Search Results (8,127)

As modern urban systems advance, video surveillance has become indispensable for ensuring high-quality urban development. Nighttime images acquired in urban monitoring scenarios are often degraded by haze and non-uniform illumination, resulting in reduced visibility, color distortion, and blurred structural boundaries. To address these issues, this paper proposes a nighttime image dehazing framework that combines mixed-norm variational atmospheric-light estimation with adaptive boundary-constrained transmission refinement. Specifically, an  L₂ − L_p mixed-norm regularization model is introduced to improve atmospheric-light estimation under complex nighttime illumination and suppress halo diffusion and color distortion around strong light sources. In addition, an adaptive boundary-constrained transmission refinement strategy with weighted soft-threshold shrinkage is developed to reduce residual artifacts while preserving structural edges. Experimental results on synthetic and real nighttime haze datasets demonstrate that the proposed method consistently outperforms representative state-of-the-art methods in both visual quality and quantitative metrics, showing superior robustness and restoration performance for nighttime urban monitoring applications. Full article

TiO₂ is normally a preferred photocatalyst; however, its photocatalytic performance is constrained by its low surface area, wide band gap, and high electron–hole pair recombination rates. The objective of this study was to optimize the photocatalytic efficiency of TiO₂ by impregnating it onto activated carbon derived from Senegalia mellifera biomass. The quantitative study involved synthesizing TiO₂ using the precipitation technique and preparing AC through both chemical and physical activation methods. The prepared AC samples were impregnated with TiO₂ NPs using the wet impregnation method. The physicochemical properties of the samples were examined using several characterization techniques, namely, FTIR, EDS, Raman, UV reflectance, STA, SEM, and BET. The photocatalytic efficiency of AC/TiO₂ composites was evaluated through methyl orange degradation. The results showed significant improvement in photocatalytic performance when TiO₂ was supported on AC. The modified photocatalyst exhibited enhanced surface area, thus increased active sites for photocatalysis, improving electron–hole separation and reducing recombination. The 50%CO₂/AC-0.5TiO₂ composite demonstrated superior photocatalytic activity under both UV and visible light irradiation. It showed 52.1% MO removal under visible light and 76.1% MO removal under UV light. The study concludes that biomass-derived AC/TiO₂ composites present a promising, cost-effective and sustainable approach of enhancing photocatalytic activities. Full article

The increasing prevalence of antimicrobial resistance, together with recurring infectious disease outbreaks, has intensified the need for alternative strategies to control microbial infections beyond conventional antibiotic therapies. Antimicrobial photodynamic therapy has emerged as a promising non-antibiotic approach in which light-activated photosensitising compounds generate reactive oxygen species that induce oxidative damage to microbial cells. Plant-derived photosensitisers have attracted increasing attention due to their structural diversity, biocompatibility, natural abundance, and potential for sustainability. Natural compounds such as curcumin, hypericin, chlorophyll derivatives, flavonoids, anthraquinones, and riboflavin exhibit favourable photochemical properties that enable efficient production of reactive oxygen species upon irradiation with visible light. Through radical- and singlet-oxygen-mediated photochemical pathways, these molecules exhibit broad-spectrum antimicrobial activity against bacteria, fungi, viruses, and biofilm-associated microorganisms. This review examines the photophysical properties and mechanisms of reactive oxygen species generation associated with plant-derived photosensitisers, together with key factors influencing their antimicrobial performance. Recent advances in nanocarrier-based delivery systems, dual-wavelength activation strategies, and synergistic combination therapies are also discussed for their potential to improve photostability, enhance reactive oxygen species generation, and increase microbial inactivation efficiency. Finally, current progress, challenges, and future research directions for advancing plant-derived photosensitisers in antimicrobial photodynamic therapy are discussed. Full article

With the advent of 6G mobile communication, the demand for ultra-high bandwidth wireless communication has increased rapidly, drawing significant attention to visible light communication (VLC) as a promising emerging technology. GaN-based laser diodes (LDs) are regarded as high-speed light sources for VLC owing to their high modulation bandwidth and high optical power density. Apart from the active region design, the LD’s structure also plays a crucial role in determining their dynamic properties, which have yet to be thoroughly studied in III-nitride LDs. In this work, we systematically investigate InGaN/GaN laser diodes with three ridge waveguide configurations: a conventional single-ridge structure, a dual-ridge large-mesa structure, and a dual-ridge small-mesa structure. The threshold current, small-signal modulation bandwidth of devices with different structures are comparatively analyzed. Experimental results reveal that the double-ridge small mesa laser diode achieves a modulation bandwidth of −3 dB at 6.02 GHz. These results provide valuable insights into the structural optimization of GaN-based high-speed laser diodes and offer practical guidance for the development of high-performance, energy-efficient VLC transmitters. Full article

Bismuth oxychloride (BiOCl) has garnered significant research interest owing to its non-toxicity, affordability, and distinct layered structure. Although BiOCl possesses promising photocatalytic potential, its large band gap and rapid photocarrier recombination restrict its practical use. In this work, a natural tourmaline mineral was effectively integrated with BiOCl to form a composite (TBO). Comprehensive characterization and photocatalytic assessments revealed that the intrinsic electric field of tourmaline notably strengthened both the adsorption capacity and the light-driven catalytic efficiency of BiOCl. Under visible-light irradiation, ofloxacin (OFX, 10 ppm) was eliminated by approximately 98% within 60 min. The apparent reaction rate constant (k) of TBO was 0.0407 min⁻¹, which was approximately 184.8 and 2.26 times those of tourmaline alone and pristine BiOCl, respectively. Furthermore, both the visible-light absorption and the separation efficiency of photogenerated electron–hole pairs were significantly enhanced. After evaluating its behavior under various simulated natural environmental conditions, TBO displayed strong potential for practical application. Reactive species trapping and analysis identified singlet oxygen (¹O₂) and superoxide radicals (·O₂⁻) as the primary active species in photocatalysis. Moreover, the degradation route of ofloxacin and the toxicity of its intermediates were systematically examined. These findings offer meaningful guidance for improving photocatalytic materials by utilizing naturally occurring minerals. Full article

Background/Objectives: Carbon dots (CDs) are promising antimicrobial nanomaterials owing to their biocompatibility, environmental friendliness, and tunable surface chemistry. This study aimed to synthesize nitrogen-doped CDs (AS-CDs) and develop a light-responsive antibacterial system through conjugation with chlorin e6 (Ce6). Methods: AS-CDs were synthesized by a microwave-assisted method using L-ascorbic acid and spermidine, followed by conjugation with Ce6. The materials were characterized by transmission electron microscopy, zeta potential analysis, and spectroscopic methods, and their antibacterial activity was evaluated against Escherichia coli, Staphylococcus aureus, and methicillin-resistant S. aureus (MRSA) under both dark and visible-light conditions. Cytotoxicity was assessed using HaCaT cells. Results: The AS-CDs exhibited a uniform nanoscale morphology with an average diameter of 6.3 nm and a positive surface charge of +15.6 mV, together with intrinsic broad-spectrum antibacterial activity. Ce6 conjugation further enhanced antibacterial efficacy under light irradiation, with the CDs-Ce6 conjugate achieving complete eradication of S. aureus and MRSA and marked inhibition of E. coli at 2.5 μg/mL. Cytotoxicity studies demonstrated low toxicity in HaCaT cells within the effective antibacterial concentration range. Conclusions: These findings highlight the potential of microwave-synthesized, photosensitizer-conjugated CDs as next-generation antimicrobial agents. This platform offers a cost-effective, sustainable, eco-friendly, and efficient platform for combating bacterial infections, with broader potential in pharmaceutical and biomedical applications. Full article

Background: In rehabilitation medicine, efficient gait analysis is crucial for evaluating postoperative recovery and frailty, especially given the increasing burden on clinicians due to an aging population. Objectives: This study aims to conduct preliminary validation of an automated linear walking evaluation system using 2D AI posture tracking. By evaluating the basic accuracy of the system on healthy individuals, we aim to establish a technical foundation for future introduction into clinical rehabilitation settings. Methods: In this observational study, we utilized a standard visible light camera for practical use. To evaluate accuracy, we compared 2D AI tracking against a gold-standard three-dimensional (3D) motion capture system during normal walking trials with 10 healthy participants. Specifically, we employed Dynamic Time Warping (DTW) to temporally align the asynchronous data streams from the 2D and 3D systems, ensuring precise comparison of joint angles. Results: Following the DTW-based alignment, the similarity with the 3D system was 0.806 ± 0.094 overall (Left: 0.797 ± 0.101, Right: 0.814 ± 0.086). Conclusions: In this preliminary validation, the proposed 2D AI posture tracking showed good agreement with the gold standard 3D motion capture for gait in healthy individuals. While the average systematic bias was within clinically acceptable limits, the observed limits of agreement suggest that this system is currently optimal as a foundational tool for gait screening. These results establish a technical foundation for the clinical application of this system. Full article

Environmental contamination by persistent industrial dyes such as Amido Black demands highly efficient photocatalysts for advanced water treatment. Structural, chemical, and optical strategies based on TiO₂ nanotube engineering are widely explored for this purpose. In this work, highly ordered TiO₂ nanotube arrays were fabricated by electrochemical anodization and subsequently decorated with Pd nanoparticles via potentiostatic electrodeposition (10–300 s), enabling precise control of Pd nanoparticle size and loading. The resulting materials were systematically characterized by SEM, TEM, XRD, XPS, UV–vis DRS, and PL spectroscopy, and their properties were correlated with the photocatalytic degradation of Amido Black under both UV and visible light irradiation. The study reveals a clear size-dependent duality in the role of Pd. For intermediate Pd nanoparticles (≈9 nm, 20 s), Pd behaves predominantly as an electron sink, forming an efficient Schottky junction with anatase TiO₂ that markedly suppresses charge carrier recombination. This configuration yields ≈ 97% Amido Black removal after 120 min of UV irradiation, with an apparent rate constant about three times higher than that of bare TiO₂ nanotubes. In contrast, for ultra-small Pd nanoparticles (≈6 nm, 10 s), interfacial defect states sensitize TiO₂ to visible light, enabling ≈ 65% degradation after 270 min and a rate constant roughly four times higher than that of undecorated nanotubes under visible illumination. At long deposition times (≥150 s), Pd agglomeration leads to enhanced photoluminescence and markedly reduced photocatalytic activity, indicating increased recombination and less effective utilization of photogenerated charges. This provides a practical design rule to rationally tailor Pd–TiO₂ nanotube photocatalysts for targeted UV or visible light applications in dye removal and broader environmental remediation scenarios Full article

The Pushbroom Imager for Cloud and Aerosol Research and Development (PICARD) visible through shortwave infrared imaging spectrometer was developed to carry a calibration laboratory environment to high altitudes, while also providing high-dynamic-range bright cloud-top radiance measurements across a field of view just under 50 degrees. The in-flight performance of this new spectroradiometer was validated in comparison to multiple reference data sources and targets using imagery collected aboard NASA’s ER-2 high-altitude aircraft during the Western Diversity Time Series (WDTS) airborne science campaign in April 2023 and the September 2024 Plankton, Aerosol, Cloud, and ocean Ecosystem (PACE) Postlaunch Airborne eXperiment (PACE-PAX), both operating out of southern California. PICARD measurements from flights over Railroad Valley Playa, Nevada, USA, were compared to high-resolution radiance spectra of the dry lakebed provided by the Radiometric Calibration Network (RadCalNet) Working Group. Direct comparison to satellite cloud radiometry was enabled by the ER-2 flying in coordination with simultaneous overpasses of the Terra, Aqua, and NOAA-20 Earth-observing satellites during WDTS and with the PACE observatory during PACE-PAX. To account for large spectral differences between incandescent laboratory sources and solar illumination, PICARD calibration relies on measurements using the Goddard Laser for Absolute Measurements of Radiance (GLAMR) to characterize and minimize spectral stray light from the instrument’s twin Offner grating spectrometers. Good agreement in comparison to reference measurements demonstrates PICARD’s ability to provide imagery for environmental science or for testing new sensor designs and retrieval algorithms for cloud and aerosol research with verified laboratory calibrations at high altitudes. Full article

9-Mesitylacridinium salts are widely recognized as efficient organic photoredox catalysts owing to their strong excited-state oxidizing power and stability under visible-light irradiation. In this study, a new mesityl acridinium derivative bearing a di-tert-butylphenyl substituent on the nitrogen atom was synthesized. The introduction of tert-butyl groups on the N-aryl moiety was primarily aimed at improving solubility and chemical stability of the acridinium salt. Starting from a 9(10H)-acridinone precursor, the target compound was obtained in high overall yield through a concise synthetic sequence. The synthesis consists of a copper-catalyzed C–N coupling reaction to install the aryl substituent on the nitrogen atom, followed by a Grignard reaction and subsequent acid treatment to afford the corresponding acridinium salt. All transformations proceeded smoothly, providing efficient access to the desired novel acridinium derivative. This work presents a practical example of the structural modification of mesitylacridinium derivatives directed toward enhanced solubility and stability, and provides a useful synthetic platform for the preparation of structurally diverse acridinium salts. Full article

Advanced oxidation processes based on photo-Fenton chemistry have gained increasing attention as effective treatment alternatives for the removal of pharmaceutical contaminants from water and wastewater systems. However, large-scale implementation remains constrained by operational requirements, limited mineralization efficiency, and challenges associated with process stability and selectivity. This review provides a critical assessment of recent advances (2022–2025) in conventional photo-Fenton and hybrid systems, including photocatalysis/photo-Fenton and sono-photo-Fenton processes, with emphasis on their performance in water and wastewater treatment applications. The removal of non-steroidal anti-inflammatory drugs, antibiotics, pharmaceutical mixtures, and real wastewater matrices is analyzed considering catalyst configuration, irradiation sources, oxidant utilization, and operating conditions relevant to practical treatment scenarios. Conventional homogeneous Fe²⁺/H₂O₂ systems enable rapid contaminant degradation but typically require acidic conditions and show limited mineralization efficiency. In contrast, iron-complexed and heterogeneous catalysts allow operation under near-neutral pH and visible-light irradiation, improving applicability in realistic water treatment systems. Hybrid photocatalysis/photo-Fenton processes enhance treatment efficiency through synergistic generation of reactive oxygen species, while ultrasound-assisted systems further intensify oxidation rates and contaminant removal. Special attention is given to oxidation mechanisms, catalyst stability, transformation products, and toxicity evolution to identify the key factors controlling treatment performance. Finally, current technological limitations, operational challenges, and design considerations for process integration, scale-up, and sustainable implementation in water and wastewater treatment are discussed. Full article

Ship detection in remote sensing imagery serves as a cornerstone of modern maritime surveillance. Existing visible light detectors suffer from severe performance degradation in adverse environmental conditions (e.g., fog, low light) due to domain gaps. Traditional global enhancement methods often lack adaptability, leading to “negative transfer”—where artifacts are introduced into clean images or mismatched with degradation types. To address these challenges, we propose CLEAR (Cognitive Large Language Model (LLM)-Empowered Adaptive Restoration) framework. Inspired by the dual-process theory of cognition, we introduce a dynamic switching mechanism between fast perception and deep reasoning. Rather than processing all images indiscriminately, it utilizes a hybrid gating mechanism to efficiently filter nominal samples, triggering Vision–Language Model (VLM) only when necessary to diagnose degradation and dispatch targeted restoration operators. Extensive experiments on the constructed HRSC-Robust dataset demonstrate that CLEAR achieves an overall mean Average Precision (mAP) at 0.5 Intersection-over-Union (IoU) of 86.92%, outperforming the baseline by 7.74%. Notably, it establishes a “fail-safe” mechanism for optical degradations. By adaptively resolving fog and low-light, it effectively mitigates detector blindness—exemplified by a doubled Recall rate (52.52%) in dark scenarios. Furthermore, a confidence-based sparse triggering strategy ensures operational efficiency, maintaining a throughput of ~11.8 FPS in nominal conditions. This work validates the potential of VLMs for interpretable and robust remote sensing tasks. Full article

Parameters of reflected light, measured in narrow or broad spectral bands, are widely analyzed for remote and proximal sensing of plant responses to stressors. Specifically, parameters of reflectance in red (R), green (G), and blue (B) spectral bands measured using simple color images can be sensitive to characteristics of plants. The conventional view is that RGB reflectance primarily reveals long-term changes in plants (days, weeks, etc.). In this study, we investigated light-induced changes in RGB reflectance in wheat (Triticum aestivum L.) and pea (Pisum sativum L.) leaves. Illumination increased this reflectance for about 10 min in wheat and about 15–20 min in pea; these changes relaxed after light intensity was decreased. The changes in RGB reflectance were strongly related to the effective quantum yield of photosystem II and non-photochemical quenching of chlorophyll fluorescence under high light intensity; these relations were absent under low light intensity. We hypothesized that changes in both RGB reflectance and photosynthetic parameters were related to the light-induced changes in chloroplast localization. A simple mathematical model of optical properties and photosynthesis in leaves was developed; results of the model-based analysis supported the proposed hypothesis. Experimental analysis of the dynamics of light transmittance additionally supported this hypothesis. Our results thus show that RGB imaging can be sensitive to fast changes in plants. Full article

In this study, TiO₂ nanoparticles (NPs), CdS NPs and TiO₂/CdS nanocomposite were synthesized via the sol–gel, hydrothermal and ex situ method, respectively. The synthesized materials were characterized using XRD, UV–vis DRS, FTIR, SEM, and EDX analysis. XRD analysis confirmed the crystalline structure of the as-prepared samples, while the bandgap energy of TiO₂ NPs, CdS NPs, and TiO₂/CdS nanocomposite were determined to be 2.98, 1.94, and 2.27 eV, respectively. Photocatalytic efficiency of TiO₂ NPs, CdS NPs, and TiO₂/CdS nanocomposite was systematically evaluated by photocatalytic degradation of crystal violet (CV) dye under visible-light irradiation. Under optimized reaction conditions of [CV concentration] = 20 mg/L, [catalyst dosage] = 0.25 g/L, and pH = 6, TiO₂/CdS nanocomposite achieved 86.3% removal of CV within 180 min, outperforming pure TiO₂ NPs (16.4%) and CdS NPs (66.9%). The enhanced performance of TiO₂/CdS nanocomposite as compared to CdS NPs is attributed to improved charge separation via heterojunction formation, while significantly superior performance over TiO₂ demonstrates successful visible-light activation. Further optimization study revealed that maximum removal efficiency of CV (97.1%) was achieved at lower dye concentration (10 mg/L). Photocatalytic degradation of CV followed pseudo-first-order kinetics. Moreover, scavenger experiments confirmed hydroxyl radicals (^•OH) as dominant reactive species. Furthermore, the TiO₂/CdS nanocomposite demonstrated good reusability with minimal activity loss after five runs. Additionally, the as-prepared nanocomposites showed significant antibacterial activity against Pseudomonas aeruginosa (P. aeruginosa). The present study indicated that TiO₂/CdS nanocomposite could be simultaneously used for degradation of organic pollutants as well as for removal of microorganisms while targeting environmental sustainability and water purification. Full article

Driven by the progress of sustainable development, environmental remediation and water treatment have become increasingly important. Photocatalysis, capable of degrading pollutants through light (especially visible light) irradiation, has received widespread research attention. Titanium dioxide(TiO₂) is a promising photocatalyst, yet its practical use is limited by low visible-light utilization and rapid photogenerated charge recombination. Herein, an S-scheme TiO₂-WO₃(Tungsten trioxide) heterojunction was successfully fabricated; the difference in Fermi levels induces a built-in electric field directed from TiO₂ to WO₃, which thus constructs the S-scheme heterojunction. The as-prepared heterojunction exhibits a markedly enhanced transient photocurrent density, with the carrier lifetime prolonged from 2.69 ns to 41.61 ns. Under visible-light irradiation, the heterojunction achieves a methylene blue (MB) removal efficiency of over 95% within 90 min, and its pseudo-first-order kinetic rate constant k reaches 0.032 min⁻¹, which is approximately 16 times that of pure TiO₂. Radical trapping experiments confirm that the dominant active species responsible for the catalytic process are photogenerated holes and the hydroxyl radicals derived therefrom. Full article