Search Results (91)

Against the backdrop of global energy transition and strict environmental regulations, supercritical carbon dioxide (scCO₂) fracturing and oil displacement technologies have emerged as pivotal green approaches in shale gas exploitation, offering the dual advantages of zero water consumption and carbon sequestration. However, the inherent low viscosity of scCO₂ severely restricts its sand-carrying capacity, fracture propagation efficiency, and oil recovery rate, necessitating the urgent development of high-performance thickeners. The current research on scCO₂ thickeners faces a critical trade-off: traditional fluorinated polymers exhibit excellent philicity CO₂, but suffer from high costs and environmental hazards, while non-fluorinated systems often struggle to balance solubility and thickening performance. The development of new thickeners primarily involves two directions. On one hand, efforts focus on modifying non-fluorinated polymers, driven by environmental protection needs—traditional fluorinated thickeners may cause environmental pollution, and improving non-fluorinated polymers can maintain good thickening performance while reducing environmental impacts. On the other hand, there is a commitment to developing non-noble metal-catalyzed siloxane modification and synthesis processes, aiming to enhance the technical and economic feasibility of scCO₂ thickeners. Compared with noble metal catalysts like platinum, non-noble metal catalysts can reduce production costs, making the synthesis process more economically viable for large-scale industrial applications. These studies are crucial for promoting the practical application of scCO₂ technology in unconventional oil and gas development, including improving fracturing efficiency and oil displacement efficiency, and providing new technical support for the sustainable development of the energy industry. This study innovatively designed an amphiphilic modified amino silicone oil polymer (MA-co-MPEGA-AS) by combining maleic anhydride (MA), methoxy polyethylene glycol acrylate (MPEGA), and amino silicone oil (AS) through a molecular bridge strategy. The synthesis process involved three key steps: radical polymerization of MA and MPEGA, amidation with AS, and in situ network formation. Fourier transform infrared spectroscopy (FT-IR) confirmed the successful introduction of ether-based CO₂-philic groups. Rheological tests conducted under scCO₂ conditions demonstrated a 114-fold increase in viscosity for MA-co-MPEGA-AS. Mechanistic studies revealed that the ether oxygen atoms (Lewis base) in MPEGA formed dipole–quadrupole interactions with CO₂ (Lewis acid), enhancing solubility by 47%. Simultaneously, the self-assembly of siloxane chains into a three-dimensional network suppressed interlayer sliding in scCO₂ and maintained over 90% viscosity retention at 80 °C. This fluorine-free design eliminates the need for platinum-based catalysts and reduces production costs compared to fluorinated polymers. The hierarchical interactions (coordination bonds and hydrogen bonds) within the system provide a novel synthetic paradigm for scCO₂ thickeners. This research lays the foundation for green CO₂-based energy extraction technologies. Full article

In the present study, we synthesized fluorocarbon-coated cobalt ferrite (CoFe₂O₄) magnetic nanoparticles using alkoxysilanes such as trimethoxy(3,3,3-trifluoropropyl)silane (TFPTMS), trimethoxy(1H,1H,2H,2H-nonafluorohexyl)silane (NFHTMS), and triethoxy(1H,1H,2H,2H-perfluorodecyl)silane (PFDTES). The synthesized nanoparticles were characterized by various techniques, including X-ray diffractometry (XRD), transmission electron microscopy (TEM/HRTEM/EDXS), Fourier transform infrared spectroscopy (FTIR), specific surface area measurements (BET), and magnetometry (VSM). To understand their surface characteristics, contact angle (CA) measurements were carried out, providing valuable insights into their hydrophobic properties. Among the samples of CoFe₂O₄ coated with fluoroalkoxysilanes, those with PFDTES surface coating had the highest water contact angle of 159.2°, indicating their superhydrophobic character. The potential of the prepared fluoroalkoxysilane-coated CoFe₂O₄ nanoparticles for the removal of waste low-SAPS synthetic engine oil from a model aqueous solution was evaluated based on three key parameters: adsorption efficiency (%), adsorption capacity (mg/g), and desorption efficiency (%). All synthesized CoFe₂O₄ samples coated with fluoroalkoxysilane showed high oil adsorption efficiency, ranging from 87% to 98%. The average oil adsorption capacity for the samples was as follows: F₃-SiO₂@CoFe₂O₄ (3.1 g of oil/g of adsorbent) > F₉-SiO₂@CoFe₂O₄ (2.7 g of oil/g of adsorbent) > F₁₇-SiO₂@CoFe₂O₄ (1.5 g of oil/g of adsorbent) as a result of increasing oleophobicity with increasing fluorocarbon chain length. The desorption results, which showed 77–97% oil recovery, highlighted the possibility of reusing the adsorbents in multiple adsorption/desorption cycles. Full article

The possibility of using the secondary cellulose-containing raw material resource of the cereal production of buckwheat, namely, its husk, as sorbents for the collection of oil and oil products is shown. In order to increase the yield of the finished product, develop porosity, and improve the sorption characteristics of the buckwheat husk, methods for its physical and chemical modification are proposed. The effect of the modification modes on the parameters of the porous structure, as well as the sorption capacity of the developed materials for various types of oil products, was studied. The selection of the optimal parameters of the buckwheat husk modification was carried out, ensuring the production of effective unsinkable sorbents based on the buckwheat husk with a reserve buoyancy of more than 20 days and a high sorption capacity of sorbents for oil of up to 6.1 g/g and waste motor oil of up to 4.9 g/g. The use of the buckwheat husk as a sorbent allows not only the elimination of oil pollution on both water and surfaces but also solving the problem of the disposal of agricultural waste. Full article

The demand for palm oil is expected to increase due to its wide use in the market. Palm oil is extracted from the fruit of the African palm tree, yielding crude palm oil (CPO) and palm kernel oil (PKO). The production process involves multiple stages, from harvesting to drying; while the problem lies in the scarcity of fresh fruit bunches and the lack of diagnosis of the process. This study proposes to carry out a WEP (Water–Energy–Product) technical assessment to optimize the use of water, energy, and raw materials in the production of CPO, calculating a series of technical parameters and indicators and determining the latter’s efficiency. The results showed that for a processing capacity of 30,000 kg/h of African palm bunches, 5070 kg/h of CPO were obtained, reaching a production yield of 69.63%, a wastewater production ratio (WPR) of 58.64 %, a fractional water consumption (FWC) of 2.38 m³/t of CPO, a total cost of freshwater (TCF) of 347.33 USD/day, a total cost of energy (TCE) of 13,235.95 USD/day, an energy-specific intensity (ESI) of 4905.66 MJ/t of CPO, a natural gas consumption index (NGCI) of 103,421.65 m³/t of CPO, an electric energy consumption index (EECI) of 165.67 kWh/t of CPO, and a net energy ratio (NER) and energy utilization index (ECI) of 165.67 kWh/t of CPO. The EUI is higher than 1. Additionally, five indicators showed an efficiency higher than 80%, highlighting the energy indicators (TCE, NGCI, and EECI), which reached the highest efficiency (95.45%) due to the predominant use of natural gas, and the water indicators (FWC and TCF), which reached 92.90% and 88.12%, respectively. Finally, improvements are required in the WPR (41.36%) and the ESI (78.13%), which merit optimization techniques using mass and energy integration, respectively. Full article

Aiming at the problem that conventional friction reducers used in fracturing cannot simultaneously possess properties such as temperature resistance, salt resistance, shear resistance, rapid dissolution, and low damage. Under the design concept of “medium-low molecular weight, salt-resistant functional monomer, supramolecular physical crosslinking aggregation, and enhanced chain mechanical strength”, acrylamide, sulfonic acid salt-resistant monomer 2-acrylamide-2-methylpropanesulfonic acid, hydrophobic association monomer, and rigid skeleton functional monomer acryloyl morpholine were introduced into the friction reducer molecular chain by free radical polymerization, and combined with the compound suspension technology to develop a new type of multi-functional viscous friction reducer suspension (SAMD), the comprehensive performance of SAMD was investigated. The results indicated that the critical micelle concentration of SAMD was 0.33 wt%, SAMD could be dissolved in 80,000 mg/L brine within 3.0 min, and the viscosity loss of 0.5 wt% SAMD solution was 24.1% after 10 min of dissolution in 80,000 mg/L brine compared with that in deionized water, the drag reduction rate of 0.1 wt% SAMD solution could exceed 70% at 120 °C and still maintained good drag reduction performance in brine with a salinity of 100,000 mg/L. After three cycles of 170 s⁻¹ and 1022 s⁻¹ variable shear, the SAMD solution restored viscosity quickly and exhibited good shear resistance. The Tan δ (a parameter characterizing the viscoelasticity of the system) of 1.0 wt% SAMD solution was 0.52, which showed a good sand-carrying capacity, and the proppant settling velocity in it could be as low as 0.147 mm/s at 120 °C, achieving the function of high drag reduction at low concentrations and strong sand transportation at high concentrations. The viscosity of 1.4 wt% SAMD was 95.5 mPa s after shearing for 120 min at 140 °C and at 170 s⁻¹. After breaking a gel, the SAMD solution system had a core permeability harm rate of less than 15%, while the SAMD solution also possessed the performance of enhancing oil recovery. Compared with common friction reducers, SAMD simultaneously possessed the properties of temperature resistance, salt resistance, shear resistance, rapid dissolution, low damage, and enhanced oil recovery. Therefore, the use of this multi-effect friction reducer is suitable for the development of unconventional oil reservoirs with a temperature lower than 140 °C and a salinity of less than 100,000 mg/L. Full article

The effect of emergent technologies for the starch extraction was studied. The evaluation of conventional extraction (MKS-WMP), ultrasound-assisted extraction (MKS-UAE), and microwave-assisted extraction (MKS-MAE) on chemical, technological, gelling, pasting, and microstructural properties of starch from mango kernel was carried out. The extraction yield was found in the values of 42.05, 50.40, and 47.43% for MKS-WMP, MKS-UAE, and MKS-MAE treatments, respectively. The amylose contents for MKS-UAE and MKS-MAE starches were significantly higher (p < 0.05) than MKS-WMP, with an increase of about 13–18%. The total phenolic content ranged from 84.89 to 90.85 mg GAE/g starch without significant differences (p > 0.05). The technological properties evidence a good water-holding capacity (80.48–90.05 g/100 g of starch) and oil-holding capacity (70.58–83.23 g/100 g of starch). The gelatinization temperature, measured by rheological analysis, ranged between 77 and 82 °C. Microstructural properties showed that ultrasound- and microwave-assisted treatments improved the shape and surface of starch granules, and that they are promising alternatives for starch extraction, providing some characteristics that could increase the applications in the food industry. Full article

Incorporating vitamin D3 (cholecalciferol) into food is hampered by its high instability and low water solubility. Due to porous structure that favors absorption and carrying of micronutrients, brewer’s spent yeast (BSY) is an economically and technically attractive alternative to overcome the shortcomings of vitamin D3 incorporation. Using heat and shear-sensitive ingredients and additives in formulations remains challenging due to the high-temperature and shear conditions during industrial processes, such as extrusion. This study aimed to produce an extruded plant-based meat product enriched with cholecalciferol. Vitamin D3, free and impregnated in BSY (BSY-VitD3), was blended with pea protein and subjected to cooking extrusion. Product features were analyzed for color, texture, moisture, water activity, absorption capacity, and vitamin retention. Adding BSY-VitD3 reduced all texture profile parameters and altered colors. Furthermore, free VitD3 enhanced extruded water and oil absorption capacity. After extrusion, vitamin retention percentages in the products were 45.4 and 91.6%, for free and BSY-VitD3, respectively. After 1-month storage of the extruded products, vitamin retention was 38.9 and 85.1% for free and BSY-VitD3 samples, respectively. Blending vitamin D3 with BSY is a simple, fast, and effective process to facilitate incorporation of the vitamin in the formulation and protect it during cooking extrusion. Full article

Porous starch, known for its large specific surface area due to internal pores, exhibits excellent adsorption capabilities. In this study, we successfully produced porous starch from lotus seeds using dextranase and conducted a comprehensive analysis of its surface morphology, crystalline structure, pasting behavior, and adsorption characteristics. The enzymatic treatment resulted in the development of a pore structure on the lotus seed starch (LS) surface without altering its crystalline structure, as confirmed by Fourier transform infrared spectroscopy and X-ray diffraction. The oil and water absorption capacities of the porous starch increased by 14% and 27%, respectively. Differential scanning calorimetry indicated a higher pasting temperature for the porous starch. This starch exhibited remarkable drug-carrying capabilities, absorbing up to 18.23 mg/g of proanthocyanidins and significantly shielding them from UV damage. In vitro release tests in simulated intestinal fluid revealed that the encapsulated proanthocyanidins (PC) achieved nearly complete release. These results underscore the potential of LS as a drug carrier and provide valuable insights for developing innovative intestinal drug delivery systems. Full article

Hydraulic fracture stimulation is one of the most effective methods to recover oil and gas from unconventional resources. In recent years, foam-based fracturing fluids have been increasingly studied to address the limitations of conventional slickwater such as high water and chemical consumption, environmental concerns, and high incompatibility with water-sensitive formations. Due to the gradual breakdown of liquid foams at reservoir conditions, the combination of silica nanoparticles (SNP) and surfactants has attracted a lot of attention to improve liquid foams’ characteristics, including their stability, rheology, and proppant-carrying capacity. This paper investigates and compares the effects of cationic and anionic surfactants on the fracturing performance of SNP-stabilized foams at the reservoir temperature of 90 °C. The experimental results of viscosity measurements were imported into a 3D fracture-propagation model to evaluate the effectiveness of fracturing foams in transporting and distributing proppants in the fracture system. At both ambient and elevated temperatures, cationic surfactant was experimentally found to have better synergistic effects with SNP than anionic surfactant in improving the apparent viscosity and proppant-carrying capacity of foams. The simulation results demonstrate that fracturing with cationic surfactant-SNP foam delivers greater performance with larger propped area by 4%, higher fracture conductivity by 9%, and higher cumulative gas production by 13%, compared to the anionic surfactant-SNP foam. This research work not only helps validate the interrelationship between fluid viscosity, proppant settlement rate, and fracture effectiveness, but it also emphasizes the importance of proppant placement in enhancing fracture conductivity and well productivity. Full article

Thiophenol (synonyms: phenyl mercaptan, benzenethiol) may appear in the aquatic environment as a result of human activity. It is used as a raw material in organic synthesis in various industries for the production of dyes, pesticides, pharmaceuticals and polymers, such as polyphenylene sulfide (PPS). It may also enter water through contamination with petroleum substances (thiophenol may be present in crude oil). Due to the fact that thiophenol is toxic to living organisms, its removal from water can be a very important task. For the first time, this paper presents experimental studies of the sorption and desorption process of thiophenol on an ion exchange resin. Thiophenol sorption experiments on AmbeLite^®IRA402 (Cl form) were tested at different pH levels (4, 7, and 9) and different ionic strengths of the aqueous solution. Its detection in water was carried out using UV spectroscopy. At pH 4, the thiophenol sorption process is basically independent of the ionic strength of the solution, but also the least effective. The sorption capacity of a thiophenol solution in distilled water is about 0.37–0.46 mg/g, for a solution with an ionic strength of 0.1 M 0.42 mg/g. At pH 7 and 9, the sorption of thiophenol from an aqueous solution is similar and definitely more effective. The sorption capacity of the thiophenol solution in distilled water is about 13.83–14.67 mg/g, and for a solution with an ionic strength of 0.1 M, it is 2.83–2.10 mg/g. The desorption efficiency of thiophenol from AmbeLite^®IRA402 resin (washing with 4% HCl) at pH 7 is 90%, which is promising for the resin reuse process. Kinetic studies were performed and a pseudo-first-order and second-order kinetic model was fitted to the obtained experimental sorption data. In most cases, the simulation showed that the pseudo-second-order model gives a better fit, especially for the sorption of thiophenol from the solution with an ionic strength of 0.1 M. The fit of the Freundlich and Langmuir isotherm models to the experimental results indicates that the latter model provides better agreement. Analysis of the infrared spectra supported by quantum chemical calculations (DFT/PCM/B3LYP/6-31g**) confirms the experimental results observed during the sorption process. At pH 7 and 9, the thiophenol is sorbed in anionic form and—together with the ion exchange processes that occur between the dissociated thiol group and the quaternary ammonium group—an interaction between the aromatic structures of thiophenolate anions and IRA402 also takes place. Full article

The carbonate fracture-cave reservoir in the Tahe oilfield, China, encounters development challenges because of its substantial burial depth (exceeding 5000 m). Its characteristics are low permeability, pronounced heterogeneity, extensive karst cavern systems, diverse connection configurations, and intricate spatial distribution. Prolonged conventional water flooding leads to predominant water channels, resulting in water channeling and limited sweep efficiency. Surfactant flooding is usually adopted in these conditions because it can mitigate water channeling and enhance sweep efficiency by lowering the interfacial tension (it refers to the force that is generated due to the unbalanced molecular attraction on the liquid surface layer and causes the liquid surface to contract) between oil and water. Nonetheless, the Tahe oilfield is a carbonate reservoir where surfactant is prone to loss near the well, thereby limiting its application. High-pressure injection flooding technology is an innovative method that utilizes injection pressure higher than the formation rupture pressure to alter reservoir permeability, specifically in low-permeability oil fields. Because of the high fluid flow rate, the contact time with the interface is decreased, enabling the ability for surfactants to reach the deep reservoir. In this article, based on the mixed adsorption mechanism of two surfactants and the hydrophilic and lipophilic equilibrium mechanisms, a set of high-temperature and high-salinity resistance surfactant systems appropriate for the Tahe oilfield is developed and its associated performance is evaluated. An oil displacement experiment is carried out to examine the effect of surfactant flooding by high-pressure injection. The results demonstrate that the ideal surfactant system can lower the interfacial tension to 10⁻² mN/m and its capacity to reduce the interfacial tension to 10⁻² mN/m after different aging periods. Besides, the surfactant system possesses excellent wettability (wetting angle changed from 135° to 42°) and certain emulsifying abilities. The oil displacement experiment shows that the oil recovery rate of surfactant flooding by high pressure reaches 26%. The effect of surfactant flooding by high-pressure injection is better than that of high-pressure injection flooding. Full article

Background: Voriconazole is an antifungal drug, which is classified under Bio-Classification System-II and has low water solubility (0.71 mg/mL) and high permeability. Hardly any endeavors have been made to increase the bioavailability of voriconazole. Objective: To develop and evaluate a solid SMEDDS (self-microemulsifying drug delivery system) for antifungal activity. Methods: Based on solubility studies of Labrafil-M 1994 CS (oil), Cremophor-RH 40 (a surfactant) and Transcutol-HP (a co-surfactant) were selected as components of the SMEDDS and a pseudo-ternary phase diagram was prepared. Thereafter, the oil, surfactant, and co-surfactant were mixed with altered weight ratios (1:1/1:2/2:1) and evaluated through various in vitro, in vivo analyses. Results: The particle size of the optimized formulation was observed to be 19.04 nm and the polydispersity index (PDI) value was found to be 0.162 with steady-state zeta potential. The optimized liquid SMEDDS was converted into a solid SMEDDS. Various adsorbents, such as Aerosil-200, Avicel-PH101, Neusilin-US2, and Neusilin UFL2 were screened to better detect the oil-absorbing capacity and flow properties of the powder. Neusilin UFL2 was selected as an adsorbent due to its better oil-absorbing capacity. DSC, X-ray diffraction, and dissolution studies were carried out to characterize the formulation. Further, the Pharmacokinetic profile was also studied in Wistar rats and the Cmax, tmax, and AUC0→t were calculated. The Cmax and AUC0→t plasma concentration is considerably better for the SMEDDS than for the pure drug and marketed formulation. Conclusions: This investigation clearly reveals the potential of developing a solid SMEDDS for candidiasis and invasive aspergillosis treatment, with better efficacy as compared to the commercially available marketed formulation. Full article

With the development of offshore oil fields, the reservoirs of X oilfield in the west of the South China Sea are poor in physical property, serious in pollution, and increasingly prominent in interlayer contradictions. Water injection dilation technology has strongly affected the development of loose sandstone reservoirs. To explore whether this technology applies to the low-permeability sandstone of X oilfield in the west of the South China Sea and the dilation effect and radius of water injection dilation technology on the target reservoir, low confining pressure rock mechanics experiments and numerical simulation of water injection in this reservoir section are carried out. The triaxial shear experiment of low confining pressure shows that the target reservoir sandstone with low-permeability can have a shear strength of 45 MPa when the effective confining pressure is 0.5 MPa, and the target reservoir core can have dilatancy. When the axial strain is 2.5%, the core dilatancy is 1%, and the permeability changes by 1.17 times. It was found that the core volume dilation was obviously under low effective confining pressure, and the permeability is 2 orders higher than in the initial condition. The numerical simulation of the target reservoir shows that the bottom-hole pressure reaches 47.12 MPa at the end of water injection in typical wells. The reservoir was deformed to different degrees around the well, and the top layer was raised by 5.58 mm. This paper characterizes the rock expansion potential and expansion flow capacity of low-permeability sandstone reservoirs from multiple perspectives and establishes a three-dimensional, full-size wellbore formation crustal stress strict matching geological model for offshore expansion wells. We have provided theoretical guidance for on-site construction. Full article

The essential oil components of traditional Chinese medicine in-hospital preparation were complex, and one-dimensional chromatographic separation was difficult to completely separate them due to the limited peak capacity. This study was carried out to establish a comprehensive two-dimensional chromatographic separation and analysis method based on countercurrent chromatography (CCC) and gas chromatography (GC). In this paper, we focused on the separation of the essential oil of the traditional Chinese medicine in-hospital preparation Wenjing Tongluo San by CCC × GC, and explored the orthogonality between the two chromatographic techniques to provide the new technical support for the screening of the active ingredients. A solvent system composed of n-hexane-ethyl acetate-methanol-water (9.5:0.5:8.5:1.5, v/v) was chosen for the first-dimensional CCC separation. All the fractions collected from CCC were transferred to GC for plotting two-dimensional contours map. The calculated capacity of the two-dimensional separation system exceeded 3000, which was 8 times more than that of the one-dimensional separation system. High orthogonality (r = 0.42) and spatial coverage factor (70.42%) were obtained. Meanwhile, all the fractions were identified by GC-MS. Our research provided a new methodology for separating essential oils in traditional Chinese medicine as well as an approach for evaluating the quality of traditional Chinese medicinal in-hospital preparation based on two-dimensional chromatographic fingerprints. Full article

After transporting oil with a mobile pipeline, it is necessary to empty the oil within the pipeline. A common method is to inject water into the inlet to push the oil out. However, due to the effects of buoyancy and surface tension, the oil within the pipeline tends to accumulate at the elevated section, forming a stagnant oil layer, which will limit the evacuation efficiency. Based on the multiphase flow theory, a hydrodynamic model of oil–water flow was utilized to describe the pressure distribution and the thickness of the stagnant oil layer within the pipeline. A numerical model for oil-carrying water flow in a downward-inclined mobile pipeline was established, and the model was solved under given initial and boundary conditions to obtain the characteristics of the oil-carrying water flow within the pipeline. The calculation results indicate that the initial water phase velocity has a promoting effect on the oil-carrying capacity of water flow. The pipe diameter is negatively correlated with the capacity. The initial thickness of the oil is not directly related to the capacity but can increase the oil phase front velocity, which can enable the oil phase to be emptied more quickly. When the initial water phase velocity is lower than the critical water phase velocity, an increase in the inclination angle will weaken the capacity of water flow to carry oil. Conversely, when the velocity of the initial water phase is higher than the critical water phase velocity, an increase in the inclination angle will enhance the capacity. Full article