Search Results (124)

Much focus is being dedicated to the development of innovative technologies for producing biodegradable polymers from plant biomass. It is proposed that annual and perennial herbaceous plants, such as miscanthus, be used as promising sources of cellulose. The component composition of miscanthus allows us to consider it as a raw material for obtaining cellulose. This paper proposes methods for cooking miscanthus lignocellulose raw materials, which allow sulfate cellulose to be obtained with a high yield (up to 52%). In the process of obtaining chemical–thermomechanical pulp, the product yield is 71%. The possibility of replacing unbleached sulfate pulp with a semi-finished product from miscanthus for paper production is considered. For all types of raw materials obtained, acceptable paper-forming properties are observed. The best strength and deformation properties are obtained for sulfate cellulose. The addition of this cellulose to the composition of waste paper fluting significantly increases the sheet density, elasticity, and energy capacity without losing tensile strength. Using miscanthus raw materials along with waste paper of grade MS 5B makes it possible to make a composite product. The resulting products have optimal mechanical properties for creating the middle layer of corrugated cardboard. Miscanthus cellulose can be considered a promising raw material for enhancing waste paper fluting. Altering the system composition utilizing miscanthus and waste paper enables a broad modification of the mechanical and optical qualities of the resultant paper. The recommended concentration of miscanthus fraction in waste paper fluting is 30%. Full article

This study addresses recurring failures of a gas boiler with a steam capacity of 65,000 kg/h, which is operating in a Polish industrial plant. To determine the cause, material examinations were carried out, including chemical composition and microstructural analysis of SA178A steel, as well as strength tests. The results revealed no significant material degradation outside the cracking zones, suggesting that the failures were primarily caused by thermo-mechanical interactions. A finite element model in Ansys Workbench software was developed, incorporating thermal and mechanical boundary conditions, to reproduce the behavior of the critical section. The analysis demonstrated stress concentrations at the junction between the box and the membrane wall, resulting from large thermal displacement differences. The plastic strains under static loading do not exceed 5%, which implies that, without considering the cyclic nature of boiler operation, the wall should not experience failure. Analysis taking into account only 3 full operating cycles indicates a continuous increase in plastic deformation, which leads to the occurrence of ratcheting. To mitigate these effects, a modification of the sealing box design was proposed. Simulations indicated a reduction in plasticized zones by approximately 65%, and the effectiveness of the solution was confirmed by two years of failure-free operation. The findings highlight the importance of an integrated diagnostic, numerical, and design approach to improving boiler durability. Full article

This work aimed to synthesize rigid polyurethane foams with improved functional properties through modification with the addition of cellulose in the form of straw: unmodified, silanized, and silanized with the addition of fumed silica. The prepared rigid polyurethane foams contained 0.5; 1; and 3 parts by weight of the modifier about the weight of the polyol used. As part of the work, a number of tests were carried out to determine the impact of the modifiers used on the reaction kinetics and on the functional properties of rigid polyurethane foams. Silanization improved thermal stability and interfacial compatibility, while silica further enhanced porosity and surface activity. The optimal properties were obtained at low loadings: 0.5 wt.% provided the best mechanical strength, and 1 wt.% yielded the most uniform cell morphology and density. Higher contents increased porosity, reduced strength, and lowered water resistance. Dynamic mechanical analysis confirmed predominantly elastic behavior, with silica-modified fillers offering the most stable thermomechanical response. Overall, even small amounts of modified straw enhanced mechanical, structural, and water-resistant properties, demonstrating its potential as a sustainable and cost-effective biofiller for eco-friendly polyurethane foams. Full article

The profound Phanerozoic destruction of the eastern North China Craton (NCC) is well documented, yet its mechanism remains debated due to limited constraints on thermal state and lithospheric thickness during the Early Cretaceous—the peak period of cratonic destruction. We address this gap through integrated geochemical analysis (major/trace elements, Sr-Nd-Pb isotopes, olivine chemistry) of Early Cretaceous (~125 Ma) Fangcheng basalts from Shandong. These basalts possess high MgO (8.14–11.31 wt%), Mg# (67.23–73.69), Ni (126–244 ppm), and Cr (342–526 ppm). Their trace elements show island arc basalt (IAB) affinities: enrichment in large-ion lithophile elements and depletion in high-field-strength elements, with negative Sr and Pb anomalies. Enriched Sr-Nd isotopic compositions [⁸⁷Sr/⁸⁶Sr(t) = 0.709426–0.709512; ε_Nd(t) = −12.60 to −13.10], unradiogenic ²⁰⁶Pb/²⁰⁴Pb(t) and ²⁰⁸Pb/²⁰⁴Pb(t) ratios (17.55–17.62 and 37.77–37.83, respectively), and slightly radiogenic ²⁰⁷Pb/²⁰⁴Pb(t) ratios (15.55–15.57) reflect an upper continental crustal signature. Covariations of major elements, Cr, Ni, and trace element ratios (Sr/Nd, Sc/La) with MgO indicate dominant olivine + pyroxene fractionation. High Ce/Pb ratios and lack of correlation between Ce/Pb or ε_Nd(t) and SiO₂ preclude significant crustal contamination. The combined isotopic signature and IAB-like trace element patterns support a lithospheric mantle source that was metasomatized by upper crustal material. Olivine phenocrysts exhibit variable Ni (1564–4786 ppm), Mn (903–2406 ppm), Fe/Mn (56.63–85.49), 10,000 × Zn/Fe (9.55–19.55), and Mn/Zn (7.07–14.79), defining fields indicative of melts from both peridotite and pyroxenite sources. High-MgO samples (>10 wt%) in the Grossular/Pyrope/Diopside/Enstatite diagram show a clinopyroxene, garnet, and olivine residue. Reconstructed primary melts yield formation pressures of 3.5–3.9 GPa (110–130 km depth) and temperatures of 1474–1526 °C, corresponding to ~60 mW/m² surface heat flow. This demonstrates retention of a ≥110–130 km thick lithosphere during peak destruction, arguing against delamination and supporting a thermo-mechanic erosion mechanism dominated by progressive convective thinning of the lithospheric base via asthenospheric flow. Our findings therefore provide crucial thermal and structural constraints essential for resolving the dynamics of cratonic lithosphere modification. Full article

A novel high-temperature-resistant W-B₄C-poly(4-methyl-1-pentene) (PMP) composite shielding material against neutron and gamma rays was developed and fabricated. Firstly, utilizing the ²³⁵U-induced fission spectrum as the source term, the compositional ratio of the W-B₄C-PMP ternary composite was optimized using the genetic algorithm-based GENOCOPIII program coupled with MCNP simulations. Then, the composite was fabricated through coupling agent modification, melt mixing, and hot pressing. Finally, the effects of coupling modification and tungsten content on the thermomechanical properties of the composite were investigated. Results demonstrated that functional groups from the silane coupling agent KH550 were successfully grafted onto the filler surfaces. For composites containing 30 wt% modified B₄C and 40 wt% modified W in the PMP matrix, the heat deflection temperature (HDT) increased by 18.5% and 19.1%, respectively, compared to their unmodified counterparts. The impact strength also improved by 31.6% and 5.0%, respectively. The variation trend of the composite’s modulus approximately followed the classical Einstein model, while its tensile strength and flexural strength conformed precisely to the model: ${\displaystyle \frac{{\mathsf{\sigma }}_{\mathrm{c}}}{{\mathsf{\sigma }}_{\mathrm{m}}}}=0.88{\mathrm{V}}_{\mathrm{f}}^{-0.02}$. Thermal analysis indicated that the composites possessed a melting point exceeding 230 °C, and their thermal stability improved with increasing filler content. Full article

This study investigates the modification of bitumen using mechanochemically devulcanized crumb rubber. The objective of this research is to enhance the performance characteristics of bituminous binders while addressing the inherent limitations associated with conventional crumb rubber (CCR), such as insufficient dispersion, elevated viscosity, and phase instability. Preliminary chemical activation of the crumb rubber was performed using a planetary ball mill, followed by thermomechanical devulcanization on a two-roll open mixing mill. Structural features of the devulcanized crumb rubber were analyzed using infrared spectroscopy, which confirmed the breakdown of S–S bonds. This study presents a comparative analysis of the performance characteristics of rubber–bitumen binders produced using both conventional rubber crumb (CRC) and devulcanized rubber crumb (DRC). The use of DCR, obtained mechanochemically from rubber waste, improved penetration, Fraass breaking point and the ring and ball softening point on average at high concentrations (20; 25% crumb rubber) compared to conventional crumb rubber by 33%, 66% and 2.4%, respectively. Optical microscopy revealed the formation of a uniform mesh-like rubber structure within the bitumen matrix, which contributes to enhanced performance characteristics of the modified binder and improved mechanical strength of the material. The key contribution of this work lies in the development and experimental validation of an efficient approach to deep devulcanization of crumb rubber via mechanochemical activation using readily available nitrogen-containing reagents. Furthermore, the study establishes a direct correlation between the degree of devulcanization, the dispersion quality of rubber particles within the bitumen matrix, and the resultant performance characteristics of the modified binder. Full article

Resol phenol–formaldehyde (PF) resin was modified with 2.5 and 5.0 wt% polymethylhydrosiloxane (PMHS). This study characterizes the modified resin and its subsequently fabricated glass fiber (GF)-reinforced composites (30–60 wt% GF). Formation of an organic–inorganic hybrid network, via reaction between Si-H groups of PMHS and hydroxyl (-OH) groups of the resol resin, was confirmed by FTIR and ¹H NMR. DSC and TGA/DTG revealed enhanced thermal stability for PMHS-modified resin: the decomposition temperature of Resol–PMHS 5.0% increased to 483 °C (neat resin: 438 °C), and char yield at 800 °C rose to 57% (neat resin: 38%). The 60 wt% GF-reinforced Resol–PMHS 5.0% composite exhibited tensile, flexural, and impact strengths of 145 ± 7 MPa, 160 ± 7 MPa, and 71 ± 5 kJ/m², respectively, superior to the unmodified resin composite (136 ± 6 MPa, 112 ± 6 MPa, and 51 ± 5 kJ/m²). SEM observations indicated improved fiber–matrix interfacial adhesion and reduced delamination. These results demonstrate that PMHS modification effectively enhances the thermo-mechanical properties of the PF resin and its composites, highlighting potential for industrial applications. Full article

To address the deficiencies of traditional emulsified asphalt-pavement maintenance material in cohesive strength, high-temperature rutting resistance, as well as adhesion to aggregates, this study developed waterborne epoxy resin-modified emulsified asphalt (WEA) binders using a two-component waterborne epoxy resin (WER) and systematically investigated their modification mechanisms and pavement performance. The results indicated that WER emulsions and curing agents could polymerize to form epoxy resin within the emulsified asphalt dispersion medium, with the modification process dominated by physical interactions. When the WER content exceeded 12%, a continuous modifier network structure was established within the emulsified asphalt. The epoxy resin formed after curing could significantly increase the polarity component of the binder, thereby increasing the surface free energy. The linear viscoelastic range of the WEA binder exhibited a negative correlation with the dosage of the WER modifier. Notably, when the WER content exceeded 6%, the high-temperature stability (rutting resistance and elastic recovery performance) of the binder was significantly enhanced. Concurrently, stress sensitivity and frequency dependence gradually decrease, demonstrating superior thermomechanical stability. Furthermore, WER significantly enhanced the interfacial interaction and adhesion between the binder and aggregates. However, the incorporation of WER adversely affects the low-temperature cracking resistance of the binder, necessitating strict control over its dosage in practical applications. Full article

In this study, a strategy was adopted to promote the formation of NiAl precipitates with the aim of enhancing strength by incorporating a 0.2 wt.% Al into a traditional ultra-low carbon bainitic (ULCB) steel alloy. By integrating thermo-mechanical control processing (TMCP) and a tailored tempering process, a new-generation steel with an outstanding combination of properties has been successfully developed for shipbuilding and marine engineering equipment. It features a yield strength of 880 MPa, a yield ratio of 0.84, and an impact toughness of 175 J. The precipitation characteristics of nanoscale particles in this steel, including NiAl intermetallics and carbides, were systematically investigated. The results show that the alloy with low Al addition formed NiAl precipitates during tempering. The high-density distributions of NiAl, (Mo, V)C, and (Ti, V, Nb)C precipitates, which exhibit slow coarsening kinetics, played a dominant role in enhancing the strength of the tempered steel. In addition to precipitation, the microstructure before and after tempering was also analyzed. It was observed that a granular bainite morphology was favorable for decreasing the yield ratio. Additionally, the formation of reverse-transformed austenite during tempering was critical for retaining toughness despite substantial strength gains. Finally, theoretical modeling was employed to quantitatively assess the contributions of these microstructural modifications to yield strength enhancement of thermo-mechanical controlled processing (TMCP) and tempered steel. This study establishes a fundamental basis for subsequent industrial-scale development and practical engineering applications of novel products. Full article

The natural variability and moisture sensitivity of bamboo limit its widespread use in construction applications. To address these challenges, densification and delignification processes have emerged as promising modification techniques. Densification and delignification processes can lead to significant improvements in the physical, mechanical, and chemical properties of solid wood. In this study, a two-step process of delignification and densification was carried out on Dendrocalamus asper bamboo specimens. The objective was to assess whether the optimized parameters of densification for natural bamboo on an open pressing system can be transferred for delignified bamboo. Delignification was achieved using an alkali solution (NaOH and Na₂SO₃) with two different temperature settings (25 °C or 100 °C). The pre-treated samples were dried in one of the two different conditions, either at 100 °C for 24 h or 25 °C for 30 days, resulting in four different groups with an average moisture content ranging from 7 to 10%. The samples were densified to 50% of their original thickness through an open thermo-mechanical press system at 160 °C with a compression rate of 6.7 mm/min and compared to densified bamboo without delignification (reference). The compression stress required to achieve a 50% degree of densification was evaluated, with untreated samples exhibiting an average value close to 17 MPa. Following treatment, the compression stress ranged from 7 to 13.4 MPa, indicating that the exposure to a high pH solution facilitates the densification process. However, a reduction in flexural properties (MOR, LOP, and MOE) was observed on the alkali-treated samples after a three-point bending test. Physical properties (water absorption and thickness swelling) were not altered after delignification. These findings demonstrate that the direct application of a densification process optimized for natural bamboo is not fully effective for chemically modified bamboo, highlighting the need for adjustments. Delignified bamboo showed an increase in free space after chemical treatment, which should be further densified under higher degrees. Full article

The transmission accuracy and meshing performance of the gearbox is determined by the internal helical gears pair. Thermal deformation of internal helical gears pair is derived from sliding friction between the contacting teeth surface, resulting in shock, vibration, and misalignments. The purpose of this paper is to compare the influence of a modified gear and an unmodified gear on the temperature field and transmission characteristics of a planetary gear system under the same working conditions. This study presents an innovative temperature field model for gear pairs utilizing Surf152 elements, integrating Hertzian contact theory, tribological principles, and finite element analysis. For the first time, we quantitatively demonstrate the enhancement of thermo-mechanical performance through topological modification in helical gears. Under light-load conditions (200 rpm), the modified gear configuration exhibits a 6.38% reduction in tooth surface temperature and a 46.5% decrease in thermal deformation compared to conventional designs. Experimental validation confirms these improvements, showing an average 62.35% reduction in transmission error. These findings establish a novel methodology for high-precision gear design while providing critical theoretical foundations for planetary gear systems, ultimately leading to significant improvements in both transmission accuracy and operational lifespan. Full article

Polydimethylsiloxane (PDMS) with good hydrophobicity and nano-SiO₂ with excellent thermal stability and mechanical properties are used as a composite coating for cellulose insulating paper in oil-immersed transformers, which effectively reduces the moisture generated by the thermal aging process, thus prolonging each transformer’s service life. This study employed molecular dynamics simulations to investigate the effects of surface-modified nano-SiO₂ with different silane coupling agents (KH570 and KH151) on the thermodynamic properties and hydrophobicity of PDMS. Four groups of anhydrous models were constructed, namely, PDMS, P-SiO₂, P-570, and P-151, as well as four corresponding groups of water-containing models: PDMS/H₂O, P-SiO₂/H₂O, P-570/H₂O, and P-151/H₂O. The results demonstrate that incorporating silane-coupled nano-SiO₂ into PDMS enhances mechanical properties, FFV, CED, MSD, diffusion coefficient, interaction energy, and hydrogen bond count, with KH570-grafted composites exhibiting optimal thermomechanical performance and hydrophobicity. At a temperature of 343 K, KH570 modification increased the bulk modulus and CED by 26.5% and 31.0%, respectively, while reducing the water molecular diffusion coefficient by 24.7% compared to that of unmodified PDMS/SiO₂ composites. The extended KH570 chains occupy additional free volume, forming a larger steric hindrance layer, restricting molecular chain mobility, suppressing hydrogen bond formation, and establishing a low energy surface. Full article

To increase the use of agricultural residues, such as date palm fibers, for the sustainable reinforcement of biocomposites, this study investigated the incorporation of varying weight percentages of date palm microfibers (DPMF) ranging from 0 wt.% to 10 wt.% into polycaprolactone (PCL) matrix. Biocomposites were fabricated using a combination of compression molding and dry blending techniques with and without sodium hydroxide (NaOH) alkali treatment. The surface modification was found to increase the surface roughness of the fibers, removing impurities such as lignin, hemicellulose, and wax, while improving crystallinity, as evidenced by FTIR, XRD, TGA, and particle size analyses. Among the different biocomposites investigated, the results for 5 wt.% DPMF content biocomposites exhibited the highest tensile properties: approximately 20% increase in tensile strength and 164% increase in Young’s Modulus in comparison to neat PCL. The crystallinity of the matrix exhibited an increasing trend from approximately 39% for neat PCL to 43% for the 5 wt.% DPMF biocomposites. Furthermore, treated biocomposites demonstrated higher water-repellency behavior and improved thermal properties. Dynamic mechanical analysis (DMA) results indicated enhanced storage moduli for alkali-treated composites; at 35 °C, the storage modulus showed approximately 22% increase compared to the untreated DPMF biocomposites, reflecting improved stiffness and thermomechanical performances. This study highlights the potential of DPMF as an efficient, eco-friendly alternative to fossil-based conventional reinforcement for biocomposite materials’ potential for sustainable rigid packaging applications. Full article

As advanced structural materials, titanium alloys have found extensive applications in aerospace, medical devices, and precision electronics industries, serving as critical components for achieving lightweight designs in high-end equipment. In aerospace applications, titanium alloy components are frequently subjected to complex thermo-mechanical loading conditions involving varying temperature levels and multiaxial stress states, which may induce progressive fatigue damage accumulation and ultimately lead to premature fracture failures. This study conducts a systematic investigation into the fatigue damage mechanisms of aerospace-grade titanium alloys under service conditions, with particular emphasis on elucidating the synergistic effects of microstructural characteristics, surface integrity parameters, and operational temperature variations on fatigue behavior. Through comprehensive analysis, the research reveals that surface modification techniques, including shot peening (SP), ultrasonic surface polling process (USRP), and laser shock peening (LSP), significantly enhance fatigue performance through two primary mechanisms: (1) the generated residual compressive stress fields effectively inhibit crack initiation and retard propagation rates; (2) improved surface integrity characteristics, such as reduced roughness and work-hardened layers, contribute to enhanced oxidation resistance thereby preserving structural integrity. Full article

The mechanical recycling of thermoplastics (especially of polyolefins) often results in recyclates with inferior properties compared to their virgin counterparts. This phenomenon is mainly due to the modification of the polymer microstructure induced by the degradation processes undergone by the materials during their service life and reprocessing. In this work, a promising route for obtaining high-melt-strength recycled high-density polyethylene (HDPE) is proposed. In particular, the exploited approach involves the utilization of a commercially available additive (i.e., Nexamite^® R305, Nexam Chemical, Lomma, Sweden), which was demonstrated to be capable of driving thermo-mechanical degradation reactions (experienced by HDPE during mechanical recycling) towards the obtainment of a long-chain branched microstructure, thereby enabling the further processing of the recycled material through technologies dominated by elongational flow. The additive-induced alterations of the polymer microstructure were exploited for the formulation of fibers, and the performed tensile characterization showed that the additive-containing material exhibits strikingly improved ductility (namely, elongation at break of 350% for the fibers stretched at a draw ratio of 60) with respect to pristine recycled HDPE. Overall, the obtained results clearly demonstrated the possibility of attaining an effective upcycling of HDPE, which could be exploited for industrially relevant high-added-value applications, hence paving the way for the achievement of full plastic circularity. Full article