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Keywords = topological domain walls

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13 pages, 5029 KiB  
Article
Crystal Structure of the Multidomain Pectin Methylesterase PmeC5 from Butyrivibrio fibrisolvens D1T
by Vincenzo Carbone, Kerri Reilly, Carrie Sang, Linley R. Schofield, William J. Kelly, Ron S. Ronimus, Graeme T. Attwood and Nikola Palevich
Biomolecules 2025, 15(5), 720; https://doi.org/10.3390/biom15050720 - 14 May 2025
Viewed by 466
Abstract
Pectin is a dynamic and complex polysaccharide that forms a substantial proportion of the primary plant cell wall and middle lamella of forage ingested by grazing ruminants. Pectin methylesterases (PMEs) are enzymes that belongs to the carbohydrate esterase family 8 (CE8) and catalyze [...] Read more.
Pectin is a dynamic and complex polysaccharide that forms a substantial proportion of the primary plant cell wall and middle lamella of forage ingested by grazing ruminants. Pectin methylesterases (PMEs) are enzymes that belongs to the carbohydrate esterase family 8 (CE8) and catalyze the demethylesterification of pectin, a key polysaccharide in cell walls. Here we present the crystal structure of the catalytic domain of PmeC5 that is associated with a gene from Butyrivibrio fibrisolvens D1T that encodes a large secreted pectinesterase family protein (2089 aa) determined to a resolution of 1.33 Å. Protein in silico modelling of the secreted pectinesterase confirmed the presence of an additional pectate lyase (PL9) and adhesin-like domains. The structure of PmeC5 was the characteristic right-handed parallel β-helical topology and active site residues of Asp231, Asp253, and Arg326 typical of the enzyme class. PmeC5 is a large modular enzyme that is characteristic of rumen B. fibrisolvens megaplasmids and plays a central role in degrading plant cell wall components and releasing methanol in the rumen environment. Such secreted PMEs are significant contributors to plant fiber digestion and methane production, making them attractive targets for both methane mitigation strategies and livestock productivity enhancement. Full article
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10 pages, 3175 KiB  
Article
Electric Field-Defined Superlattices in Bilayer Graphene: Formation of Topological Bands in Two Dimensions
by Włodzimierz Jaskólski
Materials 2025, 18(7), 1521; https://doi.org/10.3390/ma18071521 - 28 Mar 2025
Viewed by 532
Abstract
An electric field applied to the Bernal-stacked bilayer graphene opens an energy gap; its reversal in some regions creates domain walls and leads to the appearance of one-dimensional chiral gapless states localized at the walls. Here, we investigate the energy structure of bilayer [...] Read more.
An electric field applied to the Bernal-stacked bilayer graphene opens an energy gap; its reversal in some regions creates domain walls and leads to the appearance of one-dimensional chiral gapless states localized at the walls. Here, we investigate the energy structure of bilayer graphene with superlattice potential defined by an external electric field. The calculations are performed within an atomistic π-electron tight-binding approximation. We study one-dimensional and two-dimensional superlattices formed by arrays of electric-field walls in the zigzag and armchair directions and investigate different field polarizations. Chiral gapless states discretize due to the superlattice potential and transform into minibands in the energy gap. As the main result, we show that the minibands can cross at the Fermi level for some field polarizations. This leads to a new kind of two-dimensional gapless states of topological character that form Dirac-like cones at the crossing points. This also has application potential: changing the field polarization can close the energy gap and change the character of the superlattice from semiconducting to metallic. Full article
(This article belongs to the Special Issue Quantum Transport in Novel 2D Materials and Structures)
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25 pages, 717 KiB  
Review
Baryon Construction with η Meson Field
by Fan Lin and Yong-Liang Ma
Symmetry 2025, 17(4), 477; https://doi.org/10.3390/sym17040477 - 21 Mar 2025
Viewed by 439
Abstract
In the low-energy regime, baryons with Nf2 have long been constructed as skyrmions or through bag models, but such constructions for Nf=1 are hindered by the trivial topological structure of the meson field. Recent proposals suggest that [...] Read more.
In the low-energy regime, baryons with Nf2 have long been constructed as skyrmions or through bag models, but such constructions for Nf=1 are hindered by the trivial topological structure of the meson field. Recent proposals suggest that one-flavor baryons can instead be interpreted as quantum Hall droplets on the η domain wall, providing a potential link to quark–hadron continuity at high density. In retrospect, the qualitative or semi-qualitative construction of one-flavor baryons on the η domain wall reveals that these baryons can be described as quantum Hall droplets, resembling topological solitons akin to skyrmions. Using an effective theory on the η domain wall, which is conjectured to be the Chern–Simons–Higgs theory, it is discussed that its vortex solution with unit baryon numbers naturally has a spin of Nc/2, and thus can be interpreted as a baryon or multi-baryon structure. The particle–vortex duality suggests that quarks carry a fractional topological charge of 1/Nc and obey fractional statistics. In terms of chiral bag models, confinement can be attributed to the monopoles confined within the bag, and the vector meson fields on the bag surface are essential for ensuring the correct baryon number in the chiral bag framework, thereby providing deeper insights into baryons as non-trivial topological structures of the meson field. In this paper, we review the progress in this development, with a special focus on the η domain wall dynamics. Naive extensions to Nf2 are also discussed. Full article
(This article belongs to the Section Physics)
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13 pages, 6271 KiB  
Article
Bound States and Particle Production by Breather-Type Background Field Configurations
by Abhishek Rout and Brett Altschul
Symmetry 2024, 16(12), 1571; https://doi.org/10.3390/sym16121571 - 24 Nov 2024
Cited by 1 | Viewed by 685
Abstract
We investigate the interaction of fermion fields with oscillating domain walls, inspired by breather-type solutions of the sine-Gordon equation, a nonlinear system of fundamental importance. Our study focuses on the fermionic bound states and particle production induced by a time-dependent scalar background field. [...] Read more.
We investigate the interaction of fermion fields with oscillating domain walls, inspired by breather-type solutions of the sine-Gordon equation, a nonlinear system of fundamental importance. Our study focuses on the fermionic bound states and particle production induced by a time-dependent scalar background field. The fermions couple to two domain walls undergoing harmonic motion, and we explore the resulting dynamics of the fermionic wave functions. We demonstrate that while fermions initially form bound states around the domain walls, the energy provided by the oscillatory motion of the scalar field induces an outward flux of fermions and antifermions, leading to particle production and eventual flux propagation toward spatial infinity. Through numerical simulations, we observe that the fermion density exhibits quasiperiodic behavior, with partial recurrences of the bound state configurations after each oscillation period. However, the fermion wave functions do not remain localized, and over time, the density decreases as more particles escape the vicinity of the domain walls. Our results highlight that the sine-Gordon-like breather background, when coupled non-supersymmetrically to fermions, does not preserve integrability or stability, with the oscillations driving a continuous energy transfer into the fermionic modes. This study sheds light on the challenges of maintaining steady-state fermion solutions in time-dependent topological backgrounds and offers insights into particle production mechanisms in nonlinear dynamical systems with oscillating solitons. Full article
(This article belongs to the Section Physics)
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13 pages, 2915 KiB  
Article
The Nested Topological Band-Gap Structure for the Periodic Domain Walls in a Photonic Super-Lattice
by Zhen Lai, Yufu Liu, Yunlin Li, Xuezhi Wang and Xunya Jiang
Crystals 2024, 14(9), 757; https://doi.org/10.3390/cryst14090757 - 26 Aug 2024
Viewed by 985
Abstract
We study the nested topological band-gap structure of one-dimensional (1D) photonic super-lattices. One cell of the super-lattice is composed of two kinds of photonic crystals (PhCs) with different topologies so that there is a domain wall (DW) state at the interface between the [...] Read more.
We study the nested topological band-gap structure of one-dimensional (1D) photonic super-lattices. One cell of the super-lattice is composed of two kinds of photonic crystals (PhCs) with different topologies so that there is a domain wall (DW) state at the interface between the two PhCs. We find that the coupling of periodic DWs could form a new band-gap structure inside the original gap. The new band-gap structure could be topologically nontrivial, and a topological phase transition can occur if the structural or material parameters of the PhCs are tuned. Theoretically, we prove that the Hamiltonian of such coupled DWs can be reduced to the simple Su–Schrieffer–Heeger (SSH) model. Then, if two super-lattices carrying different topological phases are attached, a new topological interface state can occur at the interface between the two super-lattices. Finally, we find the nested topological band-gap structure in two-dimensional (2D) photonic super-lattices. Consequently, such nested topological structures can widely exist in complex super-lattices. Our work improves the topological study of photonic super-lattices and provides a new way to realize topological interface states and topological phase transitions in 1D and 2D photonic super-lattices. Topological interface states in super-lattices are sensitive to frequency and have high accuracy, which is desired for high-performance filters and high-finesse cavities. Full article
(This article belongs to the Special Issue Topological Photonic Crystals)
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12 pages, 2980 KiB  
Communication
Simulation Study of Localized, Multi-Directional Continuous Dynamic Tailoring for Optical Skyrmions
by Gao Tang, Chunyan Bai, Yuxing Zhang, Zhening Zhao and Dawei Zhang
Photonics 2024, 11(6), 499; https://doi.org/10.3390/photonics11060499 - 24 May 2024
Viewed by 1610
Abstract
The topological properties of optical skyrmions have enormous application value in fields such as optical communication and polarization sensing. At present, research on optical skyrmions focuses primarily on the topological principles of skyrmions and their applications. Nonetheless, extant research devoted to skyrmion-array manipulation [...] Read more.
The topological properties of optical skyrmions have enormous application value in fields such as optical communication and polarization sensing. At present, research on optical skyrmions focuses primarily on the topological principles of skyrmions and their applications. Nonetheless, extant research devoted to skyrmion-array manipulation remains meager. The sole manipulation scheme has a limited effect on the movement direction of the whole skyrmion array. Based on the interference principle of the surface plasmon polariton (SPP) wave, we propose an upgraded scheme for the tailoring of electric-field optical skyrmions. A distributed Gaussian-focused spots array is deployed. Unlike the existing manipulation, we customize the phase of the light source to be more flexible, and we have discovered optical-skyrmion tailoring channels and shaping channels. Specifically, we move the skyrmions within the channel in both directions and manipulate the shape of the topological domain walls to achieve customized transformation. This work will evolve towards a more flexible regulatory plan for tailoring optical-skyrmion arrays, and this is of great significance for research in fields such as optical storage and super-resolution microimaging. Full article
(This article belongs to the Special Issue Optoelectronic Detection Technologies and Applications)
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14 pages, 2375 KiB  
Article
Artificial Neuron Based on the Bloch-Point Domain Wall in Ferromagnetic Nanowires
by Carlos Sánchez, Diego Caso and Farkhad G. Aliev
Materials 2024, 17(10), 2425; https://doi.org/10.3390/ma17102425 - 17 May 2024
Cited by 1 | Viewed by 1310
Abstract
Nanomagnetism and spintronics are currently active areas of research, with one of the main goals being the creation of low-energy-consuming magnetic memories based on nanomagnet switching. These types of devices could also be implemented in neuromorphic computing by crafting artificial neurons (ANs) that [...] Read more.
Nanomagnetism and spintronics are currently active areas of research, with one of the main goals being the creation of low-energy-consuming magnetic memories based on nanomagnet switching. These types of devices could also be implemented in neuromorphic computing by crafting artificial neurons (ANs) that emulate the characteristics of biological neurons through the implementation of neuron models such as the widely used leaky integrate-and-fire (LIF) with a refractory period. In this study, we have carried out numerical simulations of a 120 nm diameter, 250 nm length ferromagnetic nanowire (NW) with the aim of exploring the design of an artificial neuron based on the creation and destruction of a Bloch-point domain wall. To replicate signal integration, we applied pulsed trains of spin currents to the opposite faces of the ferromagnetic NW. These pulsed currents (previously studied only in the continuous form) are responsible for inducing transitions between the stable single vortex (SV) state and the metastable Bloch point domain wall (BP-DW) state. To ensure the system exhibits leak and refractory properties, the NW was placed in a homogeneous magnetic field of the order of mT in the axial direction. The suggested configuration fulfills the requirements and characteristics of a biological neuron, potentially leading to the future creation of artificial neural networks (ANNs) based on reversible changes in the topology of magnetic NWs. Full article
(This article belongs to the Special Issue Nanowires: Growth and Applications)
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8 pages, 3455 KiB  
Article
Metal–Semiconductor Behavior along the Line of Stacking Order Change in Gated Multilayer Graphene
by Włodzimierz Jaskólski
Materials 2024, 17(8), 1915; https://doi.org/10.3390/ma17081915 - 21 Apr 2024
Viewed by 1256
Abstract
We investigated gated multilayer graphene with stacking order changes along the armchair direction. We consider that some layers cracked to release shear strain at the stacking domain wall. The energy cones of graphene overlap along the corresponding direction in the k-space, so [...] Read more.
We investigated gated multilayer graphene with stacking order changes along the armchair direction. We consider that some layers cracked to release shear strain at the stacking domain wall. The energy cones of graphene overlap along the corresponding direction in the k-space, so the topological gapless states from different valleys also overlap. However, these states strongly interact and split due to atomic-scale defects caused by the broken layers, yielding an effective energy gap. We find that for some gate voltages, the gap states cross and the metallic behavior along the stacking domain wall can be restored. In particular cases, a flat band appears at the Fermi energy. We show that for small variations in the gate voltage, the charge occupying this band oscillates between the outer layers. Full article
(This article belongs to the Special Issue Nanodevices in 2D Materials: Theory and Simulations)
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39 pages, 49187 KiB  
Article
A New Car-Body Structure Design for High-Speed EMUs Based on the Topology Optimization Method
by Chunyan Liu, Kai Ma, Tao Zhu, Haoxu Ding, Mou Sun and Pingbo Wu
Appl. Sci. 2024, 14(3), 1074; https://doi.org/10.3390/app14031074 - 26 Jan 2024
Cited by 2 | Viewed by 2266
Abstract
In recent years, the research and development of high-speed trains has advanced rapidly. The main development trends of high-speed trains are higher speeds, lower energy consumption, higher safety, and better environmental protection. The realization of a lightweight high-speed car body is one of [...] Read more.
In recent years, the research and development of high-speed trains has advanced rapidly. The main development trends of high-speed trains are higher speeds, lower energy consumption, higher safety, and better environmental protection. The realization of a lightweight high-speed car body is one of the key features in the development trend of high-speed trains. Firstly, the basic dimensions of the car body’s geometric model are determined according to the external dimensions of the body of a CRH EMU, and the specific topology optimization design domain is selected to establish the finite element analysis model; secondly, the strength and modal analyses of the topology optimization design domain are carried out to check the accuracy of the design domain and provide a comparative analysis for subsequent design. Then, the variables, constraints, and objective functions of the topology optimization design are determined to establish the mathematical model of topology optimization, and the design domain is calculated for topology optimization under single and multiple conditions, respectively. Finally, based on the topology optimization calculation results, truss-type reconstruction modeling is carried out for the car body’s side walls, roof, underframe, end walls, and other parts. Compared with the conventional EMU body structure, the weight of the reconstructed body structure is reduced by about 18%. The results of the finite element analysis of the reconstructed car-body structure prove the reliability and safety of the structure, indicating that the reconstructed car-body scheme meets the corresponding performance indicators. Full article
(This article belongs to the Collection Analysis of Dynamics of Railway Vehicles)
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11 pages, 3466 KiB  
Communication
A Simulation Study of the Dynamical Control of Optical Skyrmion Lattices through the Superposition of Optical Vortex Beams
by Gao Tang, Chunyan Bai, Tianchen Tang, Jiansheng Peng, Songlin Zhuang and Dawei Zhang
Photonics 2023, 10(11), 1259; https://doi.org/10.3390/photonics10111259 - 14 Nov 2023
Viewed by 1873
Abstract
Optical skyrmion lattices play an important role in photonic system design and have potential applications in optical transmission and storage. In this study, we propose a novel metasurface approach to calculating the dependence of the multi-beam interference principle and the angular momentum action [...] Read more.
Optical skyrmion lattices play an important role in photonic system design and have potential applications in optical transmission and storage. In this study, we propose a novel metasurface approach to calculating the dependence of the multi-beam interference principle and the angular momentum action in the spin–orbit interaction. The metasurface consists of nanopore structures, which are used to generate an optical skyrmion lattice. The superposition of optical vortex beams with circular polarization states is used to evaluate the evolution of the shape of the topological domain walls of the hexagonal skyrmion lattice. Our results show that the distribution of the skyrmion spin vector can be controlled by changing the lattice arrangement from triangular to hexagonal shapes. The distribution of skyrmion number at the microscale is further calculated. Our work has significant implications for the regulation of the shape of topological domain walls of skyrmion lattices, with potential applications in polarization sensing, nanopositioning, and super-resolution microimaging. Full article
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14 pages, 7778 KiB  
Article
Topological Edge States on Different Domain Walls of Two Opposed Helical Waveguide Arrays
by Junying Wang, Zhiwei Shi, Xifeng Ji, Yajing Zhang, Huagang Li, Yaohua Deng and Kang Xie
Photonics 2023, 10(11), 1220; https://doi.org/10.3390/photonics10111220 - 31 Oct 2023
Cited by 2 | Viewed by 1730
Abstract
Floquet topological insulators (FTIs) have richer topological properties than static systems. In this work, we designed different domain wall (DW) structures consisting of a Floquet photonic lattice with opposite helical directions. We investigated the existence and types of edge states in three shared [...] Read more.
Floquet topological insulators (FTIs) have richer topological properties than static systems. In this work, we designed different domain wall (DW) structures consisting of a Floquet photonic lattice with opposite helical directions. We investigated the existence and types of edge states in three shared coupling structures and the impact of these shared coupling structures on edge states. When two opposite helical lattices share a straight waveguide array coupling, the edge states are localized on the straight waveguide. When two opposite helical lattices share a clockwise (or anticlockwise) helical waveguide array coupling, the DWs consist of zigzag and bearded edges, but the positions of the zigzag and bearded edges of the shared clockwise waveguide array are different from those of the shared anticlockwise waveguide array. The slope and transmission rate of the edge states both vary with the degree of coupling between the shared waveguides. The characteristics of these edge states, such as transmission speed and band gap width, are also affected by the incidence angle, modulation phase factor, and helical radii, and the methods for controlling the edge states in different shared coupling structures are provided. This will help deepen our understanding of how topological structures influence the electronic and photonic properties of materials. This could also lead to combining topology with metasurface-based structured light, which would highlight many novel properties with great application potential for various fields, such as imaging, metrology, communication, quantum information processing, and light–matter interaction. Full article
(This article belongs to the Special Issue Emerging Topics in Structured Light)
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10 pages, 288 KiB  
Article
Planck Constants in the Symmetry Breaking Quantum Gravity
by Grigory E. Volovik
Symmetry 2023, 15(5), 991; https://doi.org/10.3390/sym15050991 - 27 Apr 2023
Cited by 7 | Viewed by 1841
Abstract
We consider the theory of quantum gravity in which gravity emerges as a result of the symmetry-breaking transition in the quantum vacuum. The gravitational tetrads, which play the role of the order parameter in this transition, are represented by the bilinear combinations of [...] Read more.
We consider the theory of quantum gravity in which gravity emerges as a result of the symmetry-breaking transition in the quantum vacuum. The gravitational tetrads, which play the role of the order parameter in this transition, are represented by the bilinear combinations of the fermionic fields. In this quantum gravity scenario the interval ds in the emergent general relativity is dimensionless. Several other approaches to quantum gravity, including the model of superplastic vacuum and BF theories of gravity support this suggestion. The important consequence of such metric dimension is that all the diffeomorphism invariant quantities are dimensionless for any dimension of spacetime. These include the action S, cosmological constant Λ, scalar curvature R, scalar field Φ, wave function ψ, etc. The composite fermion approach to quantum gravity suggests that the Planck constant can be the parameter of the Minkowski metric. Here, we extend this suggestion by introducing two Planck constants, bar and slash /h, which are the parameters of the correspondingly time component and space component of the Minkowski metric, gMinkμν=diag(2,/h2,/h2,/h2). The parameters bar and slash /h are invariant only under SO(3) transformations, and, thus, they are not diffeomorphism invariant. As a result they have non-zero dimensions—the dimension of time for and dimension of length for /h. Then, according to the Weinberg criterion, these parameters are not fundamental and may vary. In particular, they may depend on the Hubble parameter in the expanding Universe. They also change sign at the topological domain walls resulting from the symmetry breaking. Full article
(This article belongs to the Special Issue Symmetry and Asymmetry in Gravity Research)
18 pages, 11048 KiB  
Article
Exploring the Piezoelectric Properties of Bismuth Ferrite Thin Films Using Piezoelectric Force Microscopy: A Case Study
by Denis Misiurev, Pavel Kaspar, Dinara Sobola, Nikola Papež, Saleh H. Fawaeer and Vladimír Holcman
Materials 2023, 16(8), 3203; https://doi.org/10.3390/ma16083203 - 18 Apr 2023
Cited by 8 | Viewed by 2765
Abstract
Over recent decades, the scientific community has managed to make great progress in the theoretical investigation and practical characterization of bismuth ferrite thin films. However, there is still much work to be completed in the field of magnetic property analysis. Under a normal [...] Read more.
Over recent decades, the scientific community has managed to make great progress in the theoretical investigation and practical characterization of bismuth ferrite thin films. However, there is still much work to be completed in the field of magnetic property analysis. Under a normal operational temperature, the ferroelectric properties of bismuth ferrite could overcome the magnetic properties due to the robustness of ferroelectric alignment. Therefore, investigation of the ferroelectric domain structure is crucial for functionality of any potential devices. This paper reports deposition and analyzation of bismuth ferrite thin films by Piezoresponse Force Microscopy (PFM) and XPS methods, aiming to provide a characterization of deposited thin films. In this paper, thin films of 100 nm thick bismuth ferrite material were prepared by pulsed laser deposition on multilayer substrates Pt/Ti(TiO2)/Si. Our main purpose for the PFM investigation in this paper is to determine which magnetic pattern will be observed on Pt/Ti/Si and Pt/TiO2/Si multilayer substrates under certain deposition parameters by utilizing the PLD method and using samples of a deposited thickness of 100 nm. It was also important to determine how strong the measured piezoelectric response will be, considering parameters mentioned previously. By establishing a clear understanding of how prepared thin films react on various biases, we have provided a foundation for future research involving the formation of piezoelectric grains, thickness-dependent domain wall formations, and the effect of the substrate topology on the magnetic properties of bismuth ferrite films. Full article
(This article belongs to the Special Issue Advances in Functional Magnetic Nanomaterials)
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10 pages, 3034 KiB  
Article
Electronic Dislocation Dynamics in Metastable Wigner Crystal States
by Andrej Kranjec, Petr Karpov, Yevhenii Vaskivskyi, Jaka Vodeb, Yaroslav Gerasimenko and Dragan Mihailovic
Symmetry 2022, 14(5), 926; https://doi.org/10.3390/sym14050926 - 1 May 2022
Cited by 4 | Viewed by 2660
Abstract
Metastable states appear in many areas of physics as a result of symmetry-breaking phase transitions. An important challenge is to understand the microscopic mechanisms which lead to the formation of the energy barrier separating a metastable state from the ground state. In this [...] Read more.
Metastable states appear in many areas of physics as a result of symmetry-breaking phase transitions. An important challenge is to understand the microscopic mechanisms which lead to the formation of the energy barrier separating a metastable state from the ground state. In this paper, we describe an experimental example of the hidden metastable domain state in 1T-TaS2, created by photoexcitation or carrier injection. The system is an example of a charge density wave superlattice in the Wigner crystal limit displaying discommensurations and domain formation when additional charge is injected either through contacts or by photoexcitation. The domain walls and their crossings in particular display interesting, topologically entangled structures, which have a crucial role in the metastability of the system. We model the properties of experimentally observed thermally activated dynamics of topologically protected defects—dislocations—whose annihilation dynamics can be observed experimentally by scanning tunnelling microscopy as emergent phenomena described by a doped Wigner crystal. The different dynamics of trivial and non-trivial topological defects are quite striking. Trivial defects appear to annihilate quite rapidly at low temperatures on the timescale of the experiments, while non-trivial defects annihilate rarely, if at all. Full article
(This article belongs to the Special Issue Topological Objects in Correlated Electronic Systems)
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27 pages, 8555 KiB  
Review
Topological Excitations in Neutral–Ionic Transition Systems
by Keishi Sunami, Ryosuke Takehara, Kazuya Miyagawa, Hiroshi Okamoto and Kazushi Kanoda
Symmetry 2022, 14(5), 925; https://doi.org/10.3390/sym14050925 - 1 May 2022
Cited by 3 | Viewed by 6988
Abstract
The existence and physical properties of topological excitations in ferroelectrics, especially mobile topological boundaries in one dimension, are of profound interest. Notably, topological excitations emerging in association with the neutral–ionic (NI) phase transition are theoretically suggested to carry fractional charges and cause anomalous [...] Read more.
The existence and physical properties of topological excitations in ferroelectrics, especially mobile topological boundaries in one dimension, are of profound interest. Notably, topological excitations emerging in association with the neutral–ionic (NI) phase transition are theoretically suggested to carry fractional charges and cause anomalous charge transport. In recent years, we experimentally demonstrated mobile topological excitations in a quasi-one-dimensional (1D) ferroelectric, tetrathiafulvalene-p-chloranil [TTF-CA; TTF (C6H4S4) and CA (C6Cl4O2)], which shows the NI transition, using NMR, NQR, and electrical resistivity measurements. Thermally activated topological excitations carry charges and spins in the NI crossover region and in the ionic phase with a dimer liquid. Moreover, free solitons show a binding transition upon a space-inversion symmetry-breaking ferroelectric order. In this article, we review the recent progress in the study of mobile topological excitations emerging in TTF-CA, along with earlier reports that intensively studied these phenomena, aiming to provide the foundations of the physics of electrical conductivity and magnetism carried by topological excitations in the 1D ferroelectric. Full article
(This article belongs to the Special Issue Topological Objects in Correlated Electronic Systems)
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