Search Results (10,460)

Parabolic trough collector (PTC) plants that use solar salt as a heat transfer fluid face operational challenges due to the salt’s relatively high solidification temperature of around 240 °C, which can compromise reliability if solidification occurs within receiver tubes or piping. While electric tracing cables are typically used to heat piping, they cannot be installed on PTC receivers due to the presence of external glass covers. As an alternative, impedance heating can be employed, applying voltage directly to the steel receivers, which act as resistive heaters. This study presents experimental results on the phase-change behavior of solar salt within receivers, focusing on melting and solidification times. Tests were conducted using two dedicated receivers under vacuum and non-vacuum conditions. Under vacuum, complete melting was achieved at 4.5 V and 1.43 kW in 5.5 h, while solidification from 270 °C took about 4 h, progressing inward from the tube connections. For non-evacuated receivers, 7 V and 3.2 kW were needed for melting in 5.6 h, and solidification at 270 °C was completed in 1.45 h. These outcomes illustrate that non-evacuated tubes require nearly twice the power and have a 2.8-fold increase in heat loss rate, offering quantitative guidance for vacuum loss detection in PTC systems. Full article

Current diagnostic methods for bacterial infections in critically ill patients, including ventilator-associated pneumonia (VAP), are time-consuming, while empirical antibiotic therapy contributes to rising resistance. Bacteria-derived volatile organic compounds (VOCs) are being explored as specific biomarkers for pathogen identification and treatment monitoring. This study expands knowledge of Escherichia coli metabolism by identifying VOCs produced by both multidrug-resistant and susceptible strains, characterizing their temporal profiles during growth, and assessing VOC profile changes after imipenem exposure. Reference strains and 21 clinical isolates (derived from BAL samples of VAP patients) were cultured under controlled conditions. Headspace VOCs were preconcentrated using multibed sorption tubes and analyzed by gas chromatography–mass spectrometry (GC-MS), with compound identities confirmed using external standards. Sampling at seven time points over 24 h cultures revealed three VOC emission patterns: continuous release, temporary maximum, and compound uptake. In total, 57 VOCs were identified from the susceptible strain and 41 from the resistant one, with dimethyl disulfide, 2-butenal, ethyl acetate, and furan elevated in the resistant strain. Imipenem addition altered VOC production in the susceptible strain, with levels of six compounds elevated and seven reduced, while resistant profiles remained stable. Clinical isolates produced 71 VOCs, showing greater metabolic diversity and highlighting the relevance of isolate-derived VOCs in future studies. Full article

This work investigated the effect of high-nitrogen/low-hydrogen mixed atmosphere heat treatment on the electrochemical corrosion and wear resistance of plasma-sprayed FeCoNiCrAl high-entropy alloy (HEA) coatings. The HEA coatings were sequentially prepared through annealing at 400, 600, and 800 °C for 6 h. The heat treatment method was conducted in a vacuum tube furnace under 0.1 MPa total pressure, with gas flow rates set to 300 sccm N₂ and 100 sccm H₂. The XRD results indicated that the as-deposited coating exhibited α-Fe (BBC) and Al_0.9Ni_4.22 (FCC) phases, with an Fe_0.64N_0.36 nitride phase generated after 800 °C annealing. The electrochemical measurements suggested that an exceptional corrosion performance with higher thicknesses of passive film and double-layer capacitance can be detected based on the point defect model (PDM) and effective capacitance model. Wear tests revealed that the friction coefficient at 800 °C decreased by 3.84% compared to that in the as-sprayed state due to the formation of a dense nitride layer. Molecular orbital theory pointed out that the formation of bonding molecular orbitals, resulting from the overlap of valence electron orbitals of different atomic species in the HEA coating system, stabilized the structure by promoting atomic interactions. The wear mechanism associated with stress redistribution and energy balance from compositional synergy is proposed in this work. Full article

Objectives: This study evaluated the comfort of using silicone tubes installed in the oral cavity as a reservoir for a hydrogel that allows for a slow delivery of the active substance acting locally or systemically. Methods: Perforated silicone tubes 8 cm long with two internal diameters were used: T1 (1.5 mm) and T2 (2.4 mm). The reservoirs were filled with hydrogel placebo formulations: carbomer 1.5% (C), hydroxyethylcellulose 4% (HEC), or hydroxypropylmethylcellulose (hypromellose) 3% (HPMC). Physical parameters of the gel were determined with a viscometer and a texture analyzer. During 4 h of application, the volunteers reported sensory perceptions, and the rate of gel erosion was evaluated. The results were correlated with the viscosity, rheology, and dissolution rate of the gels measured in vitro. Results: Volunteers reported only mild discomfort wearing the device, preferring smaller-sized tubes. The tubes were easy to apply and generally comfortable, with no reports of significant discomfort. Despite similar viscosity and rheology, the polymer type had a significant impact on erosion rate, both in vitro and in vivo. After 4 h of application in vivo, more than 90% of the carbomer gel remained in the tube, while in the case of less cohesive HPMC or HEC gels, this was about 50%. A statistically significant correlation was observed between the in vitro and in vivo mean erosion percentages for the HEC and HPMC gels. Conclusions: This study supports the use of silicone tubes as effective reservoir devices for prolonging the residence time of drug formulations in the oral cavity. Full article

This study investigates how three flat-tube connector structures—conventional, ribbed flat-tube, and flange-connected—affect solid oxide fuel cell (SOFC) performance. The analysis employs a multi-physics modeling approach to examine the coupled effects of flow fields, gas species transfer, electrochemical reaction, and solid–liquid heat transfer. Results indicate that, under specific conditions, adding internal connector structures can enhance gas transport within the cell, leading to improvements in current density and output power. The flange-connected structure SOFC demonstrated superior output performance, particularly at a flange length of 30 mm, at which it achieved a 4.13% increase in power density compared to the conventional flat-tube SOFC and promoted a more uniform temperature distribution, effectively alleviating uneven temperature distribution inside the cell. Full article

In industrial production, flue gas heat exchangers are often affected by the low-temperature condensation of industrial flue gas due to the influence of the working environment, resulting in serious ash deposition and corrosion. In order to solve this problem, in this study, we developed an ash deposition and corrosion monitoring system to compare the ash deposition prevention performance and corrosion resistance of different materials, as well as its influence on the heat transfer performance of different materials in the same environment. The following coatings were selected for the experiment (values in parentheses are the concentrations of the added compounds): ND, Q235, 316L, Ni-Cu (0.4 g/L)-P, Ni-P-SiO₂ (40 g/L), Ni-Cu (0.4 g/L)-P-SiO₂ (20 g/L), Ni-Cu (0.4 g/L)-P-SiO₂ (40 g/L), and Ni-Cu (0.4 g/L)-P-SiO₂ (60 g/L). The results show that the Ni-Cu (0.4 g/L)-P-SiO₂ (40 g/L) coating has excellent corrosion resistance, while the Ni-Cu (0.4 g/L)-P-SiO₂ (60 g/L) coating shows excellent antifouling performance. Through the comparative analysis of polarization curves, impedance spectra, and coupled corrosion experiments, the test materials were ranked as follows based on their corrosion resistance: 316L > Ni-Cu-P-SiO₂ (40 g/L) > Ni-Cu-P-SiO₂ (20 g/L) > Ni-P-SiO₂ > Ni-Cu-P-SiO₂ (60 g/L) > Ni-Cu-P > ND > Q235. It was also demonstrated that the new coated pipes were able to reduce the exhaust temperature below the dew point and maximize the recovery of energy from the exhaust gas. The acid–ash coupling mechanism of the coating in the flue gas environment was further analyzed, and an acid–ash coupling model based on Cu and SiO₂ is proposed. This model analyzes the effect of the coating under the acid–ash coupling mechanism. Using coated tubes in heat exchangers helps to recover waste heat from coal-fired boilers, enhance heat exchange efficiency, extend the service life of heat exchangers, and reduce costs. Full article

Several decades after the development of FEM in computer-based form, which is a milestone in the evaluation of mechanical systems, the method has been adopted to analyze the biomechanical response of human skeletal structures. This innovative technique has generated new questions, but also new results, and, at the same time, competitive environments with explosive development, in the recent period. This research is focused on analyzing, using FEM, the extreme thermal variations produced at the level of two oro-facial systems (one control and one subjected to orthodontic therapy using a fixed metallic orthodontic appliance). The objective of the study was to determine the temperature evolution in different dental structures subjected to extreme temperatures given by variations between very cold and very hot foods. Each system was exposed to a succession of extreme thermal regimes (70…−18…70… °C and −18…70…−18… °C). In order to conduct this research, we used the case of a 14-year-old female patient. Following an orthodontic evaluation, we discovered that the patient had dento-alveolar disharmony with crowding. The straight-wire method of applying a fixed metallic orthodontic appliance was chosen. As complementary examinations, the patient was subjected to a bimaxillary CBCT. Using a series of programs (InVesalius, Geomagic, SolidWorks, and AnsysWorkbench), a three-dimensional model was obtained. This model contained jaws and teeth. Also, brackets, tubes, and orthodontic wires can be incorporated into the model. Following the simulations carried out in this study, it was found that thermal variations from the dental pulp are more severe for the oro-facial system with a fixed metallic orthodontic appliance (regardless of the type of thermal stimulus used). Thus, even today, with all the facilities available in the dental materials industry, metallic orthodontic devices present significant thermal conductivity, generating harmful effects on the dental structures. The reading of the results was performed on the virtual model, more precisely, on the internal dental structures (enamel, dentin, and pulp). A statistical study was not performed because it was considered that, in other patients, the results would be similar. Full article

The application of precast assembled pier systems in high-seismicity regions is often constrained by their seismic performance limitations. To validate the optimization effect of GFRP confinement on the hysteretic performance of bridge piers, this study first conducted axial compression tests on 54 glass fiber-reinforced polymer (GFRP)-confined concrete cylindrical specimens. The investigation focused on the effects of fiber layers (6 and 10), orientation angles ($\pm 45°$, $\pm 60°$, $\pm 80°$), slenderness ratios (2 and 4), and compression section configurations (fully loaded vs. core concrete loading only) on confinement efficacy. The experimental results demonstrate that specimens with $\pm 60°$ fiber angles achieved an optimal balance between strength and ductility, exhibiting an average strength enhancement of 298.0% and a maximum axial strain of 2.7% compared to unconfined concrete. Subsequently, two GFRP tube-confined concrete bridge piers with varying fiber layers (PRCG1: 6 layers; PRCG2: 10 layers) and one unconfined reference pier (PRC) were designed and fabricated. All specimens employed grout-filled sleeves to connect caps and piers. Pseudo-static tests revealed that GFRP confinement effectively mitigated damage in plastic hinge zones and enhanced seismic performance. Compared to the PRC, PRCG1 and PRCG2 exhibited increases in ultimate displacement by 19.50% and 28.57%, in ductility coefficients by 18.56% and 27.84%, and in cumulative hysteretic energy dissipation by 13.90% and 26.43%, respectively. At the 5% drift ratio, their load capacities increased by 26.74% and 23.25%, stiffnesses improved by 28.91% and 25.51%, and residual displacements decreased by 20.89% and 11.17%. The accuracy and applicability of the GFRP tube-confined bridge pier model, developed based on the Lam–Teng model, were validated through numerical simulations using the OpenSees fiber element approach. Full article

This study investigates the impact of arc-hardening parameters on a groove-shaped S45C steel tube, with a focus on surface hardness and microstructure. According to the findings, when arc quenching occurs, the tube’s surface hardness increases significantly compared to its original hardness. The surface layer hardness can increase to 50.3 HRC, which is 3.4 times greater than the untreated surface. Changing arc quenching parameters such as current intensity, gas flow rate, arc length, scan speed, heating angle, and cooling angle causes a variation in surface hardness due to the balance of heat input and cooling value. Moreover, the microhardness distribution is divided into three zones: the hardened zone (with a high hardness value), the heat-affected zone (HAZ), which has rapidly declining hardness, and the base metal (with a low hardness value). The hardened zone could have a hardness with a load of 0.3 N of 440 HV and a case depth of about 900 μm. The next zone is the HAZ, where the hardness with a load of 0.3 N drops significantly. The hardness in the base metal zone recovers to its original value of 152 HV. Interestingly, the microstructure, under the hardness distribution, illustrates the relationship between the hardness value and its phases. The hardened zone consists of martensite and residual austenite phases, resulting in a high hardness value. The bainite phase constitutes the HAZ, which correlates to the zone of rapid hardness reduction. Finally, the base metal zone has ferrite and pearlite microstructures, indicating the softest zone. The investigation’s findings may increase our understanding of the arc-hardening process and widen its industrial applications. Full article

The internal flow field and hydrodynamic properties of a photocatalytic reactor are crucial for the enhancement of degradation performance. In this study, TiO₂ films were loaded on the surface of quartz glass tubes and activated with UV-LEDs. Combining the degradation experiments with computational fluid dynamics (CFD) numerical simulations, the regulation laws of film surface area, flow field configuration, ratio of film surface area to solution volume (S/V), inlet flow rate and diameter on the reaction process were systematically evaluated. The results showed that the film surface area was positively correlated with the degradation efficiency of tetracycline hydrochloride (TCH). The degradation rate of TCH ranged between 32.15% and 64.83% in 12 equal film area flow field configurations. It was further found that the S/V value was positively correlated with the degradation efficiency only for the same flow field configuration, and the degradation rate of TCH was enhanced by 32.73% when the S/V value was increased from 0.018 m⁻¹ to 0.034 m⁻¹. In addition, as the flow rate increases, the optimal inlet diameter increases accordingly (10, 25, 40, 55, and 70 mL/min corresponded to 10, 15, 20, 20, and 25 mm, respectively). The optimum structural parameters of the reactor were determined as follows: inlet flow rate of 10 mL/min, inlet diameter of 10 mm, flow field configuration type b, S/V value of 0.034 m⁻¹, and height of 450 mm. The degradation rate of TCH under these conditions was 96.34%. The relationship between the film-reactor flow field and degradation efficiency of the photocatalytic reactor established in this study provides a reference for optimizing the design of tubular catalytic reactors. Full article

The incidence of fire accidents resulting from refrigerant leaking following the rupture of air conditioning condenser tubes has escalated in recent years. Corrosion from carboxylic acid is a primary cause in the rupture of copper tubes. The influence of lubricating oil and iron filings generated by the wear of air conditioning compressors on the corrosion of condenser copper tubes is rarely mentioned in the existing research. In order to simulate the environmental conditions inside the air conditioning unit, this study utilizes acetic acid vapor to corrode copper tubes and explores the effects of lubricating oil and iron powder on copper tube corrosion. The results demonstrate that copper corrosion follows a dendritic corrosion pattern, achieving a maximum depth of 51 μm after 28 days in 1% acetic acid vapor. A small amount of copper hydroxy acetate appears in the early stage. Copper hydroxy acetic and basic carbonate copper are converted into acetic acid copper hydrate as the acetic acid vapor increases over time. The ultimate products appear as turquoise-blue crystals. POE lubricant diminishes the corrosion rate by establishing an oil layer barrier that mitigates the volatilization of acetic acid. Iron powder preferentially reacts with acetic acid to initially protect the copper tube. The Fe³⁺ produced oxidizes the copper in acetic acid, hence the concentration of copper acetate rises, which facilitates the crystallization of copper acetate. Full article

At present, high-resolution and reliable inductive sensors have increasingly emerged as a pivotal component in the advancement of flexible electronic devices. The integration of liquid metal with flexible substrates presents a promising approach for the fabrication of inductive sensors. This paper introduces a novel paperclip-type helical coil inductive sensor, characterized by advancements in both structural design and a simplified manufacturing process. The sensor comprises a fine silicone tube filled with liquid metal, encapsulated within polydimethylsiloxane (PDMS) glue. A significant innovation of this design is its complete elimination of the need for high-precision sacrificial metal molds. This approach bypasses complex processes such as precision mold machining, demolding, and post-mold residue cleaning, thereby significantly streamlining the production work-flow. We optimized the parameters of the paperclip-type helical coil, the aspect ratio, and the number of turns, achieving the maximum sensitivity under limited conditions. Experimental results demonstrate that this sensor is capable of tensile, pressure, and non-contact distance sensing. The linearity of the tensile sensing is exceptional ($R^2=0.999$), with consistent performance observed after 800 tensile cycles. The pressure sensing range extends from 0 to 230 kPa, and the non-contact distance sensing is effective within a range of 10 mm. Furthermore, the sensor exhibits strong performance in monitoring human physiological activities and metal distance detection, demonstrating significant application potential in flexible electronics and wearable devices. Full article

Numerous infants have been conceived by in vitro fertilization (IVF) and other assisted reproductive technologies (ART). Increasing evidence indicates that these approaches induce minor alterations in molecules during the initial phases of embryogenesis. This narrative review examines the molecular pathophysiology of embryonic cardiogenesis in the context of assisted reproductive technology, emphasizing transcriptional and epigenetic regulation. Essential transcription factors for cardiac development, including NKX2-5, GATA4, TBX5, ISL1, MEF2C, and HAND1/2, play a crucial role in mesodermal specification, heart tube formation, and chamber morphogenesis. Animal models and human preimplantation embryos have demonstrated that ART-related procedures, including gamete micromanipulation, supraphysiological hormone exposure, and extended in vitro culture, can alter the expression or epigenetic programming of these genes. Subsequent to ART, researchers have identified anomalous patterns of DNA methylation, alterations in histones, and modifications in chromatin accessibility in cardiogenic loci. These alterations indicate that errors occurred during the initial reprogramming process, potentially resulting in structural congenital heart abnormalities (CHDs) or modifications in cardiac function later in life. Analysis of the placental epigenome in babies conceived using assisted reproductive technology reveals that imprinted and developmental genes critical for cardiac development remain dysfunctional. This review proposes a mechanistic theory about the potential subtle alterations in the cardiogenic gene network induced by ART, synthesizing findings from molecular embryology, transcriptomics, and epigenomics. Understanding these molecular issues is crucial not only for enhancing ART protocols but also for evaluating the cardiovascular risk of children conceived by ART postnatally and for early intervention. Full article

The energy requirements for conditioning spaces have been increasing primarily due to population growth and climate change. This paper shows a comparison between an adsorption (ADC) and absorption cooling (ABC) systems to keep a building below the 25 °C set-point in dynamic conditions, utilizing a latent heat storage tank with MgCl₂·6H₂O and erythritol, and employing evacuated tube and parabolic trough collectors. The storage tank geometry is a plate heat exchanger. An auxiliary system was incorporated to control the temperature range of the solar cooling systems. The results showed that the coefficient of performance was kept around 0.40–0.60 and 0.70 for adsorption and absorption cooling, respectively. The latent heat storage tank with erythritol captured more solar energy than MgCl₂·6H₂O. A maximum solar fraction of 0.96 was obtained with MgCl₂·6H₂O, a thickness of 0.15 m, 20 m² of parabolic trough collector area, and absorption cooling, while the energy supply was fully satisfied with a solar collector with erythritol, a thickness of 0.1 m, 13 m² of parabolic trough area, and absorption cooling. In general, erythritol obtained better results of solar collector fractions than MCHH; however, it has less thermal stability than MgCl₂·6H₂O, and the cost is higher. Full article

Under the continuous tightening of global carbon emission policies, the search for sustainable low-emission energy sources is of great significance to reduce the reliance on the use of fossil fuels and to save energy and reduce emissions. Biodiesel–ethanol–graphene mixed fuel has high combustion efficiency and low emission characteristics, and an in-depth study of its evaporation and microexplosion characteristics during the heating process can help to better understand the characteristics of this fuel. In this paper, the evaporation, microexplosion, sub-droplet distribution and kinematic properties of biodiesel–ethanol–graphene droplets under different temperatures, volumes and mixing ratios were investigated by simulating the air atmosphere using a modified tube furnace experimental platform. It was found that the BD50E50 (1%G) droplet produced a weak microexplosion under 600 °C, and three secondary droplets were formed, with the largest secondary droplet area reaching 5.28 mm². The BD50E50 (1%G) droplet produced strong microexplosion under 800 °C conditions, and 10 secondary droplets were formed, with the largest secondary droplet area of 3.02 mm². Different intensities of microexplosion and ejection phenomena produced by the biodiesel–ethanol–graphene droplets during the heating process were found, and it was found that the temperature and droplet volume determine whether the microexplosion of the mixed droplets can occur or not, while the intensity of the microexplosion determines the number of secondary droplets and the speed of movement. Additionally, the velocity and acceleration of secondary droplets produced by ejection were significantly greater than those produced by microexplosion. These studies provide a theoretical basis for the application of this fuel. Full article