Search Results (42)

The rapid growth of the hydrogen industry, driven by global decarbonization efforts, has intensified the need for safe and large-capacity storage systems. Although hydrogen is one of the most abundant elements on Earth, its storage remains technically challenging due to its chemical reactivity and stringent containment requirements. Previous research has primarily emphasized the material-level behavior of polymer liners, composites, and metal alloys because chemical compatibility plays a critical role in aboveground high-pressure tanks. However, for underground storage systems, long-term structural stability is governed not only by material performance but also by the geo-mechanical behavior of deep rock masses. This study proposes a seismic design approach for Lined Rock Caverns (LRCs), a deep underground storage concept capable of sustaining high internal pressure. The method incorporates ground-induced deformation and evaluates the additional influence of internal pressure on lining behavior. Numerical analyses demonstrate that internal pressure has a significant stabilizing effect on the structural response by reducing ovalization and suppressing nonlinear deformation mechanisms. The results highlight that internal pressure is not a secondary load but a key design parameter that must be integrated into the seismic evaluation of LRC-based hydrogen storage facilities. Full article

Intermittent water supply is common in Palestine, prompting schools to rely on on-site water storage systems, including underground and roof tanks. Prolonged and uncontrolled water storage leads to quality degradation, especially with free residual chlorine (FRC) depletion. Hence, this poses health risks to students and staff. This pilot (field) study evaluated the effectiveness of booster chlorination under the current storage conditions to optimize and improve the existing chlorination process. Four schools were selected based on the type of water storage systems (two with underground tanks, two with roof tanks) and building age. Booster chlorination was applied at two chlorine doses (0.5 mg/L and 1 mg/L). FRC was monitored until levels dropped below 0.05 mg/L. Results show that the currently applied chlorine dose (0.5 mg/L) is insufficient to reach the minimum national FRC standard (0.2 mg/L) after 30 min. In contrast, a 1 mg/L chlorine dose is more effective in maintaining the minimum FRC concentration limit for a longer time. In addition, manual mixing is ineffective in large underground tanks, while it is effective in roof tanks. This study urges the need to revise the national chlorination guidelines and to adjust chlorination practices to ensure safe drinking water in schools. Full article

Oil contamination in subsurface soils caused by leaks from underground storage tanks (USTs) and industrial facilities has become a significant geo-environmental concern. Total petroleum hydrocarbons (TPH) migrate through the ground and are difficult to remediate once dispersed; thus, prevention of migration is critical. This study experimentally investigated a hybrid liner system combining three barrier mechanisms—physical, reactive, and absorptive—to prevent TPH migration in the subsurface. Laboratory-scale experiments were conducted using a soil box simulating groundwater flow, in which Type A (100% polynorbornene powder) and Type B (mixed bentonite–sand–polyolefin–polynorbornene) liners were embedded under different soil types and spill distances. Results showed that permeability decreased rapidly after oil contact, reaching the transition zone within 120 H. Type A responded more quickly and achieved lower permeability, while Type B provided comparable but slower reduction owing to its mixed composition. These findings demonstrate that hybrid liners effectively block oil migration without hindering groundwater flow and that soil condition and spill location should be considered when selecting liner type for field applications. Full article

Strategic petroleum reserves are critical for energy security. In Japan, 0.5 million kiloliters of crude oil (12% of the state-owned reserves) is stored using underground rock-cavern tanks, which comprise unlined horizontal tunnels bored into bedrock. Crude oil is held within the tank by water inside the tank, the pressure of which is kept higher than that of the crude oil by natural groundwater and irrigation water. This study applied microbial DNA-based monitoring to assess the water environments in and around national petroleum-stockpiling bases (the Kuji, Kikuma, and Kushikino bases) using the rock-cavern tanks. Forty-five water samples were collected from the rock-cavern tanks, water-supply tunnels, and observation wells. Principal-component analysis and hierarchical clustering indicated that microbial profiles of the water samples reflect the local environments of their origins. Particularly, the microbial profiles of water inside the rock-cavern tanks were distinct from other samples, revealing biological conditions and hence environmental characteristics within the tanks. Moreover, the clustering analysis indicated distinct features of water samples that have not been detected by other monitoring methods. Thus, microbial DNA-based monitoring provides valuable information on the in situ environments of rock-cavern tanks and can serve as an extremely sensitive measurement to monitor the underground oil storage. Full article

The transition to a sustainable energy future hinges on the development of reliable large-scale hydrogen storage solutions to balance the intermittency of renewable energy and decarbonize hard-to-abate industries. Underground hydrogen storage (UHS) in salt caverns emerged as a technically and economically viable strategy, leveraging the unique geomechanical properties of salt formations—including low permeability, self-healing capabilities, and chemical inertness—to ensure safe and high-purity hydrogen storage under cyclic loading conditions. This review provides a comprehensive analysis of the advantages of salt cavern hydrogen storage, such as rapid injection and extraction capabilities, cost-effectiveness compared to other storage methods (e.g., hydrogen storage in depleted oil and gas reservoirs, aquifers, and aboveground tanks), and minimal environmental impact. It also addresses critical challenges, including hydrogen embrittlement, microbial activity, and regulatory fragmentation. Through global case studies, best operational practices for risk mitigation in real-world applications are highlighted, such as adaptive solution mining techniques and microbial monitoring. Focusing on China’s regional potential, this study evaluates the hydrogen storage feasibility of stratified salt areas such as Jiangsu Jintan, Hubei Yunying, and Henan Pingdingshan. By integrating technological innovation, policy coordination, and cross-sector collaboration, salt cavern hydrogen storage is poised to play a pivotal role in realizing a resilient hydrogen economy, bridging the gap between renewable energy production and industrial decarbonization. Full article

This study investigates sewage treatment technologies at manned and unmanned converter stations and pumped storage power stations across various regions of China, considering the regional differences in water availability, infrastructure, and ecological conditions. Using a multi-criteria evaluation approach, this study analyzes key factors, such as economic characteristics, technical characteristics, and efficiency, to assess the most suitable sewage treatment solutions. Powered Eco-type Sewage Treatment Units and Powered Underground Units perform best in southern and eastern China, where advanced infrastructure supports high treatment demands. Conversely, Septic Tanks show the lowest performance across all the regions, particularly in remote and water-scarce areas like northeast and northwest China. For pumped storage power stations, AAO+MBR and Multi-stage A/O processes are most effective in regions with high water reuse needs. This study highlights the necessity of region-specific water management strategies and technological upgrades to ensure efficient sewage treatment and sustainable water use across China’s power grid infrastructure. Full article

Achieving net-zero greenhouse gas emissions by 2050 requires CO₂-neutral industrial process heat, with seasonal energy storage (SES) playing a crucial role in balancing supply and demand. This study reviews thermal energy storage (TES) and Power-to-X (P2X) technologies for applications without thermal grids, assessing their feasibility, state of the art, opportunities, and challenges. Underground TES (UTES), such as aquifer and borehole storage, offer 1–26 times lower annual heat storage costs than above-ground tanks. For P2X, hydrogen storage in salt caverns is 80% less expensive than in high-pressure tanks. Methane and methanol storage costs depend on CO₂ sourcing, while Renewable Metal Energy Carriers (ReMECs), such as aluminum and iron, offer high energy density and up to 580 times lower storage volume, with aluminum potentially achieving the lowest Levelized Cost of X Storage (LCOXS) at a rate of 180 EUR/MWh of energy discharged. Underground TES and hydrogen caverns are cost-effective but face spatial/geological constraints. P2X alternatives have established infrastructure but have lower efficiency, whereas ReMECs show promise for large-scale storage. However, economic viability remains a challenge due to very few annual cycles, which require significant reductions of investment cost and annual cost of capital (CAPEX), as well as improvements in overall system efficiency to minimize losses. These findings highlight the trade-offs between cost, space requirements, and the feasibility of SES deployment in industry. Full article

Urban areas face challenges with water scarcity, and the use of non-conventional water resources for uses not requiring potable quality is being promoted more and more by governments and international agencies. However, non-conventional water resources, such as rainwater and greywater, need to be treated before use to avoid health risks and possible nuisance (smell, bacteria and algae proliferation in storage tanks, etc.). This study is aimed at demonstrating the feasibility of a system reusing treated greywater for toilet flushing, relying on a nature-based treatment technology—ground-based green façades—with limited maintenance requirements which is therefore easily replicable for decentralized treatment systems, like those of greywater reuse at building scales. The demonstrative system has been installed at the University of Jordan’s Al-Zahra dormitory in Amman and uses a degreaser as the primary treatment followed by ground-based green façade technology as a secondary treatment mechanism. The effluent is stored in an underground tank and directed to a tertiary treatment mechanism with UV lamps to remove pathogens before being reused for lawn irrigation and toilet flushing. Samples from influent and effluent were analyzed for various physical, chemical, and microbiological characteristics. The degreaser significantly reduced turbidity, TSS, total BOD₅, and total COD levels in greywater. When combined with the green wall façades, the system demonstrated high removal efficiencies, particularly for turbidity, TSS, total COD, and total BOD₅. The treated effluent met irrigation reuse standards for all the parameters, including total coliform and E. coli concentrations. The UV disinfection unit proved to be an effective post-treatment step, ensuring that water quality standards for reuse were met. The system’s overall performance highlights its ability to manage low- to medium-strength greywater. Results suggest the applied green wall system has significant potential for wider adoption in urban settings. Full article

This study investigates innovative solutions for balancing energy supply and demand using long-term thermal energy storage (TES) systems, with a focus on tank thermal energy storage (TTES) for European buildings, which account for approximately 40% of energy consumption in the European Union. Research conducted at the Technical University of Košice explores the potential of TTES systems for efficient and long-term energy storage. The accumulation is carried out in three existing underground tanks of different volumes. Among various outputs, we present the cooling process resulting from covering the water surface and the effect of tank size on cooling. The findings indicate that covering the water surface in the tanks can effectively double the energy retention time, thereby extending the cooling period. A tank with a larger volume cools slower and better ensures the formation of temperature layers. Temperature layering allows for better utilization of the tanks’ potential in terms of energy. The overall result is a significant reduction in heat losses and CO₂ emissions. These results demonstrate the critical role of TTES in stabilizing renewable energy sources, especially solar energy, to support sustainable energy solutions in buildings by providing reliable and long-term energy storage. Full article

Due to the extensive utilization of liquid nature gas (abbreviated as LNG) resources and a multitude of considerations, LNG storage tanks are gradually transitioning towards smaller footprints and heightened safety standards. Consequently, underground LNG storage tanks are being designed and constructed. However, underground LNG storage tanks release a considerable quantity of cold into the ground under both accidental and normal conditions. The influence of cold results in the ground freezing, which further compromises the safety of the structure. Existing research has neglected to consider the effects of this. This oversight could potentially lead to serious safety accidents. In this work, a complete set of experiments using a novel LNG underground storage tank fluid-solid-thermal coupled cryogenic leakage scale model were conducted for the first time to simulate the effect of the tank on the soil temperature field, stress field, and displacement field and to analyze the development of the three fields and the results of the effect. This research helps the related personnel to better design, construct, and evaluate the LNG underground storage tanks to avoid the catastrophic engineering risks associated with cryogenic leakage and helps to improve the design process of LNG underground storage tanks. Full article

The seismic response of underground liquefied natural gas (LNG) storage tanks has been a significant focus in both academic and engineering circles. This study utilized Ansys (2021R1) to conduct seismic analyses of large-capacity LNG tanks, considering the fluid–structure–soil coupling interaction (FSSI), and it was solved using the Volume of Fluid model (VOF) and Finite Element Method (FEM). The mechanical properties of both the LNG tank structure and soil were simulated using solid elements, and seismic acceleration loads were applied. An analysis of liquefied natural gas was performed using fluid elements within FLUENT. Initially, a modal analysis of the tank was conducted, which revealed lower frequencies for a full-liquid tank (3.193 Hz) compared to an empty tank (3.714 Hz). Subsequently, the seismic responses of both the aboveground and underground LNG tank structures were separately simulated, comparing the acceleration, stress, and displacement of the tank wall structures. The findings indicate that the peak relative displacement of the aboveground empty tank wall is 122 mm, less than that of a full tank (136 mm), while the opposite holds true for underground tanks. The period and wave height of LNG liquid shaking in underground tanks are lower than those in aboveground tanks, which is more conducive to tank safety. The deformation and acceleration of underground tanks are lower than those of aboveground tanks, but the Mises stress is higher. The results indicate that underground LNG tank structures are safer under earthquake conditions. Full article

Amid the ongoing global warming crisis, there has been growing interest in hydrogen energy as an environmentally friendly energy source to achieve carbon neutrality. A stable and large-scale hydrogen storage infrastructure is essential to satisfy the increasing demand for hydrogen energy. Particularly for hydrogen refueling stations located in urban areas, technological solutions are required to ensure the stability of adjacent civil structures in the event of hydrogen storage tank explosions. In this study, a numerical analysis using equivalent trinitrotoluene (TNT) and Concrete Damage Plasticity (CDP) models was employed to analyze the dynamic behavior of the ground in response to hydrogen gas explosions in shallow underground hydrogen storage facilities and to assess the stability of nearby structures against explosion effects. According to the simulation results, it was possible to ensure the structural stability of nearby buildings and tunnel structures by maintaining a minimum separation distance. In the case of nearby building structures, a distance of at least 6 to 7 m is needed to be maintained from the underground hydrogen storage facility to prevent explosion damage from a hydrogen gas explosion. For nearby tunnel structures, a distance of at least 10 m is required to ensure structural stability. Full article

The impact of hydrocarbon spills in the unsaturated zone is a significant environmental concern, particularly in locations where contamination arises from leaks in underground fuel storage tanks (USTs). This paper presents the outcomes achieved through the utilization of VLEACH, a finite-difference numerical model, to assess the concentrations of organic contaminants in the solid, liquid, and gas phases within the vadose zone. Additionally, it evaluates the mass transfer of pollutants to the aquifer as part of an environmental assessment for the placement of a forthcoming service station. The study encompasses an analysis of 18 scenarios under realistic conditions based on actual field data. These scenarios were constructed, taking into account various factors, including the nature of the leak (one-time or permanent), the depth of the phreatic level, and the soil conditions and properties. The results highlight the potential environmental consequences of a permanent leak as compared to those resulting from a specific accident. The findings further emphasize the substantial influence of soil moisture on transport phenomena within the vadose zone. Variations in soil moisture significantly alter hydraulic conductivity, impact magnitudes, transport velocities, and even the predominant transport mechanism. Consequently, precise delineation of soil moisture becomes a crucial parameter in such simulations. Additionally, it has been observed that each component of BTEX (benzene, toluene, ethylbenzene, and xylene) experiences varying transport velocities through the vadose zone. Benzene, having a greater propensity to concentrate in the liquid and gas phases, exhibits the swiftest movement through the vadose zone. The detection of benzene in aquifers can serve as an indicator of the potential future arrival of the remaining BTEX compounds. Full article

The development of cost-effective technologies for the treatment of water contaminated by petrochemicals is an environmental priority. This issue is of paramount importance for countries like Saudi Arabia owing to its scarce water resources. Of particular concern are automobile fuels, such as gasoline and diesel, that can contaminate water aquifers from leaking underground fuel storage tanks. Owing to the cost-effectiveness of adsorption-based technologies, low-cost high surface-area commercial activated carbon was used for the adsorptive removal of contaminants from the emulsified fuel-contaminated water. Batch equilibrium experiments showed a high efficacy of the adsorbent. Even with small amounts of the adsorbent, a removal efficiency of more than 97% was obtained for both gasoline as well as diesel. Three different well-known batch adsorption isotherm models, namely the Langmuir, Freundlich, and Temkin, were used for describing the experimental data. The best results were obtained using the Freundlich isotherm followed by the Langmuir model. The maximum capacity was found to be 8.3 g gasoline and 9.3 g diesel per gram of the adsorbent at ambient conditions for a neutral contaminated aqueous solution. Full article

The spill pressure of the contaminant source is an important factor affecting the amount, location, form, and behavior of the dense non-aqueous phase liquids (DNAPLs) that plume in a contaminated subsurface environment. In this study, perchloroethylene (PCE) infiltration, distribution and, remediation via a surfactant-enhanced aquifer remediation (SEAR) technique for a PCE spill event are simulated to evaluate the effects of the spill pressure of the contaminant source on the DNAPLs’ behavior in two-dimensional homogeneous and heterogeneous aquifers. Five scenarios with different spill pressures of contamination sources are considered to perform the simulations. The results indicate that the spill pressure of the contaminant source has an obvious influence on the distribution of DNAPLs and the associated efficiency of remediation in homogeneous and heterogeneous aquifers. As the spill pressure increases, more and more contaminants come into the aquifer and the spread range of contamination becomes wider and wider. Simultaneously, the remediation efficiency of contamination also decreases from 93.49% to 65.90% as the spill pressure increases from 33.0 kPa to 41.0 kPa for a heterogeneous aquifer with 200 realizations. The simulation results in both homogeneous and heterogeneous aquifers show the same influence of the spill pressure of the contaminant source on PCE behaviors in the two-dimensional model. This study indicates that the consideration of the spill pressure of the contaminant sources (such as underground petrol tanks, underground oil storage, underground pipeline, and landfill leakage) is essential for the disposal of contaminant leakage in the subsurface environment. Otherwise, it is impossible to accurately predict the migration and distribution of DNAPLs and determine the efficient scheme for the removal of contaminant spills in groundwater systems. Full article