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34 pages, 7396 KB  
Article
A Dynamic Succession-Based Life-Cycle Simulation Model for Projecting Carbon Source–Sink Transitions in Urban Plant Communities
by Xiaxi Liuyang, Jiayu Lu and Yang Cao
Biology 2026, 15(13), 1072; https://doi.org/10.3390/biology15131072 (registering DOI) - 4 Jul 2026
Abstract
Urban plant communities are widely regarded as important nature-based solutions for climate mitigation, yet their actual carbon benefits remain uncertain: vegetation growth is accompanied by carbon emissions from construction and long-term maintenance, and existing assessments rarely integrate community succession, interspecific competition, and maintenance-related [...] Read more.
Urban plant communities are widely regarded as important nature-based solutions for climate mitigation, yet their actual carbon benefits remain uncertain: vegetation growth is accompanied by carbon emissions from construction and long-term maintenance, and existing assessments rarely integrate community succession, interspecific competition, and maintenance-related emissions within a consistent life-cycle framework. To address these limitations, this study developed a dynamic succession-based life-cycle simulation model to project the 50-year carbon source–sink transitions of 150 typical urban plant communities in Tianjin, China. The model updates plant structural attributes—diameter at breast height, crown width, and tree height—iteratively by linking individual plant growth to environmental suitability and neighborhood competition through a Plant Health Index. Simulated structural trajectories were coupled with biomass equations and carbon content coefficients to estimate aboveground carbon sequestration, while construction and maintenance emissions were quantified using life cycle assessment, enabling evaluation of modeled net carbon balance rather than gross carbon sequestration alone. Under the modeled 50-year scenario, most communities were projected to act as carbon sources during the early stage but gradually shifted toward carbon sinks as biomass accumulated; 86.1% of the communities were projected to become net carbon sinks after 50 years (a scenario-based projection under specified growth, maintenance, and emission assumptions). The highest modeled net carbon balance reached 3186.08 kg C ha−1, whereas the weakest community remained a slight carbon source at −81.21 kg C ha−1. Vertical structural complexity and species richness were the strongest positive predictors of modeled net carbon balance, followed by three-dimensional green quantity and canopy closure. Among maintenance processes, fertilization was the dominant emission source, followed by pesticide application and irrigation; comparative scenario analysis showed that resource-saving maintenance consistently improved projected net carbon balance relative to high-maintenance management. These results suggest that low-carbon planting design should prioritize locally adapted species, multi-layered vertical structures, and adaptive maintenance over simply maximizing planting density or minimizing inputs. The results represent scenario-based projections of aboveground vegetation carbon balance; belowground biomass, soil carbon, litter carbon, dead organic matter, and parameter uncertainty were not fully incorporated, and future studies should address these limitations to improve the robustness and transferability of the proposed framework. Full article
(This article belongs to the Section Ecology)
18 pages, 12049 KB  
Article
A Hybrid VRT-S-BR Method for Composite Electromagnetic Scattering from Targets Above Vegetated Rough Surfaces
by Yu-Feng Zou, Shui-Rong Chai, Xiao-Jie Qu, Jia-Jun Li, Kun Chao, Li-Xin Guo and Wei Liu
Remote Sens. 2026, 18(13), 2183; https://doi.org/10.3390/rs18132183 (registering DOI) - 4 Jul 2026
Viewed by 78
Abstract
This paper proposes a hybrid Vector Radiative Transfer Shooting (VRT-S)-Bouncing Ray (BR) method, referred to as the VRT-S-BR method, for predicting composite electromagnetic scattering from targets above vegetation-covered rough surfaces. In this proposed framework, the vegetation layer is modeled as a stratified random [...] Read more.
This paper proposes a hybrid Vector Radiative Transfer Shooting (VRT-S)-Bouncing Ray (BR) method, referred to as the VRT-S-BR method, for predicting composite electromagnetic scattering from targets above vegetation-covered rough surfaces. In this proposed framework, the vegetation layer is modeled as a stratified random medium and incorporated into the BR solver through VRT-S-derived amplitude modulation and deterministic phase compensation. Specifically, an offline database of vegetation-induced complex reflection coefficients is first generated using the VRT-S model over a set of incidence angles. During the BR ray-tracing process, these coefficients are used to replace the conventional Fresnel reflection terms on a per-interaction basis, thereby accounting for vegetation-induced attenuation and coherent scattering effects. In addition, a facet-dependent phase compensation scheme is introduced to describe propagation-path variations of individual rays through the vegetation canopy, avoiding the empirical random phase perturbation used in previous hybrid models. The proposed method is validated against field-measured backscattering data over natural grassland, achieving root mean square height (RMSE) values of 1.82 dB and 3.10 dB for horizontal-horizontal (HH) and vertical-vertical (VV) polarizations, respectively. Numerical results further demonstrate the capability of the method to characterize target–vegetation coupled scattering under different percentages of vegetation cover, vegetation heights, terrain backgrounds, and bistatic observation geometries. Full article
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17 pages, 34129 KB  
Article
Field Investigation and Stability Analysis of Gob-Side Roadway Retention with an 8 m Coal Pillar in Extra-Thick Coal Seam Mining
by Tao Ding, Wei Wang, Chunwang Zhang, Wenyang Zhang and Yulong Chen
Processes 2026, 14(13), 2187; https://doi.org/10.3390/pr14132187 (registering DOI) - 4 Jul 2026
Viewed by 60
Abstract
To improve the stability of gob-side entry in the mining of extra-thick coal seams, we examined the field practice of reserving a narrow coal pillar with a width of 8 m in a 17 m thick coal seam. A combination of roof directional [...] Read more.
To improve the stability of gob-side entry in the mining of extra-thick coal seams, we examined the field practice of reserving a narrow coal pillar with a width of 8 m in a 17 m thick coal seam. A combination of roof directional hydraulic fracturing and pouring concrete to consolidate the coal pillars was proposed and applied to reduce the deformation of the gob entry. First, roof directional hydraulic fracturing inhibits the vertical stress transmission to the key roof strata, and it transfers more vertical stress to the gob and reduces the lateral abutment stress in the roof. Subsequently, the narrow coal pillar is strengthened with a reinforced concrete wall, forming a strong–weak coupled bearing structure capable of bearing the overburden load, and the higher stiffness of the reinforced concrete wall effectively resists the lateral deformation of the coal pillar into the roadway. Additionally, the feasibility of this application was verified by comparing the results with the roadway convergence for a 43 m coal pillar on site. The results show that the maximum convergence, stability time, and advanced influence range were all significantly decreased by the proposed method, and the gob-side entry stability was improved. The proposed method and the results obtained provide a valuable reference for mining in similar conditions. Full article
(This article belongs to the Special Issue Experimental and Numerical Simulation of Coal Mining)
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28 pages, 4207 KB  
Article
Multivariate Coupling Model and Reservoir Characteristics of Enhanced Geothermal Reservoirs
by Qiang Li, Fuling Wang, Jingjuan Wu, Qingchao Li and Gan Zhang
Energies 2026, 19(13), 3180; https://doi.org/10.3390/en19133180 - 3 Jul 2026
Viewed by 253
Abstract
The reliance on a single evaluation parameter represents a major limitation in traditional geothermal reservoir assessment models, hindering accurate and effective evaluation of geothermal extraction performance. Moreover, mechanical deformation induced by cold fluid injection exerts a significant influence on both fluid flow behavior [...] Read more.
The reliance on a single evaluation parameter represents a major limitation in traditional geothermal reservoir assessment models, hindering accurate and effective evaluation of geothermal extraction performance. Moreover, mechanical deformation induced by cold fluid injection exerts a significant influence on both fluid flow behavior and geothermal energy recovery. In this study, a thermo-hydraulic–mechanical (THM)-coupled single-fracture model is developed based on the physical properties of the solid matrix and the seepage characteristics of the fluid, using a finite-element framework for heat and mass transfer. This model enables a multi-parameter evaluation of geothermal extraction efficiency as well as reservoir rock deformation. The simulation results indicate that reservoir temperature decreases progressively from the injection well to the production well, resulting in a gradual decline in the outlet temperature after an initial stable production period of approximately 200 days. The presence of a preferential “fastest flow path” between the injection and production wells plays a critical role in sustaining the stable production phase, whereas the development of a tongue-shaped isotherm pattern is a primary factor responsible for the reduction in outlet temperature during the later stages of extraction. In addition, thermally induced rock deformation further modifies geothermal extraction efficiency, mainly through its effects on reservoir permeability and top vertical displacement. Overall, this study provides reliable and effective fundamental data for geothermal exploitation in specific geological reservoirs, thereby supporting the role of geothermal energy as a viable supplement to fossil fuel resources. Full article
(This article belongs to the Special Issue Subsurface Energy and Environmental Protection—2nd Edition)
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19 pages, 10746 KB  
Article
Localization Algorithms for Hearing Devices Influenced by Individual Variability in Ear Acoustics
by Jakeh E. Orr and Yan Gai
Biomimetics 2026, 11(7), 467; https://doi.org/10.3390/biomimetics11070467 - 3 Jul 2026
Viewed by 154
Abstract
Background: Head-related transfer functions (HRTFs) contain time and level cues and may be utilized in automatic algorithms to identify locations of sound, a desirable feature for next-generation hearing devices. Due to substantial variability in individual head sizes and ear acoustics, individualized HRTFs are [...] Read more.
Background: Head-related transfer functions (HRTFs) contain time and level cues and may be utilized in automatic algorithms to identify locations of sound, a desirable feature for next-generation hearing devices. Due to substantial variability in individual head sizes and ear acoustics, individualized HRTFs are expected to provide the best localization results. However, acquiring individualized HRTFs for each user is time-consuming. Methods: This study constructed three binaural and/or monaural algorithms suitable for hearing devices. A linear classifier was trained on HRTF databases from a subset of subjects and used to predict sound locations for other individuals to evaluate cross-subject variability. Results: Using the CIPIC Database, a “two-step” method achieved a horizontal localization error of 1.0° and a vertical error of 30.4° sequentially. With the 3D3A Database, the horizontal and vertical errors were 5.6° and 36.5°, respectively. Both datasets yielded improved accuracy when frontal and rear hemifields were simulated separately, with trends remaining consistent across databases. When subjects were grouped by gender, classifiers trained on women’s HRTFs performed well in predicting men’s localization, whereas classifiers trained on men’s HRTFs resulted in significantly larger errors. Conclusions: These findings offer insights into the localization cues embedded in HRTFs and demonstrate the influences of inter-subject variability for spatial hearing devices. Full article
(This article belongs to the Special Issue Exploration of Bio-Inspired Computing: 3rd Edition)
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20 pages, 7419 KB  
Article
Experimental Study on the Seismic Performance of Assembled Shear Walls Based on UHPC Connections
by Gang Chen, Shiwei Yuan, Qizhen Zheng, Libo Long, Huiyan Li and Decai Nong
Buildings 2026, 16(13), 2644; https://doi.org/10.3390/buildings16132644 (registering DOI) - 2 Jul 2026
Viewed by 146
Abstract
This paper investigates the seismic performance of precast concrete shear-wall subassemblies connected by post-cast ultra-high performance concrete (UHPC) zones and short lap-spliced reinforcement with a lap length of 10d, where d denotes the diameter of the reinforcement bar. Seven quasi-static cyclic [...] Read more.
This paper investigates the seismic performance of precast concrete shear-wall subassemblies connected by post-cast ultra-high performance concrete (UHPC) zones and short lap-spliced reinforcement with a lap length of 10d, where d denotes the diameter of the reinforcement bar. Seven quasi-static cyclic tests were conducted, including one cast-in-place control specimen, five specimens with horizontal UHPC back-cast joints at the wall base, and one exploratory specimen with both horizontal and vertical UHPC back-cast joints. The variables considered were the joint arrangement and the axial compression ratio. The specimens with horizontal joints generally exhibited compression-flexure-dominated damage, and the crushing zone shifted from the wall-footing interface to the ordinary concrete immediately above the UHPC back-cast zone. The specimen with the vertical joint (TW6) exhibited bending-shear damage, accompanied by limited in-plane lateral slip at the beam–wall joint and shear damage of several vertical bars. Specimen TW2, with an axial compression ratio of 0.30, was identified as a construction-quality-sensitive case because an insufficient local UHPC cover caused splitting damage and reduced hysteretic stability. The strain measurements indicate that, within the limits of the present instrumentation, the 10d lap in the UHPC zone provided effective stress transfer in the tested specimens; however, direct interface-slip and bond-slip tests are still required for generalized design verification. Under an axial compression ratio of 0.20, TW1 and TW6 showed comparable seismic indices to the cast-in-place specimen, but the conclusions are limited to the tested configurations. All specimens reached ultimate drift ratios greater than 1/100, and their seismic performance is discussed together with failure mode, stiffness degradation, energy dissipation, and connection reliability. Full article
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21 pages, 2550 KB  
Article
Concept and Numerical Analysis of a Vehicle-Motion Energy Harvesting Turbine Integrated with a Noise Barrier
by Paweł Ligęza, Michał Przepiórski and Hubert Jabłoński
Energies 2026, 19(13), 3140; https://doi.org/10.3390/en19133140 (registering DOI) - 2 Jul 2026
Viewed by 205
Abstract
The paper presents the concept of a turbine-based energy harvester designed to recover kinetic energy from airflow generated by a moving vehicle and integrated with a roadside acoustic barrier. The proposed solutions employ a vertical-axis aerodynamic turbine positioned within a cavity in the [...] Read more.
The paper presents the concept of a turbine-based energy harvester designed to recover kinetic energy from airflow generated by a moving vehicle and integrated with a roadside acoustic barrier. The proposed solutions employ a vertical-axis aerodynamic turbine positioned within a cavity in the barrier and various airflow guiding structures intended to enhance the efficiency of energy transfer from turbulent airflow to the turbine rotor. To evaluate the effectiveness of the proposed concepts, two-dimensional CFD simulations were conducted in the ANSYS Fluent environment using the k–ε turbulence model. Three airflow deflector geometries and one reference configuration without a deflector were analyzed. The performance of each configuration was assessed based on the maximum instantaneous power and the average power generated by the turbine during a single vehicle pass-by event. The results demonstrated a significant influence of the airflow guide geometry on system performance. The most effective configuration achieved an average power output of approximately 7 W during a single vehicle pass-by event, whereas the configuration without an airflow guide exhibited significantly lower energy recovery efficiency. The obtained findings confirm the potential of the analyzed technology as a power source for autonomous low-power roadside infrastructure systems. Full article
(This article belongs to the Section D: Energy Storage and Application)
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28 pages, 1935 KB  
Article
Corporate Resilience Through Inclusive and Sustainable Cocoa Partnerships: Integrated Value Chain Governance in Sulawesi, Indonesia
by Muhammad Muhajirin Saing, Rahim Darma and Andi Dirpan
Sustainability 2026, 18(13), 6710; https://doi.org/10.3390/su18136710 - 2 Jul 2026
Viewed by 111
Abstract
This study examines how corporate resilience is developed through inclusive and sustainable cocoa partnerships within integrated value chain governance in Sulawesi, Indonesia. Using an interpretive qualitative multiple-case study design, the research compares PT Mars Symbioscience Indonesia in Luwu Timur and PT Papandayan Cocoa [...] Read more.
This study examines how corporate resilience is developed through inclusive and sustainable cocoa partnerships within integrated value chain governance in Sulawesi, Indonesia. Using an interpretive qualitative multiple-case study design, the research compares PT Mars Symbioscience Indonesia in Luwu Timur and PT Papandayan Cocoa Industries (Barry Callebaut) in Polewali Mandar. Data were collected from January to May 2025 through semi-structured interviews with 21 actors representing corporate, intermediary, farmer, financial, and local government stakeholders, and were triangulated with company documents, policy texts, and the relevant literature. The data were analyzed thematically using NVivo, supported by process tracing and cross-case comparison. The findings show that both firms combine certification, traceability, procurement arrangements, monitoring, and knowledge transfer, but organize these instruments through different partnership architectures. Mars follows a vertically integrated capability-building model involving 4250 farmers and 17 trained collectors, whereas Barry Callebaut relies on an intermediary- and standards-centered model through PT Bumi Surya Selaras, involving 3125 farmers in 126 farmer groups. These findings suggest that inclusive and sustainable cocoa partnerships function not only as supply-chain coordination mechanisms but also as institutional arrangements for governing smallholder-based production resources and long-term supply sustainability. Across cases, these partnerships were reported and interpreted as supporting supply stability, cocoa bean quality improvement, and risk mitigation. This suggests that corporate resilience in smallholder-based cocoa value chains is co-produced through the integration of governance mechanisms, farmer capacity building, intermediary coordination, and sustainable resource management. Full article
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16 pages, 1122 KB  
Article
Analytical Study of Complex Heat Transfer During Steady-State Natural Convection near a Vertical Surface
by Andriy A. Avramenko, Igor V. Shevchuk, Nataliia P. Dmitrenko, Vladimir G. Demchenko, Andrii I. Tyrinov, Kyryl O. Fedortsev and Andrii S. Kobzar
Axioms 2026, 15(7), 497; https://doi.org/10.3390/axioms15070497 (registering DOI) - 2 Jul 2026
Viewed by 112
Abstract
In this study we derived an analytical solution to the problem of radiation heat transfer under free convection near a vertical plate with a slip condition on its surface. While solving the problem, new equations for temperature and velocity profiles, boundary layer thickness, [...] Read more.
In this study we derived an analytical solution to the problem of radiation heat transfer under free convection near a vertical plate with a slip condition on its surface. While solving the problem, new equations for temperature and velocity profiles, boundary layer thickness, and Nusselt number were obtained. The obtained expressions make it possible to estimate the influence of slip and radiation effects on free convection, and to identify effects that favor heat transfer enhancement. Full article
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24 pages, 28316 KB  
Article
Mechanical Characterization and Artificial Floor Design for Underhand Cut-And-Fill Mining in a Kaolinized Altered Orebody
by Yantian Yin, Zhihai An, Weiguo Li, Chao Peng, Shuyan Du and Chengpeng Liu
Processes 2026, 14(13), 2157; https://doi.org/10.3390/pr14132157 - 2 Jul 2026
Viewed by 142
Abstract
Thin, steeply dipping orebodies hosted in kaolinized altered fault zones are difficult to mine safely because of weak rock mass integrity, water sensitivity, and limited self-supporting capacity. This study investigates the F20 ore-bearing altered structural zone at Changtai Mining and develops an artificial [...] Read more.
Thin, steeply dipping orebodies hosted in kaolinized altered fault zones are difficult to mine safely because of weak rock mass integrity, water sensitivity, and limited self-supporting capacity. This study investigates the F20 ore-bearing altered structural zone at Changtai Mining and develops an artificial floor design for downward drift-and-fill mining. Engineering geological characterization, rock mass quality evaluation, mechanical analysis, and three-dimensional numerical simulation were combined to assess floor-bearing requirements and regional recovery stability. The results show that the wall rocks are grade III, whereas the ore-bearing altered zone is grade IV and represents the controlling weak component. For the preferred 3.5 m × 3.5 m drift, an equivalent artificial floor bearing thickness of about 1.0 m is required. Numerical evaluation indicates that supported drifts remain stable, but crosscut–drift intersections are the main deformation and damage concentration zones. A representative 0.5 m drift offset significantly weakens the load-transfer path of the floor–rock system. The proposed vertically aligned, short drift, rapid backfill scheme with a reinforced composite artificial floor provides a practical basis for safe recovery of weak kaolinized altered orebodies. Full article
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17 pages, 5391 KB  
Article
Erosion Assessment at Earthen Archeological Sites by Morphometric Analysis of Digital Surface Models: The Case of Huaca Fortaleza (Pampa Grande, Peru, 600–750 AD)
by Luigi Magnini, Maria Ilaria Pannaccione Apa, Robert F. Gutiérrez Cachay, Pierdomenico Del Gaudio, Carlos Eduardo Wester La Torre and Guido Ventura
Appl. Sci. 2026, 16(13), 6610; https://doi.org/10.3390/app16136610 - 2 Jul 2026
Viewed by 81
Abstract
Earthen archeological sites may be damaged by rain-induced erosion processes. Huaca Fortaleza (HF; 600–750 AD) is an originally four-level truncated pyramid in the semi-arid Lambayeque region of northern Peru, an area affected by seasonal intense rain due to El Niño Southern Oscillation (ENSO). [...] Read more.
Earthen archeological sites may be damaged by rain-induced erosion processes. Huaca Fortaleza (HF; 600–750 AD) is an originally four-level truncated pyramid in the semi-arid Lambayeque region of northern Peru, an area affected by seasonal intense rain due to El Niño Southern Oscillation (ENSO). We use data from a UAV-based photogrammetric survey and generate a Digital Surface Model from which we extract selected geomorphometric parameters and apply a hillslope diffusion model. The obtained data show that HF steep flanks exhibit a marked erosion expressed by a drainage network of parallel rills and gullies with architectural structures controlling pathways for concentrated flow. The southwestern flank is affected by gravity instability. Localized pits at the top of HF cause infiltration of rainwater. The erosion by ENSO rainfall is responsible for extensive architectural loss, with the HF lower platforms now entirely obliterated. We calculate vertical erosion rates of 0.28–0.38 m/century, a range of values comparable with that estimated for river incision. Erosion due to diffusion processes is estimated in the order of ~0.015 m/century. Our approach represents a transferable methodology applicable to other earthen archeological sites affected by erosion worldwide. Full article
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27 pages, 3609 KB  
Article
Hyperspectral Estimation of Layer-Specific Leaf Nitrogen Content in Potato Canopy by Integrating Fractional-Order Derivatives and Three-Band Spectral Indices
by Ming Jin, Liaoyuan Ma, Liang Cheng, Zhiying Liu, Zijun Tang, Wangyang Li, Ruiqi Du, Tao Sun, Youzhen Xiang and Fucang Zhang
Plants 2026, 15(13), 2045; https://doi.org/10.3390/plants15132045 - 1 Jul 2026
Viewed by 164
Abstract
To address the insufficient characterization of vertical heterogeneity in potato canopy leaf nitrogen content (LNC), this study developed a layer-specific LNC estimation framework based on canopy hyperspectral reflectance, fractional-order derivative (FOD) transformation, and two-band and three-band optimized spectral indices. Partial least squares regression [...] Read more.
To address the insufficient characterization of vertical heterogeneity in potato canopy leaf nitrogen content (LNC), this study developed a layer-specific LNC estimation framework based on canopy hyperspectral reflectance, fractional-order derivative (FOD) transformation, and two-band and three-band optimized spectral indices. Partial least squares regression (PLSR) was then used to evaluate the predictive ability of the selected spectral indices for Top, Middle, and Bottom LNC. Field experiments were conducted from 2022 to 2023 in the semi-arid region of Yulin, Shaanxi Province, China. Canopy hyperspectral reflectance from 350 to 1830 nm and LNC measurements of upper (Top), middle (Middle), and lower (Bottom) leaves were synchronously acquired during the tuber formation stage. The results showed that potato canopy LNC exhibited a clear vertical gradient, following the order Top LNC > Middle LNC > Bottom LNC. Traditional vegetation indices were significantly correlated with LNC, but their correlations decreased with increasing canopy depth, with the highest correlation for Bottom LNC being only 0.524. Compared with traditional vegetation indices, FOD-based two-band indices showed stronger Pearson correlations with layer-specific LNC. Under FOD1.5, the maximum absolute Pearson correlation coefficients (|r|) between the selected two-band indices and LNC reached 0.855, 0.849, and 0.814 for Top, Middle, and Bottom LNC, respectively. The three-band optimized spectral indices further enhanced spectral information extraction, with maximum |r| values of 0.893, 0.885, and 0.852, respectively. However, cross-year validation produced substantially lower R2 values, indicating limited temporal transferability of the selected indices and the need for further validation before broader application. Compared with the traditional vegetation index model, it increased the testing-set R2 for Bottom LNC by 0.279 and reduced RMSE from 0.159 to 0.113. These results suggest that FOD1.5-integrated three-band optimized spectral indices can improve the indirect estimation of layer-specific LNC from canopy reflectance, particularly for Bottom LNC, where the reflectance–LNC association is affected by canopy signal attenuation and mixing. The findings provide a methodological reference for describing canopy vertical nitrogen status and functional heterogeneity in potato, while their broader applicability requires further validation across growth stages, cultivars, sites, and nitrogen management conditions. Full article
(This article belongs to the Special Issue Advanced Remote Sensing and AI Techniques in Agriculture and Forestry)
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13 pages, 6092 KB  
Article
Effects of Substituted Tryptamines on the Excitonic Structure of the Tubulin Tryptophan Network
by Matthew T. Colbourne, Lea Gassab and Travis J. A. Craddock
Photonics 2026, 13(7), 636; https://doi.org/10.3390/photonics13070636 - 30 Jun 2026
Viewed by 198
Abstract
Microtubules contain ordered aromatic amino acid networks whose optical excitations have been proposed to support non-trivial energy-transfer dynamics. Here, we examined whether bound tryptamine ligands can perturb the excitonic structure of the tubulin tryptophan network. A virtual screen of 294 tryptamines was performed [...] Read more.
Microtubules contain ordered aromatic amino acid networks whose optical excitations have been proposed to support non-trivial energy-transfer dynamics. Here, we examined whether bound tryptamine ligands can perturb the excitonic structure of the tubulin tryptophan network. A virtual screen of 294 tryptamines was performed across seven known binding regions of the tubulin heterodimer using AutoDock Vina 1.2.6. From this screen, top-ranked tryptamine ligands were carried forward for excited-state analysis. Geometry optimization and time-dependent density functional theory (TD-DFT) calculations were used to obtain vertical excitation energies and transition dipole moments for the ligand-bound states in the ultraviolet range. These ligand properties were then incorporated into a tight-binding Hamiltonian describing the tubulin tryptophan excitation network in order to evaluate changes in exciton energies and eigenvector delocalization. The calculations indicate that tryptamine binding can modify the excitonic landscape of tubulin in a ligand-dependent manner, with the magnitude of the perturbation governed by excitation wavelength, transition dipole strength, and spatial orientation relative to the intrinsic tryptophan network. These results show that substituted tryptamines differ in how they perturb the modeled tubulin tryptophan excitonic manifold, but they do not by themselves establish experimentally resolvable modulation of tubulin or microtubule photophysics. The present work should therefore be interpreted as a first-pass computational screening framework for prioritizing ligands and defining future experimental tests. Full article
(This article belongs to the Section Biophotonics and Biomedical Optics)
28 pages, 11147 KB  
Article
Decoding Elevation-Mediated Wildfire Regimes in Mountain Forest Landscapes Using Hybrid Machine Learning
by Lehan Ma, Ruiheng Huang, Qiulin Liao, Changlin Li, Sheng Chen, Dapeng Li, Weiwei Wang, Hui Qiu, Tian Dou, Xiaoyuan Wu, Yuchi Cao, Jiaao Chen, Peng Xiao, Yi Tang, Yueyuan Huang and Shouyun Shen
Forests 2026, 17(7), 775; https://doi.org/10.3390/f17070775 - 30 Jun 2026
Viewed by 104
Abstract
Wildfire regimes in mountain forest landscapes are shaped by complex interactions among topography, climate, vegetation, and human activity. However, predicting and interpreting fire occurrence in topographically heterogeneous regions remains challenging because fire–environment relationships vary strongly across elevation gradients and temporal scales. This study [...] Read more.
Wildfire regimes in mountain forest landscapes are shaped by complex interactions among topography, climate, vegetation, and human activity. However, predicting and interpreting fire occurrence in topographically heterogeneous regions remains challenging because fire–environment relationships vary strongly across elevation gradients and temporal scales. This study developed a hybrid machine-learning framework integrating an Information Value Model (IVM), Random Forest (RF), and Convolutional Neural Network (CNN) to decode elevation-mediated wildfire regimes in western Sichuan, China, a mountainous forest region characterized by strong vertical environmental gradients and high ecological conservation value. Multi-source datasets, including Moderate Resolution Imaging Spectroradiometer (MODIS) burned-area records, topographic variables, monthly meteorological data, vegetation indices, land-cover information, and human-accessibility proxies, were integrated at a 500 m spatial resolution. Environmentally comparable non-fire samples were generated from unburned vegetated pixels, and model training, RF-based feature selection, hyperparameter tuning using Particle Swarm Optimization (PSO), and performance evaluation were conducted within a nested spatial block cross-validation framework. The model produced continuous wildfire occurrence probabilities and showed strong discriminatory performance under the adopted validation protocol, with AUC values exceeding 0.95 across temporal datasets and low probability-error metrics. RF importance and correlation analyses identified mean temperature, elevation, and precipitation as the dominant predictors of wildfire probability. Spatial analyses revealed pronounced elevation-mediated differentiation in wildfire regimes: low-elevation valleys showed higher fire probability and stronger associations with human-accessibility proxies, whereas high-elevation plateau areas exhibited lower and more scattered fire patterns associated with climatic constraints. Seasonal and monthly analyses further showed that winter and spring fires dominated the regional fire regime, with risk intensifying during the pre-monsoon dry period. By combining probabilistic fire-risk mapping, spatial-context learning, and elevation-gradient interpretation, this study provides a transferable framework for understanding wildfire regimes in complex mountain forest landscapes. The findings support adaptive forest fire management, targeted monitoring, and risk zoning in mountainous regions where forest ecosystems, human activities, and conservation values intersect. Full article
(This article belongs to the Section Natural Hazards and Risk Management)
18 pages, 4393 KB  
Article
Multiscale Source Apportionment of Heavy Metals in Mining-Affected Farmland Soils Using PCA-PMF Modeling
by Xiao-Zhou Deng, Yong-Hong Ma, Wen-Ying Wu, Zhi-Gang Peng, Zhi-Hao Zhao, Kun Gao, Jia-Jia Guo and Wei Chen
Toxics 2026, 14(7), 579; https://doi.org/10.3390/toxics14070579 - 30 Jun 2026
Viewed by 211
Abstract
Polymetallic mining severely disrupts farmland soil ecosystems, yet the vertical migration of heavy metals, interlayer pollution disparities between topsoil and deep soil, and quantitative source apportionment of composite pollutants remain poorly understood in mining–agricultural overlapping zones. Two core hypotheses were accordingly proposed: mining-derived [...] Read more.
Polymetallic mining severely disrupts farmland soil ecosystems, yet the vertical migration of heavy metals, interlayer pollution disparities between topsoil and deep soil, and quantitative source apportionment of composite pollutants remain poorly understood in mining–agricultural overlapping zones. Two core hypotheses were accordingly proposed: mining-derived heavy metals can migrate downward and accumulate in deep soil layers, and the coupling of geostatistical analysis and receptor modeling enables reliable differentiation between geogenic and anthropogenic pollution sources. To test these hypotheses, 512 topsoil and 148 deep soil samples were collected from the Fenghuang Mining Area for quantification of eight metals and metalloids (including As). Geostatistical approaches, the single pollution index (Pi), and Nemerow comprehensive pollution index (PN) were utilized to characterize spatial heterogeneity and evaluate pollution severity, while a coupled PCA–PMF receptor model was adopted for quantitative source identification; vertical comparisons of element concentrations across soil profiles further validated the robustness of source apportionment outputs. The results revealed extensive heavy metal enrichment in both soil layers, with only topsoil Cd exceeding China’s risk screening value for agricultural land. Hg exhibited pronounced spatial variability and prominent anthropogenic fingerprints, and all target metals displayed consistent spatial distribution patterns along vertical soil profiles. Four distinct pollution sources were discriminated: geogenic sources dominating Cu, Zn, Cr, and Ni accumulation, mining-industrial emissions as the major contributor to Hg pollution, mixed industrial–agricultural inputs governing As and Pb enrichment, and traffic activities serving as the primary Cd source. Cd was identified as the priority pollutant threatening local farmland security. Confirmed downward percolation of anthropogenic metals creates persistent latent ecological risks across the study area, where mining and industrial discharges represent the dominant anthropogenic pollution inputs. This work systematically elucidates the geochemical signatures, vertical migration pathways, and quantitative source contributions of heavy metals in mining-disturbed farmlands, delivering solid scientific support for targeted source control, tiered risk management, and soil ecological remediation within the Fenghuang Mining Area. Moreover, the multi-method integrated analytical framework developed herein provides transferable guidance for heavy metal pollution mitigation in global polymetallic mining–agricultural regions with analogous geological and industrial backgrounds. Full article
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