Search Results (28)

Irish potato (Solanum tuberosum) is a critical crop for food security and economic growth in Tsangano and Angónia Districts, Central Mozambique. Challenges like inconsistent yields and variable quality are often linked to suboptimal soil conditions, which limit production. This study aimed to classify and evaluate the suitability of soils for potato cultivation in Tete Province, where detailed soil assessments remain limited. Four pedons—TSA-P01 and TSA-P02 in Tsangano and ANGO-P01 and ANGO-P02 in Angónia—were examined for bulk density, texture, pH, organic carbon, and nutrient content using a combination of pedological methods and laboratory soil analysis. To determine each site’s potential for growing Irish potatoes, these factors were compared to predetermined land suitability standards. The pedons were very deep (>150 cm) and had textures ranging from sandy clay loam to sandy loam. TSA-P02 had the lowest bulk density (0.78 Mg m⁻³) and the highest available water capacity (182.0 mm m⁻¹). The soil pH ranged from 5.6 to 7.9, indicating neutral to slightly acidic conditions. Nutrient analysis revealed low total nitrogen (0.12–0.22%), varying soil organic carbon (0.16–2.73%), and cation exchange capacity (10.1–11.33 cmol⁽⁺⁾ kg⁻¹). Pedons TSA-P01, ANGO-P1, and ANGO-P02 were characterized by eluviation and illuviation as dominant pedogenic processes, while in pedon TSA-P02, shrinking and swelling were the dominant pedogenic processes. Weathering indices identified ANGO-P01 as most highly weathered, while TSA-P02 was least weathered and had better fertility indicators. According to USDA Taxonomy, the soils were classified as Ultisols, Vertisols, and Alfisols, corresponding to Acrisols, Alisols, Vertisols, and Luvisols in the WRB for Soil Resources. All studied soils were marginally suitable for potato production (S3f) due to dominant fertility constraints, but with varying minor limitations in climate, topography, and soil physical properties. The findings hence recommended targeted soil fertility management to enhance productivity and sustainability in potato cultivation. Full article

Geological storage of CO₂ in coal seam is an effective way for carbon emission reduction. Evaluating the adsorption-induced swelling behavior of confined coal is essential for this carbon emission reduction strategy. Based on the thermodynamic theory and the Gibbs adsorption model, a thermodynamic method for evaluating the gas adsorption-induced swelling behavior of confined coal was established. The influences of factors such as stress, gas pressure, and the state of gas on the adsorption-induced swelling behavior of confined coal were discussed. The predicted swelling deformation from the thermodynamic method based on the ideal gas hypothesis was consistent with the experimental result only under the condition of low-pressure CO₂ (<2 MPa). The predicted swelling deformation from that method was larger than the experimental result under the condition of high-pressure CO₂ (>2 MPa). However, the method based on the real gas hypothesis always had better prediction results under both the low- and high-pressure CO₂ conditions. From the perspective of phase equilibrium and transfer, in the process of CO₂ adsorption by the confined coal, gas molecules transfer from the adsorption site of high chemical potential to the low chemical potential. Taking the real gas as ideal gas will result in the surface energy increase in the established model. Consequently, the prediction result will be larger. Therefore, for geological storage of CO₂ in coal seam, it is necessary to take the real gas state to predict the adsorption-induced swelling behavior of the coal. In the process of CO₂ adsorption by the confined coal, when its pressure is being closed to the critical pressure, capillary condensation phenomenon will occur on the pore surface of the confined coal. This can make an excessive adsorption of CO₂ by the coal. With the increase in the applied stress, the adsorption capacity and adsorption-induced swelling deformation of the confined coal decrease. Compared to N₂ with CO₂, the coal by CO₂ adsorption always shows swelling deformation under the simulated condition of ultra-high-pressure injection. However, the coal by N₂ adsorption will shows shrinking deformation due to the pore pressure effect after the equilibrium pressure. Taking the difference in the adsorption-induced swelling behavior and pore compression effect, N₂ can be mixed to improve the injectivity of CO₂. This suggests that CO₂ storage in the deep burial coal seam can be carried out by its intermittent injection under high-pressure condition along with mixed N₂. Full article

pH sensitivity of chitosan allows for precise phase transitions in acidic environments, controlling swelling and shrinking, making chitosan suitable for drug delivery systems. pH transitions are modulated by the presence of cross-linkers by the functionalization of the chitosan chain. This review relays a summary of chitosan functionalization and tailoring to optimize drug release. The potential to customize chitosan for different environments and therapeutic uses introduces opportunities for drug encapsulation and release. The focus on improving drug encapsulation and sustained release in specific tissues is an advanced interpretation, reflecting the evolving role of chitosan in achieving targeted and more efficient therapeutic outcomes. This review describes strategies to improve solubility and stability and ensure the controlled release of encapsulated drugs. The discussion on optimizing factors like cross-linking density, particle size, and pH for controlled drug release introduces a deeper understanding of how to achieve specific therapeutic effects. These strategies represent a refined approach to designing chitosan-based systems, pushing the boundaries of sustained release technologies and offering new avenues for precise drug delivery profiles. Full article

This study investigates the stabilization of expansive soil using basic oxygen furnace (BOF) slag, an eco-friendly steel by-product, as an alternative to conventional stabilizers like ordinary Portland cement. By evaluating varying concentrations of BOF slag and lime as an activator, the research aims to improve the soil’s mechanical properties, addressing issues like low bearing capacity and high shrink–swell potential. Bentonite clay was treated with different BOF slag ratios (10%, 20%, and 30%) and activated with lime (1%, 3%, and 5%). After mixing and compaction, samples were cured and tested for unconfined compressive strength (UCS), shear wave velocity (BE), and free swell. Microscopic analyses (SEM) provided insight into structural changes post-stabilization, revealing improved properties with increased BOF and lime concentrations. Notably, stabilization with 30% BOF slag and 5% lime achieves a compressive strength of 810 kPa, meeting the minimum subgrade soil stabilization requirement (700 kPa) set by the Federal Highway Administration. This research underscores the potential of BOF slag as a sustainable and practical material for bentonite clay stabilization, offering a promising solution for enhancing soil properties while contributing to environmental sustainability through industrial by-product repurposing. Full article

Expansive clays present serious issues in a variety of engineering applications, including roadways, light buildings, and infrastructure, because of their notable volume changes with varying moisture content. Tough weather conditions can lead to drying and shrinking, which alters expansive clays’ hydro-mechanical properties and results in cracking. The hydro-mechanical behavior of Al-Ghatt expansive clay and the impact of wetting and drying cycles on the formation of surface cracks are addressed in this investigation. For four cycles of wetting and drying and three vertical stress levels, i.e., 50 kPa, 100 kPa, and 200 kPa, were investigated. The sizes and patterns of cracks were observed and classified. A simplified classification based on main track and secondary branch tracks is introduced. The vertical strain measure at each cycle, which showed swell and shrinkage, was plotted. The hydromechanical behavior of the clay, which corresponds to three levels of overburden stress as indicated by its swell potential and hydraulic conductivity was observed. It was found that at low overburden stresses of 50 kPa, the shrinkage is high and drops with increasing the number of cycles. Al-Ghatt clay’s tendency to crack is significantly reduced or eliminated by the 200 kPa overburden pressure. The results of this work can be used to calculate the depth of a foundation and the amount of partial soil replacement that is needed. Full article

Dendritic hydrogels based on carbosilane crosslinkers are promising drug delivery systems, as their amphiphilic nature improves the compatibility with poorly water-soluble drugs. In this work, we explored the impact of the complementary polymer on the amphiphilic properties of the dendritic network. Different polymers were selected as precursors, from the highly lipophilic propylene glycol (PPG) to the hydrophilic polyethylene glycol (PEG), including amphiphilic Pluronics L31, L35 and L61. The dithiol polymers reacted with carbosilane crosslinkers through UV-initiated thiol–ene coupling (TEC), and the resultant materials were classified as non-swelling networks (for PPG, PLU_L31 and PLU_L61) and high-swelling hydrogels (for PEG and PLU_L35). The hydrogels exhibited thermo-responsive properties, shrinking at higher temperatures, and exhibited an intriguing drug release pattern due to internal nanostructuring. Furthermore, we fine-tuned the dendritic crosslinker, including hydroxyl and azide pendant groups in the focal point, generating functional networks that can be modified through degradable (ester) and non-degradable (triazol) bonds. Overall, this work highlighted the crucial role of the amphiphilic balance in the design of dendritic hydrogels with thermo-responsive behavior and confirmed their potential as functional networks for biomedical applications. Full article

Natural biopolymers offer a sustainable alternative for improving soil behavior due to their inert nature, small dosage requirement, and applicability under ambient temperatures. This research evaluates the efficacy of natural biopolymers for ameliorating an expansive soil by using a 0.5% dosage of cationic chitosan, charge-neutral guar gum, and anionic xanthan gum during compaction. The results of laboratory investigations indicate that the flow through and volume change properties of the expansive soil were affected variably. The dual porosity, characterized by low air entry due to inter-aggregate pores (AEV₁ of 4 kPa) and high air entry due to the clay matrix (AEV₂ of 200 kPa) of the soil, was healed using chitosan and guar gum (AEV of 200 kPa) but was enhanced by the xanthan gum (AEV₁ of 100 kPa and AEV₂ of 200 kPa). The s-shaped swell–shrink path of the soil comprised structural (e from 1.23 to 1.11), normal (e from 1.11 to 0.6), and residual stages (e ranged from 0.6–0.43). This shape was converted into a j-shaped path through amendment using chitosan and guar gum, showing no structural volume change, with e from about 1.25 to 0.5, but was reverted to a more pronounced form by xanthan gum, with e from 1.5 to 1.32, 1.32 to 0.49, and 0.49 to 0.34 in the three stages, respectively. The consolidation behavior of the soil was largely unaffected by the addition of biopolymers such that the saturated hydraulic conductivity decreased from 10⁻⁹ m/s to 10⁻¹² m/s over a void ratio decrease from 1.1 to 0.6. At a seating stress of 5 kPa, the swelling potential (7.8%) of the soil slightly decreased to 6.9% due to the addition of chitosan but increased to 9.4% and 12.2% with guar gum and xanthan gum, respectively. The use of chitosan and guar gum will allow the compaction of the investigated expansive soil on the dry side of optimum. Full article

Biologically derived hydrogels have attracted attention as promising polymers for use in biomedical applications because of their high biocompatibility, biodegradability, and low toxicity. Elastin-mimetic polypeptides (EMPs), which contain a repeated amino acid sequence derived from the hydrophobic domain of tropoelastin, exhibit reversible phase transition behavior, and thus, represent an interesting starting point for the development of biologically derived hydrogels. In this study, we succeeded in developing functional EMP-conjugated hydrogels that displayed temperature-responsive swelling/shrinking properties. The EMP-conjugated hydrogels were prepared through the polymerization of acrylated EMP with acrylamide. The EMP hydrogel swelled and shrank in response to temperature changes, and the swelling/shrinking capacity of the EMP hydrogels could be controlled by altering either the amount of EMP or the salt concentration in the buffer. The EMP hydrogels were able to select a uniform component of EMPs with a desired and specific repeat number of the EMP sequence, which could control the swelling/shrinking property of the EMP hydrogel. Moreover, we developed a smart hydrogel actuator based on EMP crosslinked hydrogels and non-crosslinked hydrogels that exhibited bidirectional curvature behavior in response to changes in temperature. These thermally responsive EMP hydrogels have potential use as bio-actuators for a number of biomedical applications. Full article

The weather variations around the world are already having a profound impact on agricultural production. This impacts apple production and the quality of the product. Through agricultural precision, growers attempt to optimize both yield and fruit size and quality. Two experiments were conducted using field-grown “Gala” apple trees in Geneva, NY, USA, in 2021 and 2022. Mature apple trees (Malus × domestica Borkh. cv. Ultima “Gala”) grafted onto G.11 rootstock planted in 2015 were used for the experiment. Our goal was to establish a relationship between stem water potential (Ψ_trunk), which was continuously measured using microtensiometers, and the growth rate of apple fruits, measured continuously using dendrometers throughout the growing season. The second objective was to develop thresholds for Ψ_trunk to determine when to irrigate apple trees. The economic impacts of different irrigation regimes were evaluated. Three different water regimes were compared (full irrigation, rainfed and rain exclusion to induce water stress). Trees subjected the rain-exclusion treatment were not irrigated during the whole season, except in the spring (April and May; 126 mm in 2021 and 100 mm in 2022); that is, these trees did not receive water during June, July, August and half of September. Trees subjected to the rainfed treatment received only rainwater (515 mm in 2021 and 382 mm in 2022). The fully irrigated trees received rain but were also irrigated by drip irrigation (515 mm in 2021 and 565 mm in 2022). Moreover, all trees received the same amount of water out of season in autumn and winter (245 mm in 2021 and 283 mm in 2022). The microtensiometer sensors detected differences in Ψ_trunk among our treatments over the entire growing season. In both years, experimental trees with the same trunk cross-section area (TCSA) were selected (23–25 cm⁻² TCSA), and crop load was adjusted to 7 fruits·cm⁻² TCSA in 2021 and 8.5 fruits·cm⁻² TCSA in 2022. However, the irrigated trees showed the highest fruit growth rates and final fruit weight (157 g and 70 mm), followed by the rainfed only treatment (132 g and 66 mm), while the rain-exclusion treatment had the lowest fruit growth rate and final fruit size (107 g and 61 mm). The hourly fruit shrinking and swelling rate (mm·h⁻¹) measured with dendrometers and the hourly Ψ_trunk (bar) measured with microtensiometers were correlated. We developed a logistic model to correlate Ψ_trunk and fruit growth rate (g·h⁻¹), which suggested a critical value of −9.7 bars for Ψ_trunk, above which there were no negative effects on fruit growth rate due to water stress in the relatively humid conditions of New York State. A support vector machine model and a multiple regression model were developed to predict daytime hourly Ψ_trunk with radiation and VPD as input variables. Yield and fruit size were converted to crop value, which showed that managing water stress with irrigation during dry periods improved crop value in the humid climate of New York State. Full article

As one of the most important anisotropic intelligent materials, bi-layer stimuli-responsive actuating hydrogels have proven their wide potential in soft robots, artificial muscles, biosensors, and drug delivery. However, they can commonly provide a simple one-actuating process under one external stimulus, which severely limits their further application. Herein, we have developed a new anisotropic hydrogel actuator by local ionic crosslinking on the poly(acrylic acid) (PAA) hydrogel layer of the bi-layer hydrogel for sequential two-stage bending under a single stimulus. Under pH = 13, ionic-crosslinked PAA networks undergo shrinking (-COO⁻/Fe³⁺ complexation) and swelling (water absorption) processes. As a combination of Fe³⁺ crosslinked PAA hydrogel (PAA@Fe³⁺) with non-swelling poly(3-(1-(4-vinylbenzyl)-1H-imidazol-3-ium-3-yl)propane-1-sulfonate) (PZ) hydrogel, the as-prepared PZ-PAA@Fe³⁺ bi-layer hydrogel exhibits distinct fast and large-amplitude bidirectional bending behavior. Such sequential two-stage actuation, including bending orientation, angle, and velocity, can be controlled by pH, temperature, hydrogel thickness, and Fe³⁺ concentration. Furthermore, hand-patterning Fe³⁺ to crosslink with PAA enables us to achieve various complex 2D and 3D shape transformations. Our work provides a new bi-layer hydrogel system that performs sequential two-stage bending without switching external stimuli, which will inspire the design of programmable and versatile hydrogel-based actuators. Full article

Neurons spend most of their energy building ion gradients across the cell membrane. During energy deprivation the neurons swell, and the concomitant mixing of their ions is commonly assumed to lead toward a Donnan equilibrium, at which the concentration gradients of all permeant ion species have the same Nernst potential. This Donnan equilibrium, however, is not isotonic, as the total concentration of solute will be greater inside than outside the neurons. The present theoretical paper, in contrast, proposes that neurons follow a path along which they swell quasi-isotonically by co-transporting water and ions. The final neuronal volume on the path is taken that at which the concentration of impermeant anions in the shrinking extracellular space equals that inside the swelling neurons. At this final state, which is also a Donnan equilibrium, all permeant ions can mix completely, and their Nernst potentials vanish. This final state is isotonic and electro-neutral, as are all intermediate states along this path. The path is in principle reversible, and maximizes the work of mixing. Full article

The pH-responsive fluorescent P(1,8-naphthalic anhydride (NA)-acrylic acid (AA)) matrix was successfully prepared by a doping method using poly(acrylic acid) (PAA) as a pH-sensitive polymer and NA as a fluorescent tracer. The fluorescent behaviors of the used NA dispersed in PAA frameworks were demonstrated based on fractal features combined with various characterizations, such as small-angle X-ray scattering (SAXS) patterns, photoluminescence (PL) spectra, scanning electron microscope (SEM) images, thermogravimetry (TG) profiles, Fourier transform infrared (FT-IR) spectroscopy, and time-resolved decays. The effects of NA-doping on the representative fluorescent P(NA-AA) were investigated, in which the fluorescent performance of the doped NA was emphasized. The results indicated that aggregated clusters of the doped NA were gradually serious with an increase in NA doping amount or extension of NA doping time, accompanied by an increase in mass fractal dimension (D_m) values. Meanwhile, the doped NA presented stable fluorescent properties during the swelling–shrinking process of PAA. Ibuprofen (IBU) was used as a model drug, and fractal evolutions of the obtained P(NA-AA) along with the drug loading and releasing behaviors were evaluated via SAXS patterns, in which the drug-loaded P(NA-AA) presented surface fractal (D_s) characteristics, while the D_m value varied from 2.94 to 2.58 during sustained drug-release in pH 2.0, indicating occurrences of its structural transformation from dense to loose with extension of IBU-releasing time. Finally, the cytotoxicity and cellular uptake behaviors of the obtained P(NA-AA) were preliminarily explored. These demonstrations revealed that the resultant P(NA-AA) should be a potential intelligent-responsive drug carrier for targeted delivery. Full article

Processes responsible for natural recovery of compacted forest soils are poorly understood, making estimating their recovery problematic. Bulk density was measured over 7 years at nine boreal forest sites in Alberta, Canada, where harvest-only and three skidding treatments were installed (~10,000 samples). Air and soil temperatures, soil moisture and redox potential, and snow depth were also measured on the harvest-only and adjacent seven-cycle skid trail. Significant increases in bulk density occurred when the soil water potential was wetter than −25 kPa. After 1 year, an additional significant increase in bulk density of 0.03 Mg m⁻³ was measured across all treatments, soil depths, and sites. The increase is attributed to the soil mechanics process of rebound and disruption of soil biological processes. By year 7, the secondary increase in bulk density had recovered in trafficked soil, but not on the harvest-only area. Some soil freezing had no effect on bulk density, which was moderated by the depth of the snowpack. The array of soil physical processes, soil texture, water supply, mechanics of water freezing in soil, and weather required to make soil freezing an effective decompacting agent did not occur. The shrink–swell process was not relevant because the soils remained wet. As a result, the bulk density of the trafficked soil failed to recover after 7 years to a depth of 20 cm. The freeze–thaw process as a decompaction agent is far more complex than commonly assumed, and its effectiveness cannot be assumed because soil temperatures below 0 °C are measured. Full article

A phenomenon causing instability of soil structure and associated hydraulic properties in recently tilled soils is aggregate fragmentation induced by wetting and drying cycles. We analyzed data from three experiments in Puerto Rico, the UK and China measuring fragmentation and resulting evolution of aggregate size distributions during successive wetting and drying cycles in heavy textured soils. Aggregate distributions were represented as the cumulative fraction F of aggregates passing through successively larger sieve sizes X. To a good approximation, all distributions exhibited similarity in that the aggregate diameter X(F) corresponding to F in a given test distribution was always a characteristic multiple $\overline{\alpha }$ of X(F) in a fixed reference distribution, where $\overline{\alpha }$ for a distribution was calculated as its mean weight aggregate diameter (MWD) divided by the MWD of the reference distribution. In most cases, $\overline{\alpha }$ for a given soil varied inversely with the square of the number of wetting and drying cycles. For different soils of similar initial aggregate sizes, $\overline{\alpha }$ for a given wet–dry cycle decreased with increasing activity coefficient, reflecting the enhancing effect of soil shrink–swell potential on fragmentation. Results highlight usefulness of the van Bavel mean weight diameter as a natural scaling parameter for characterizing aggregate distributions. Full article

Soil shrink–swell behavior is a common phenomenon in farmland, which usually alters the process of water and solute migration in soil. In this paper, we report on a phenomenological investigation aimed at exploring the impact of drying–wetting cycles on the shrink–swell behavior of soil in farmland. Samples were prepared using clay loam collected from farmland and subjected to four drying–wetting cycles. The vertical deformation of soil was measured by a vernier caliper, and the horizontal deformation was captured by a digital camera and then calculated via an image processing technique. The results showed that the height, equivalent diameter, volume and shrinkage-swelling potential of the soil decreased with the repeated cycles. Irreversible deformation (shrinkage accumulation) was observed during cycles, suggesting that soil cracks might form owing to previous drying rather than current drying. The vertical shrinkage process consisted of two stages: a declining stage and a residual stage, while the horizontal shrinkage process had one more stage, a constant stage at the initial time of drying. The VG-Peng model fit the soil shrinkage curves very well, and all shrinkage curves had four complete shrinkage zones. Drying–wetting cycles had a substantial impact on the soil shrinkage curves, causing significant changes in the distribution of void ratio and moisture ratio in the four zones. However, the impact weakened as the number of cycles increased because the soil structure became more stable. Vertical shrinkage dominated soil deformation at the early stage of drying owing to the effect of gravity, while nearly isotropic shrinkage occurred after entering residual shrinkage. Our study revealed the irreversible deformation and deformation anisotropy of clay loam collected from farmland during drying–wetting cycles and analyzed the shrink–swell behavior during cycles from both macroscopic and microscopic points of view. The results are expected to improve the understanding of the shrink–swell behavior of clay loam and the development of soil desiccation cracks, which will be benefit research on water and solute migration in farmland. Full article