Search Results (521)

Rice straw is a highly produced agricultural waste with a high cellulose content, which can be used as a cellulose source. Nevertheless, more sustainable extraction and purification strategies are needed to reduce the consumption of chemicals during the production of cellulose-derived materials. In this way, an integrated method based on subcritical water extraction and bleaching with hydrogen peroxide was used for isolating cellulose from rice straw. The cellulose fibres obtained were converted into microcrystalline cellulose (MCC) by applying acid hydrolysis with HCl 2N at 60 °C to reduce the fibre amorphous fraction. High cellulose purity (86%) and crystallinity (67%) were obtained in the isolated fibres. The influence of high-shear homogenisation (12,000 rpm) during hydrolysis was analysed, compared to mild stirring (350 rpm) at different times (30 and 60 min). High-shear homogenisation greatly accelerated the hydrolysis process of the amorphous fraction of the fibres, contributing to the reduction in particle size (to about 10 µm), defibration, increased crystallinity (70–72%), and shorter cellulose chains (92,400–61,600 g/mol) for a given treatment time. After 30–60 min of treatment, the resulting MCCs exhibited properties within the range reported for commercial AVICEL, with greater reinforcing performance in PHBV films. These MCCs resulted in lower water vapour permeability, while improved oxygen barrier properties were mainly observed for those obtained under high-shear hydrolysis conditions. Full article

The construction sector plays a central role in global resource depletion and waste generation, with construction and demolition activities accounting for more than one-third of total waste produced in the European Union. Despite growing interest in circular construction, one of the major barriers to large-scale material reuse is the lack of reliable information on the type, quantity, location, and availability of secondary materials during the early stages of a project. The research addresses this gap between architectural design and planning decision-making by providing a replicable workflow for urban scale circular economy strategies. This study presents the application of a spatially explicit bottom-up Material Stock Analysis (MSA) to quantify and map the embedded materials within an urban district of Milan. The adopted methodology combines municipal GIS datasets, historical cartography, building archetype classification, and literature-derived material intensity coefficients. The result is the estimation of stock amounts disaggregated by material type and the creation of a secondary material cadaster, that allows us to visualize their distributions and generate material-specific spatial analyses and heat maps. Applied to the Porta Vittoria district in Milan, the workflow reveals that masonry accounts for over 66% of the total embedded mass, underscoring the need to factor the reuse of masonry and brick materials into the early design phases, from material selection to architectural concept. Ultimately, the study equips architects, urban planners, and policymakers with decision-support information to steer design and governance toward circular future cities. Full article

Additive manufacturing offers transformative opportunities but faces barriers due to costly, imported filaments. This study at Caraga State University, Cabadbaran Campus, developed a prototype automated filament extrusion system using recycled thermoplastics, specifically polypropylene (PP) and PET, to address material scarcity and plastic waste. Employing a developmental–descriptive design, the system integrated heating, extrusion, spooling, and microcontroller-based controls. Results confirmed functional capability, producing filaments with acceptable dimensional consistency, though challenges in accuracy and flexibility remain. The project advances sustainable, affordable 3D printing, supports circular economy principles, enhances technical education, and empowers local innovators toward inclusive, environmentally responsible manufacturing. Full article

Food loss and waste—FLW—represent a critical global challenge, primarily across postharvest handling, storage, and distribution. Shelf life limitations—arising from microbial activity and proliferation, physicochemical degradation, and environmental interactions—are major contributors to these losses. Intrinsic factors such as pH, water activity, nutrient composition, and biological structure interact with extrinsic conditions including temperature, humidity, gaseous atmosphere, and light exposure, ultimately leading to quality deterioration and consumer rejection. A comprehensive insight into these mechanisms is essential to improve preservation strategies and reduce FLW. This review critically examines the determinants of food shelf life and highlights the strategic role of innovative packaging technologies in mitigating degradation pathways. Particular emphasis is placed on active packaging systems, including commonly studied technologies such as oxygen and ethylene scavengers, carbon dioxide emitters and absorbers, moisture regulators, antimicrobial- and antioxidant-releasing materials, and flavor and odor control systems. Their mechanisms of action, material design, performance factors, and practical limitations are discussed. Innovative packaging technologies actively modulate spoilage, extend shelf life, and preserve both sensory and nutritional quality, moving beyond conventional passive barriers. When combined with optimized supply chains and sustainable materials, these systems can strengthen food system stability and advance global sustainability goals. Full article

Magnesium hydroxide is attracting growing interest as a versatile, halogen-free flame retardant, and this review surveys its production routes, structure–property relationships and use in polymer systems from commodity polyolefins to advanced bio-based materials. Industrial Mg(OH)₂ is still predominantly obtained from mining or hydration of MgO, but increasing attention is being devoted to recovery from seawater and saltwork brines, where precipitation from Mg²⁺-rich streams followed by controlled rehydration or direct precipitation yields fine, high-purity powders suitable for flame retardant use and simultaneously valorizes saline wastes. In parallel, hydrothermal synthesis has been extensively explored to tailor particle size and morphology by adjusting the precursor, solvent, temperature and time, enabling high-surface-area Mg(OH)₂ or MgO with narrow size distributions that are attractive for high-performance composites also evaluated via ball milling, crushing and refining. More recently, process intensification strategies such as microwaves and ultrasounds have been proposed to shorten reaction times, lower temperatures and better control nucleation and growth, opening paths toward energy efficient production of structured Mg(OH)₂ from both conventional and brine-derived precursors. The second part of the review analyzes how the intrinsic endothermic decomposition and basic character of Mg(OH)₂ can be utilized across a broad range of polymer matrices and how surface functionalization strategies extend its applicability. In addition to “as received” powders, stearic acid and other fatty acids, metal soaps and various organic coupling agents are widely used to render the surface more hydrophobic, enhance dispersion and interfacial adhesion, and in some cases introduce additional char-forming or barrier functionality. In terms of the application, the review methodically synthesizes and contrasts fire and mechanical data for Mg(OH)₂-containing polyolefins (HDPE, LLDPE, PP and EVA) utilized in cables and building products, expandable polymers and foams, biopolymers (PLA and PBS), and elastomers. The review places particular emphasis on the balance between loading level, processability, flame performance and mechanical integrity. This review aims to provide a comprehensive framework for designing next-generation Mg(OH)₂-based flame-retardant systems for both conventional and emerging polymer technologies. To this end, it integrates advances in sustainable feedstocks, controlled synthesis and surface engineering with the rapidly expanding application space. Full article

Achieving a circular and climate-neutral bioeconomy by 2050 requires not only high-quality recycling but also the large-scale integration of renewable carbon from biomass and atmospheric CO₂ into material systems. Plastics represent the world’s largest and most rapidly growing carbon sink, positioning them as a critical intervention point for replacing fossil-based feedstocks with renewable alternatives. Because plastic packaging is one of the most visible material streams encountered by consumers in daily life, a transition toward sustainable, recyclable bioplastics has the potential to deliver both meaningful environmental benefits and strong societal impact, accelerating public awareness and acceptance of renewable carbon solutions. Poly(ethylene furanoate) (PEF)—a fully bio-based polyester synthesized from plant-derived 2,5-furandicarboxylic acid (FDCA) and monoethylene glycol (MEG)—offers a promising pathway toward more sustainable packaging due to its superior mechanical strength and gas-barrier performance relative to polyethylene terephthalate (PET). This study presents a cradle to grave life cycle assessment (LCA) of PEF resin production and PEF bottle applications, using industrially relevant, at-scale process data covering biomass feedstock conversion, polymer synthesis, packaging manufacture, use phase, and end of life. Bottle applications were selected as a focal point due to their technical maturity, commercial relevance, and suitability for direct comparison with incumbent PET systems. The results indicate that PEF can reduce greenhouse gas emissions by up to 71% and fossil resource depletion by 26% compared to PET at the resin level when biogenic carbon uptake is included. Moreover, the material’s enhanced functional properties enable lightweight, recyclable bottle designs with carbon footprint reductions of up to 88% for 500 mL formats under a baseline recycling rate scenario of 72%, with the remaining share directed to municipal solid-waste incineration with energy recovery. Sensitivity analyses reveal that virgin PEF maintains environmental advantages over PET even when PET incorporates high levels of recycled content, highlighting the complementary roles of renewable carbon and circular material strategies. Prospective scenario modeling underscores the importance of sustainable feedstock selection and process electrification, with sucrose-based routes offering the largest potential for further decarbonization. Overall, the findings demonstrate that PEF is a scalable biopolymer capable of delivering substantial climate benefits while supporting circularity objectives. By targeting a highly visible consumer application—plastic packaging—this transition amplifies the societal impact of adopting renewable carbon materials. The study provides actionable insights for policymakers, industry stakeholders, and sustainability practitioners working to advance a more resilient, renewable, and consumer-recognizable plastics economy. Full article

Traffic noise adversely affects residents near expressways, calling for sustainable noise mitigation solutions. This study developed three eco-friendly sound-absorbing panels from sand, industrial slag, and microporous ceramics. By optimizing aggregate gradation, the influence of porosity and flow resistivity on absorption coefficients was analyzed to determine optimal mix ratios. The panels were integrated into perforated metal noise barriers and evaluated through reverberation room and sound insulation tests. Field simulations using SoundPLAN for a residential project in Taizhou validated real-world performance. Results showed that slag panels achieved a Noise Reduction Coefficient (NRC) of 0.70, while sand and ceramic panels both reached 0.55. All configurations maintained a weighted sound reduction index (R_w) of 25–26 dB. Empirical simulations confirmed that a 2.5 m high barrier keeps noise levels within the 60 dB limit. Compared with traditional glass wool, these inorganic panels offer comparable noise reduction, superior non-combustibility, and better weather resistance, making them effective for frequency-specific noise control in urban engineering applications. Full article

The dramatic increase in the volume of postconsumer textile waste poses not only a major environmental problem but also an untapped opportunity for the development of sustainable infrastructure through the use of synthetic and composite textile waste-derived materials (SCTWDMs) in the field of asphalt pavement engineering, contributing to the achievement of the United Nations Sustainable Development Goals (SDGs 9, 11, 12, and 13). This systematic review was performed according to the PRISMA (Preferred Reporting Items for Systematic Reviews and Meta-Analyses) guidelines. A systematic search of the literature in the field of SCTWDMs in asphalt pavement engineering was performed between 2010 and 2025 using the Web of Science and Scopus databases. A total of 65 studies were identified and analysed according to the inclusion and exclusion criteria of the current review. The quality of the studies and the risk of bias were assessed according to the transparency of the methods and the reporting of the results. The triangulated methodological framework consisted of bibliometric analysis, systematic review, and SWOT analysis. The bibliometric analysis was carried out via VOSviewer software version 1.6.20. The results of this study indicate an increase in the number of publications in SCTWDMs; however, there is fragmentation in the field. This denotes poor interrelationships among themes, insufficient collaboration across research streams, and scattered networks of keyword associations, suggesting a lack of a coherent research framework for SCTWDM research. The results of this study indicate that SCTWDMs generally improve the rheological properties, cracking resistance, and mechanical characteristics of asphalt mixtures. However, variability in fibre properties, optimisation of dosage, and limited field validation remain major challenges in SCTWDMs. The SWOT analysis also highlights important technical, institutional, and standardisation barriers, as well as opportunities for further development in sustainable pavement technologies. Despite this, the body of evidence is limited by heterogeneity in study design and a lack of long-term results. The review is not preregistered, but all the methodological procedures are transparently described. In conclusion, this body of evidence offers a strategic direction for further research, policy development, and industry practice, highlighting the importance of linking laboratory results to applications to position SCTWDMs as a viable option within the global sustainability agenda. Full article

The article is devoted to the study of the properties of the obtained heat-insulating refractory materials, based on fireclay scrap of various fractions (2.5 mm, 1.0 mm, 0.5 mm, and 0.1 mm) using a complex of mineral and oxide additives. The fillers used were titanium dioxide powder and silicon production wastes, which included microsilica powder, aluminum oxide, zinc oxide, zirconium oxide, chromium oxide, iron oxide, cement, lime, and baking soda. The choice of these fillers was due to the fact that they initially have corrosion resistance. Liquid glass acted as a binder. The resulting thermal barrier material was tested to determine its physical and mechanical properties, namely, thermal conductivity, porosity, compressive strength, and microstructure. According to the obtained results for the physical and mechanical properties, the secondary refractory material had properties close to GOST. So, according to GOST 12170-2021, the thermal conductivity values of the obtained materials were included in the 0.03–15.0 W/(m·K) range. The porosity values of the obtained samples complied with GOST 2409-2014 and were not more than 30%. The maximum compressive strength was 171.31 kgf/mm². The microstructure of the material of the obtained samples was very porous, and the pores were evenly distributed throughout the volume, which is extremely important for heat-insulating materials. A distinctive feature of the technology was the absence of a high-temperature firing stage: the required physical and mechanical properties of the material were achieved when heated to 180–300 °C with subsequent slow cooling in the furnace, which significantly reduces energy consumption compared to traditional refractory technologies. The use of waste from the production of chamotte scrap and microsilica will help to reduce negative impacts on the environment, save natural resources, and expand the raw material base. Full article

Research on edible and biodegradable film packaging (EBFP) has increased significantly to explore sustainable alternatives to synthetic packaging and mitigate its environmental impacts. Biomaterials extracted from agricultural food waste (AFW) may be utilized for the fabrication of EBFP as an alternative packaging for meat and meat products. The focal point of this review is to explore the potential AFW biomaterials and bioactive compounds available in industry, and their utilization techniques for fabricating EBFP with ideal mechanical parameters suitable for use as a packaging material. Moreover, research studies have been summarized related to EBFP’s efficacy on meat shelf life, physicochemical, oxidative, and microbial qualities during storage experiments. EBFP fabricated with AFW biomaterials, such as proteins, carbohydrates, essential oils, and bioactive compounds, exhibits favorable film-forming capacity, mechanical properties, barrier properties, biodegradability, and synergy with meat. Latest advances in the application of AFW biomaterials and bioactive compounds based on EBFP for meat packaging are directed toward novel fabrication processes such as electrospinning, solvent casting, and combination of both to produce a hybrid film, which markedly improves the mechanical and barrier properties. Moreover, including bioactive materials from AFW enhances the antioxidant and antimicrobial properties of EBFP to combat the oxidative rancidity and bacteria, fungi, and molds in meat to prolong shelf life. Incorporation of AFW biomaterials and bioactive compounds has improved the intelligent properties of EBFP, which has been effectively used in meat packaging to detect freshness and spoilage of meat through color and pH changes. Full article

Rising environmental concerns have intensified interest in waste valorisation and the development of sustainable, bio-based materials through green chemistry approaches. In this study, proteins extracted from waste lentil and chickpea seeds were used to develop protein-based films using a range of carboxylic acids as cross-linkers. The acids facilitated protein unfolding and promoted intermolecular interactions, allowing tunable control over mechanical strength, barrier performance, and water resistance. In addition to their structural role, the inherent bioactivity of selected carboxylic acids imparted added functionality to the resulting materials. Physical characterisation and FTIR secondary structure analysis revealed that the acid-type, plasticiser, and, in some cases, protein fraction composition influenced the final material performance. Liquid monocarboxylic acids produced cohesive and flexible films, with tensile strength ranging from ~1 to 23 MPa, with formic acid yielding the strongest films. Lactic acid and its blends improved flexibility and reduced permeability, achieving water vapour permeability (WVP) of 5.76 ± 0.7 × 10⁻¹² g m m⁻² s⁻¹ Pa⁻¹ and oxygen permeability (OP) of 5.8 ± 0.0 × 10⁻¹³ mL m m⁻² s⁻¹ Pa⁻¹ at low acid loadings. In contrast, solid di- and polycarboxylic acids tended to crystallise at higher concentrations. Citric acid was an exception, exhibiting behaviour distinct from the other solid acids and producing clear, crystal-free films with excellent flexibility, showing elongation at break (EAB) up to ~326%. Preliminary proof-of-concept application testing demonstrated the suitability of selected films for vegetable shelf-life extension for up to 17 days and for gradual lactic acid release, supporting their potential use as biodegradable cosmetic mask/patch platforms. Full article

The problem of industrial waste disposal is becoming increasingly pressing. For a long time, one of the primary methods of managing hazardous industrial waste was to dispose of it for long periods (decades) in engineered landfills. However, over time, due to various climatic, geological, and other changes, landfills begin to cause significant harm to the environment and human health. Old landfills, many built in the mid-20th century, pollute the air, soil, and groundwater. Therefore, the issue of decommissioning “old” landfills is becoming increasingly pressing. This study aimed to develop technological solutions for the safe extraction and processing of hazardous liquid waste from an aged industrial landfill. An integrated treatment chain was designed, comprising extraction, multi-barrier water treatment, vacuum evaporation, and lithification. Optimal lithification compositions were identified: for the salt concentrate–sludge–spent media mixture, a ratio of 68.2% sorbent D, 28.0% salt concentrate, and 3.8% dewatered sludge/spent media yielded a loose granular geocomposite; for oil-containing waste, the optimal ratio using lime and opoka was 1:0.9:0.5 (bottom sediments/CaO/opoka). Biotesting confirmed that the lithified waste is Hazard Class V (non-hazardous), whereas the untreated waste is Class III (moderately hazardous). The resulting geocomposite is suitable for on-site technical reclamation, closing the material cycle. Full article

Construction and demolition waste (CDW) constitutes the largest single waste stream in the European Union by weight, yet the EU’s circular material use rate remains low, at around 12%, indicating substantial distance from policy ambitions for circular resource use. This paper presents a systematic narrative review of the literature on circular economy integration in CDW management, with a focus on the EU context. The review pursues three objectives: (i) to critically assess the gap between reported CDW recovery performance and genuine material circularity; (ii) to systematically identify and analyse persistent barrier domains to circular economy adoption in CDW management; and (iii) to evaluate the potential of digital and governance-oriented innovations to address these barriers. The review scope is explicitly delimited to the EU regulatory and institutional context, drawing on a corpus of 42 sources identified through systematic Scopus searches. The review identifies five persistent barrier domains—legal, technical, social, behavioural, and economic—with regulatory fragmentation and secondary material devaluation as the most structurally entrenched. Apparent compliance with the 70% recovery target under Directive 2008/98/EC conceals widespread downcycling and inconsistent reporting. A decisive paradigm shift is observed in recent research, from material characterisation towards systemic circularity, digital demolition frameworks, and governance. Emerging technologies—including AI-enabled sorting, Building Information Modelling, Digital Twins, and Digital Product Passports—offer significant potential to enhance material traceability, recovery quality, and decision-making across the CDW value chain. However, technological innovation alone is insufficient, Design for Deconstruction remains an underutilised upstream strategy, and lasting progress depends on coherent regulatory frameworks, institutional coordination, and market conditions that support circular practices. Future research should therefore focus on governance mechanisms, longitudinal performance assessment, and the scalability of digitally enabled circular solutions. Full article

The rapid accumulation of plastic waste has become a major environmental concern, while at the same time, it is necessary to create opportunities to rethink how these materials can be reintegrated into productive use, particularly within the construction sector. This study provides a sustainability-oriented review of the reuse of plastic waste, both fossil-based plastics and bioplastics, as building materials, with a specific emphasis on structured decision-support approaches. A systematic literature review was conducted to identify and analyze peer-reviewed studies examining the incorporation of plastic waste into construction applications, including composites, panels, insulation systems, and structural or non-structural components. Particular attention is given to research applying Multi-Criteria Decision Analysis (MCDA) and SWOT analysis as tools for evaluating sustainability performance across environmental, economic, technical, and social dimensions. The findings indicate that recycled plastic and bioplastic-based construction materials can deliver significant advantages, such as diverting waste from disposal pathways, reducing reliance on virgin resources, and, in certain cases, enhancing durability. However, these materials also face important challenges, including limitations in recyclability, concerns related to fire performance, regulatory acceptance, and uncertainties in end-of-life management. MCDA-based studies underscore the critical role of criteria selection and weighting, especially regarding environmental impact reduction and cost competitiveness, in shaping final rankings and decision outcomes. SWOT analyses, in turn, offer complementary strategic insights by highlighting issues related to market readiness, regulatory frameworks, and implementation barriers. By integrating these decision-oriented evaluation approaches, this review contributes to more transparent and evidence-based material selection processes and supports policy development aimed at strengthening circular economy strategies for plastic waste reuse in the built environment. Full article

The transition toward sustainable food packaging requires the integration of biodegradable materials with functional bioactivity. Chlorogenic acid (CGA), a naturally abundant polyphenol, has emerged as a multifunctional compound with the capacity to simultaneously modulate polymer structure and impart active and intelligent functionalities. This review critically examines recent advances in CGA-containing packaging systems, covering fabrication strategies from physical incorporation and chemical grafting to nanostructured and stimuli-responsive architectures. The analysis reveals that CGA plays a dual role. At the molecular level, it regulates the polymer network structure through hydrogen bonding, covalent interactions, and conformational rearrangement. This, in turn, influences mechanical strength, barrier performance, and optical properties. Functionally, CGA provides antioxidant and antimicrobial activity, although its effectiveness depends strongly on the incorporation strategy and concentration. Notably, nanostructured systems and conjugation approaches enable controlled release and enhanced stability. These methods overcome limitations associated with rapid diffusion and environmental degradation, including oxidation, UV exposure, and pH-related instability. Despite these advances, key challenges remain, including CGA instability, uncontrolled release behavior, and limited regulatory and scalability data. Furthermore, while CGA is well established in active packaging, its application in intelligent systems remains limited in the literature, with only a few studies reported on its intelligent applications. Overall, this review highlights the structure–function relationships governing CGA-containing packaging systems and outlines future directions for the rational design of cost-effective, scalable, and multifunctional packaging systems, positioning CGA as a promising component in sustainable strategies for food preservation and waste reduction. Full article