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Search Results (872)

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Keywords = suspended sediment

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18 pages, 5098 KiB  
Article
Quantification of Suspended Sediment Concentration Using Laboratory Experimental Data and Machine Learning Model
by Sathvik Reddy Nookala, Jennifer G. Duan, Kun Qi, Jason Pacheco and Sen He
Water 2025, 17(15), 2301; https://doi.org/10.3390/w17152301 - 2 Aug 2025
Viewed by 242
Abstract
Monitoring sediment concentration in water bodies is crucial for assessing water quality, ecosystems, and environmental health. However, physical sampling and sensor-based approaches are labor-intensive and unsuitable for large-scale, continuous monitoring. This study employs machine learning models to estimate suspended sediment concentration using images [...] Read more.
Monitoring sediment concentration in water bodies is crucial for assessing water quality, ecosystems, and environmental health. However, physical sampling and sensor-based approaches are labor-intensive and unsuitable for large-scale, continuous monitoring. This study employs machine learning models to estimate suspended sediment concentration using images captured in natural light, named RGB, and near-infrared (NIR) conditions. A controlled dataset of approximately 1300 images with SSC values ranging from 1000 mg/L to 150,000 mg/L was developed, incorporating temperature, time of image capture, and solar irradiance as additional features. Random forest regression and gradient boosting regression were trained on mean RGB values, red reflectance, time of captured, and temperature for natural light images, achieving up to 72.96% accuracy within a 30% relative error. In contrast, NIR images leveraged gray-level co-occurrence matrix texture features and temperature, reaching 83.08% accuracy. Comparative analysis showed that ensemble models outperformed deep learning models like Convolutional Neural Networks and Multi-Layer Perceptrons, which struggled with high-dimensional feature extraction. These findings suggest that using machine learning models and RGB and NIR imagery offers a scalable, non-invasive, and cost-effective way of sediment monitoring in support of water quality assessment and environmental management. Full article
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17 pages, 2032 KiB  
Article
The Impact of Hydrological Streamflow Drought on Pollutant Concentration and Its Implications for Sustainability in a Small River in Poland
by Leszek Hejduk, Ewa Kaznowska, Michał Wasilewicz and Agnieszka Hejduk
Sustainability 2025, 17(15), 6995; https://doi.org/10.3390/su17156995 - 1 Aug 2025
Viewed by 166
Abstract
The paper presents the results of investigations into the relationship between selected water quality parameters and hydrological streamflow drought in a small river situated in the Mazovian Lowlands in Poland. As hydrological streamflow drought periods become more frequent in Poland, investigations about the [...] Read more.
The paper presents the results of investigations into the relationship between selected water quality parameters and hydrological streamflow drought in a small river situated in the Mazovian Lowlands in Poland. As hydrological streamflow drought periods become more frequent in Poland, investigations about the relationship between flow and water quality parameters can be an essential contribution to a better understanding of the impact of low flow on the status of water rivers. Data from a three-year study of a small lowland river along with significant agricultural land management was used to analyze the connection between low flows and specific water quality indicators. The separation of low-flow data from water discharge records was achieved using two criteria: Q90% (the discharge value from a flow duration curve) and a minimum low-flow duration of 10 days. During these periods, the concentration of water quality indicators was determined based on collected water samples. In total, 30 samples were gathered and examined for pH, suspended sediments, dissolved substances, hardness, ammonium, nitrates, nitrites, phosphates, total phosphorus, chloride, sulfate, calcium, magnesium, and water temperature during sampling. The study’s main aim was to describe the relation between hydrological streamflow droughts and chosen water quality parameters. The analysis results demonstrate an inverse statistically significant relationship between concentration and low-flow values for total hardness and sulfate. In contrast, there was a direct relationship between nutrient indicators, suspended sediment concentration, and river hydrological streamflow drought. Statistical tests were applied to compare the datasets between years, revealing statistical differences only for nutrient indicators. Full article
(This article belongs to the Topic Water Management in the Age of Climate Change)
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26 pages, 1533 KiB  
Article
Optimization of Agricultural and Urban BMPs to Meet Phosphorus and Sediment Loading Targets in the Upper Soldier Creek, Kansas, USA
by Naomi E. Detenbeck, Christopher P. Weaver, Alyssa M. Le, Philip E. Morefield, Samuel Ennett and Marilyn R. ten Brink
Water 2025, 17(15), 2265; https://doi.org/10.3390/w17152265 - 30 Jul 2025
Viewed by 220
Abstract
This study was developed to identify the optimal (most cost-effective) strategies to reduce sediment and phosphorus loadings in the Upper Soldier Creek, Kansas, USA, watershed using the Watershed Management Optimization Support Tool (WMOST) suite of programs. Under average precipitation, loading targets for upland [...] Read more.
This study was developed to identify the optimal (most cost-effective) strategies to reduce sediment and phosphorus loadings in the Upper Soldier Creek, Kansas, USA, watershed using the Watershed Management Optimization Support Tool (WMOST) suite of programs. Under average precipitation, loading targets for upland total phosphorus (TP) could be met with use of grassed swales for treating urban area runoff and of contouring for agricultural runoff. For a wet year, the same target could be met, but with use of a sand filter with underdrain for the urban runoff. Both annual and daily TP loading targets from Total Maximum Daily Loads (TMDLs) were exceeded in simulations of best management practice (BMP) solutions for 14 alternative future climate scenarios. We expanded the set of BMPs to include stream bank stabilization (physical plus riparian restoration) and two-stage channel designs, but upland loading targets could not be met for either TP or total suspended solids (TSS) under any precipitation conditions. An optimization scenario that simulated the routing of flows in excess of those treated by the upland BMPs to an off-channel treatment wetland allowed TMDLs to be met for an average precipitation year. WMOST can optimize cost-effectiveness of BMPs across multiple scales and climate scenarios. Full article
(This article belongs to the Special Issue Optimization-Simulation Modeling of Sustainable Water Resource)
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8 pages, 7294 KiB  
Interesting Images
A Rocky Intertidal Desert at the Head of a Large Macrotidal Estuary in Quebec, Canada
by Ricardo A. Scrosati
Diversity 2025, 17(8), 535; https://doi.org/10.3390/d17080535 - 30 Jul 2025
Viewed by 249
Abstract
This article documents the widespread absence of sessile species in bedrock intertidal habitats at the head of the St. Lawrence Estuary, a large macrotidal estuary located in eastern Canada. Extensive observations revealed that no seaweeds or sessile invertebrates occurred anywhere (including cracks and [...] Read more.
This article documents the widespread absence of sessile species in bedrock intertidal habitats at the head of the St. Lawrence Estuary, a large macrotidal estuary located in eastern Canada. Extensive observations revealed that no seaweeds or sessile invertebrates occurred anywhere (including cracks and crevices) on substrate areas that become exposed to the air during low tides. Only one sessile species, a green filamentous alga, was found submerged in tidepools. The lack of truly marine sessile species is likely explained by the very low water salinity of this coast, while the absence of sessile freshwater species on intertidal substrates outside of tidepools likely responds to a combination of oligohaline conditions during high tides and daily exposures to the air during low tides, which freshwater species are typically not adapted to. Influences of winter ice scour and coastal suspended sediments are likely secondary. Experimental research could unravel the interactive effects of these abiotic stressors. Overall, this “intertidal desert” could be a useful model system to further explore the boundaries of life on our planet. Full article
(This article belongs to the Collection Interesting Images from the Sea)
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18 pages, 3824 KiB  
Article
An Integrated TDR Waveguide and Data Interpretation Framework for Multi-Phase Detection in Soil–Water Systems
by Songcheng Wen, Jingwei Wu and Yuan Guo
Sensors 2025, 25(15), 4683; https://doi.org/10.3390/s25154683 - 29 Jul 2025
Viewed by 220
Abstract
Time domain reflectometry (TDR) has been validated for monitoring water level evolution and riverbed scouring in the laboratory. Previous studies have also validated the feasibility of field-based single hydrological parameter monitoring using TDR. However, the current research focuses on developing separated TDR sensing [...] Read more.
Time domain reflectometry (TDR) has been validated for monitoring water level evolution and riverbed scouring in the laboratory. Previous studies have also validated the feasibility of field-based single hydrological parameter monitoring using TDR. However, the current research focuses on developing separated TDR sensing systems, and integrated measurements of multiple hydrological parameters from a single reflected waveform have not been reported. This study presents an improved helical probe sensor specifically designed for implementation in geologically hard soils, together with an improved data interpreting methodology to simultaneously determine water surface level, bed elevation, and suspended sediment concentration from a single reflection signal. Experimental comparisons were conducted in the laboratory to evaluate the measuring performance between the traditional dual-needle probe and the novel spiral probe under the same scouring conditions. The experiments confirmed the reliability and superior performance of spiral probe in accurately capturing multiple hydrological parameters. The measurement errors for the spiral probe across multiple hydrological parameters were all within ±10%, and the accuracy further improved with increased probe embedding depth in the sand medium. Across all tested parameters, the spiral probe showed enhanced measurement precision with a particularly significant improvement in suspended sediment concentration detection. Full article
(This article belongs to the Section Environmental Sensing)
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21 pages, 5274 KiB  
Article
Sediment Flushing Operation Mode During Sediment Peak Processes Aiming Towards the Sustainability of Three Gorges Reservoir
by Bingjiang Dong, Lingling Zhu, Shi Ren, Jing Yuan and Chaonan Lv
Sustainability 2025, 17(15), 6836; https://doi.org/10.3390/su17156836 - 28 Jul 2025
Viewed by 262
Abstract
Asynchrony between the movement of water and sediment in a reservoir will affect long-term maintenance of the reservoir’s capacity to a certain extent. Based on water and sediment data on the Three Gorges Reservoir (TGR) measured over the years and a river network [...] Read more.
Asynchrony between the movement of water and sediment in a reservoir will affect long-term maintenance of the reservoir’s capacity to a certain extent. Based on water and sediment data on the Three Gorges Reservoir (TGR) measured over the years and a river network model, optimization of the dispatching mode of the reservoir’s sand peak process was studied, and the corresponding water and sediment dispatching indicators were provided. The results show that (1) sand peak discharge dispatching of the TGR can be divided roughly into three stages, namely the flood detention period, the sediment transport period, and the sediment discharge period. (2) According to the process of the flood peak and the sand peak, a division method for each period is proposed. (3) A corresponding scheduling index is proposed according to the characteristics of the sand peak process and the needs of flood control scheduling. This research can provide operational indicators for the operation and management of the sediment load in the TGR and also provide technical support for sustainable reservoirs similar to TGR. Full article
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14 pages, 3283 KiB  
Review
Impact of Internal Solitary Waves on Marine Suspended Particulate Matter: A Review
by Zhengrong Zhang, Xuezhi Feng, Xiuyao Fan, Yuchen Lin and Chaoqi Zhu
J. Mar. Sci. Eng. 2025, 13(8), 1433; https://doi.org/10.3390/jmse13081433 - 27 Jul 2025
Viewed by 197
Abstract
Suspended particulate matter (SPM) plays a pivotal role in marine source-to-sink sedimentary systems. Internal solitary waves (ISWs), a prevalent hydrodynamic phenomenon, significantly influence vertical mixing, cross-shelf material transport, and sediment resuspension. Acting as energetic nonlinear waves, ISWs can disrupt the settling trajectories of [...] Read more.
Suspended particulate matter (SPM) plays a pivotal role in marine source-to-sink sedimentary systems. Internal solitary waves (ISWs), a prevalent hydrodynamic phenomenon, significantly influence vertical mixing, cross-shelf material transport, and sediment resuspension. Acting as energetic nonlinear waves, ISWs can disrupt the settling trajectories of suspended particles, enhance lateral transport above the pycnocline, and generate nepheloid layers nearshore. Meanwhile, intense turbulent mixing induced by ISWs accumulates large quantities of SPM at both the leading surface and trailing bottom of the waves, thereby altering the structure and dynamics of the intermediate nepheloid layers. This review synthesizes recent advances in the in situ observational techniques for SPM under the influence of ISWs and highlights the key mechanisms governing their interactions. Particular attention is given to representative field cases in the SCS, where topographic complexity and strong stratification amplify ISWs–sediment coupling. Finally, current limitations in observational and modeling approaches are discussed, with suggestions for future interdisciplinary research directions that better integrate hydrodynamic and sediment transport processes. Full article
(This article belongs to the Special Issue Marine Geohazards: Characterization to Prediction)
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20 pages, 4961 KiB  
Article
Modelling of Water Level Fluctuations and Sediment Fluxes in Nokoué Lake (Southern Benin)
by Tètchodiwèï Julie-Billard Yonouwinhi, Jérôme Thiébot, Sylvain S. Guillou, Gérard Alfred Franck Assiom d’Almeida and Felix Kofi Abagale
Water 2025, 17(15), 2209; https://doi.org/10.3390/w17152209 - 24 Jul 2025
Viewed by 505
Abstract
Nokoué Lake is located in the south of Benin and is fed by the Ouémé and Sô Rivers. Its hydrosedimentary dynamics were modelled using Telemac2D, incorporating the main environmental factors of this complex ecosystem. The simulations accounted for flow rates and suspended solids [...] Read more.
Nokoué Lake is located in the south of Benin and is fed by the Ouémé and Sô Rivers. Its hydrosedimentary dynamics were modelled using Telemac2D, incorporating the main environmental factors of this complex ecosystem. The simulations accounted for flow rates and suspended solids concentrations during periods of high and low water. The main factors controlling sediment transport were identified. The model was validated using field measurements of water levels and suspended solids. The results show that the north–south current velocity ranges from 0.5 to 1 m/s during periods of high water and 0.1 to 0.5 m/s during low-water periods. Residual currents are influenced by rainfall, river discharge, and tides. Complex circulation patterns are caused by increased river flow during high water, while tides dominate during low water and transitional periods. The northern, western, and south-eastern parts of the lake have weak residual currents and are, therefore, deposition zones for fine sediments. The estimated average annual suspended solids load for 2022–2023 is 17 Mt. The model performance shows a strong agreement between the observed and simulated values: R2 = 0.91 and NSE = 0.93 for water levels and R2 = 0.86 and NSE = 0.78 for sediment transport. Full article
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21 pages, 13177 KiB  
Article
Links Between the Coastal Climate, Landscape Hydrology, and Beach Dynamics near Cape Vidal, South Africa
by Mark R. Jury
Coasts 2025, 5(3), 25; https://doi.org/10.3390/coasts5030025 - 18 Jul 2025
Viewed by 275
Abstract
Coastal climate processes that affect landscape hydrology and beach dynamics are studied using local and remote data sets near Cape Vidal (28.12° S, 32.55° E). The sporadic intra-seasonal pulsing of coastal runoff, vegetation, and winds is analyzed to understand sediment inputs and transport [...] Read more.
Coastal climate processes that affect landscape hydrology and beach dynamics are studied using local and remote data sets near Cape Vidal (28.12° S, 32.55° E). The sporadic intra-seasonal pulsing of coastal runoff, vegetation, and winds is analyzed to understand sediment inputs and transport by near-shore wind-waves and currents. River-borne sediments, eroded coral substrates, and reworked beach sand are mobilized by frequent storms. Surf-zone currents ~0.4 m/s instill the northward transport of ~6 105 kg/yr/m. An analysis of the mean annual cycle over the period of 1997–2024 indicates a crest of rainfall over the Umfolozi catchment during summer (Oct–Mar), whereas coastal suspended sediment, based on satellite red-band reflectivity, rises in winter (Apr–Sep) due to a deeper mixed layer and larger northward wave heights. Sediment input to the beaches near Cape Vidal exhibit a 3–6-year cycle of southeasterly waves and rainy weather associated with cool La Nina tropical sea temperatures. Beachfront sand dunes are wind-swept and release sediment at ~103 m3/yr/m, which builds tall back-dunes and helps replenish the shoreline, especially during anticyclonic dry spells. A wind event in Nov 2018 is analyzed to quantify aeolian transport, and a flood in Jan–Feb 2025 is studied for river plumes that meet with stormy seas. Management efforts to limit development and recreational access have contributed to a sustainable coastal environment despite rising tides and inland temperatures. Full article
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20 pages, 7401 KiB  
Article
Measurement of Suspended Sediment Concentration at the Outlet of the Yellow River Canyon: Using Sentinel-2 Images and Machine Learning
by Genxin Song, Youjing Jiang, Xinyu Lei and Shiyan Zhai
Remote Sens. 2025, 17(14), 2424; https://doi.org/10.3390/rs17142424 - 12 Jul 2025
Viewed by 321
Abstract
The remote sensing inversion of the Suspended Sediment Concentration (SSC) at the Yellow River estuary is crucial for regional sediment management and the advancement of monitoring techniques for highly turbid waters. Traditional in situ methods and low-resolution imagery are no longer sufficient for [...] Read more.
The remote sensing inversion of the Suspended Sediment Concentration (SSC) at the Yellow River estuary is crucial for regional sediment management and the advancement of monitoring techniques for highly turbid waters. Traditional in situ methods and low-resolution imagery are no longer sufficient for high-accuracy studies. Using SSC data from the Longmen Hydrological Station (2019–2020) and Sentinel-2 imagery, multiple models were compared, and the random forest regression model was selected for its superior performance. A non-parametric regression model was developed based on optimal band combinations to estimate the SSC in high-sediment rivers. Results show that the model achieved a high coefficient of determination (R2 = 0.94) and met accuracy requirements considering the maximum SSC, MAPE, and RMSE. The B4, B7, B8A, and B9 bands are highly sensitive to high-concentration sediment rivers. SSC exhibited significant seasonal and spatial variation, peaking above 30,000 mg/L in summer (July–September) and dropping below 1000 mg/L in winter, with a positive correlation with discharge. Spatially, the SSC was higher in the gorge section than in the main channel during the flood season and higher near the banks than in the river center during the dry season. Overall, the random forest model outperformed traditional methods in SSC prediction for sediment-laden rivers. Full article
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20 pages, 3656 KiB  
Article
Wetland Ecological Restoration and Geomorphological Evolution: A Hydrodynamic-Sediment-Vegetation Coupled Modeling Study
by Haiyang Yan, Bing Shi and Feng Gao
J. Mar. Sci. Eng. 2025, 13(7), 1326; https://doi.org/10.3390/jmse13071326 - 10 Jul 2025
Viewed by 236
Abstract
This study developed a coupled hydrodynamic-sediment-vegetation model to investigate the effects of Spartina alterniflora management and Suaeda salsa restoration on coastal wetland geomorphological evolution and vegetation distribution. Special attention is paid to the regulatory roles of tidal dynamics, sea-level rise, sediment supply, and [...] Read more.
This study developed a coupled hydrodynamic-sediment-vegetation model to investigate the effects of Spartina alterniflora management and Suaeda salsa restoration on coastal wetland geomorphological evolution and vegetation distribution. Special attention is paid to the regulatory roles of tidal dynamics, sea-level rise, sediment supply, and sediment characteristics. The study shows that the management of Spartina alterniflora significantly alters the sediment deposition patterns in salt marsh wetlands, leading to intensified local erosion and a decline in the overall stability of the wetland system; meanwhile, the geomorphology of wetlands restored with Suaeda salsa is influenced by tidal range, sediment settling velocity, and suspended sediment concentration, exhibiting different deposition and erosion patterns. Under the scenario of sea-level rise, when sedimentation rates fail to offset the rate of sea-level increase, the wetland ecosystem faces the risk of collapse. This study provides scientific evidence for the ecological restoration and management of coastal wetlands and offers theoretical support for future wetland conservation and restoration policies. Full article
(This article belongs to the Section Coastal Engineering)
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23 pages, 4329 KiB  
Article
Sediment Fingerprinting Enables the Determination of Soil Erosion Sources and Sediment Transport Processes in a Topographically Complex Nile Headwater Basin
by Amartya K. Saha, Christopher L. Dutton, Marc Manyifika, Sarah C. Jantzi and Sylvere N. Sirikare
Soil Syst. 2025, 9(3), 70; https://doi.org/10.3390/soilsystems9030070 - 4 Jul 2025
Viewed by 315
Abstract
Sediment fingerprinting was utilized to identify potential hotspots of soil erosion and sediment transport pathways in the Nile Nyabarongo Upper Catchment (NNYU) in Rwanda, where rivers and reservoirs are suffering from alarmingly high levels of sedimentation. Sediment fingerprinting is a practical approach used [...] Read more.
Sediment fingerprinting was utilized to identify potential hotspots of soil erosion and sediment transport pathways in the Nile Nyabarongo Upper Catchment (NNYU) in Rwanda, where rivers and reservoirs are suffering from alarmingly high levels of sedimentation. Sediment fingerprinting is a practical approach used to identify erosional hotspots and sediment transport processes in highly mountainous regions undergoing swift land use transformation. This technique involves a statistical comparison of the elemental composition of suspended sediments in river water with the elemental composition of soils belonging to different geological formations present in the catchment, thereby determining the sources of the suspended sediment. Suspended sediments were sampled five times over dry and wet seasons in all major headwater tributaries, as well as the main river channel, and compared with soils from respective delineated watersheds. Elemental composition was obtained using laser ablation inductively coupled plasma mass spectrometry, and elements were chosen that could reliably distinguish between the various geological types. The final results indicate different levels of sediment contribution from different geological types. A three-level intervention priority system was devised, with Level 1 indicating the areas with the most serious erosion. Potential sources were located on an administrative map, with the highest likely erosion over the study period (Level 1) occurring in Kabuga cell in the Mwogo sub-catchment, Nganzo and Nyamirama cells in the Nyagako sub-catchment and Kanyana cell in the NNYU downstream sub-catchment. This map enables the pinpointing of site visits in an extensive and rugged terrain to verify the areas and causes of erosion and the pathways of sediment transport. Sediment concentrations (mg L−1) were the highest in the Secoko and Satinsyi tributaries. The composition of suspended sediment was seen to be temporally and spatially dynamic at each sampling point, suggesting the need for an adequate number of sampling locations to identify erosion hotspots in a large mountainous watershed. Apart from prioritizing rehabilitation locations, the detailed understanding of critical zone soil–land cover–climate processes is an important input for developing region-specific watershed management and policy guidelines. Full article
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28 pages, 31155 KiB  
Article
Numerical Simulation of Treatment Capacity and Operating Limits of Alkali/Surfactant/Polymer (ASP) Flooding Produced Water Treatment Process in Oilfields
by Jiawei Zhu, Mingxin Wang, Keyu Jing, Jiajun Hong, Fanxi Bu and Zhihua Wang
Energies 2025, 18(13), 3420; https://doi.org/10.3390/en18133420 - 29 Jun 2025
Viewed by 340
Abstract
As an enhanced oil recovery (EOR) technique, alkali/surfactant/polymer (ASP) flooding effectively mitigates production decline in mature oilfields through chemical flooding mechanisms. The breakthrough of ASP chemical agents poses challenges to the green and efficient separation of oilfield produced water. In this paper, sedimentation [...] Read more.
As an enhanced oil recovery (EOR) technique, alkali/surfactant/polymer (ASP) flooding effectively mitigates production decline in mature oilfields through chemical flooding mechanisms. The breakthrough of ASP chemical agents poses challenges to the green and efficient separation of oilfield produced water. In this paper, sedimentation separation of produced water was simulated using the Eulerian method and the RNG k–ε model. In addition, the filtration process was simulated using a discrete phase model (DPM) and a porous media model. The distribution characteristics of oil/suspended solids obtained through simulation, along with the water quality parameters at each treatment node, were systematically extracted, and the influence of operating conditions on treatment capacity was analyzed. Simulations reveal that elevated treatment loads and produced water polymer concentrations synergistically impair ASP flooding produced water treatment efficiency. Fluctuations of operating conditions generate oil/suspended solids content in output water ranges spanning 13–78 mg/L and 19–92 mg/L, respectively. The interpolation method is adopted to determine the critical water quality parameters of each treatment node, ensuring that the treated produced water meets the treatment standards. The operating limits of the ASP flooding produced water treatment process are established. Full article
(This article belongs to the Special Issue Advances in Wastewater Treatment, 2nd Edition)
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29 pages, 9360 KiB  
Article
Modeling Metal(loid)s Transport in Arid Mountain Headwater Andean Basin: A WASP-Based Approach
by Daniela Castillo, Ricardo Oyarzún, Pablo Pastén, Christopher D. Knightes, Denisse Duhalde, José Luis Arumí, Jorge Núñez and José Antonio Díaz
Water 2025, 17(13), 1905; https://doi.org/10.3390/w17131905 - 26 Jun 2025
Viewed by 367
Abstract
The occurrence of toxic metal(loid)s in surface freshwater is a global concern due to its impacts on human and ecosystem health. Conceptual and quantitative metal(loid) models are needed to assess the impact of metal(loid)s in watersheds affected by acid rock drainage. Few case [...] Read more.
The occurrence of toxic metal(loid)s in surface freshwater is a global concern due to its impacts on human and ecosystem health. Conceptual and quantitative metal(loid) models are needed to assess the impact of metal(loid)s in watersheds affected by acid rock drainage. Few case studies have focused on arid and semiarid headwaters, with scarce hydrological and hydrochemical information. This work reports the use of WASP8 (US EPA) to model Al, Fe, As, Cu, and SO42− concentrations in the Upper Elqui River watershed in north–central Chile. Calibrated model performance for total concentrations was “good” (25.9, RRMSE; 0.7, R2-d) to “very good” (0.8–0.9, R2-d). The dissolved concentrations ranged between “acceptable” (56.3, RRMSE), “good” (28.6, RRMSE; 0.7 d), and “very good” (0.9, R2-d). While the model validation achieved mainly “very good” (0.8–0.9, R2-d) predictions for total concentrations, the predicted dissolved concentrations were less accurate for all indicators. Sensitivity analysis showed that the partition coefficient is a sensitive constant for estimating dissolved concentrations, and that integrating sorption and sediment interaction reduces the model error. This work highlights the need for detailed and site-specific information on the reactive and hydrodynamic properties of suspended solids, which directly impact the partition coefficient, sedimentation, and resuspension velocity calibration. Full article
(This article belongs to the Special Issue Monitoring and Modelling of Contaminants in Water Environment)
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17 pages, 1618 KiB  
Article
A Phosphorus Microfractionation (P-MF) Method for Measuring Phosphorus Fractions in Small Quantities of Suspended Solids and Sediments: Detailed Method and Example Application
by Jacob B. Taggart, Rebecca L. Ryan, A. Woodruff Miller, Theron G. Miller and Gustavious P. Williams
Environments 2025, 12(7), 218; https://doi.org/10.3390/environments12070218 - 26 Jun 2025
Viewed by 368
Abstract
The standard methods for sediment phosphorus (P) fractionation are impractical for use with suspended solids due to the inherent difficulties associated with collecting sufficient sample quantities for analysis. To allow the fractionation analysis of small quantities of suspended solids or sediment, we developed [...] Read more.
The standard methods for sediment phosphorus (P) fractionation are impractical for use with suspended solids due to the inherent difficulties associated with collecting sufficient sample quantities for analysis. To allow the fractionation analysis of small quantities of suspended solids or sediment, we developed a P-microfractionation (P-MF) method and evaluated the minimum sample size threshold. The dry mass threshold is likely <1.0 g for Utah Lake suspended solids and between 0.35 and 0.99 g for Utah Lake sediments, though we recommend experimentation to refine these thresholds for other locations, as Utah Lake sediment P concentrations are high (~1000 mg kg−1). We estimated dry mass using duplicate samples, as drying a sample changes the P fractions. We show that Utah Lake suspended solids have a significantly higher P content across most P fractions compared to those in sediments, emphasizing the importance of considering suspended solids when managing water nutrient levels in eutrophic water bodies. P-MF has the potential to enable researchers to use reasonably sized water samples to assess the P sorption behavior of suspended solids, a measurement not typically performed. Full article
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