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Keywords = water transport

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26 pages, 16359 KiB  
Article
CFD Design Performance Analysis for a High-Speed Propeller
by Marian Ristea, Adrian Popa and Octavian-Narcis Volintiru
Appl. Sci. 2025, 15(15), 8754; https://doi.org/10.3390/app15158754 (registering DOI) - 7 Aug 2025
Abstract
It is recognized that boats which intervene in dangerous situations are characterized by high maneuverability, have good governance properties, and must be equipped with high-speed propellers. This paper proposes a computerized analysis, using Computational Fluid Dynamics modeling, of a high-speed propeller, in open [...] Read more.
It is recognized that boats which intervene in dangerous situations are characterized by high maneuverability, have good governance properties, and must be equipped with high-speed propellers. This paper proposes a computerized analysis, using Computational Fluid Dynamics modeling, of a high-speed propeller, in open water, from the perspective of velocity and pressure manifested on the propeller blades. The use of numerical methods allows to determine the thrust forces on the propellers, to highlight the areas in the propeller blade where the maximum and minimum pressures occur, to identify the cavitation zone and to visualize the degree of turbulence of the fluid flow on the propeller blades in rotational motion. The analysis proves to be an efficient procedure in determining the characteristics of a high-speed propeller before deciding its production/manufacture. The Shear Stress Transport method was used for fluid turbulence analysis and the “Thrust–Propeller RPM” diagram and “Torque–propeller RPM” diagram finalized this study, the mentioned diagrams being the most important in choosing an efficient propeller for a given boat. Full article
(This article belongs to the Special Issue Recent Advances and Emerging Trends in Computational Fluid Dynamics)
15 pages, 6405 KiB  
Article
Rainy Season Onset in Northeast China: Characteristic Changes and Physical Mechanisms Before and After the 2000 Climate Regime Shift
by Hanchen Zhang, Weifang Wang, Shuwen Li, Qing Cao, Quanxi Shao, Jinxia Yu, Tao Zheng and Shuci Liu
Water 2025, 17(15), 2347; https://doi.org/10.3390/w17152347 - 7 Aug 2025
Abstract
The rainy season characteristics are directly modulated by atmospheric circulation and moisture transport dynamics. Focusing on the characteristics of the rainy season onset date (RSOD), this study aims to advance the understanding and prediction of climate change impacts on agricultural production and disaster [...] Read more.
The rainy season characteristics are directly modulated by atmospheric circulation and moisture transport dynamics. Focusing on the characteristics of the rainy season onset date (RSOD), this study aims to advance the understanding and prediction of climate change impacts on agricultural production and disaster mitigation strategies. Based on rainfall data from 66 meteorological stations in northeast China (NEC) from 1961 to 2020, this study determined the patterns of the RSOD in the region and established its mechanistic linkages with atmospheric circulation and water vapor transport mechanisms. This study identifies a climatic regime shift around 2000, with the RSOD transitioning from low to high interannual variability in NEC. Further analysis reveals a strong correlation between the RSOD and atmospheric circulation characteristics: cyclonic vorticity amplifies before the RSOD and dissipates afterward. Innovatively, this study reveals a significant transition in the water vapor transport paths during the early rainy season in NEC around 2000, shifting from eastern Mongolia–Sea of Japan to the northwestern Pacific region. Moreover, the advance or delay of the RSOD directly influences the water vapor transport intensity—an early (delayed) RSOD is associated with enhanced (weakened) water vapor transport. These findings provide a new perspective for predicting the RSOD in the context of climate change while providing critical theoretical underpinnings for optimizing agricultural strategies and enhancing disaster prevention protocols. Full article
(This article belongs to the Section Water and Climate Change)
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21 pages, 2803 KiB  
Article
A New Concrete Freeze–Thaw Damage Model Based on Hydraulic Pressure Mechanism and Its Application
by Lantian Xu, Yuchi Wang, Yuanzhan Wang and Tianqi Cheng
Materials 2025, 18(15), 3708; https://doi.org/10.3390/ma18153708 - 7 Aug 2025
Abstract
Freeze–thaw damage is one of the most important factors affecting the durability of concrete in cold regions, and how to quantitatively characterize the effect of freeze–thaw cycles on the degree of damage of concrete is a widely concerning issue among researchers. Based on [...] Read more.
Freeze–thaw damage is one of the most important factors affecting the durability of concrete in cold regions, and how to quantitatively characterize the effect of freeze–thaw cycles on the degree of damage of concrete is a widely concerning issue among researchers. Based on the hydraulic pressure theory, a new concrete freeze–thaw damage model was proposed by assuming the defect development mode of concrete during freeze–thaw cycles. The model shows that the total amount of defects due to freeze–thaw damage is related to the initial defects and the defect development capacity within the concrete. Based on the new freeze–thaw damage model, an equation for the loss of relative dynamic elastic modulus of concrete during freeze–thaw cycles was established using the relative dynamic elastic modulus of concrete as the defect indicator. In order to validate the damage model using relative dynamic elastic modulus as the defect index, freeze–thaw cycle tests of four kinds of concrete with different air content were carried out, and the rationality of the model was verified by the relative dynamic elastic modulus of concrete measured under different freeze–thaw cycling periods. On this basis, a freeze–thaw damage model of concrete was established considering the effect of air content in concrete. In addition, the model proposed in this paper was supplemented and validated by experimental data from other researchers. The results show that the prediction model proposed in this study is not only easy to apply and has clear physical meaning but also has high accuracy and general applicability, which provides support for predicting the degree of freeze–thaw damage of concrete structures in cold regions. Full article
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18 pages, 7479 KiB  
Article
Development and Validation of a Custom-Built System for Real-Time Monitoring of In Vitro Rumen Gas Fermentation
by Zhen-Shu Liu, Bo-Yuan Chen, Jacky Peng-Wen Chan and Po-Wen Chen
Animals 2025, 15(15), 2308; https://doi.org/10.3390/ani15152308 - 6 Aug 2025
Abstract
While the Ankom RF system facilitates efficient high-throughput in vitro fermentation studies, its high cost and limited flexibility constrain its broader applicability. To address these limitations, we developed and validated a low-cost, modular gas monitoring system (FerME), assembled from commercially available components. To [...] Read more.
While the Ankom RF system facilitates efficient high-throughput in vitro fermentation studies, its high cost and limited flexibility constrain its broader applicability. To address these limitations, we developed and validated a low-cost, modular gas monitoring system (FerME), assembled from commercially available components. To evaluate its performance and reproducibility relative to the Ankom RF system (Ankom Technology, Macedon, NY, USA), in vitro rumen fermentation experiments were conducted under strictly controlled and identical conditions. Whole rumen contents were collected approximately 2 h post-feeding from individual mid- or late-lactation dairy cows and immediately transported to the laboratory. Each fermenter received 50 mL of processed rumen fluid, 100 mL of anaerobically prepared artificial saliva buffer, and 1.2 g of the donor cow’s diet. Bottles were sealed with the respective system’s pressure sensors, flushed with CO2, and incubated in a 50 L water bath maintained at 39 °C. FerME (New Taipei City, Taiwan) and Ankom RF fermenters were placed side-by-side to ensure uniform thermal conditions. To assess the effect of filter bag use, an additional trial employed Ankom F57 filter bags (Ankom Technology, Macedon, NY, USA; 25 μm pore size). Trial 1 revealed no significant differences in cumulative gas production, volatile fatty acids (VFAs), NH3-N, or pH between systems (p > 0.05). However, the use of filter bags reduced gas output and increased propionate concentrations (p < 0.05). Trial 2, which employed filter bags in both systems, confirmed comparable results, with the FerME system demonstrating improved precision (CV: 4.8% vs. 13.2%). Gas composition (CH4 + CO2: 76–82%) and fermentation parameters remained consistent across systems (p > 0.05). Importantly, with 12 pressure sensors, the total cost of FerME was about half that of the Ankom RF system. Collectively, these findings demonstrate that FerME is a reliable, low-cost alternative for real-time rumen fermentation monitoring and could be suitable for studies in animal nutrition, methane mitigation, and related applications. Full article
(This article belongs to the Section Animal System and Management)
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19 pages, 14381 KiB  
Article
Temperature and Humidity Anomalies During the Summer Drought of 2022 over the Yangtze River Basin
by Dengao Li, Er Lu, Dian Yuan and Ruisi Liu
Atmosphere 2025, 16(8), 942; https://doi.org/10.3390/atmos16080942 - 6 Aug 2025
Abstract
In the summer of 2022, central and eastern China experienced prolonged extreme high temperatures and severe drought, leading to significant economic losses. To gain a more profound understanding of this drought event and furnish a reference for forecasting similar events in the future, [...] Read more.
In the summer of 2022, central and eastern China experienced prolonged extreme high temperatures and severe drought, leading to significant economic losses. To gain a more profound understanding of this drought event and furnish a reference for forecasting similar events in the future, this study examines the circulation anomalies associated with the drought. Employing a diagnostic method focused on temperature and moisture anomalies, this study introduces a novel approach to quantify and compare the relative significance of moisture transport and warm air dynamics in contributing to the drought. This study examines the atmospheric circulation anomalies linked to the drought event and compares the relative contributions of water vapor transport and warm air activity in causing the drought, using two parameters defined in the paper. The results show the following: (1) The West Pacific Subtropical High (WPSH) was more intense than usual and extended westward, consistently controlling the Yangtze River Basin. Simultaneously, the polar vortex area was smaller and weaker, the South Asian High area was larger and stronger, and it shifted eastward. These factors collectively led to weakened water vapor transport conditions and prevailing subsiding air motions in the Yangtze River Basin, causing frequent high temperatures. (2) By defining Iq and It to represent the contributions of moisture and temperature to precipitation, we found that the drought event in the Yangtze River Basin was driven by both reduced moisture supplies in the lower troposphere and higher-than-normal temperatures, with temperature playing a dominant role. Full article
(This article belongs to the Section Meteorology)
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13 pages, 1165 KiB  
Article
Simulation of the Adsorption Bed Process of Activated Carbon with Zinc Chloride from Spent Coffee Grounds for the Removal of Parabens in Treatment Plants
by Wagner Vedovatti Martins, Adriele Rodrigues Dos Santos, Gideã Taques Tractz, Lucas Bonfim-Rocha, Ana Paula Peron and Osvaldo Valarini Junior
Processes 2025, 13(8), 2481; https://doi.org/10.3390/pr13082481 - 6 Aug 2025
Abstract
Parabens—specifically methylparaben (MeP), ethylparaben (EtP), propylparaben (PrP), and butylparaben (BuP)—are widely used substances in everyday life, particularly as preservatives in pharmaceutical and food products. However, these compounds are not effectively removed by conventional water and wastewater treatment processes, potentially causing disruptions to human [...] Read more.
Parabens—specifically methylparaben (MeP), ethylparaben (EtP), propylparaben (PrP), and butylparaben (BuP)—are widely used substances in everyday life, particularly as preservatives in pharmaceutical and food products. However, these compounds are not effectively removed by conventional water and wastewater treatment processes, potentially causing disruptions to human homeostasis and the endocrine system. This study conducted a transport and dimensional analysis through simulation of the adsorption process for these parabens, using zinc chloride-activated carbon derived from spent coffee grounds (ACZnCl2) as the adsorbent, implemented via Aspen Properties® and Aspen Adsorption®. Simulations were performed for two inlet concentrations (50 mg/L and 100 mg/L) and two adsorption column heights (3 m and 4 m), considering a volumetric flow rate representative of a medium-sized city with approximately 100,000 inhabitants. The results showed that both density and surface tension of the parabens varied linearly with increasing temperature, and viscosity exhibited a marked reduction above 30 °C. Among the tested conditions, the configuration with 50 mg∙L−1 inlet concentration and a 4 m column height demonstrated the highest adsorption capacity and better performance under adsorption–desorption equilibrium. These findings indicate that the implementation of adsorption beds on an industrial scale in water and wastewater treatment systems is both environmentally and socially viable. Full article
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15 pages, 3048 KiB  
Article
Hydrogen-Rich Water Attenuates Diarrhea in Weaned Piglets via Oxidative Stress Alleviation
by Pengfei Zhang, Jingyu Yang, Zhuoda Lu, Qianxi Liang, Xing Yang, Junchao Wang, Jinbiao Guo and Yunxiang Zhao
Biology 2025, 14(8), 997; https://doi.org/10.3390/biology14080997 - 5 Aug 2025
Viewed by 25
Abstract
Early weaning of piglets elicits weaning stress, which in turn induces oxidative stress and consequently impairs growth and development. Hydrogen-rich water (HRW), characterized by selective antioxidant properties, mitigates oxidative stress damage and serves as an ideal intervention. This study aimed to evaluate the [...] Read more.
Early weaning of piglets elicits weaning stress, which in turn induces oxidative stress and consequently impairs growth and development. Hydrogen-rich water (HRW), characterized by selective antioxidant properties, mitigates oxidative stress damage and serves as an ideal intervention. This study aimed to evaluate the effects of HRW on weaned piglets, specifically investigating its impact on growth performance, diarrhea incidence, antioxidant function, intestinal morphology, gut microbiota, and hepatic metabolites. The results demonstrate that HRW significantly increased the average daily feed intake and significantly reduced the diarrhea rate in weaned piglets. Analysis of serum oxidative stress indicators revealed that HRW significantly elevated the activities of total antioxidant capacity and total superoxide dismutase while significantly decreasing malondialdehyde concentration. Assessment of intestinal morphology showed that HRW significantly increased the villus height to crypt depth ratio in the duodenum, jejunum, and ileum. Microbial analysis indicated that HRW significantly increased the abundance of Prevotella in the colon. Furthermore, HRW increased the abundance of beneficial bacteria, such as Akkermansia, in the jejunum and cecum, while concurrently reducing the abundance of harmful bacteria like Escherichia. Hepatic metabolite profiling revealed that HRW significantly altered the metabolite composition in the liver of weaned piglets. Differentially abundant metabolites were enriched in oxidative stress-related KEGG pathways, including ABC transporters; pyruvate metabolism; autophagy; FoxO signaling pathway; glutathione metabolism; ferroptosis; and AMPK signaling pathways. In conclusion, HRW alleviates diarrhea and promotes growth in weaned piglets by enhancing antioxidant capacity. These findings provide a scientific foundation for the application of HRW in swine production and serve as a reference for further exploration into the mechanisms underlying HRW’s effects on animal health and productivity. Full article
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13 pages, 2022 KiB  
Article
A Practical Method for Ecological Flow Calculation to Support Integrated Ecological Functions of the Lower Yellow River, China
by Xinyuan Chen, Lixin Zhang and Lei Tang
Water 2025, 17(15), 2326; https://doi.org/10.3390/w17152326 - 5 Aug 2025
Viewed by 27
Abstract
The lower Yellow River is characterized by low water discharge and a high sediment load, resulting in a fragile aquatic ecosystem. It is important to develop a reasonable method of ecological flow calculation that can be applied to the water-scarce rivers like the [...] Read more.
The lower Yellow River is characterized by low water discharge and a high sediment load, resulting in a fragile aquatic ecosystem. It is important to develop a reasonable method of ecological flow calculation that can be applied to the water-scarce rivers like the Yellow River. In this paper, we selected the Huayuankou hydrological station in the lower Yellow River as our study site and assessed the ecological flow using several methodologies including the monthly frequency calculation method, the sediment transportation method, the habitat simulation method, and the improved annual distribution method. Based on the seasonal applicability of the four methods across months of the year, we established an ecological flow calculation method that considers the integrated ecological functions of the lower Yellow River. In this method, ecological flow in the lower Yellow River during the dry season (November to March) can be determined by using the improved annual distribution method, ecological flow in the fish spawning period (April to June) can be calculated using the habitat simulation method, and the ecological flow during the flood season (July to October) can be calculated using the sediment transportation method. The optimal ecological flow regime for the Huayuankou section was determined using the established method. The ecological flow regimes derived in our study ranged from 310 m3/s to 1532 m3/s. However, we also observed that the ecological flow has a relatively low assurance rate during the flood season in the lower Yellow River, with the assurance rate not exceeding 63%. This highlights the fact that more attention should be given in reservoir regulations to facilitating sediment transport downstream. Full article
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19 pages, 6218 KiB  
Article
Quantitative Relationship Between Electrical Resistivity and Water Content in Unsaturated Loess: Theoretical Model and ERT Imaging Verification
by Hu Zeng, Qianli Zhang, Cui Du, Jie Liu and Yilin Li
Geosciences 2025, 15(8), 302; https://doi.org/10.3390/geosciences15080302 - 5 Aug 2025
Viewed by 23
Abstract
As a typical porous medium, unsaturated loess demonstrates critical hydro-mechanical coupling properties that fundamentally influence geohazard mitigation, groundwater resource evaluation, and foundation stability in geotechnical engineering. This investigation develops a novel theoretical framework to overcome the limitations of existing models in converting electrical [...] Read more.
As a typical porous medium, unsaturated loess demonstrates critical hydro-mechanical coupling properties that fundamentally influence geohazard mitigation, groundwater resource evaluation, and foundation stability in geotechnical engineering. This investigation develops a novel theoretical framework to overcome the limitations of existing models in converting electrical resistivity tomography (ERT) profiles into water content distributions for unsaturated loess through quantitative inversion modeling. Systematic laboratory investigations on remolded loess specimens with controlled density and water content conditions revealed distinct resistivity–water interaction mechanisms. A characteristic two-stage decay pattern was identified: resistivity exhibited an exponential decrease from 420 Ω·m (water saturation (Sw = 10%)) to 90 Ω·m (Sw = 40%), followed by asymptotic stabilization at Sw ≥ 40%. The derived quantitative correlation provides a robust mathematical basis for water content profile inversion. Field validation through integrated ERT and borehole data demonstrated exceptional predictive accuracy in shallow strata (<20 m depth), achieving mean absolute errors of <5%. However, inversion reliability decreased with depth (>20 m), primarily attributed to density-dependent charge transport mechanisms. This underscores the necessity of incorporating coupled thermo-hydro-mechanical processes for deep-layer characterization. This study provides a robust framework for engineering applications of ERT in loess terrains, offering significant advancements in geotechnical monitoring and geohazard prevention. Full article
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18 pages, 2365 KiB  
Article
Integrated Environmental–Economic Assessment of CO2 Storage in Chinese Saline Formations
by Wentao Zhao, Zhe Jiang, Tieya Jing, Jian Zhang, Zhan Yang, Xiang Li, Juan Zhou, Jingchao Zhao and Shuhui Zhang
Water 2025, 17(15), 2320; https://doi.org/10.3390/w17152320 - 4 Aug 2025
Viewed by 208
Abstract
This study develops an integrated environmental–economic assessment framework to evaluate the life cycle environmental impacts and economic costs of CO2 geological storage and produced water treatment in saline formations in China. Using a case study of a saline aquifer carbon storage project [...] Read more.
This study develops an integrated environmental–economic assessment framework to evaluate the life cycle environmental impacts and economic costs of CO2 geological storage and produced water treatment in saline formations in China. Using a case study of a saline aquifer carbon storage project in the Ordos Basin, eight full-chain carbon capture, utilization, and storage (CCUS) scenarios were analyzed. The results indicate that environmental and cost performance are primarily influenced by technology choices across carbon capture, transport, and storage stages. The scenario employing potassium carbonate-based capture, pipeline transport, and brine reinjection after a reverse osmosis treatment (S5) achieved the most balanced outcome. Breakeven analyses under three carbon price projection models revealed that carbon price trajectories critically affect project viability, with a steadily rising carbon price enabling earlier profitability. By decoupling CCUS from power systems and focusing on unit CO2 removal, this study provides a transparent and transferable framework to support cross-sectoral deployment. The findings offer valuable insights for policymakers aiming to design effective CCUS support mechanisms under future carbon neutrality targets. Full article
(This article belongs to the Special Issue Mine Water Treatment, Utilization and Storage Technology)
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16 pages, 12003 KiB  
Article
Corrosion Mechanism of Austenitic Stainless Steel in Simulated Small Modular Reactor Primary Water Chemistry
by Iva Betova, Martin Bojinov and Vasil Karastoyanov
Metals 2025, 15(8), 875; https://doi.org/10.3390/met15080875 - 4 Aug 2025
Viewed by 78
Abstract
In the present paper, impedance spectroscopy was employed to study the corrosion and anodic oxidation of stainless steel (AISI 316L at 280 °C/9 MPa) in contact with the boron-free primary coolant of a small modular reactor at two levels of KOH concentration. Analysis [...] Read more.
In the present paper, impedance spectroscopy was employed to study the corrosion and anodic oxidation of stainless steel (AISI 316L at 280 °C/9 MPa) in contact with the boron-free primary coolant of a small modular reactor at two levels of KOH concentration. Analysis of impedance spectra with a distribution of relaxation times revealed contributions from the oxide layer and its interface with the coolant. Glow-Discharge Optical Emission Spectroscopy (GDOES) was used to estimate the thickness and elemental composition of the formed oxides. A quantitative interpretation of the impedance data using the Mixed-Conduction Model allowed us to estimate the kinetic and transport parameters of oxide growth and dissolution, as well as iron dissolution through oxide. The film thicknesses following exposure agreed with ex-situ analyses. The obtained corrosion and release rates were used for comparison with laboratory and industrial data in nominal pressurized water reactor primary coolants. Full article
(This article belongs to the Special Issue Advances in Corrosion and Failure Analysis of Metallic Materials)
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14 pages, 2310 KiB  
Article
A High-Fidelity Model of the Peach Bottom 2 Turbine-Trip Benchmark Using VERA
by Nicholas Herring, Robert Salko and Mehdi Asgari
J. Nucl. Eng. 2025, 6(3), 28; https://doi.org/10.3390/jne6030028 - 4 Aug 2025
Viewed by 139
Abstract
This work presents a high-fidelity simulation of the Peach Bottom turbine trip (PBTT) benchmark using the Virtual Environment for Reactor Applications (VERA), a multiphysics reactor modeling tool developed by the U.S. Department of Energy’s Consortium for Advanced Simulation of Light Water Reactors energy [...] Read more.
This work presents a high-fidelity simulation of the Peach Bottom turbine trip (PBTT) benchmark using the Virtual Environment for Reactor Applications (VERA), a multiphysics reactor modeling tool developed by the U.S. Department of Energy’s Consortium for Advanced Simulation of Light Water Reactors energy innovation hub. The PBTT benchmark, based on a 1977 transient event at the end of cycle 2 in a General Electric Type-4 boiling water reactor (BWR), is a critical test case for validating core physics models with thermal feedback during rapid reactivity events. VERA was employed to perform end-to-end, pin-resolved simulations from conditions at the beginning of cycle 1 through the turbine-trip transient, incorporating detailed neutron transport, fuel depletion, and subchannel thermal hydraulics. The simulation reproduced key benchmark observables with high accuracy: the peak power excursion occurred at 0.75 s, matching the scram time and closely aligning with the benchmark average of 0.742 s; the simulated maximum power spike was approximately 7600 MW, which is within 3% of the benchmark average of 7400 MW; and void-collapse dynamics were consistent with benchmark expectations. Reactivity predictions during cycles 1 and 2 remained within 1500 pcm and 400 pcm of criticality, respectively. These results confirm VERA’s ability to model complex coupled neutronic and thermal hydraulic behavior in a BWR turbine-trip transient, which will support its use in future studies of modeling dryout, fuel performance, and uncertainty quantification for transients of this type. Full article
(This article belongs to the Special Issue Validation of Code Packages for Light Water Reactor Physics Analysis)
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21 pages, 5750 KiB  
Article
Numerical Simulations of Coupled Vapor, Water, and Heat Flow in Unsaturated Deformable Soils During Freezing and Thawing
by Sara Soltanpour and Adolfo Foriero
Geotechnics 2025, 5(3), 51; https://doi.org/10.3390/geotechnics5030051 - 4 Aug 2025
Viewed by 53
Abstract
Freezing and thawing cycles significantly affect the mechanical and hydraulic behavior of soils, posing detrimental challenges for infrastructures in cold climates. This study develops and validates a coupled Thermal–Hydraulic–Mechanical (THM) model using COMSOL Multiphysics (Version 6.3) to demonstrate the complexities of vapor and [...] Read more.
Freezing and thawing cycles significantly affect the mechanical and hydraulic behavior of soils, posing detrimental challenges for infrastructures in cold climates. This study develops and validates a coupled Thermal–Hydraulic–Mechanical (THM) model using COMSOL Multiphysics (Version 6.3) to demonstrate the complexities of vapor and water flux, heat transport, frost heave, and vertical stress build-up in unsaturated soils. The analysis focuses on fine sand, sandy clay, and silty clay by examining their varying susceptibilities to frost action. Silty clay generated the highest amount of frost heave and steepest vertical stress gradients due to its high-water retention and strong capillary forces. Fine sand, on the other hand, produced a minimal amount of frost heave and a polarized vertical stress distribution. The study also revealed that vapor flux is more noticeable in freezing fine sand, while silty clay produces the greatest water flux between the frozen and unfrozen zones. The study also assesses the impact of soil properties including the saturated hydraulic conductivity, the particle thermal conductivity, and particle heat capacity on the frost-induced phenomena. Findings show that reducing the saturated hydraulic conductivity has a greater impact on mitigating frost heave than other variations in thermal properties. Silty clay is most affected by these changes, particularly near the soil surface, while fine sand shows less noticeable responses. Full article
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21 pages, 4289 KiB  
Article
H2 Transport in Sedimentary Basin
by Luisa Nicoletti, Juan Carlos Hidalgo, Dariusz Strąpoć and Isabelle Moretti
Geosciences 2025, 15(8), 298; https://doi.org/10.3390/geosciences15080298 - 3 Aug 2025
Viewed by 193
Abstract
Natural hydrogen is generated by fairly deep processes and/or in low-permeability rocks. In such contexts, fluids circulate mainly through the network of faults and fractures. However, hydrogen flows from these hydrogen-generating layers can reach sedimentary rocks with more typical permeability and porosity, allowing [...] Read more.
Natural hydrogen is generated by fairly deep processes and/or in low-permeability rocks. In such contexts, fluids circulate mainly through the network of faults and fractures. However, hydrogen flows from these hydrogen-generating layers can reach sedimentary rocks with more typical permeability and porosity, allowing H2 flows to spread out rather than be concentrated in fractures. In that case, three different H2 transport modes exist: advection (displacement of water carrying dissolved gas), diffusion, and free gas Darcy flow. Numerical models have been run to compare the efficiency of these different modes and the pathway they imply for the H2 in a sedimentary basin with active aquifers. The results show the key roles of these aquifers but also the competition between free gas flow and the dissolved gas displacement which can go in opposite directions. Even with a conservative hypothesis on the H2 charge, a gaseous phase exists at few kilometers deep as well as free gas accumulation. Gaseous phase displacement could be the faster and diffusion is neglectable. The modeling also allows us to predict where H2 is expected in the soil: in fault zones, eventually above accumulations, and, more likely, due to exsolution, above shallow aquifers. Full article
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19 pages, 4765 KiB  
Article
Dehydration-Driven Changes in Solid Polymer Electrolytes: Implications for Titanium Anodizing Efficiency
by Andrea Valencia-Cadena, Maria Belén García-Blanco, Pablo Santamaría and Joan Josep Roa
Materials 2025, 18(15), 3645; https://doi.org/10.3390/ma18153645 - 3 Aug 2025
Viewed by 217
Abstract
This study investigates the thermal stability and microstructural evolution of the solid electrolyte medium used in DLyte® dry electropolishing and dry anodizing processes. Samples were thermally aged between 30 °C and 45 °C to simulate Joule heating during industrial operation. Visual and [...] Read more.
This study investigates the thermal stability and microstructural evolution of the solid electrolyte medium used in DLyte® dry electropolishing and dry anodizing processes. Samples were thermally aged between 30 °C and 45 °C to simulate Joule heating during industrial operation. Visual and SEM analyses revealed shape deformation and microcrack formation at temperatures above 40 °C, potentially reducing particle packing efficiency and electrolyte performance. Particle size distribution shifted from bimodal to trimodal upon aging, with an overall size reduction of up to 39.5% due to dehydration effects, impacting ionic transport properties. Weight-loss measurements indicated a diffusion-limited dehydration mechanism, stabilizing at 15–16% mass loss. Fourier transform infrared analysis confirmed water removal while maintaining the essential sulfonic acid groups responsible for ionic conductivity. In dry anodizing tests on titanium, aged electrolytes enhanced process efficiency, producing TiO2 films with improved optical properties—color and brightness—while preserving thickness and uniformity (~70 nm). The results highlight the need to carefully control thermal exposure to maintain electrolyte integrity and ensure consistent process performance. Full article
(This article belongs to the Special Issue Novel Materials and Techniques for Dental Implants)
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