Search Results (287)

Runoff recharge increases during the wet season in arid inland river basins; however, solute inputs along river courses, evaporite salt dissolution, and leaching from saline sediments may still substantially modify the chemical composition of surface waters. To identify the sources of major ions, hydrochemical controlling processes, and salt-enriched river reaches during the wet season in the Cele River Basin, 107 surface water samples were collected from the mainstream of the Cele River and five major tributaries in August 2025. Field and laboratory analyses were conducted for pH, total dissolved solids (TDS), electrical conductivity (EC), dissolved oxygen (DO), and major ions, including Na⁺, K⁺, Ca²⁺, Mg²⁺, Cl⁻, SO₄²⁻, and HCO₃⁻. Piper diagrams, Gibbs diagrams, ionic ratios, Spearman correlation analysis, and principal component analysis (PCA) were used to characterize the major-ion composition, hydrochemical facies, and controlling factors. The results show that the surface waters were generally weakly alkaline, with pH values ranging from 7.42 to 8.46. TDS and EC exhibited pronounced spatial heterogeneity, with higher salinity levels in the Buzang River, the Cele River mainstream, and the Uluk Say River, and relatively lower mineralization in the Bostan River and Nur River. SO₄²⁻ and Cl⁻ dominated the anionic composition, together accounting for 80.3% of total anions, whereas Ca²⁺ + Mg²⁺ and Na⁺ + K⁺ jointly controlled the cationic composition, accounting for 57.3% and 42.7% of total cations, respectively. The Piper diagram indicated that the Cl·SO₄–Na·Ca type was the dominant hydrochemical facies, accounting for 67.3%, suggesting a pronounced sulfate–chloride salt-enrichment signature during the wet season. Evidence from Gibbs diagrams, ionic end-member ratios, and PCA further indicates that the hydrochemical composition is primarily constrained by rock weathering and jointly influenced by sulfate and chloride salt dissolution, evaporation–concentration processes, and leaching from saline sediments. These processes reflect the coexistence of runoff dilution and salt reloading during the wet season. The Buzang River, Cele River mainstream, and Uluk Say River should be prioritized for continuous water-quality monitoring and salinity-risk early warning, while TDS, EC, Na⁺, Cl⁻, and SO₄²⁻ can serve as core indicators for diagnosing wet-season water–salt processes and tracking water-quality baselines. This study identifies the key salt-enriched reaches, major ion sources, and hydrochemical control mechanisms of surface waters in the Cele River Basin during the wet season, providing a scientific basis for water-quality protection, oasis agricultural water regulation, and sustainable water–salt management in arid inland river basins. Full article

Catchment characteristics significantly influence water composition in pristine mountain lakes, receiving similar atmospheric deposition. We analysed these relationships for 20 subalpine and alpine catchment–lake systems in the High Tatra Mountains (Slovakia), using a comprehensive new dataset of detailed catchment characteristics and mean water chemistry from 2021 to 2024. Redundancy analysis indicated that catchment characteristics explained 47% of the spatial variability in lake hydrochemistry. The most influential parameters were land cover (20%), terrain slope (11%), lake-to-catchment area ratio (8%), and bedrock geology (8%). Cation concentrations were dominated by Ca²⁺, while anions were dominated by HCO₃⁻. Concentrations of Na⁺, K⁺, Cl⁻, dissolved organic carbon (DOC), and total organic nitrogen (TON) were higher, while NO₃⁻ was lower, in lakes with greater soil and vegetation cover in catchments. Concentrations of Na⁺, K⁺, Mg²⁺, Ca²⁺, HCO₃⁻, Cl⁻, SO₄²⁻, silicon (Si), and DOC decreased with increasing altitude, whereas Na⁺, K⁺, SO₄²⁻, NO₃⁻, NH₄⁺, and Si increased with catchment slope. Catchment bedrock geology affected K⁺, SO₄²⁻, and Si concentrations in lake water. More than 50% of the observed variability remained unexplained, indicating that additional climatic and hydrological drivers may influence lake hydrochemistry and represent important directions for future research. Full article

The Yishu Fault Zone (YSFZ) is located in a key tectonic transition zone shaped by the interaction between the Pacific and Tethyan tectonic domains in eastern China. Despite sparse geothermal borehole coverage across this region, the deeply incised fault structures create favorable hydrogeological prerequisites for fault-mediated subsurface heat migration and hydrothermal fluid circulation. This study integrates hydrochemistry, multi-isotope tracing (δD, δ¹⁸O, ⁸⁷Sr/⁸⁶Sr, and δ³⁴S), multi-mineral equilibrium modeling, and silica–enthalpy mixing analysis to constrain the evolution process and genetic mechanism of geothermal groundwater in the middle segment of the YSFZ. The geothermal groundwater displays weakly alkaline to alkaline properties and in situ temperatures of 35.2~75.0 °C, which is characterized by the HCO₃–Na, SO₄–Na, and Cl·SO₄–Na type. Stable isotope signatures demonstrate that the geothermal groundwater is recharged by the atmospheric precipitation with elevations of 822~1274 m. The hydrochemical evolution of the geothermal waters is governed by silicate weathering, evaporite dissolution, and cation exchange. The ⁸⁷Sr/⁸⁶Sr ratios indicate mixed solute contributions from silicate and evaporite lithologies, whereas the δ³⁴S signatures suggest that SO₄²⁻ is predominantly derived from gypsum dissolution. Two distinct hydrochemical evolution patterns can be identified in the study area. Samples GG1 and GG5 are characterized by HCO₃⁻ enrichment, whereas GG2, GG3, and GG4 exhibit enrichment in Na⁺ and SO₄²⁻. Reservoir temperatures estimated using multi-mineral equilibrium geothermometry range from 56.7 °C to 92.1 °C, with circulation depths of 1648~2304 m and cold-water mixing ratios of 48%~69%. The results of this study provide geochemical evidence for hidden geothermal resource exploration in deep fault zones. Full article

Quantitative source apportionment of groundwater contamination is essential for sustainable water resource management, yet the performance of receptor models in complex hydrogeological settings remains debated. This study employed Positive Matrix Factorization (PMF) and PCA-APCS-MLR (Principal Component Analysis–Absolute Principal Component Score–Multiple Linear Regression) models to analyze 16 hydrochemical parameters from 460 groundwater samples (collected at 339 sites), delineating pollution sources and characterizing the groundwater chemistry in the southern recharge zone of Poyang Lake, China’s largest freshwater lake. Both models consistently identified five primary pollution sources: mixed anthropogenic activities (contributing 13.6% and 8.6%, respectively), natural geological processes (28.9% and 45.6%), sewage discharge (23.5% and 24.4%), industrial effluents (13.3% and 12.1%), and agricultural practices (20.6% and 9.3%). Notably, heightened contamination was observed near industrial parks and urban centers through two models. The integrated analysis revealed that anthropogenic activities—particularly sewage discharge, agricultural practices, and industrial effluents—are the dominant drivers of groundwater quality deterioration. These human-induced inputs account for the vast majority of the pollution load (reaching up to ~71%), fundamentally altering the natural hydrochemical regime. Notably, elevated Mn²⁺ and NH₄⁺-N concentrations are intricately linked to a combination of industrial effluents and legacy domestic sewage, which exacerbate the mobilization of natural background elements within the aquifer. These findings provide critical mechanistic insights into the complex interplay between human activities and groundwater hydrochemistry, demonstrating how dual-receptor modeling can unravel overlapping natural and anthropogenic inputs. Ultimately, this study offers a scientific basis for targeted pollution control and the sustainable management of global freshwater lake recharge zones. Full article

Groundwater is one of the basic requirements for life, economic and social developments in the Bazo River catchment, Rift Valley, Southern Ethiopia. In the study area, availability of water is faced with several problems, such as quality issues due to high levels of fluoride in some samples, spring scarcity in the lowlands, unprotected river water used for drinking, and high demand for good quality water. The aim of this study was to investigate the hydrogeochemical characteristics and to evaluate groundwater quality for domestic and irrigation uses. Thirty-four primary groundwater samples were collected from the field and analyzed in the water quality lab of Arba Minch University. Two water quality indices (WQI and EWQI), a variety of irrigation water quality indices, and GIS-based spatial analysis were utilized in this study. Cations were present in the descending order of Na > Ca > Mg > K > Fe, and anions were HCO₃⁻ > Cl > SO₄ > NO₃⁻ > F. Excepting two samples (BH8 and SP3), the water samples were acceptable for drinking. Sodium, TDS, and fluoride levels were over the limit of drinking water in BH8 and SP3. Rock–water interaction, cation exchange, and silicate mineral weathering were the main hydrogeochemical reactions that controlled groundwater composition in the area, based on Gibb’s diagram, chloro-alkaline indices, and major ions ratios. Groundwater facies were identified as Ca.HCO₃, Na.HCO₃ and mixed Ca-Na/Ca.Mg.Na.HCO₃ types using a Piper plot. The water quality index was computed, and its spatial variations were mapped using GIS. About 82.35% of groundwater samples were excellent for drinking use and 94.12% (SAR) of groundwater were acceptable for irrigation. These study results are useful to help develop inclusive strategies and interventions to address groundwater quality aspects in the study area, underlining the significance of managing and monitoring water resources. The findings underscore the need for effective management and monitoring strategies to ensure sustainable groundwater resources in the Bazo River catchment. Full article

Soil erosion is a critical environmental issue restricting ecological security and agricultural sustainable development in China. Traditional studies have predominantly focused on physical driving factors such as hydraulic and wind erosion, while the regulatory effects of hydrochemistry on soil erosion have long been neglected. To clarify the mechanisms and regulatory processes of hydrochemistry-driven soil erosion in China, this study collected 795 relevant publications from the Web of Science Core Collection spanning from 2000 to 2025. Based on bibliometric methods, visualization software including VOSviewer 1.6.20 and CiteSpace 6.4.R1 were adopted to analyze publication trends, author distributions, research institutions, and keyword co-occurrence characteristics. The results indicated that the number of publications concerning hydrochemistry-driven soil erosion in China has increased year by year since 2000. China ranks first in total publication output, showing a dominant research position in this field. The Chinese Academy of Sciences contributed the largest number of publications among all research institutions. Keyword co-occurrence analysis over the past 25 years demonstrated that soil erosion, runoff, and water erosion serve as the core research hotspots. Further analysis revealed the regulatory mechanisms of key hydrochemical parameters (e.g., pH value, ionic strength, and dissolved organic carbon) throughout erosion processes. In-depth keyword analysis confirmed that current research on hydrochemistry-driven soil erosion in China remains at the preliminary stage, lacking comprehensive exploration of microcosmic mechanisms and systematic regulation strategies. Therefore, intensified research efforts and optimized regulatory frameworks are urgently required in future studies. This study can provide theoretical foundations and technical references for improving the understanding of erosion driving mechanisms and enhancing soil erosion management efficiency across diverse regions of China. Full article

Groundwater serves as a vital source of domestic and agricultural water in rural areas of the Songnen Plain. Its chemical composition and water quality directly impact public health and regional sustainable development, making them subjects of significant concern. This study employed a comprehensive analytical framework, integrating Piper trilinear diagrams, ionic ratio analysis, the Water Quality Index (WQI), and the Human Health Risk Assessment (HHRA) model, to preliminarily evaluate groundwater conditions in a rural township of the Songnen Plain. The multi-method approach was designed to provide scientific insights for groundwater pollution prevention and remediation strategies in the region. Results indicate that the predominant groundwater chemical type in the study area is HCO₃-Ca. The hydrochemical process is primarily controlled by weathering and dissolution of silicate and carbonate minerals, accompanied by cation exchange. The WQI ranged from 84.78 to 192.82, with an average of 132.68, indicating overall moderate water quality. Fe and Mn are significant factors affecting water quality. The potential non-carcinogenic risks posed by groundwater to children, females, and males (0.988, 0.701, 0.534) and carcinogenic risks (1.77 × 10⁻⁵, 6.27 × 10⁻⁵, 4.81 × 10⁻⁵) are both below the USEPA recommended threshold (1.0, 1 × 10⁻⁴), indicating that the health risks were generally acceptable, though the HI for children approached the threshold. The results underscore the need for targeted mitigation of elevated Fe/Mn concentration (e.g., via aeration biofilters) while highlighting the region’s low health risks under current conditions. This work provides a template for integrating geochemical and health risk paradigms in groundwater management. Full article

Phosphogypsum (PG) stacks are traditionally assessed as sources of legacy inorganic contaminants, but the behavior of emerging contaminants in these chemically complex systems remains poorly understood. This opinion article proposes that PFAS, if present in PG stacks, may not be adequately described by partitioning concepts derived from dilute groundwater or ordinary soil porewater systems. Instead, the low-pH, high-ionic-strength, and calcium–sulfate-rich conditions of PG leachate may promote hydrochemistry-mediated repartitioning of PFAS. Under such conditions, PFAS may exhibit reduced apparent aqueous stability, enhanced association with PG particles or colloids, retention on particle surfaces, and enrichment at air–water interfaces, forming potential hidden reservoirs with the potential for delayed release and episodic remobilization. Consequently, dissolved concentrations alone may underestimate total PFAS storage and long-term groundwater risk in and around PG stack systems. Overall, this study highlights the need to shift from conventional dilute-system assumptions toward a hydrochemically mediated multiphase framework for PFAS occurrence assessment, monitoring design, and risk evaluation in phosphogypsum environments and other chemically complex industrial waste systems. Full article

Groundwater is the primary source of livestock watering across the arid pasturelands of western Kazakhstan, yet no systematic field hydrochemical assessment has been published for this region in over 40 years. This study presents the first systematic field-based hydrochemical characterisation of groundwater sources used for pasture livestock watering in the West Kazakhstan Region and Aktobe Region, filling a critical data gap that has persisted since the Soviet era. Specifically, it characterises the hydrochemistry, water quality, and infrastructure condition of groundwater sources, and evaluates the groundwater resource potential against current and projected livestock water demand. A total of 139 groundwater samples were collected along 11,182 km of field routes during May–July 2025, and analysed for 25 physicochemical parameters; hydrochemical classification was performed using AquaChem 11, and spatial analysis was conducted in ArcGIS 10.8. The groundwater chemistry distribution is bimodal: fresh bicarbonate-calcium-magnesium waters (TDS < 3.0 g/L) constitute approximately 80% of samples, while highly mineralised chloride-sulphate-sodium waters (TDS up to 9.91 g/L) occur in salt-dome-influenced discharge zones. Nitrate concentrations exceeded 50 mg/L in 23–36% of samples, with maxima of 635 mg/L, reflecting intensive anthropogenic contamination near livestock facilities. Predictive exploitable fresh groundwater resources exceed current livestock demand by a factor of 162. The principal constraint on pasture water supply is not resource scarcity but the non-operational status of 51–75% of inspected watering infrastructure, a legacy of post-Soviet institutional collapse that requires urgent rehabilitation. Full article

The evolution of groundwater in the Puhe River Basin is closely related to the ecological security of the Beijing–Tianjin–Hebei water source conservation zone. Based on 122 groundwater samples, this study systematically investigated the hydrochemical characteristics, evolution mechanisms, and water quality of shallow groundwater using mathematical statistics, Piper diagrams, ionic ratio analysis, and a variable fuzzy pattern recognition model. The results showed that shallow groundwater in the middle and upper reaches is generally weakly alkaline, fresh to hard water, with HCO₃–Ca and HCO₃·SO₄–Ca as the dominant hydrochemical facies. Groundwater hydrochemistry is primarily controlled by rock weathering, and the dissolution of silicate and carbonate rocks is the main source of major ions. Calcite and dolomite are in dynamic equilibrium between dissolution and precipitation, whereas gypsum and halite remain undersaturated. Overall, groundwater quality is generally good; however, anthropogenic activities in cultivated and construction lands have altered local hydrochemical composition and caused water quality deterioration in some areas. These findings improved the understanding of groundwater hydrochemical evolution in typical small watersheds of the northern Hebei hilly region and provided a scientific basis for the sustainable management and protection of groundwater resources in the Beijing–Tianjin–Hebei water source conservation area. Full article

This study investigated spring water in the core area and buffer zone of the Shibing Dolomite Karst World Heritage Site using one-year monthly monitoring, hydrochemistry, nitrate dual isotopes, and the MixSIAR model. The buffer zone spring exhibits shallow fissure-conduit flow with rapid hydrological response, anthropogenic nitrate dominance (>62%), nitrification as the main process, and limited denitrification. Its nitrate concentration shows seasonal peaks. In contrast, the core area spring is recharged by deep fissure water, with natural nitrate sources (>80%), stable nitrate levels (5–7.4 mg/L), and potential local denitrification. Nitrogen export in the buffer zone increases 4.5 times in the rainy season (NO₃⁻ accounting for 93% of TN). The core area shows higher TN export flux per unit area (3.34 vs. 0.4 g/m²/a) and greater DON proportion. Nitrogen export far exceeds that from rocky desertified areas, suggesting that dissolved nitrogen leaching drives karst rocky desertification evolution. Full article

Understanding how the development of large-scale coal mining bases affects river hydrochemistry is a key scientific issue in the field of water environment research. In this study, the Qingyang–Binzhou section of the Jinghe River Basin was selected as the study area, and a total of 29 water samples were collected in April 2025 from the upper to lower reaches of the coal mining base. Hydrochemical analysis, ion ratio methods, and the positive matrix factorization (PMF) model were comprehensively applied to systematically characterize the hydrochemical features and identify the pollution sources in the river under the influence of large-scale coal mining activities. The results showed that the mean concentrations of Na⁺, SO₄²⁻, Cl⁻, and total dissolved solids (TDS) in the mainstream were as high as 414 mg/L, 728 mg/L, 226 mg/L, and 1636 mg/L, respectively, reflecting a significant impact of coal mining activities on river hydrochemistry. Four spatial variation patterns were observed along the river: the first pattern was characterized by “stable in the upper reaches, sharp increase in the middle reaches, and fluctuating increase in the lower reaches,” represented by Na⁺ and SO₄²⁻; the second pattern showed “stable in the upper reaches, slight decrease in the middle reaches, and fluctuating decrease in the lower reaches,” represented by pH; the third pattern exhibited “fluctuating in the upper reaches, sharp decrease in the middle reaches, and extremely low levels in the lower reaches,” represented by NO₃⁻; and the fourth pattern was dominated by irregular variations controlled by nitrogen transformation processes, represented by NH₄⁺ and NO₂⁻. Gibbs plots and ion ratio diagrams indicated that the hydrochemistry of sites unaffected by coal mine drainage was primarily controlled by rock weathering, whereas contaminated samples shifted toward the evaporation-concentration zone and extended beyond its typical range, reflecting an “anthropogenic salinization effect” induced by the input of mine water superimposed on the arid to semi-arid climatic background. The PMF model identified three main pollution sources: coal mining and mine water discharge (48.3%), domestic sewage (30.2%), and carbonate weathering (21.5%). This study reveals the significant modification mechanism of river hydrochemistry by large-scale coal mining base development, providing a scientific basis for targeted water pollution control in the Jinghe River Basin and for water environment management in similar mining areas. Full article

Surface water quality, serving as a key link between domestic water use and agricultural production, impacts both the drinking water safety of local residents and the sustainable use of irrigated soil. To better protect water resources and enhance their sustainable value, this study collected 50 water samples from the areas surrounding Nansi Lake. Using the Piper trilinear diagram, Gibbs model, and ion ratio analysis, the main hydrochemical types were identified. Based on this, the entropy-weighted water quality index (EWQI) was used to evaluate the water’s suitability for drinking, while irrigation water quality indicators were applied to assess its suitability for irrigation. The results indicate that during both dry and rainy seasons, Na⁺ and SO₄²⁻ dominate the water, with average total dissolved solids (TDS) of 1279 mg/L and 1163 mg/L, respectively, indicating moderately elevated salinity. The ion concentrations follow the order: SO₄²⁻ > HCO₃⁻ > Cl⁻ > NO₃⁻ > F⁻ and Na⁺ > Ca²⁺ > Mg²⁺ > K⁺. From a hydrochemical perspective, mixed-type and Cl-Na-type waters prevailed in both seasons. The chemical composition of surface water in the study area is largely governed by rock weathering, with ions primarily originating from the dissolution of silicate and evaporite minerals. Furthermore, cation exchange processes play a significant role in shaping the evolution of the water chemistry. The water quality evaluation indicates that surface water in the study area is generally Class II, representing good water quality. However, Class IV and Class V water exist in some areas, where the primary exceedance parameter is SO₄²⁻, which is a key factor influencing water quality. Irrigation suitability is generally good. Systematic investigation of surface water hydrochemistry and quality is of great practical significance for ensuring safe drinking and irrigation water and promoting sustainable socio-economic development. Full article

This study presents the first watershed-scale assessment of the impact of thermal spring discharges on the hydrochemistry and water quality of the Soummam basin (northeastern Algeria). Fourteen stations were monitored during three campaigns (October 2024, December 2024 and March 2025), combining physicochemical analyses, hydrochemical diagrams, and water quality indices (WQI and IWQI). The results reveal a clear spatial gradient in water composition, from low-mineral Ca-HCO₃/Ca-SO₄ facies in upstream areas to highly mineralized Na-Cl facies associated with thermal springs (Sidi Yahia and Sillal). Electrical conductivity reaches up to 27,359 µS/cm, reflecting intense mineralization driven by evaporite dissolution and deep water–rock interaction. This thermomineral signature propagates downstream through mixing and ion exchange processes, leading to progressive salinity enrichment. Water quality indices highlight significant degradation in thermally influenced zones, with approximately 50% of samples unsuitable for drinking (WQI > 300) and more than 60% classified as highly restricted for irrigation (IWQI < 40). Cluster analysis further confirms the distinction between severely impacted, moderately affected, and relatively preserved waters. Overall, the findings demonstrate that thermal discharges represent a major and persistent driver of salinization, emphasizing the need to incorporate geothermal influences into water resource management strategies in semi-arid environments. Full article

The hydrogeochemical characterization of shallow volcanic lakes at the Sete Cidades Volcano (São Miguel, Azores) provides new insights into the processes controlling water chemistry in low-depth lacustrine systems within active volcanic environments. Fourteen lakes (0.6–4 m deep) were sampled during two campaigns (winter 2024 and spring/summer 2025), combining in situ physicochemical measurements and major ion analyses along vertical profiles. The lakes are holomictic, cold (11.3–17.6 °C), slightly acidic (pH 5.66–5.95), and weakly mineralized (EC ~65–69 µS/cm), indicating dilute waters of predominantly meteoric origin. Hydrochemical facies are dominated by Na–Cl type, with strong correlations between chloride and conductivity (r = 0.857), supporting a major contribution from marine atmospheric deposition. To move beyond correlation-based interpretation, Gibbs diagrams and saturation indices (PHREEQC) were applied to constrain the dominant geochemical processes. Most samples plot within the precipitation dominance field, while all calculated saturation indices are negative (SI < 0), indicating undersaturation with respect to carbonate, evaporite, and silicate minerals. These results demonstrate that water chemistry is primarily controlled by atmospheric inputs, with only minor contributions from water–rock interaction and negligible influence of evaporation or mineral equilibrium processes. Seasonal increases in HCO₃⁻ and dissolved CO₂ at depth suggest enhanced organic matter decomposition during warmer periods, highlighting the role of biogeochemical processes in modulating carbon dynamics in shallow systems. The absence of a clear hydrothermal signature further distinguishes these lakes from deeper volcanic systems in the Azores. This study provides the first integrated hydrogeochemical framework for shallow volcanic lakes in the region, combining classical hydrochemistry with process-based tools. The results establish a quantitative baseline for assessing environmental change and improve the interpretation of external (atmospheric) versus internal (geochemical and biological) controls in volcanic lake systems. Full article