Search Results (21)

Thermal oils have been utilized as heat transfer fluids for several decades in many applications, including industrial facilities, power plants and solar receiver systems. Despite their large employment, very few data are available about oils behavior under thermal stress and related degradation processes. For these reasons, the thermal stability of a silicone-based diathermic oil, Bluesil FLD 550 HT, was investigated in the present work. A laboratory-scale set-up was assessed to perform controlled heating tests, and fresh and thermally aged oils samples were analyzed to determine changes in chemical composition and thermo-physical features. Degradation products in the gaseous and vapor phase were also detected and analyzed by online and offline measurements. The obtained results are compared with the ones present for aromatic oils, largely employed as heat transfer media. Bluesil showed a higher thermal resistance compared to aromatic materials, and, thanks to its low volatility together with a high chemical stability, it was successfully tested up to 500 °C. According to its polymeric structure, thermal degradation processes occur mainly through Si-O bond scission, leading to both the segmentation of silicone chains and the formation of cross-linked species as byproducts. Full article

Industrial hemp is mainly cultivated for its fibers aimed at the production of textiles, paper, and cordage; the inflorescences for medicinal purposes; and the seeds are used by the food industry due to their high nutritional and functional matrix of protein, fiber, lipids, and microelements. Hemp seed oil (HsO) is a unique source of polyunsaturated fatty acids, with a phenomenal ω6:ω3 ratio of 2.5–3.0, significantly enhancing human health when consumed daily. HsO is mostly obtained through cold pressing due to minimal thermal treatment, and although of lower yield compared to solvent extraction, it presents higher quality lipid fractions and organoleptic characteristics such as color, taste, flavor, and density. Although HsO is a powerful source of polyunsaturated fatty acids, antioxidants, and phytosterols, its production lacks standardized quality control parameters, except for THC, which is subject to EU legislation. Therefore, it is essential to build up a quality protocol system for standardizing seed conservation, oil extraction methods, and quality parameters. This review aims to display an overall nutritional framework of the HsO and encourage further research into its use in the food value chain. Full article

Hydrogen storage technologies are key enablers for the development of low-emission, sustainable energy supply chains, primarily due to the versatility of hydrogen as a clean energy carrier. Hydrogen can be utilized in both stationary and mobile power applications, and as a low-environmental-impact energy source for various industrial sectors, provided it is produced from renewable resources. However, efficient hydrogen storage remains a significant technical challenge. Conventional storage methods, such as compressed and liquefied hydrogen, suffer from energy losses and limited gravimetric and volumetric energy densities, highlighting the need for innovative storage solutions. One promising approach is hydrogen storage in metal hydrides, which offers advantages such as high storage capacities and flexibility in the temperature and pressure conditions required for hydrogen uptake and release, depending on the chosen material. However, these systems necessitate the careful management of the heat generated and absorbed during hydrogen absorption and desorption processes. Thermal energy storage (TES) systems provide a means to enhance the energy efficiency and cost-effectiveness of metal hydride-based storage by effectively coupling thermal management with hydrogen storage processes. This review introduces metal hydride materials for hydrogen storage, focusing on their thermophysical, thermodynamic, and kinetic properties. Additionally, it explores TES materials, including sensible, latent, and thermochemical energy storage options, with emphasis on those that operate at temperatures compatible with widely studied hydride systems. A detailed analysis of notable metal hydride–TES coupled systems from the literature is provided. Finally, the review assesses potential future developments in the field, offering guidance for researchers and engineers in advancing innovative and efficient hydrogen energy systems. Full article

As more renewable energy sources are integrated into the United Kingdom’s power grid, flexibility services are becoming integral to ensuring energy security. This has encouraged the proliferation of Lithium-ion battery storage systems, with 85 GW in development. However, battery degradation impacts both system lifespan and the economic viability of large-scale projects. With rising commodity costs and supply chain issues, maximising the value of energy storage is critical. Traditional methods of mitigating battery ageing rely on static limits based on inflexible warranties, which do not fully account for the complexity of battery degradation. This study examined an alternative, degradation-aware current derating strategy to improve system performance. Using an optimisation model simulating UK energy trading, combined with an electro-thermal and semi-empirical battery model, we assessed the impact of this approach. Interviews with industry leaders validated the modelled parameters and the relevance of the alternative strategy. Results show the degradation-aware strategy can extend battery lifetime by 5–8 years and improve net present value and internal rate of return over a 15-year period compared with traditional methods. These findings highlight the economic benefits of flexible, degradation-aware operational strategies and suggest that more adaptive warranties could accelerate renewable energy integration and lower costs for storage operators. Full article

A reduction in greenhouse gases has become an inescapable requirement. An effective scenario for achieving carbon neutrality is to develop a hydrogen economy. Its success, however, requires strict control of the different processes involved in planned hydrogen chains. The energy chain considered in this paper is a stationary application which involves the production of hydrogen by electrolysis (a power-to gas process) and its combustion in gas turbine combined cycles to generate electricity (a gas-to-power process). In such applications, the need is twofold: (i) to control the risk of explosive atmospheres by performing safe gas detection in the presence of hydrogen and (ii) to secure the reliability of all chain processes using hydrogen-rich gases by achieving reliable analyses of these gases. This paper is dedicated to the development of hydrogen energy to decarbonize the thermal production of electricity. We will first describe the hydrogen chain that would best suit the power generation sector. Then, we will highlight the properties of hydrogen that are critical for its reliable operation. Finally, we will review the sensing technologies suitable for hydrogen-containing fuels. This review paper was published as part of a Joint Industrial Project (JIP) aimed at enabling the safe and reliable deployment of hydrogen energy. Full article

In the era of decarbonization driven by environmental concerns and stimulated by legislative measures such as Fit for 55, the industry and transportation sectors are increasingly replacing petroleum-based fuels with those derived from renewable sources. For many years, the share of these fuels in blends used to power compression ignition engines has been growing. The primary advantage of this fuel technology is the reduction of GHG emissions while maintaining comparable engine performance. However, these fuel blends also have drawbacks, including limited ability to form stable mixtures or the requirement for chemical stabilizers. The stability of these mixtures varies depending on the type of alcohol used, which limits the applicability of such fuels. This study focuses on evaluating the impact of eight types of alcohol fuels, including short-chain (methanol, ethanol, propanol) and long-chain alcohols (butanol, pentanol, hexanol, heptanol, and octanol), on the most critical operational parameters of an industrial engine and exhaust emissions. The engines being compared operated at a constant speed and under a constant load, either maximum or close to maximum. The study also evaluated the effect of alcohol content in the mixture on combustion process parameters such as peak cylinder pressure and heat release, which are the basis for parameterizing the engine’s combustion process. Determining ignition delay and combustion duration is fundamental for optimizing the engine’s thermal cycle. As the research results show, both the type of alcohol and its concentration in the mixture influence these parameters. Another parameter important from a usability perspective is engine stability, which was also considered. Engine performance evaluation also includes assessing emissions, particularly the impact of alcohol content on NO_x and soot emissions. Based on the analysis, it can be concluded that adding alcohol fuel to diesel in a CI engine increases ignition delay (up to 57%), p_max (by approximately 15–20%), HRR_max (by approximately 80%), and PPR_max (by approximately 70%). Most studies indicate a reduction in combustion duration with increasing alcohol content (by up to 50%). For simple alcohols, an increase in thermal efficiency (by approximately 15%) was observed, whereas for complex alcohols, a decrease (by approximately 10%) was noted. The addition of alcohol to diesel slightly worsens the stability of the CI engine. Most studies pointed to the positive impact of adding alcohol fuel to diesel on NOx emissions from the compression ignition engine, with the most significant reductions reaching approximately 50%. Increasing the alcohol fuel content in the diesel blend significantly reduced soot emissions from the CI engine (by up to approximately 90%). Full article

The high carbon emissions and pollution of China’s thermal power industry chain have exacerbated environmental and climate degradation. Therefore, accelerating the green transformation process is of great significance in promoting the sustainable development of enterprises. This study selected 30 listed thermal power enterprises in China as research objects, analyzed their data from 2018 to 2022, set targeted input–output indicators for different stages, and used a two-stage dynamic data envelopment analysis (DEA) model to evaluate and measure the efficiency of the green transformation of Chinese thermal power enterprises. In addition, this study also uses the logarithmic mean Divisia index (LMDI) method to analyze the driving effects of green transformation. The results indicate that in terms of overall efficiency, there is a significant difference in the overall performance of these 30 thermal power enterprises, with a large difference in average efficiency values. Efficiency values are related to enterprise size. In terms of stage efficiency, the average efficiency value of thermal power enterprises in the profit stage was significantly higher than that in the transformation stage, and the profitability of Chinese thermal power enterprises was better. In terms of sub-indicator efficiency, the efficiency of each indicator shows a “U”-shaped trend, and there is a certain correlation between the operating costs and revenue of thermal power enterprises, the market value of green transformation, and related indicators. In addition, the most important factor affecting the efficiency of green transformation is the sewage cost they face, whereas their operational capabilities have the least impact on their green transformation. In this regard, thermal power enterprises should increase their investment in the research and development of key technologies for thermal power transformation and continuously optimize their energy structure. The government will increase financial support for thermal power green transformation enterprises and correspondingly increase emission costs. Full article

Biomass storage is an essential requirement in the supply chain of bio-refineries and power plants. This research aims to evaluate the influence of long-term outdoor storage (1 year) of baled rockrose (Cistus laurifolius L.) shrub biomass on biofuel’s quality, pre-treatment processes and on combustion emissions in an industrial boiler. The raw material was obtained from different rockrose shrublands in north central Spain. A total of 233 t_WM (tones of wet matter) of biomass were used to produce biofuels (30 mm of milled biomass and Ø 8 mm pellets) in the pre-treatment pilot plants at CEDER-CIEMAT. The combustion tests were conducted in an industrial moving grate boiler with a thermal power of 50 MWth, in a 17 MWe power plant. Outdoor storage improved some biofuel quality parameters, mainly the reduction in ash content, which allowed 30 mm of milled material to be classified as class I1 (ISO 17225-9:2022) and pellets as class I3 (ISO 17225-2-2021). No significant differences were observed in the total specific mass flow and energy consumption in the pre-treatment processes. The combustion tests had similar results, with the emissions being below the limits established in the directive (EU) 2015/2193. The results obtained indicated that the 1-year outdoor storage of rockrose-baled biomass, under Mediterranean conditions, was feasible for its subsequent use as biofuel. Full article

Thermal power generation based on coal has been identified as the second largest polluting industry due to the greenhouse gas emissions caused by coal combustion. The pollution caused by this industry is not limited to power generation, but it also manifests itself throughout the use of products. Although a huge emphasis has been placed on replacing coal-based power generation with renewable resources, we showed that Indian power generation will depend on coal for more than fifty percent of its demand in the near future. In our study, we utilized a combination of linear cointegration, non-linear cointegration, ARIMA, and the VECM to forecast the use of coal based on the Indian industrial index and the amount of electricity generated through coal combustion required to meet the demand. Given that pollution and carbon emissions are inherent in the coal usage cycle, we drafted policy implications and recommendations to mitigate the consequences, green the coal usage cycle, and improve the coal supply chain. Full article

The battery electric passenger vehicle (BEPV) has the potential to conserve electric energy and reduce carbon emissions, making it an effective tool for achieving low-carbon development in the road transport industry by replacing the internal combustion engine vehicle (ICEV). Several factors, such as comprehensive electricity power generation efficiency, proportion of thermal power, vehicle technical performance, regional mileage credibility and low temperature, affect the BEPV’s electricity energy consumption and carbon emissions. In this study, an electricity conservation index model and a carbon emission reduction index model for multilevel BEPVs are established to evaluate their capabilities of electricity energy conservation and carbon emissions reduction, considering the electricity supply chain, including the generation and transmission of electricity. The research shows that the electricity energy conservation ability of BEPVs is not outstanding, but their carbon emissions reduction ability is strong. When the composition of energy for electricity generation is transformed from 2025 to 2035, with a 10% increase in comprehensive electricity generation efficiency, all levels of BEPVs show fruitful electricity energy conservation ability. When the proportion of thermal power decreases to 10%, the carbon emissions reduction is exponentially reduced to 1/25 to 1/30 of ICEV’s total carbon emissions. However, the regional mileage credibility weakens the BEPVs’ ability to save energy and reduce emissions in most Chinese provinces except for the southwest and the south regional provinces, where the regional mileage credibility parameter can increase the energy conservation and carbon emission reduction performance of A00+A0 level BEPV. Low temperatures make BEPV models lose their electricity energy conservation advantage, but most models still have the characteristic of carbon emissions reduction. On this basis, the electricity energy consumption and carbon emissions of all BEPV models are higher than those of ICEVs when the low temperature endurance mileage accuracy is added. Full article

Thermal power plants, TPP, are one of the main players in the phosphoric acid and fertilizer production value chain. The control of power plant assets involves considerable complexity and is subject to several constraints, affecting the asset’s reliability and, most importantly, plant operators’ safety. The main focus of this paper is to investigate the potential of an agent-based digital twin architecture for collaborative prognostic of power plants. Based on the ISO 13374:2015 scheme for smart condition monitoring, the proposed architecture consists of a collaborative prognostics system governed by several smart DT agents connected to both physical and virtual environments. In order to apprehend the potential of the developed agent-based architecture, experiments on the architecture are conducted in a real industrial environment. We show throughout the paper that our proposed architecture is robust and reproduces TPP static and dynamic behavior and can contribute to the smart monitoring of the plant in case of critical conditions. Full article

The tobacco industry is an important contributor to realizing the carbon reduction goal. Less attention is paid to the carbon emissions of the tobacco industry. The tobacco production system is generally a carbon sink, where carbon sequestration by photosynthesis in tobacco planting and by soil are sufficient to offset the carbon emissions of the tobacco production system. This work proposed an integrated framework of life-cycle assessment (LCA) and Source-Sink Model to determine the optimal allocation of carbon sources to sinks with the objective of maximizing the profitable external benefits. From an economic perspective, internal carbon sources could be offset by the internal carbon sink of the tobacco production system. The additional internal carbon sinks can be transferred in the form of carbon trading, increasing external revenue. A case-study tobacco manufacturing plant in Sichuan, China, was chosen to demonstrate the feasibility of the proposed work. This study assesses the carbon footprint and economic benefits of a tobacco industry supply chain case (from tobacco cultivation to finished product) and analyzes the energy restructuring of different percentages of renewable energy to replace thermal power. The objective of the study is to maximise the offsetting of carbon emissions from the tobacco production system, while achieving optimal internal costs and profitable external benefits. Full article

The constant search for the proper management of non-degradable waste in conjunction with the circular economy makes the thermal pyrolysis of plastics an important technique for obtaining products with industrial interest. The present study aims to produce pyrolytic oil from thermoplastics and their different mixtures in order to determine the best performance between these and different mixtures, as well as to characterize the liquid fraction obtained to analyze its use based on said properties. This was carried out in a batch type reactor at a temperature of 400 °C for both individual plastics and their mixtures, from which the yields of the different fractions are obtained. The liquid fraction of interest is characterized by gas chromatography and its properties are characterized by ASTM standards. The product of the pyrolysis of mixtures of 75% polystyrene and 25% polypropylene presents a yield of 82%, being the highest, with a viscosity of 1.12 cSt and a calorific power of 42.5 MJ/kg, which has a composition of compounds of carbon chains ranging between C6 and C20, for which it is proposed as a good additive agent to conventional fuels for industrial use. Full article

Hot-melt pressure-sensitive adhesive (HMPSA) is an environmentally benign adhesive which is typically processed without solvent in industries. However, casting solution method is commonly used for experimental purposes in the lab for convenience. Therefore, seven types of solvent with different polarities, including toluene as the most commonly used solvent, were investigated in this work to study the feasibilities. Quick bond strength and holding power were tested with different types of solvents and different adhesive weight percent in the prepared solutions. Through viscosity measurement, thermal analysis, and compositional analysis, the correlation between the chosen solvents and adhesive performance was further explored. It was found that the differences in the obtained bond strength of HMPSA treated with a variety of solvents were due to physical reasons instead of chemical reactions, and a solvent with similar polarity to toluene (e.g., tetrachloride, octane) should be considered as an option because a similar polymer chain relaxation could be maintained as the original HMPSA without solvent treatment. In this study, the mechanism of choosing toluene as common solvent for HMPSA testing was analyzed, and the feasibility of optional solvents was discussed. Full article

The food industry is responsible for supplying the food demand of the ever-increasing global population. The food chain is one of the major contributors to greenhouse gas (GHG) emissions, and global food waste accounts for one-third of produced food. A solution to this problem is preserving crops, vegetables, and fruits with the help of an ancient method of sun drying. For drying agricultural and marine products, several types of dryers are also being developed. However, they require a large amount of energy supplied conventionally from pollutant energy sources. The environmental concerns and depletion risks of fossil fuels persuade researchers and developers to seek alternative solutions. To perform drying applications, sustainable solar power may be effective because it is highly accessible in most regions of the world. Greenhouse dryers (GHDs) are simple facilities that can provide large capacities for drying agricultural products. This study reviews the integration of GHDs with different solar technologies, including photovoltaic (PV), photovoltaic-thermal (PVT), and solar thermal collectors. Additionally, the integration of solar-assisted greenhouse dryers (SGHDs) with heat pumps and thermal energy storage (TES) units, as well as their hybrid configuration considering integration with other renewable energy sources, is investigated to improve their thermal performance. In this regard, this review presents and discusses the most recent advances in this field. Additionally, the economic analysis of SGHDs is presented as a key factor to make these sustainable facilities commercially available. Full article