coefficient, cluster analysis, and spatial statistics, we examine shifts in Shandong’s water use structure from 2001 to 2023. We find that while agriculture remained the largest water consumer over this period, industrial, household, and ecological water use steadily increased, signaling a move toward more balanced resource distribution. Across Shandong’s 16 regions (cities), the water use patterns varied considerably, particularly in terms of agriculture, industry, and ecological needs. Among these, agricultural, industrial, and domestic water use were distributed relatively evenly, whereas ecological water use showed greater regional disparities. These results may have the potential to guide policymakers in refining water allocation strategies, improving industrial planning, and boosting the water use efficiency in Shandong and the country ore broadly. Full article

The increasing demand for sustainable practices in road construction has prompted the search for environmentally friendly and cost-effective materials. This study explores the incorporation of reclaimed asphalt pavement (RAP) and Panasqueira mine waste (greywacke aggregates) as full replacements for virgin aggregates in hot mix asphalt (HMA), aligning with the objectives of UN Sustainable Development Goal 9. Three asphalt mixtures were prepared: a reference mixture (MR) with granite aggregates, and two modified mixtures (M15 and M20) with 15% and 20% RAP, respectively. All mixtures were evaluated through Marshall stability, stiffness modulus, water sensitivity, and wheel tracking tests. The results demonstrated that mixtures containing RAP and mine waste met Portuguese specifications for surface courses. Specifically, the M20 mixture showed the highest stiffness modulus, improved moisture resistance, and the best performance against permanent deformation. These improvements are attributed to the presence of stiff aged binder in RAP and the mechanical characteristics of the greywacke aggregates. Overall, the findings confirm that the combined use of RAP and mining waste provides a technically viable and sustainable alternative for asphalt pavement construction, contributing to resource efficiency and circular economy goals. Full article

The aim of the study was to evaluate the use of sunflower and sesame oilseed press cakes, which are by-products of oil extraction, as functional ingredients in cookie production. The quality characteristics of these by-products were assessed, including water activity, pH, total phenolic content, and antioxidant activity, and HPLC analysis of the phenolic compounds was performed. Subsequently, cookies were prepared by replacing wheat flour with 30% or 50% press cake. The addition of sunflower press cake significantly increased the total phenolic content (up to 8.6 mg GAE/g dm) and antioxidant activity (up to 75.9%) in the cookies, whereas adding sesame press cake showed a less pronounced effect, reaching 0.91 g GAE/g dm and 8.9% for total phenolic content and antioxidant activity, respectively. HPLC analysis indicated that chlorogenic acid and its derivatives dominated in sunflower-enriched cookies, while sesame samples contained lignans such as sesamol and sesamin. Our study shows that 50% substitution improves the health-promoting properties of cookies and does not differ significantly from the 30% level in consumer sensory evaluations. These findings support the use of sunflower and sesame press cakes as valuable ingredients in food applications. This represents an important step toward developing healthier and more nutritious food products while supporting the principles of the circular economy through the upcycling of valuable raw materials. Full article

Phosphogypsum, a byproduct of orthophosphoric acid production, is one of the large-tonnage wastes. Since phosphogypsum mainly consists of CaSO₄ 2H₂O, it can be considered as an alternative gypsum-bearing raw material in the production of gypsum binders. However, its features, such as particle morphology and the presence of impurities, can negatively affect the characteristics of phosphogypsum-based binders. Identification of these factors will allow us to develop methods for their minimization and increasing the efficiency of phosphogypsum use from the required source as a raw material for the production of phosphogypsum-based binders. In this regard, the manuscript contains a comprehensive and comparative analysis of phosphogypsum and natural gypsum, which makes it possible to establish their differences in chemical composition and structural and morphological features, which subsequently affect the properties of the phosphogypsum-based binder. It has been established that the key factor negatively affecting the strength of phosphogypsum-based paste (2.58 MPa) is its high water demand (0.89), which is due to the high values of the specific surface area of the particles and the presence of a large number of conglomerates with significant porosity in phosphogypsum. It has been suggested that preliminary grinding of phosphogypsum can help reduce the amount of water required to obtain fresh phosphogypsum-based paste with a standard consistency and improve its physical and mechanical properties. Full article

To study the generation and dissipation process of agglomerate fog in mountainous expressways and deeply understand the hazard mechanisms of agglomerate fog sections in mountainous expressways, based on the analysis of the geographical location characteristics of mountainous expressways and the spatial and temporal distribution characteristics of agglomerate fog, the airspace constitutive model of agglomerate fog in mountainous expressways was constructed based on Newton constitutive theory. Firstly, the properties of the Newtonian fluid and cluster fog were compared and analyzed, and the influence mechanism of environmental factors such as the altitude difference, topography, water system, valley effect, and vegetation on the generation and dissipation of agglomerate fog in mountainous expressways was analyzed. Based on Newton’s constitutive theory, the constitutive model of temperature, humidity, wind speed, and agglomerate fog points in the foggy airspace of the mountainous expressway was established. Then, the time and spatial distribution of fog in Chongqing and Guizhou from 2021 to 2023 were analyzed. Finally, the model was verified by using the meteorological data and fog warning data of Liupanshui City, Guizhou Province in 2023. The results show that the foggy airspace of mountainous expressways can be defined as “the space occupied by the agglomerate fog that occurs above the mountain expressway”; The temporal and spatial distribution of foggy airspace on expressways in mountainous areas is closely related to the topography, water system, vegetation distribution, and local microclimate formed by thermal radiation. The horizontal and vertical movements of the atmosphere have little influence on the foggy airspace on expressways in mountainous areas. The specific manifestation of time distribution is that the occurrence of agglomerate fog is concentrated from November to April of the following year, and the daily occurrence time is mainly concentrated between 4:00–8:00 and 18:00–22:00. The calculation results of the foggy airspace constitutive model of the expressway in the mountainous area show that when there is low surface radiation or no surface radiation, the fogging value range is [90, 100], and the fogging value range is [50, 70] when there is high surface radiation (>200), and there is generally no fog in other intervals. The research results can provide a theoretical basis for traffic safety management and control of mountainous expressway fog sections. Full article

This study investigates the thermal dynamics and material behavior involved in the baking process for Lebanese flatbread, focusing on the heat transfer mechanisms, water loss, and dough expansion under high-temperature conditions. Despite previous studies on flatbread baking using impingement or conventional ovens, this work presents the first experimental investigation of the traditional Lebanese flatbread baking process under realistic industrial conditions, specifically using a high-temperature tunnel oven with direct flame heating, extremely short baking times (~10–12 s), and peak temperatures reaching ~650 °C, which are essential to achieving the characteristic pocket formation and texture of Lebanese bread. This experimental study characterizes the baking kinetics of traditional Lebanese flatbread, recording mass loss pre- and post-baking, thermal profiles, and dough expansion through real-time temperature measurements and video recordings, providing insights into the dough’s thermal response and expansion behavior under high-temperature conditions. A custom-designed instrumented oven with a steel conveyor and a direct flame burner was employed. The dough, prepared following a traditional recipe, was analyzed during the baking process using K-type thermocouples and visual monitoring. Results revealed that Lebanese bread undergoes significant water loss due to high baking temperatures (~650 °C), leading to rapid crust formation and pocket development. Empirical equations modeling the relationship between baking time, temperature, and expansion were developed with high predictive accuracy. Additionally, an energy analysis revealed that the total energy required to bake Lebanese bread is approximately 667 kJ/kg, with an overall thermal efficiency of only 21%, dropping to 16% when preheating is included. According to previous CFD (Computational Fluid Dynamics) simulations, most heat loss in similar tunnel ovens occurs via the chimney (50%) and oven walls (29%). These findings contribute to understanding the broader thermophysical principles that can be applied to the development of more efficient baking processes for various types of bread. The empirical models developed in this study can be applied to automating and refining the industrial production of Lebanese flatbread, ensuring consistent product quality across different baking environments. Future studies will extend this work to alternative oven designs and dough formulations. Full article

Prolonged drought and soil degradation severely affect soil fertility and limit crop productivity. Superabsorbent hydrogels offer an effective solution for improving water retention in soil and supporting plant growth. In this work, we examined the performance of superabsorbent hydrogels based on sodium alginate, acrylic acid (AA), and poly (ethylene oxide) (PEO) cross-linked with 12.5 kGy using e-beam irradiation. The hydrogels were assessed in various aqueous environments by examining network characteristics, swelling capacity, and swelling kinetics to evaluate the impact of water’s electrical conductivity (which ranges from 0.05 to 321 μS/cm). Morphological and chemical structure changes were evaluated using SEM and FTIR techniques. The results demonstrated that water conductivity significantly affected the physicochemical properties of the hydrogels. Swelling behavior showed notable sensitivity to electrical conductivity variations, with swelling degrees reaching 28,400% at 5 μS/cm and 14,000% at 321 μS/cm, following first-order and second-order kinetics. FTIR analysis confirmed that structural modifications correlated with water conductivity, particularly affecting the O–H, C–H, and COOH groups sensitive to the ionic environment. SEM characterization revealed a porous morphology with an interconnected microporous network that facilitates efficient water diffusion. These hydrogels show exceptional swelling capacity and are promising candidates for sustainable agriculture applications. Full article

This article presents a spatial analysis of projects selected by city residents and implemented in five successive editions (2015–2019) of the participatory budgeting in Częstochowa, Poland. The study examines the relationship between the type of hard projects (small investments in public infrastructure and landscaping) and the pre-existing characteristics of the land use of each district. Kernel density estimation and Spearman correlation analysis were used. The highest spatial density occurred in projects related to the modernization of roads and sidewalks, recreation, and greenery, indicating a relatively high number of proposals within or near residential areas. Key correlations included the following: (1) greenery projects were more common in districts lacking green areas; (2) recreational infrastructure was more frequently chosen in areas with significant water features; (3) street furniture projects were mostly selected in districts with sparse development, scattered buildings, and postindustrial sites; (4) educational infrastructure was often chosen in low-density, but developing districts. The selected projects often reflect local deficits in specific land use or public infrastructure, but also stress the predestination of the recreational use of waterside areas. Full article

To ensure water source security and sustainability of the national major strategic project “South-to-North Water Diversion”, this study aims to evaluate the spatio-temporal evolution characteristics of the ecosystem service value (ESV) in its water source area from 2002 to 2022. This study reveals its changing trends and main influencing factors, and thereby provides scientific support for the ecological protection and management of the water source area. Quantitative assessment of the ESV of the region was carried out using the Equivalence Factor Method (EFM), aiming to provide scientific support for ecological protection and resource management decision-making. In the past 20 years, the ESV has shown an upward trend year by year, increasing by 96%. The regions with the highest ESV were Garzê Prefecture and Aba Prefecture, which increased by 130.3% and 60.6%, respectively. The ESV of Xinlong county, Danba county, Rangtang county, and Daofu county increased 4.8 times, 1.5 times, 12.5 times, and 8.9 times, respectively. In the last two decades, arable land has decreased by 91%, while the proportions of bare land and water have decreased by 84% and 91%, respectively. Grassland had the largest proportion. Forests and grasslands, vital for climate regulation, water cycle management, and biodiversity conservation, have expanded by 74% and 43%, respectively. It can be seen from Moran’s I index values that the dataset as a whole showed a slight positive spatial autocorrelation, which increased from −0.041396 to 0.046377. This study reveals the changing trends in ESV and the main influencing factors, and thereby provides scientific support for the ecological protection and management of the water source area. Full article