Search Results (457)

This study examined the effects of pollution from the Shituru hydrometallurgic complex on the Upper Lufira Basin, Democratic Republic of the Congo, between September 2015 and September 2017. Physico-chemical water variables and trace metal elements in water and sediment, as well as diversity and infection parameters of monopisthocotylan parasites infesting Clarias ngamensis, were assessed at three sites: the Lufira River, Panda River, and Lake Tshangalele. We hypothesised that low pollution would correlate with greater ectoparasite species richness and higher infection parameters. Results indicated severe ecological degradation in the highly polluted Panda River (with high concentrations of TMEs; e.g., 510.830 ± 0.86; 82.470 ± 0.200 µg/L for Co²⁺ and Cu²⁺ in water; 15,771 ± 7068 and 1585 ± 1450 µg/g for Cu²⁺ and Zn²⁺ in the sediment), where neither fish nor parasites were present. Across the other sites, eight parasite species were identified. Seven species occurred on fish from the slightly polluted Lufira River (mean intensity (MI) of 31.28 ± 28.95 parasites per infested fish), while five were found in Lake Tshangalele (MI: 3.23 ± 2.89 parasites per infested fish), confirming the hypothesis. Three species, Quadriacanthus halajiani, Q. domatanai, and Macrogyrodactylus clarii, demonstrated potential as sensitive bioindicators of aquatic pollution in the region. Full article

In soils, it is key to not simply determine the behavior of the major elements but also understand the fate of trace and ultra-trace elements that can often have disproportionate effects on these complex systems. Soils, including agricultural soils, constitute a reservoir of nanoparticles and natural colloids of multiple origins. Nonetheless, only limited information is available on the concentrations and fate of nanoparticles in soils, due largely to the difficulty of distinguishing anthropogenically generated particles from the complex soil matrices in which they are found. Bulk measurements are often unable to quantify the key contributions of trace pollutants (i.e., needle in a haystack); however, single particle techniques have recently become available for studying complex agricultural systems, including soils. For example, the characterization of engineered nanoparticles or incidentally generated particulate pollutants within a natural soil or sediment is now possible using techniques such as single particle inductively coupled plasma mass spectrometry (SP-ICP-MS). Nonetheless, in order to exploit the single particle techniques, it is first necessary to representatively sample the soils. The approach presented here has been designed to help better understand the impact of incidental and engineered nanoparticles on agricultural soils. In this study, we examine two approaches for extracting colloidal particles (CP) from soils in order to facilitate their characterization by single particle inductively coupled plasma mass spectrometry using a sector field- (SP-ICP-SF-MS) and time-of-flight- (SP-ICP-ToF-MS) based instruments. A novel sampling methodology consisting of an ultrasound-assisted continuous-flow extraction (USCFE) was developed and compared to a commonly used batch extraction procedure. Metal containing colloidal particles (M–CP) were quantified and characterized following their extraction in ultrapure water and tetrasodium pyrophosphate (TSPP). At least five successive extraction cycles of 18 h each were required to optimally extract Si–CP (ca. 6 × 10¹⁵ kg⁻¹) using the batch extraction approach, whereas similarly high numbers of CP could be extracted by USCFE in about 3 h. The combined use of continuous flow, ultrasound and TSPP improved the sampling of colloidal particles and nanoparticles from an agricultural soil. Due to its higher sensitivity, SP-ICP-SF-MS was used to measure the smallest detectable M–CP in the soil extracts. SP-ICP-ToF-MS was used to determine the multi-elemental composition of the extracted colloidal particles. Full article

Aquatic environments have been a critical source of nutrition for millennia, with wild fisheries supplying protein and nutrients to populations worldwide. A notable shift has occurred in recent decades with the expansion of aquaculture, now representing a fast-growing sector in food production. Aquaculture plays a key role in mitigating the depletion of wild fish stocks and addressing issues related to overfishing. Despite its potential benefits, the sustainability of both wild and farmed aquatic food systems is challenged by anthropogenic pollution. Contaminants from agricultural runoff, industrial discharges, and domestic effluents enter freshwater systems and eventually reach marine environments, where they may be transported globally through ocean currents. Maintaining water quality is paramount to food safety, environmental integrity, and long-term food security. In addition to conventional seafood products such as fish and shellfish, foods such as those derived from microalgae are gaining attention in Western markets for their high nutritional value and potential functional properties. These organisms have been consumed in Asia for generations and are now being explored as sustainable foods and ingredients as an alternative source of protein. Contaminants in aquatic food products include residues of agrochemicals, persistent organic pollutants (POPs) such as dioxins, polychlorinated biphenyls (PCBs), and per- and polyfluoroalkyl substances (PFASs), as well as brominated flame retardants and heavy metals. Public and scientific attention has intensified around plastic pollution, particularly microplastics and nanoplastics, which are increasingly detected in aquatic organisms and are the subject of ongoing toxicological and ecological risk assessments. While the presence of these hazards necessitates robust risk assessment and regulatory oversight, it is important to balance these concerns against the health benefits of aquatic foods, which are rich in omega-3 fatty acids, high-quality proteins, vitamins, and trace elements. Furthermore, beyond direct human health implications, the environmental impact of pollutant sources must be addressed through integrated management approaches to ensure the long-term sustainability of aquatic ecosystems and the food systems they support. This review covers regulatory frameworks, risk assessments, and management issues relating to aquatic environments, including the impact of climate change. It aims to serve as a comprehensive resource for researchers, policymakers, food businesses who harvest food from aquatic systems and other stakeholders. Full article

Baijiu, China’s traditional distilled spirit, is produced through solid-state fermentation and distillation of grains, resulting in a highly complex chemical and sensory profile. However, exogenous impurities introduced via raw materials, water, equipment, packaging, or the surrounding environment pose significant challenges to both safety and quality. These impurities, including heavy metals, plasticizers, pesticide residues, mycotoxins, environmental pollutants, and un-authorized food additives, are associated with neurotoxicity, carcinogenicity, endocrine disruption, and sensory defects. This narrative review synthesizes current knowledge on their sources, reported concentration ranges in Baijiu (generally at trace µg/kg–mg/kg levels), analytical detection methods with sub-mg/kg sensitivity, and control strategies for these substances. Regulatory frameworks, including China’s standards, are critically assessed, with emphasis on gaps such as the lack of explicit limits for certain classes of impurities. Case studies of contamination incidents are discussed to illustrate practical risks and monitoring gaps. Emerging trends, including low- and zero-alcohol Baijiu, are also considered in relation to changing impurity profiles and detection requirements. Recommendations include tightening regulatory limits, adopting portable and real-time detection technologies, and promoting the development of “pure Baijiu” that meets international safety and quality expectations. Future research priorities center on high-resolution mass spectrometry, advanced real-time monitoring, and eco-friendly analytical solutions, ensuring that Baijiu maintains both cultural heritage and global competitiveness. Full article

This study conducts a comprehensive bibliometric analysis of literature from 2000 to 2025, aiming to map the intellectual landscape and evolving trends in research on heavy metal transport within watershed ecosystems. By leveraging the Citespace literature visualization tool, we analyzed publication trends, intellectual bases, and, most importantly, the dynamic shifts in research fronts through keyword co-occurrence and clustering analysis. The findings reveal a clear trajectory from basic geochemical theories to specific applications, characterized by three prominent themes: (1) the evolution of pollution source tracking from single-method tracing to coupled multi-method quantitative modeling; (2) the establishment of a comprehensive risk evaluation chain spanning regional assessments to targeted analyses of sensitive receptors; and (3) the analysis indicates that the current research on heavy metal transport in watershed environments remains somewhat fragmented, with limited cross-comparative synthesis across different metal species and watershed contexts, and uneven progress in applying advanced data-driven and multi-model approaches. Addressing these issues is crucial for enhancing the predictive power of models and formulating effective strategies. This study thus provides a detailed overview of the field’s development while highlighting critical pathways for future research to strengthen the scientific foundation for preventing and controlling heavy metal pollution in watershed ecosystems. Full article

Trace metals and metalloids pose persistent threats to freshwater ecosystems, yet their trophic transfer and sublethal effects across food webs remain poorly understood. We investigated bioaccumulation patterns and biomarker responses in a predator–prey system comprising Prussian carp (Carassius gibelio) and Great Cormorant (Phalacrocorax carbo) nestlings from the Danube floodplain wetland Kopački rit Nature Park (Croatia) during 2023–2024. Concentrations of arsenic (As), selenium (Se), cadmium (Cd), mercury (Hg) and lead (Pb) were determined in Prussian carp liver and in Great Cormorant whole blood. The activities of acetylcholinesterase (AChE), carboxylesterase (CES), glutathione S-transferase (GST) and the levels of reactive oxygen species (ROS) and reduced glutathione (GSH) were measured in brain, muscle and gill tissues of Prussian carp, as well as in plasma and S9 blood fractions of Great Cormorants. In addition, tissue-specific metal concentration ratios (TSMCR) were calculated to assess the relative magnitude of recent dietary exposure in the predator compared to the prey. Biomarker activity showed strong tissue- and fraction-specific variation, with temporal differences. Exposure–response modelling revealed significant associations between As, Cd, and Hg and specific biomarkers, particularly in gill and plasma. Cross-species comparisons indicated elevated TSMCR as a proxy for recent trophic exposure only for Hg in 2023, whereas As and Se exhibited lower TSMCR. These findings demonstrate that metal exposure in floodplain systems induces physiological responses and Hg poses the greatest prey-to-predator exposure risk, highlighting the value of integrating pollutant measurements with mechanistic biomarker endpoints to evaluate ecosystem-level impacts. Full article

Environmental contamination with heavy metals, resulting from industrialization, urbanization, and agricultural intensification, poses serious ecological and health risks. Horses, due to their grazing behavior and close association with human environments, serve as reliable sentinel species for assessing environmental pollution. This study aimed to evaluate the bioaccumulation of heavy metals and trace elements in different biological matrices of horses—blood, hair, hooves, and synovial fluid—and to investigate their relationship with hematological biomarkers as indicators of physiological stress. Samples were collected from horses raised in anthropogenically influenced areas and analyzed using inductively coupled plasma mass spectrometry (ICP–MS). Hematological parameters were determined with an automated analyzer to assess systemic effects. The results revealed significant variations in metal concentrations among matrices, with keratinized tissues reflecting long-term exposure, while blood and synovial fluid indicated recent contamination. Correlations between elevated metal levels and altered hematological values suggested oxidative stress and adaptive physiological responses. These findings demonstrate the value of multi-matrix biomonitoring in evaluating both environmental quality and animal health. Horses effectively reflect the cumulative impact of heavy metal exposure, supporting their role as bioindicators within a One Health framework that links environmental, animal, and human well-being. Full article

Rare earth elements and yttrium (REY) are emerging contaminants of concern due to their widespread use in modern technologies, persistence, and unknown ecological effects. This study presents the first assessment of REY in seawater and sediments of Pula Bay, Croatia, a semi-enclosed, industrialized coastal system. Surface seawater and sediment samples were analyzed using ICP-MS, following optimized preconcentration and digestion protocols. PAAS-normalized REY patterns and λ Polynomial Modelling identified natural and anthropogenic fractionation signatures. Dissolved ΣREE in seawater ranged from 17.6 to 45.9 ng L⁻¹, with naturally elevated concentrations from continental runoff and evidence of anthropogenic Gd (up to 33%) linked to sewage outputs. Sediment ΣREE concentrations varied from 134.8 to 218.2 mg kg⁻¹, with spatial variation reflecting terrigenous and anthropogenic inputs. Local MREE_PAAS and HREE_PAAS enrichment associated with industrial and municipal inputs distinguished anthropogenic contributions from the lithogenic background. While seawater remains largely unaffected, pollution and risk assessments indicate moderate to high sediment contamination by MREEs and HREEs, showing potential concern for benthic organisms near industrial and urban hotspots. These findings highlight the combined influence of natural and anthropogenic processes on REY distribution in coastal systems and underscore the need for further studies of potential REY effects in impacted coastal environments. Full article

The worldwide issue of surface water contamination by heavy metals is a matter of great concern, as it has the potential to affect human health. This study intended to compute heavy metal contamination and human health risks in surface water using the following pollution indices: heavy metal pollution index (HPI), contamination index (CI), metal index (MI), ecological risk index (ERI), human health risk and statistical analysis. For this purpose, eleven water samples were gathered and analyzed by ICP-AES for trace metals such as Pb, As, Zn, Cd, Cu, and Ni. The results showed that heavy metal concentrations varied significantly throughout the study area, with Pb, As, and Cd levels exceeding the WHO limits for drinking purposes. Pollution indices indicated low to high water contamination, with HPI results ranging from 16.41 to 862.18 and from 12.76 to 774.03, above the critical value of 100, requiring serious interventions to reduce heavy metal pollution. MI results range from 0.90 to 20.92 and from 0.70 to 18.41 and CI values range from 0.34 to 20.38 and from 0.15 to 17.86 in the dry and wet periods, respectively, with different contamination levels observed throughout the study area; ERI showed low to considerable ecological risk. Nonetheless, the non-carcinogenic risk, THI < 1, indicates low health risks, while the carcinogenic risk for As and Cd was significantly higher than the negligible threshold of 10⁻⁶, suggesting tolerable health risks. However, managing the contaminated area and minimizing the metal concentrations and predominant routes through which metals impact human health should be priorities for long-term development and to establish a favorable environment. Full article

Managed aquifer recharge (MAR) can address challenges pertaining to water quality and security, land subsidence, and aquifer degradation. This study has been conducted in the irrigated plains of Indus River Basin (IRB) of Pakistan, where groundwater is being used for drinking, agriculture, industries, and other commercial purposes and where the Punjab Government is implementing the MAR project. The study aims to assess the existing level of heavy metals and trace elements contamination in the groundwater and to set baseline data for the suitability of the site for the MAR project. Groundwater samples from 20 tubewells were collected from an area of 1522 km² to investigate the level of heavy metals concentration in groundwater and to assess its suitability for irrigation and drinking. Samples were analyzed for Aluminum (Al), Arsenic (As), Barium (Ba), Cadmium (Cd), Cobalt (Co), Copper (Cu), Chromium (Cr), Lead (Pb), Manganese (Mn), Molybdenum (Mo), Nickel (Ni), Selenium (Se), Strontium (Sr), and Zinc (Zn). To elucidate the contamination trend of these metals, the Heavy Metal Pollution Index (HPI), Heavy Metal Index (HI), geostatistical description, Pearson correlation analysis, and geospatial mapping were employed. Results showed that groundwater in the study area is not suitable for drinking and may pose serious health risks. It should be, however, generally suitable for irrigation. This concludes that the site is suitable for the implementation of a MAR project where the intended use of groundwater is for irrigation. It has been recommended that the groundwater may not be used for direct human consumption in the study area. It has been recommended, too, that targeted monitoring of identified hotspots and assessment of soil and crop uptake are conducted so that industrial or wastewater discharge into irrigation supplies may be prevented and controlled. For policy decisions, distinguishing irrigation suitability from potable-water safety is essential. Full article

Spirulina and Chlorella are nutrient-rich microalgae widely consumed as dietary supplements; however, their high biosorption capacity raises concerns regarding the accumulation of environmental contaminants. This study analyzed 52 commercially available Spirulina and Chlorella products (29 conventional, 23 organic) to assess the co-occurrence of heavy metals and pharmaceutical residues, as these two classes of contaminants represent distinct yet complementary indicators of environmental pollution—heavy metals reflect long-term inputs from natural and industrial sources, while pharmaceuticals signal more recent contamination linked to human activity and wastewater discharge. To the best of our knowledge, this is the first study to investigate the presence of pharmaceutical residues—including cardiovascular drugs, antidepressants, antibiotics, and sulfonamides—in both conventional and organic formulations of microalgae-based dietary supplements. The analyses were performed using Inductively Coupled Plasma Mass Spectrometry and liquid chromatography coupled to tandem mass spectrometry. Aluminum, manganese, strontium, and zinc were the dominant trace elements. All samples complied with EU regulatory limits for toxic metals. More importantly, a wide range of pharmaceutical residues was detected in the supplements. Caffeine was the most frequently found compound, followed by metronidazole, carbamazepine, benzocaine, and tramadol. Particular concern is raised by the calculated TWI (% of tolerable weekly intake) for aluminum. Principal Component Analysis revealed significant compositional differences between Spirulina and Chlorella products, with vanadium notably elevated in conventionally cultivated Spirulina. Surprisingly, no significant differences were observed between organic and conventional products within each algal type. Our findings provide a novel contribution to the field by highlighting the presence of pharmaceutical residues in microalgae-based supplements and addressing a critical knowledge gap concerning potential chronic exposure to these contaminants through dietary intake. Full article

This study examines the impact of an unintended fire at the Drava International plastic processing facility near Osijek, Croatia, on soil quality and the potential human health risks associated with agricultural soils within a 10 and 20 km radius. Surface soil samples (0–5 cm) were collected from ten locations within 10 km three days after the incident, and eight composite samples were taken from sites 10–20 km away 17 days’ post-event. Additionally, 18 control samples previously collected for soil fertility or quality monitoring were included for comparative analysis. In total, 36 agricultural soil samples were analyzed for pH, organic matter, total phosphorus, potassium, calcium, magnesium, and trace elements (Cr, Co, Ni, Cu, Zn, As, Pb). Eighteen post-fire samples were also analyzed for polycyclic aromatic hydrocarbons (PAHs), dioxins, and perfluoroalkyl substances (PFAS). Ecological risk was assessed using the pollution load index (PLI) and enrichment factor (EF), while human health risk was evaluated through the estimation of incremental lifetime cancer risk (ILCR) and individual carcinogenic risks (CRi) for As, Cr, Ni, and Pb. Results showed that concentrations of dioxins (TEQ LB and UB), dioxin-like PCBs, and non-dioxin-like PCBs in samples within 10 km were either below detection limits or present in trace amounts (4.0 × 10⁻⁶ mg/kg). PFAS compounds were not detected (<0.0005 mg/kg). The total concentration of non-dioxin-like PCBs ranged from 0.0023 to 0.0047 mg/kg, well below the maximum permissible levels. Post-fire contamination profiles revealed consistently higher PAH concentrations in the 0–10 km zone (mean 0.100 mg/kg) compared to the 10–20 km zone (mean 0.062 mg/kg). Twenty PLI values exceeded the threshold of 1 (range: 1.00–1.26), indicating moderate pollution, while the remaining values (PLI 0.82–0.99) suggested no pollution. EF values indicated minimal to moderate enrichment (EF < 2), supporting the conclusion that metal presence was predominantly geological with limited anthropogenic influence. All ILCR values for adults and children remained below the acceptable threshold of 1 × 10⁻⁴, indicating low carcinogenic risk under both pre- and post-fire conditions. CRi values followed a consistent decreasing trend across exposure pathways: ingestion > dermal absorption > inhalation. Full article

The Arieș River, in the Apuseni Mountains of Romania, has been historically impacted by gold mining, resulting in elevated concentrations of metal trace elements. This study assessed the river’s ecological status between 2022 and 2024 by integrating physico-chemical parameters at four sites and diatom-based bioindicators at the same sites in 2024 across monitoring sectors. Key results showed strong mining influence downstream of Baia de Arieș, with episodic acidification (pH down to 5.7), elevated conductivity (>400 μS/cm), and notable exceedances in metal trace elements, particularly Cu (up to 237 μg/L) and Cd (up to 4.18 μg/L). Analysis showed a dominance of α-mesosaprobic taxa (e.g., Amphora ovalis, Navicula cryptocephala, Nitzschia inconspicua), including teratological forms, at polluted sites, while sensitive species persisted upstream. Multivariate analyses indicated that metal trace elements and nutrients are the main drivers of chemical and biological patterns. These findings highlight diatoms as sensitive bioindicators of mining-related impacts. Incorporating diatom-based monitoring into management strategies can support early detection of pollution and more effective protection of freshwater ecosystems. Full article

Trace metal pollution has become an increasing concern in urban areas, mainly due to industrial activities and heightened human activities near water bodies. This study aimed to quantify the level of pollution caused by the trace metals Co, Cr, Cu, Mn, Ni, and Zn in surface sediments of Aurá and Guamá rivers, as well as Guajará Bay, in the metropolitan region of Belém (Northern Brazil). A total of 33 sediment samples were collected—14 from the Aurá River, 7 from the Guamá River, and 12 from Guajará Bay—during both the wet and dry seasons to capture seasonal variability. The studied trace metals were measured through inductively coupled plasma optical emission spectrometry (ICP-OES), and the decreasing order of concentration detected was the following: Mn > Zn > Cr > Ni > Co > Cu. To assess the degree of pollution, three geochemical indicators were employed: the Geoaccumulation Index (Igeo), which compares observed concentrations with natural background levels to classify contamination severity; the Enrichment Factor (EF), which helps distinguish between natural and anthropogenic sources of metals using a reference element (typically aluminum or iron); and the Mean-ERM-Quotient, which evaluates the potential ecotoxicological risk of the metals based on benchmark values for adverse effects on aquatic organisms. Based on these indicators, the sediments of the studied area can be classified as showing “moderate contamination and enrichment”. The metals Zn and Cu exhibited the highest degrees of enrichment, likely of anthropogenic origin. Overall, this study revealed that areas closer to sites of intense human activity are more susceptible to trace metal contamination, especially during the wet season. Frequent monitoring of areas classified as “contaminated” and time-series data are necessary to examine more deeply the pollution of river sediments and their potential changes concerning shifts in the status of urbanization and industrialization. Full article

Marine protected areas (MPAs) near the coast are a global concern due to potential impact of anthropogenic activities highly relevant when it comes to trace elements pollution in sediment. This study aims to assess the levels of trace elements in sediment, their potential mobility and the ecological risk in Tremiti Islands, a sensitive and vulnerable MPA. Sediment was analyzed for granulometry, mineralogy, pseudo-metal concentrations and available fractions using BCR method. Statistical analysis and different pollution and ecological risk indices were applied to interpret the results, determine the contamination levels and assess the element availability and their potential impact using Sediment Quality Guidelines. Spatial variability in grain size and mineralogy was found across the sampling sites. The finer quartz-rich sediments exhibiting higher trace element concentrations. Site-specific enrichments were evident for As and Zn at Cala Spido and for Pb at Cala Matano. Cu and Mn showed notable potential bioavailability with residual fractions below 30% at all sites; low Cd concentrations were found, but it was highly available. Cala Spido and Grotta del Sale showed higher contamination-degree, while Pagliai and Cala Matano stood out for their higher ecological risk and availability indexes. These findings demonstrated that even within a Marine Protected Area, site-specific anthropogenic pressures can significantly influence sediment quality and ecological risk. Full article