Search Results (437)

Plastic pyrolysis is widely used to treat polyolefin-rich waste; however, wax byproducts generated during these processes are typically regarded as low-value intermediates. Here, a byproduct-compatible upcycling strategy is proposed to convert polyethylene (PE) pyrolysis wax into activated carbon, enabling integration of functional carbon production into existing recycling value chains. Thermal oxidation was employed to stabilize the wax prior to carbonization, and stabilization at 300 °C yielded a mechanically stable precursor with a high carbon yield. Subsequent carbonization and KOH activation at 900 °C produced an activated carbon (PEWax_AC) with a specific surface area of 1704 m²/g, exceeding that of a representative commercial activated carbon (1575 m²/g). Microstructural analysis revealed predominantly amorphous carbon with locally ordered domains. In symmetric supercapacitor cells, PEWax_AC exhibited higher capacitance at low rates and superior rate capability at high scan rates and current densities, along with reduced charge-transfer resistance. Specifically, PEWax_AC delivered a specific capacitance of 22.9 F/g at 5 mV/s and exhibited a rate retention of 18.6% from 0.1 to 7.0 A/g. These findings demonstrate that plastic pyrolysis wax is a viable and scalable carbon precursor for high-performance supercapacitor electrodes. Full article

Water-In-Salt (WIS) electrolytes are expected to replace expensive, environmentally harmful organic electrolytes while delivering high voltages and improving system safety. In this study, analysis of the failure modes, mechanisms, and effects of a highly concentrated potassium acetate (KAc) electrolyte was conducted through electrolyte degradation at 2 V in a conventional EDLC carbon-based symmetric configuration. The adopted method provides a simplified yet effective approach for assessing the complexity and interconnectivity of degradation mechanisms in a WIS supercapacitor. The effects analysis included electrochemical stability studies, post-mortem characterizations (SEM-EDS and XPS), low-frequency impedance fitting, and cell reassembly using end-of-life electrodes. Among the failure modes analyzed, electrolyte decomposition and pore blocking exhibit strong physicochemical correlations and high failure rates. Therefore, they should be prioritized in the design of new WIS electrolyte compositions for next-generation energy storage systems. Full article

Supercapacitors (SCs) are highly attractive energy storage devices, and modern research is focused on using waste materials to reduce environmental impact. This study processed biowaste from local brewery production to produce a highly specific mesoporous activated carbon (AC) for SC electrode scaffolds. Polyaniline (PANI) was synthesized and incorporated into the AC scaffold, thereby enhancing performance. The AC and PANI combination (ACP) achieved a specific capacitance of 173.7 F/g at 1 A/g, with 92% retention after 5000 cycles. Using NdFeB (ACN) particles, the anode showed a specific capacitance of 127 F/g and over 99% retention. An asymmetrical ACN//ACP cell demonstrated promising performance with 70% efficiency. This study highlights the potential of using biowaste for high-performance SC electrodes and the effective synergy between AC and PANI. Full article

This work presents a compact, self-powered wireless CO₂ sensing node for autonomous environmental monitoring. The system integrates a high-efficiency multijunction photovoltaic (PV) module, a 4000 F hybrid supercapacitor operating at 3.6–4.2 V, and a custom power management system in a LiPo-sized form factor. The PV module, composed of nine parallel triple-junction solar cells, achieves an average efficiency of 27% and delivers peak power at 4.26 V under 600 W/m² irradiance. The sensing unit includes miniaturized CO₂, humidity, and temperature sensors with LoRa-based wireless communication. The low-power NDIR CO₂ sensor provides a resolution of 15–20 ppm and a response time of ~45 s. Week-long tests demonstrated fully autonomous operation with reliable 5 min data transmission, capturing diurnal CO₂ variations associated with plant activity even under low irradiance. Energy storage occurs for irradiance levels ≥65 W/m², and long-term simulations confirm stable supercapacitor voltage over yearly cycles. This work demonstrates a compact multijunction solar–hybrid supercapacitor platform capable of sustaining WSN for long-term, maintenance-free CO₂ monitoring under real-world and low-irradiance conditions. Our results demonstrate that the sensing node can reliably monitor plant-driven CO₂ dynamics, clearly resolving the expected photosynthesis–respiration cycles and their dependence on incident solar radiation, while simultaneously sustaining its energy budget under highly challenging illumination and transmission conditions. Full article

Dimensioning the energy storage systems for a heavy-duty fuel cell hybrid electric vehicle is not straightforward. This study proposes a methodology to address this challenge, aiming to maximize efficiency while mitigating the aging effects on the energy storage systems. Various configurations of storage system ratios have been analyzed using the concept of hybridization percentage, which represents the ratio between the supercapacitor weight and the total weight of the energy storage elements. Simulations were conducted using models developed in AVL Cruise MTM. A case study is included to test the methodology, incorporating commercial components, a standard driving cycle, and a rule-based energy management strategy. The conclusions of this application example illustrate the types of results that can be obtained by using this hybrid energy storage system sizing methodology. Findings for this case study suggest that for cycles lacking extreme power peaks, non-hybridized configurations can be the optimal solution, as the battery size reduction outweighs the benefits of hybridization in terms of efficiency, achieving 76.08% without supercapacitors compared to 65.7% with a high hybridization grade of 32.4%, and overall cost. However, sensitivity analysis reveals that if the optimization weights are adjusted to prioritize aging over efficiency, the optimal configuration shifts to a 6.48% hybridization grade at a 0.3C threshold. Full article

We present an investigation to develop innovative composite fibrous electrodes optimized for a supercapacitor with a “green” low-cost aqueous electrolyte, superconcentrated potassium formate, which raises the maximum energy storage device voltage beyond the water electrolysis limit. Three types of electrospun nanofiber mats are investigated for optimum pseudocapacitance with this electrolyte: polyaniline (PANI)/polyacrylonitrile (PAN) fibers, without or with 1 wt% or 10 wt% graphene nanoplatelets (GNP). These nanofiber mats are considered as standalone electrodes or in bilayer formations with a phenolic-derived activated carbon fabric. Supercapacitor cells with these electrodes are tested electrochemically via electrical impedance spectroscopy, cyclic voltammetry and galvanostatic charge–discharge at different current densities. The supercapacitor with hybrid electrode bilayers of activated carbon fabric and electrospun fiber mat consisting of PANI:PAN at 50:50 w/w with 10 wt% GNP exhibited the best performance with an energy and a power density of 39 Wh/kg and 6057 W/kg of electrodes, respectively. Full article

The growing demand for efficient and sustainable energy storage has intensified interest in green materials known for their high-power density. In this work, we evaluated the electrochemical and electrical performance of coin-cell supercapacitors with activated carbon electrodes from palm kernel shell. Two activated carbons were obtained using KOH and ZnCl₂ as activating agents at 700 °C and then superficially modified with nitric acid. The KOH-activated carbon electrodes showed the highest specific surface area (1181 m² g⁻¹) and the best electrochemical behavior, reaching an average gravimetric capacitance of 56. ± 9.2 F g⁻¹. The coins were characterized electrically by series and parallel arrangements, yielding specific energy and specific power densities of 2.6 Wh kg⁻¹ and 475 W kg⁻¹, and 1.8 Wh kg⁻¹ and 353 W kg⁻¹, at 0.001 A and 0.75 V for parallel and series arrangements, respectively. Full article

This paper proposes a unified energy management, fault detection, and fault-tolerant control (EMS–FDI–FTC) framework for Hybrid Hydrogen Electric Vehicles (HHEVs) integrating a fuel cell (FC), battery (Bat), and supercapacitor (SC). While such multi-source architectures enable high-efficiency propulsion under dynamic driving conditions, actuator and state faults such as FC voltage sag, Bat internal resistance increase, and SC capacitance degradation can compromise safety, availability, and component lifetime. The proposed framework converts real-world GPS-recorded vehicle speed profiles into route-aware traction power demand and combines interpretable model-based indicators with an AI-based fault detection and classification module. Based on the diagnosis outcome, a fault-tolerant supervisory strategy performs online power reallocation among the FC, Bat, and SC while enforcing operational constraints. Validation is conducted in a MATLAB-based software-in-the-loop (SIL) environment using three urban driving routes collected from on-road measurements in Tunisia with injected ground-truth faults. The results demonstrate reliable fault classification performance and effective service continuity during fault intervals, supplying over 94% of the demanded energy across all routes, with energy-not-served remaining below 0.02 kWh. In addition, processor-in-the-loop (PIL) implementation on an STM32F407VG controller confirms real-time feasibility with a 10 Hz supervisory sampling rate and execution time margins compatible with embedded automotive deployment. Overall, the proposed closed-loop framework provides a practical route-aware diagnosis-to-control solution for robust and fault-resilient HHEV operation under realistic driving variability. All energy and efficiency indicators reported in this study are derived from control-oriented component models and are intended for consistent comparative evaluation across routes and operating scenarios, rather than absolute representation of a specific commercial vehicle. Full article

Supercapacitor modules for energy storage systems often require complex active balancing circuits to manage voltage imbalances between series-connected cells. This paper proposes a modified forward converter topology that passively charges and balances supercapacitor modules simultaneously. The proposed solution is modular, provides galvanic isolation, and is self-regulating, eliminating the need for dedicated sensors or complex control logic. Voltage equalization is achieved autonomously through coupled inductors, naturally directing current to the cells with the lowest voltage during the period when the converter is off. This work details the operating principle of the converter and analyzes two architectures: a non-crossover configuration and a crossover configuration. This study validated the system performance through PSIM simulations and a hardware prototype. The experimental results demonstrate that both configurations successfully charge and balance the supercapacitors. However, the crossover and non-crossover configurations achieve faster equalization under certain imbalance conditions. In contrast, the crossed configuration exhibits a smaller final voltage discrepancy between cells compared to the non-crossover architecture. The proposed converter proves to be a simple, robust, and effective solution for managing supercapacitor modules. Full article

Porous highly cross-linked polymer (PIP) was synthesized by a polycondensation reaction between hexachlorocyclotriphosphazene and piperazine. The obtained polymer has a surface area of 76.9 m²/g and a mesoporous structure. After carbonization, the obtained product (PIP-C) has a surface area of 177 m²/g. The obtained carbon product contained nitrogen and phosphorus heteroatoms, which leads to a higher specific capacitance (155.6 F/g) and catalytical activity in the electroreduction of oxygen (15.9 A/g). This work shows the possibility of the use of such porous phosphazene polymers as precursors for heteroatom-doped carbon materials, which might be used in electrochemical devices like electrodes for supercapacitors or metal-free electrocatalysts in fuel cells. Full article

Porous nickel oxide nanoparticles with a hierarchical structure and high specific surface area were obtained by green synthesis followed by thermal annealing. The influence of the choice of precursor plant extract (Fumaria officinalis L. and Origanum vulgare L.) and the extractants in aqueous solutions on the parameters of the synthesized particles was studied. Characterization of the NiO morphology and composition, as well as the specific surface area, was performed using X-ray diffraction (XRD), scanning electron microscopy (SEM), and the BET method of nitrogen thermal desorption. Resulting particles have a spherical shape and a size from 30 to 50 nm. According to the data obtained, it can be seen that when the precursor is changed from Fumaria officinalis L. to Origanum vulgare L., the size of the synthesized particles increases, while the structure becomes more friable. It has been revealed that certain parameters and the nature of the assembly of porous particles lead to an increase in the surface area: the highest value of the SSA of 130.0 m²/g is observed in NiO nanoparticles obtained using Fumaria officinalis L. extract based on isopropyl alcohol. Also, a relatively high SSA value of 73.5 m²/g is observed in nanoparticles obtained using the same extractant for Origanum vulgare L. extract, while the use of an ethyl alcohol-based extractant for Fumaria officinalis L. resulted in the lowest value of 40.2 m²/g. The developed semiconductor particles are promising for use in catalysis, sensors, and as part of supercapacitor electrodes and functional layers in device structures for solar cells. Full article

Microbial fuel cells (MFCs) utilizing livestock wastewater represent a critical path toward sustainable energy and net-zero emissions. To maximize this potential, this study investigates a novel circuit configuration, integrating twin MFCs with dual supercapacitors in a closed-loop system, to enhance charge storage and electricity generation. By utilizing molasses-seawater anolytes, the study establishes a performance benchmark for optimizing energy recovery in future livestock wastewater treatment applications. The self-adjusting potential difference between interconnected MFCs is verified, and supercapacitors significantly improve energy harvesting by reducing load impedance and balancing capacitor plate charges. Voltage gain across supercapacitors exceeds that of single MFC charging, demonstrating the benefits of series integration. Experimental results reveal that catholyte properties—electrical conductivity, salinity, pH, and dissolved oxygen—strongly influence MFC performance. Optimal conditions for a neutralized anolyte (pH 7.12) include dissolved oxygen levels of 5.37–5.68 mg/L and conductivity of 24.3 mS/cm. Under these conditions, supercapacitors charged with sterile diluted seawater catholyte store up to 40% more energy than individual MFCs, attributed to increased output current. While the charge balance mechanism of supercapacitors contributes to storage efficiency, its impact is less pronounced than that of conductivity and oxygen solubility. The interplay between electrochemical activation and charge balancing enhances overall electricity harvesting. These findings provide valuable insights into optimizing MFC-supercapacitor systems for renewable energy applications, particularly in livestock wastewater treatment. Full article

The field of electrochemical devices, encompassing energy storage, fuel cells, electrolysis, and sensing, is fundamentally reliant on the electrode materials that govern their performance, efficiency, and sustainability. Traditional materials, while foundational, often face limitations such as restricted reaction kinetics, structural deterioration, and dependence on costly or scarce elements, driving the need for continuous innovation. Emerging electrode materials are designed to overcome these challenges by delivering enhanced reaction activity, superior mechanical robustness, accelerated ion diffusion kinetics, and improved economic feasibility. In energy storage, for example, the shift from conventional graphite in lithium-ion batteries has led to the exploration of silicon-based anodes, offering a theoretical capacity more than tenfold higher despite the challenge of massive volume expansion, which is being mitigated through nanostructuring and carbon composites. Simultaneously, the rise of sodium-ion batteries, appealing due to sodium’s abundance, necessitates materials like hard carbon for the anode, as sodium’s larger ionic radius prevents efficient intercalation into graphite. In electrocatalysis, the high cost of platinum in fuel cells is being addressed by developing Platinum-Group-Metal-free (PGM-free) catalysts like metal–nitrogen–carbon (M-N-C) materials for the oxygen reduction reaction (ORR). Similarly, for the oxygen evolution reaction (OER) in water electrolysis, cost-effective alternatives such as nickel–iron hydroxides are replacing iridium and ruthenium oxides in alkaline environments. Furthermore, advancements in materials architecture, such as MXenes—two-dimensional transition metal carbides with metallic conductivity and high volumetric capacitance—and Single-Atom Catalysts (SACs)—which maximize metal utilization—are paving the way for significantly improved supercapacitor and catalytic performance. While significant progress has been made, challenges related to fundamental understanding, long-term stability, and the scalability of lab-based synthesis methods remain paramount for widespread commercial deployment. The future trajectory involves rational design leveraging advanced characterization, computational modeling, and machine learning to achieve holistic, system-level optimization for sustainable, next-generation electrochemical devices. Full article

Electrospinning has emerged as a powerful technique for fabricating customised nanofibrous materials with integrated functional nanostructures, offering significant advantages for electrochemical energy applications. This review highlights recent advances in using electrospun nanofibres directly as active components in devices such as batteries, supercapacitors, and fuel cells. The emphasis is on the role of composite design, fibre morphology and surface chemistry in enhancing charge transport, catalytic activity and structural stability. Integrating carbon-based frameworks, conductive polymers, and inorganic nanostructures into electrospun matrices enables multifunctional behaviour and improves device performance. The resulting nanofibrous composite materials, often after heat treatment, can be used directly as electrodes or self-supporting layers, eliminating the need for additional processing steps such as size reduction or preparation of slurries and inks for creating functional nanofibre-based deposits. The importance of composite nanofibres as an emerging strategy for overcoming challenges related to scalability, long-term durability, and interface optimisation is also discussed. This review summarises the key results obtained to date and highlights the potential of electrospun nanofibres as scalable, high-performance materials for next-generation energy technologies, outlining future directions for their rational design and integration. Full article

The maritime industry faces significant challenges from energy consumption and air pollution. Fuel cells, especially hydrogen types, offer a promising clean alternative with high energy density and rapid refueling, but their slow dynamic response necessitates integration with lithium batteries (energy storage) and supercapacitors (power storage). This paper investigates a hybrid vessel power system combining a fuel cell with a Hybrid Energy Storage System (HESS) to address these limitations. An improved droop control strategy with adaptive coefficients is developed to ensure balanced State of Charge (SOC) and precise current sharing, enhancing system performance. A comprehensive protection strategy prevents overcharging and over-discharging through SOC limit management and dynamic filter adjustment. Furthermore, the Parrot Optimization Algorithm (POA) optimizes HESS capacity configuration by simultaneously minimizing battery degradation, supercapacitor degradation, DC bus voltage fluctuations, and system cost under realistic operating conditions. Simulations show SOC balancing within 100 s (constant load) and 135 s (variable load), with the lithium battery peak power cut by 18% and the supercapacitor peak power increased by 18%. This strategy extends component life and boosts economic efficiency, demonstrating strong potential for fuel cell-powered vessels. Full article