Search Results (1,522)

Sintered nano-silver paste is widely used in electronic packaging due to its excellent thermal and electrical conductivity. A phenomenological variable-order fractional constitutive model has been developed to characterize the evolution of its mechanical properties, incorporating dependencies on both temperature and strain rate. Based on the Weissenberg number and classical Arrhenius equation, a formulation for relaxation time with temperature and strain rate dependence has been proposed. A temperature- and rate-sensitive fractional order is introduced to capture the coupled influences of thermal and strain rate effects. Furthermore, the effects of temperature and the strain rate on the elastic modulus and relaxation time are quantitatively described through established coupling criteria. Simulation results demonstrate that the proposed model offers high accuracy and strong predictive capability. Comparisons with the classical Anand model highlight the effectiveness of the variable-order fractional model, particularly at lower temperatures. Full article

Owing to multiple non-covalent interactions, ionic groups impart unique chemical and physical properties into polymers including ion conductivity/mobility, permeation, and intrinsic healability. Ionenes contain ionic groups in their polymer backbone, which offer great versatility in polymer design. Herein, selected aliphatic and aromatic imidazoles were synthesized, which were used as monomeric building blocks for the preparation of thermoplastic ionenes by following a Sn2 step growth reaction across organic halides. The structure and molecular weight of the polymers was characterized by Fourier transform infrared (FTIR) and nuclear magnetic resonance (NMR) techniques. Once polymerized, anion-exchange reactions were carried out to replace the halides with four other counter-anions. Subsequently, the effect of the nature of the anion and the cation on the polymers’ thermal and hygroscopic properties was studied in detail by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and FTIR spectroscopy. Depending on the chemical structures of the polymeric cations and the related anions, tailored polymers with a glass transition temperature (T_g) in the range of 30 °C to 131 °C and a thermal stability varying between 170 °C and 385 °C were obtained. Full article

Finite element (FE) models are widely used in structural health monitoring to represent real structures and assess their condition, but discrepancies often arise between numerical and actual structural behavior due to simplifying assumptions, uncertain parameters, and environmental influences. Temperature variation, in particular, significantly affects structural stiffness and modal properties, yet it is often treated as noise in traditional model updating methods. This study treats temperature changes as valuable information for model updating and structural damage quantification. The Bayesian model updating approach (BMUA) is a probabilistic approach that updates uncertain model parameters by combining prior knowledge with measured data to estimate their posterior probability distributions. However, traditional BMUA methods assume mass is known and only update stiffness. A novel BMUA framework is proposed that incorporates thermal buckling and temperature-dependent stiffness estimation and introduces an algorithm to eliminate the coupling effect between mass and stiffness by using temperature-induced stiffness changes. This enables the simultaneous updating of both parameters. The framework is validated through numerical simulations on a three-story aluminum shear frame under uniform and non-uniform temperature distributions. Under healthy and uniform temperature conditions, stiffness parameters were estimated with high accuracy, with errors below 0.5% and within uncertainty bounds, while mass parameters exhibited errors up to 13.8% that exceeded their extremely low standard deviations, indicating potential model bias. Under non-uniform temperature distributions, accuracy declined, particularly for localized damage cases, with significant deviations in both parameters. Full article

Aphid control often relies on synthetic pesticides, but their overuse has raised concerns about resistance development and negative impact on wildlife and human health. Consequently, the search for new biopesticide agents has gained significant attention. Nemertide alpha-1, a peptide toxin from the marine nemertean worm Lineus longissimus (Gunnerus, 1770), is known for its pesticide activity but has less documented biological safety. This study investigates the aphid feeding deterrence and biological safety of the experimental biopesticide nemertide alpha-1. Nemertide alpha-1 demonstrated a clear dose-dependent repellent effect on the penetration behaviour of the green peach aphid (Myzus persicae, Sulzer). It also demonstrates bacteriostatic and bactericidal effects in an MIC (Minimum Inhibitory Concentration) assay, respectively, on E. coli (MIC: 112.5 µM) and S. aureus (MIC: 28.4 µM). In a bacterial liposome leakage assay, nemertide alpha-1 exhibits a less pronounced effect than the melittin control (20% maximum leakage at 100 µM), strengthening the hypothesis on the specificity of its neurotoxic mode of action. It is not toxic to mammalian cell U-937 GTB with only a slight decline in the percentage of survival at the highest concentration tested (80 µM). Finally, nemertide alpha-1 displays thermal stability over time for four weeks in three different conditions: cold (6 °C), room temperature (20–24 °C), and physiological temperature (37 °C). Nemertide alpha-1 deters green peach aphid feeding in the low micromolar range and exhibits low antimicrobial properties and very low toxicity to human cells. Its potential utility is further underscored by thermal stability over time. Full article

Catalytic upgrading of vacuum residue (VR) is critical for enhancing fuel yield and reducing waste in petroleum refining. This study explores VR cracking over a novel cerium-loaded acidified metakaolinite catalyst (MKA800–20%Ce) prepared via calcination at 800 °C, acid leaching, and wet impregnation with 20 wt.% Ce. The catalyst was characterized using FTIR, BET, XRD, TGA, and GC–MS to assess structural, textural, and thermal properties. Catalytic cracking was carried out in a fixed-bed batch reactor at 350 °C, 400 °C, and 450 °C. The MKA800@Ce20% catalyst showed excellent thermal stability and surface activity, especially at higher temperatures. At 450 °C, the catalyst yielded approximately 11.72 g of total liquid product per 20 g of VR (representing a ~61% yield), with ~3.81 g of coke (~19.1%) and the rest as gaseous products (~19.2%). GC-MS analysis revealed enhanced production of light naphtha (LN), heavy naphtha (HN), and kerosene in the 400–450 °C range, with a clear temperature-dependent shift in product distribution. Structural analysis confirmed that cerium incorporation enhanced surface acidity, redox activity, and thermal stability, promoting deeper cracking and better product selectivity. Kinetics were investigated using an eight-lump first-order model comprising 28 reactions, with kinetic parameters optimized through a genetic algorithm implemented in MATLAB. The model demonstrated strong predictive accuracy taking into account the mean relative error (MRE = 9.64%) and the mean absolute error (MAE = 0.015) [MAE: It is the absolute difference between experimental and predicted values; MAE is dimensionless (reported simply as a number, not %. MRE is relative to the experimental value; it is usually expressed as a percentage (%)] across multiple operating conditions. The above findings highlight the potential of Ce-modified kaolinite-based catalysts for efficient atmospheric pressure VR upgrading and provide validated kinetic parameters for process optimization. Full article

While material extrusion via fused filament fabrication (FFF) offers design flexibility and rapid prototyping, its practical use in engineering is limited by mechanical challenges, including residual stresses, geometric distortions, and potential interlayer debonding. These issues arise from the dynamic thermal profiles during FFF, including temperature gradients, non-uniform hardening, and rapid thermal cycling, which lead to uneven internal stress development depending on fabrication parameters and object topology. These problems can compromise the structural integrity and mechanical properties of FFF parts, especially when the load-bearing capacity and geometric accuracy are critical. This study focuses on polylactic acid (PLA) due to its widespread application in engineering. It introduces a computational framework for coupled thermo-mechanical simulations of the FFF process using ABAQUS (Version 2020) finite element software. A key innovation is an automated subroutine that converts G-code into a time-resolved event series for finite element activation. The simulation framework explicitly models the sequential stages of printing, cooling, and detachment, enabling prediction of adhesive loss and post-process warpage. A transient thermal model evaluates the temperature distribution during FFF, providing boundary conditions for a mechanical simulation that predicts residual stresses and warping. Uniquely, the proposed model incorporates the detachment stage, enabling a more realistic and experimentally validated prediction of warpage and residual stress release in FFF-fabricated components. Although the average deviation between predicted and measured displacements is about 10.6%, the simulation adequately reflects the spatial distribution and magnitude of warpage, confirming its practical usefulness for process optimization and design validation. Full article

Extreme ultraviolet (EUV) pellicles must withstand intense thermal stress during exposure due to their limited heat dissipation, which results from their ultrathin geometry and the vacuum environment within EUV scanners. To address this challenge, we investigated the crystalline phase-dependent emissivity of nanometer-thick molybdenum disilicide (MoSi₂) membranes. Membranes exhibiting amorphous, hexagonal, and tetragonal phases were independently prepared via controlled annealing, and their thermal radiation properties were evaluated using heat-load testing under emulated EUV scanner conditions. The Hall effect measurements revealed distinct variations in carrier density and mobility across phases, which were theoretically correlated with emissivity using the Lorentz–Drude model. The results demonstrate that emissivity increases in the hexagonal phase due to increased carrier density and reduced scattering, offering improved thermal radiation performance. These findings establish the phase engineering of conductive silicides as a viable strategy for enhancing radiative cooling in EUV pellicles and offer a theoretical framework applicable to other high-temperature nanomaterials. Full article

This study elucidated the evolution and catastrophic failure mechanisms of concrete’s mechanical properties under high-temperature and moisture-coupled environments. Specimens underwent hygrothermal shock simulation via constant-temperature drying (100 °C/200 °C, 4 h) followed by water quenching (20 °C, 30 min). Uniaxial compression tests were performed using a uniaxial compression test machine with synchronized multi-scale damage monitoring that integrated digital image correlation (DIC), acoustic emission (AE), and infrared thermography. The results demonstrated that hygrothermal coupling reduced concrete ductility significantly, in which the peak strain decreased from 0.36% (ambient) to 0.25% for both the 100 °C and 200 °C groups, while compressive strength declined to 42.8 MPa (−2.9%) and 40.3 MPa (−8.6%), respectively, with elevated elastic modulus. DIC analysis revealed the temperature-dependent failure mode reconstruction: progressive end cracking (max strain 0.48%) at ambient temperature transitioned to coordinated dual-end cracking with jump-type damage (abrupt principal strain to 0.1%) at 100 °C and degenerated to brittle fracture oriented along a singular path (principal strain band 0.015%) at 200 °C. AE monitoring indicated drastically reduced micro-damage energy barriers at 200 °C, where cumulative energy (4000 mV·ms) plummeted to merely 2% of the ambient group (200,000 mV·ms). Infrared thermography showed that energy aggregation shifted from “centralized” (ambient) to “edge-to-center migration” (200 °C), with intensified thermal shock effects in fracture zones (ΔT ≈ −7.2 °C). The study established that hygrothermal coupling weakens the aggregate-paste interfacial transition zone (ITZ) by concentrating the strain energy along singular weak paths and inducing brittle failure mode degeneration, which thereby provides theoretical foundations for fire-resistant design and catastrophic failure warning systems in concrete structures exposed to coupled environmental stressors. Full article

Electrochemical processes within a lithium-ion battery cause electrode expansion and gas generation, thus resulting in battery swelling and, in severe cases, reliability and safety issues. This paper presents the mechanisms responsible for swelling, including thermal expansion, lithium intercalation, electrode interphase layer growth, lithium plating, and gas generation, while highlighting their dependence on material properties, design considerations, C-rate, temperature, state of charge (SoC), and voltage. The paper then discusses how swelling correlates with capacity fade, impedance rise, and thermal runaway, and demonstrates the potential of using swelling as a diagnostic and prognostic metric for battery health. Swelling models that connect microscopic mechanisms to macroscopic deformation are then presented. Finally, the paper presents strategies to mitigate swelling, including materials engineering, surface coatings, electrolyte formulation, and mechanical design modifications. Full article

We review and as well obtain some new results on the temperature dependence of spatially nonlocal response functions of graphene and their applications to the calculation of both the equilibrium and nonequilibrium Casimir and Casimir–Polder forces. After a brief summary of the properties of the polarization tensor of graphene obtained within the Dirac model in the framework of quantum field theory, we derive the expressions for the longitudinal and transverse dielectric functions. The behavior of these functions at different temperatures is investigated in the regions below and above the threshold. Special attention is paid to the double pole at zero frequency, which is present in the transverse response function of graphene. An application of the response functions of graphene to the calculation of the equilibrium Casimir force between two graphene sheets and the Casimir–Polder forces between an atom (nanoparticle) and a graphene sheet is considered with due attention to the role of a nonzero energy gap, chemical potential and a material substrate underlying the graphene sheet. The same subject is discussed for out-of-thermal-equilibrium Casimir and Casimir–Polder forces. The role of the obtained and presented results for fundamental science and nanotechnology is outlined. Full article

After an aero-engine shuts down, the high temperature within the core flow path prevents conventional borescope probes from performing immediate internal inspections due to their limited thermal resistance, thereby constraining rapid turnaround capabilities for aircraft. To address this challenge, this study proposes an active cooling strategy using coolant flow to keep the probe within a safe temperature range. Three cooling structures incorporating pressure-drop modules—annular, annular-slit, and round-hole configurations—were designed and numerically investigated to assess the effects of geometric parameters and coolant properties (temperature, pressure, nitrogen mixing ratio) on cooling performance. The results demonstrate that the round-hole structure with a 1.0 mm diameter achieves optimal cooling, maintaining an average probe mirror temperature of 286.2 K under coolant conditions of 285 K and 0.5 MPa. Cooling efficiency exhibits a strong linear negative correlation with coolant temperature, while its relationship with pressure is highly structure-dependent. Nitrogen doping significantly improves the heat transfer capacity of the coolant. The implemented three-stage pressure-drop module performs consistently, with the pressure loss per stage determined solely by the inlet pressure. This study provides valuable insights and a theoretical foundation for the design of high-temperature-resistant borescope equipment capable of operating in the harsh environments of aero-engines. Full article

Wood density is a key property since it affects almost every other property of wood such as its elasto-mechanical, acoustic, thermal, or electrical properties. Hence, it is essential to determine wood density for the interpretation of any other property test. Density measurements are usually carried out gravimetrically by measuring the wood specimens’ dimensions and taking their weight. In order to be independent of moisture, wood density is measured at an absolute dry state. However, depending on which wood properties shall be measured after the oven-dry density is determined, heating the wood up to 103 °C can be problematic because the volatile components of the wood can evaporate. For this reason, the drying conditions (temperature in °C (60, 80, 103 °C)), duration in h (8, 16, 24, 48 h)) required to achieve an absolute dry state inside wood specimens—being obligatory for the analysis of various physical, mechanical, or even biological properties—were examined for different softwood and hardwood species. Basically, oven-dry measurements (i.e., 48 h at 103 °C) themselves contained a significant error, which was considered to be the result of deviations in the handling of the specimens and the scales used. Using temperatures below 103 °C was critical for the determination of absolute dry mass and dimensions. Wood specimens with a high content of volatile ingredients led to an apparently increased residual MC (e.g., shown for Scots pine heartwood), thus volatile ingredients were considered an additional source of error during oven-dry measurements. Full article

The paper presents the development and experimental verification of an electrothermal model of a heatsink-less thermoelectric generator (TEG) implemented in the LTspice simulator. The model incorporates key physical phenomena, including the Seebeck effect, the Peltier effect, and Joule heating. It also takes into account a variable convective thermal resistance to the environment that depends on the temperature of the thermoelectric module’s cold side. The model was calibrated using experimental measurements of the open-circuit Seebeck voltage and the output voltage under resistive load connected to the TEC1-12706-SR thermoelectric module (TEM), under controlled temperature gradients. The model’s accuracy was validated by comparing simulation results with measured output voltages and power generated by the TEG for various load resistances and ambient temperatures. The simulations showed good agreement with the experimental data. The analysis and tests also confirmed the existence of an optimal load resistance that maximizes power transfer from the module, which is consistent with the principle of matching the load to the TEG’s internal resistance. We present the comparison between the theoretical model of a TEG and its physical properties. We used the results of the measurements to tailor the model, so finally we were able to achieve consistency of measurements with experiment within 10–17%. The developed model is a useful tool for rapid design and optimization of energy-harvesting systems using TEGs, enabling the integration of these generators into autonomous IoT systems and wearable electronics, without the need for a traditional heatsink. Full article

Activated carbon F-400 was modified by using different oxidation agents: nitric acid, sulfuric acid, and ozone. The influence of the type of carbon surface groups on adsorption effectiveness towards selected aromatic compounds was analyzed. The commercial carbon F-400 was deashed and modified, and the obtained materials were characterized by using different techniques to determine their textural, thermal, morphological, and surface properties: low-temperature adsorption/desorption isotherms of nitrogen, scanning electron microscopy (SEM), Boehm titration, and Fourier transform infrared spectroscopy (FTIR). The adsorption properties towards four aromatic compounds, i.e., toluene, 4-nitrotoluene, nitrobenzene, and 4-nitrobenzoic acid, were evaluated based on isotherm measurements. Adsorption equilibrium data were analyzed by applying the generalized Langmuir isotherm. The influence of carbon surface groups and adsorbate functional groups in interaction mechanisms was discussed. It was found there was a strong effect of oxidation on adsorption efficiency. The adsorption capacity of modified activated carbon F-400 strongly depends on the type of oxidant used, e.g., in the case of toluene, the use of ozone as an oxidant gives a sorption capacity of 5.51 mmol/g, and of nitric acid—4.20 mmol/g. Full article

We present a systematic study on the fabrication of gold nanoislands by microwave-assisted annealing, a rapid and energy-efficient alternative to conventional thermal treatments. Gold thin films with nominal thicknesses of 4, 5, 6, 8, and 10 nm are deposited by thermal evaporation directly onto BK7 glass substrates, with and without a 3 nm chromium adhesion layer. The samples are subsequently annealed in a microwave kiln, where microwave irradiation is absorbed and converted to heat within the graphite-coated cavity (kiln), allowing the substrate temperature to exceed 550 °C, the threshold required for film dewetting. This process induces a controlled morphological evolution from continuous thin films to well-defined nanoislands, with the final size distribution strongly dependent on the initial film thickness. Compared with oven-based annealing, microwave treatment promotes faster and more uniform heating, which enhances atomic diffusion and accelerates dewetting while reducing the risk of substrate deformation or excessive coalescence. The resulting nanoislands exhibit tailored size-dependent plasmonic properties, with clear correlations between film thickness, crystallite size, and optical absorption features. Importantly, the method is cost-efficient, requiring shorter processing times and lower energy input, while enabling reproducible fabrication of high-quality plasmonic nanostructures on inexpensive glass substrates, suitable for applications in sensing, photonics, and nanophotonics. Full article