Search Results (25)

Almost forty years ago, dye-sensitized solar cells (DSSCs) appeared as a promising route for harnessing the energy of the sun and for converting it into electricity. In the following years, a huge number of studies have been dedicated to increase the global photovoltaic efficiencies and stability of DSSCs. Thiocyanate ruthenium complexes bearing chelating nitrogen donor ligands turned out to be among the best performing photosensitizers. In the last 15 years, a lot of work has also been dedicated to the preparation of efficient thiocyanate-free Ru dyes. In this review, these two families of ruthenium(II) complexes are presented: (a) dyes presenting thiocyanate ligands and (b) thiocyanate-free dyes. The coverage, mainly from 2021, is not exhaustive, but exemplifies the most recent design approaches and photovoltaic properties of these two classes of Ru(II) photosensitizers. Full article

Integrative conservation research on animal behavior and nutritional health can contribute to the ex situ conservation of endangered species. Stereotypic behavior, a repetitive behavior without practical function, is associated with animal welfare in its manner and frequency for captive animals. Exploring the potential relationship between stereotypic behavior and internal factors, such as intestinal flora, could improve ex situ conservation, especially for endangered species. In this study, we analyzed the typical behavior characteristics of the endangered sun bears (Helarctos malayanus) under captive conditions based on the behavior sampling method. The seasonal and annual changes in the intestinal flora of H. malayanus in captivity were studied by 16S rDNA high-throughput sequencing technology based on non-invasive fecal sample collection. This study provides the first evidence of a potential association between the gut microbiota and stereotypic behavior characteristics of captive H. malayanus. The results can significantly improve our understanding of the stereotypical behavior of H. malayanus in captivity and contribute to the captive breeding and conservation efforts of this endangered species. Full article

The wind turbine gearbox, used as a multiplier, is one of the main components directly related to a wind turbine’s efficiency and lifespan. Therefore, strict control of the gearbox and its manufacturing processes and even minor improvements in this component strongly and positively impact energy production/generation over time. Since only some papers in the literature analyze the mechanical aspect of wind turbines, focusing on some parts in depth, this paper fills the gap by offering an analysis of the gearbox component under the highest amount of stress, namely relating to the sun shaft, as well as a more holistic analysis of the main gear drives, its components, and the lubrification system. Thus, this work diagnoses the fracture mechanics of a 1600 kW gearbox to identify the main reason for the fracture and how the chain of events took place, leading to catastrophic failure. The diagnoses involved numerical simulation (finite element analysis—FEA) and further analysis of the lubrication system, bearings, planetary stage gears, helical stage gears, and the high-speed shaft. In conclusion, although the numerical simulation showed high contact stresses on the sun shaft teeth, the region with the unexpectedly nucleated crack was the tip of the tooth. The most likely factors that led to premature failure were the missed lubrication for the planetary bearings, a lack of cleanliness in regard to the raw materials of the gears (voids found), and problems with the sun shaft heat treatment. With the sun gear’s shaft, planet bearings, and planet gears broken into pieces, those small and large pieces dropped into the oil, between the gears, and into the tooth ring, causing the premature and catastrophic gearbox failure. Full article

Yunnan Dendrocalamus sinicus Chia et J. L. Sun (YDS) is a giant bamboo species with a diameter at breast height of up to nearly 40 cm. It is endemic to Yunnan, China, and only a very small portion of it is directly used as load-bearing beams and columns in the dwellings of ethnic minorities, such as in Dai architecture. Due to the structural characteristics of its hollow and thin walls, systematic physical and mechanical property testing of this species faces significant challenges in terms of methods and means. This issue has become one of the main barriers to the realization of its large-scale industrial use. Therefore, this paper systematically tests and studies YDS’s three kinds of strength (tension, compression, and shear), modulus of elasticity, and six Poisson’s ratios with the help of digital image correlation (DIC) technology and self-created material testing methods. The (1) tensile, compressive, and shear strengths and moduli in longitudinal, radial, and chordal directions; (2) tensile strengths and moduli of bamboo green, flesh, and yellow layers in the thickness direction of the bamboo wall; and (3) six Poisson’s ratios under tensile and compressive stresses were obtained for YDS. It was also found that the tensile strength (378.8 MPa) of the green layer of YDS exceeded the yield strength (355 MPa) of 45# steel, making it a potential high-strength engineering material or fiber-reinforced material. Full article

In the summer of 2022, an intense heatwave swept through Northern Europe, with London bearing a significant impact. While nature-based solutions are often considered to be ideal responses to such heatwaves, experiences from the 2022 heatwave and others revealed potential drawbacks, particularly for urban green spaces. Prolonged dry spells, frequently accompanying heatwaves, result in excessively dry soil and the subsequent decline of vegetation in large parks. In the present study, microclimate simulations were conducted for Hyde Park in London, a location that experienced such drought during the 2022 heatwave, to examine its microclimatic performance in terms of thermal comfort and tree health. In alignment with the observations, ENVI-met could replicate the lack of noticeable cooling effects during the daytime and only marginal cooling during the nighttime. To address these challenges, mitigation scenarios were explored, incorporating heat mitigation measures such as part-time irrigation, temporary sun sails, and façade greenery. The findings demonstrated that implementing these measures could reduce heat stress by up to 13 K PET (physiologically equivalent temperature). These practical solutions emerged as effective remedies for mitigating the impact of heatwaves on urban green spaces and, hence, improving future urban development overall. Full article

Bacteria and phages are two of the most abundant biological entities in the gut microbiome, and diet and host phylogeny are two of the most critical factors influencing the gut microbiome. A stable gut bacterial community plays a pivotal role in the host’s physiological development and immune health. A phage is a virus that directly infects bacteria, and phages’ close associations and interactions with bacteria are essential for maintaining the stability of the gut bacterial community and the entire microbial ecosystem. Here, we utilized 99 published metagenomic datasets from 38 mammalian species to investigate the relationship (diversity and composition) and potential interactions between gut bacterial and phage communities and the impact of diet and phylogeny on these communities. Our results highlight the co-evolutionary potential of bacterial–phage interactions within the mammalian gut. We observed a higher alpha diversity in gut bacteria than in phages and identified positive correlations between bacterial and phage compositions. Furthermore, our study revealed the significant influence of diet and phylogeny on mammalian gut bacterial and phage communities. We discovered that the impact of dietary factors on these communities was more pronounced than that of phylogenetic factors at the order level. In contrast, phylogenetic characteristics had a more substantial influence at the family level. The similar omnivorous dietary preference and closer phylogenetic relationship (family Ursidae) may contribute to the similarity of gut bacterial and phage communities between captive giant panda populations (GPCD and GPYA) and omnivorous animals (OC; including Sun bear, brown bear, and Asian black bear). This study employed co-occurrence microbial network analysis to reveal the potential interaction patterns between bacteria and phages. Compared to other mammalian groups (carnivores, herbivores, and omnivores), the gut bacterial and phage communities of bamboo-eating species (giant pandas and red pandas) exhibited a higher level of interaction. Additionally, keystone species and modular analysis showed the potential role of phages in driving and maintaining the interaction patterns between bacteria and phages in captive giant pandas. In sum, gaining a comprehensive understanding of the interaction between the gut microbiota and phages in mammals is of great significance, which is of great value in promoting healthy and sustainable mammals and may provide valuable insights into the conservation of wildlife populations, especially endangered animal species. Full article

The unceasing quest for a profound comprehension of the Earth system propels the continuous evolution of novel methods for Earth observation. Of these, the Lagrange points situated in the cislunar space proffer noteworthy prospects for space-based Earth observation. Although extant research predominantly centers on Moon-based Earth observation and the L1 point within the Sun-Earth system, the realm of cislunar space remains relatively unexplored. This paper scrutinizes the overarching characteristics of the L1 point within the Earth-Moon system concerning Earth observation. A pivotal enhancement is introduced through the incorporation of the halo orbit. This research comprehensively analyzes the relative motion between the halo orbiter and the Earth, achieved via orbit determination within a rotating coordinate system, followed by a transformation into the Earth coordinate system. Subsequently, numerical simulations employing ephemeris data unveil the observing geometry and Earth observation characteristics, encompassing the distribution of nadir points, viewing angles, and the spatiotemporal ground coverage. As a point of reference, we also present a case study involving a Moon-based platform. Our findings reveal that the motion of the halo orbit, perpendicular to the lunar orbital plane, results in a broader range of nadir point latitudes, which can extend beyond 42°N/S, contingent upon the orbit’s size. Additionally, it manifests a more intricate latitude variation, characterized by the bimodal peaks of the proposed temporal complexity curve. The viewing angles and the spatiotemporal ground coverage closely resemble those of Moon-based platforms, with a marginal enhancement in coverage frequency for polar regions. Consequently, it can be deduced that the Earth observation characteristics of the L1 point within the Earth-Moon system bear a close resemblance to those of Moon-based platforms. Nevertheless, considering the distinct advantages of Moon-based platforms, the lunar surface remains the paramount choice, boasting the highest potential for Earth observation within cislunar space. In summation, this study demonstrates the Earth observation characteristics of the L1 point within the Earth-Moon system, emphasizing the distinctions between this and Moon-based platforms. Full article

Erythropoietic protoporphyria (EPP) is a genetic disorder stemming from reduced ferrochelatase expression, the final enzyme in the pathway of heme biosynthesis. A closely related condition, X-linked protoporphyria (XLP), bears similar clinical features although it arises from the heightened activity of δ-aminolevulinic acid synthase 2 (ALAS2), the first and normally rate-controlling enzyme in heme biosynthesis in developing red blood cells. Both of these abnormalities result in the buildup of protoporphyrin IX, leading to excruciating light sensitivity and, in a minority of cases, potentially fatal liver complications. Traditionally, managing EPP and XLP involved sun avoidance. However, the emergence of innovative therapies, such as dersimelagon, is reshaping the therapeutic landscape for these conditions. In this review, we summarize salient features of the properties of dersimelagon, shedding light on its potential role in advancing our understanding of treatment options for EPP and XLP. Full article

By definition, children constitute a vulnerable population, especially when they are chronically ill and/or disabled. A characteristic of chronically ill and disabled children is that they also suffer from indirect effects of their disease, such as immobilization, chronic inflammation, reduced time outdoors in the sun, osteotoxic effects of disease-targeted therapy (like glucocorticoids), and poor nutrition. All these factors may lead to bone fragility due to secondary osteoporosis, a co-morbidity that may be overlooked in the context of serious underlying diseases. The ultimate goal of osteoporosis diagnosis and monitoring in this setting is the early identification, prevention, and treatment of low-trauma long bone and vertebral fractures; indeed, vertebral fractures are a frequently under-diagnosed manifestation of overt bone fragility in this context. Efforts to prevent first-ever fractures are also meritorious, including encouragement of weight-bearing activities, optimization of nutritional status, including calcium and vitamin D supplementation, and the diagnosis and treatment of delayed growth and puberty; however, these conservative measures may be insufficient in those at high risk. Numerous natural history studies have shown that vertebral fractures are more common than non-vertebral (i.e., long bone) fractures in at-risk children. Not surprisingly, the cornerstone of secondary osteoporosis monitoring is lateral spine imaging for the early detection of vertebral collapse. Although dual-energy x-ray absorptiometry (DXA) is the gold standard to measure bone mineral density, digital X-ray radiogrammetry may be used as a surrogate measure of bone strength if dual-energy x-ray absorptiometry is not available. In the event that preventive measures fail, treatment with bisphosphonates may be appropriate. Typically, treatment with intravenous bisphosphonates is reserved for children with overt bone fragility and limited potential for spontaneous recovery. However, there is increasing attention to very high-risk children, such as boys with Duchenne muscular dystrophy, who may benefit from bisphosphonate therapy prior to first-ever fractures (given their high fracture frequency and essentially absent potential for spontaneous recovery). This article provides a contemporary overview of the definition and diagnosis of osteoporosis in children with chronic illness, along with the approach to monitoring those at risk and the evidence for currently recommended intervention strategies. Full article

Hydrocharis morsus-ranae is a free-floating species growing in lakes and slow-flowing rivers near the shore in Europe and Western Asia, and as an invasive plant in the USA and Canada. Light-requiring plants of this species can also grow in the shade, up to about 30% of full sunlight. In this paper we present the data about the photosynthetic apparatus of sunny and shady H. morsus-ranae plants grown in the sun and in the shade in nature. Methods of light and transmission electron microscopy, biochemistry, chlorophyll fluorescence induction as well as the principal component analysis were used. It was found that leaves of plants growing in shade differed from those in the sun with such traits as thickness of a blade, palisade and spongy parenchyma, ultrastructure of chloroplasts, and quantum efficiency of photosynthetic electron transport, the content of chlorophylls and carotenoids, anthocyanins and phenilpropanoids. By these traits, H. morsus-ranae shady plants are similar with shade-bearing plants that indicates their adaptation to light intensity lowering. The ordination plots (PCA) suggested a clear structural and functional shift of plants growing in different lighting showing relationship to light changes in the natural environment. Thus, our results displayed the high phenotypic plasticity of the H. morsus-ranae photosynthetic apparatus, which ensures its acclimation to changing light environment and wide distribution of this species. Full article

At the most basic level, the assessment of a species’ status involves knowing where it occurs. Determining the presence of rare species is difficult, and can be further confounded by the presence of a more common look-alike species. We investigated one of the few places in the world where three species of bears have been reported to co-occur at a fine scale: Balpakram National Park, Meghalaya, India. Asiatic black bears (Ursus thibetanus) are fairly common, and we sought to determine whether sun bears (Helarctos malayanus) and/or sloth bears (Melursus ursinus) also resided there. The local Garo language has words for three types of bears, and some local people reported the continued presence of a small type of bear, possibly the sun bear, but the probable extirpation of sloth bears. Because these bears look somewhat alike, local people and government forest officers could not provide convincing accounts of the presence of more than one species. We measured claw marks on climbed trees, a method used to differentiate sun bears from Asiatic black bears where both are known to occur; however, this method turned out to be unreliable for detecting sun bears where their presence was unknown because sun bear-sized marks are not distinguishable from juvenile black bears. We recommend targeted camera trapping near recent purported sightings of the other two bear species. Full article

Modern zoos strive to construct habitats which both enable and encourage animals to engage in species-specific behaviour, without compromising their visibility to visitors. Here, we present the findings of a within-zoo move to a custom-built exhibit (Islands at Chester Zoo, UK) with respect to the behaviour of four mammal species; the Sumatran orangutan (Pongo abelii), crested macaque (Macaca nigra), Malayan tapir (Tapirus indicus) and the Malayan sun bear (Helarctos malayanus). We used full activity budgets along with Compositional Data Analysis (CoDA) to gain insight into how the move to a more naturalistic exhibit influenced behaviour. Engagement in abnormal behaviour remained low during the study period for all four species, suggesting no adverse responses to the change in environment. Following the move, both the non-human primate species spent more time engaged in positive social interactions with conspecifics, highlighting the importance of social support during enclosure moves. Time spent visible to the public was largely unaffected by the enclosure move for the Sumatran orangutan, whilst the movement to a new environment increased visibility for the Malayan sun bear and decreased visibility for the crested macaque and Malayan tapir. We demonstrate the value of monitoring behaviour throughout the translocation of zoo-housed species and outline the positive behavioral impacts of providing individuals with naturalistic, species-appropriate environments. Full article

Sustaining good bone health into older age is key for preventing osteoporosis. Bone health is associated with several lifestyle factors. This study investigates older adults’ adherence to bone health-promoting lifestyle recommendations dependent on osteoporosis status. Cross-sectional data of 1610 community-dwelling older adults (65–75 years) residing in Bremen, Germany (53.4% female) were included. The Osteoporosis Self-Assessment Tool and self-reported osteoporosis diagnosis were used to classify participants by osteoporosis status (low risk, high risk, diagnosis). Adherence to bone health recommendations regarding calcium and vitamin D intake, sun exposure, alcohol consumption, resistance/weight-bearing exercise, and physical activity were assessed. Descriptive statistics were applied, stratified by sex and osteoporosis status. A total of 91 women (10.6%) and 15 men (2.0%) reported an osteoporosis diagnosis, 457 women (43.2%) and 311 men (41.4%) were classified as having a high risk, and 311 women (36.2%) and 425 men (56.6%) as having a low risk. Adherence to bone health recommendations was high for calcium intake (93.3–100.0%), vitamin D intake (77.8–93.3%), and sun exposure (86.7–97.7%). Lower adherence was observed regarding resistance/weight-bearing exercise (36.3–54.4%), physical activity (14.3–57.7%), and alcohol consumption (40.0–72.4%). In conclusion, tailored prevention strategies are needed that focus on older adults with an osteoporosis diagnosis or who are at high risk. Full article

Sunlight conditions can reduce drivers’ visibility, which is a safety concern on road networks. This research introduces a method to study sun glare incidence in road environments. Sun glare areas during daylight hours are automatically detected from mobile laser scanning (MLS) and aerial laser scanning (ALS) point clouds. The method comprises the following steps. First, the Sun’s position (solar altitude and azimuth) referring to a location is calculated. Second, the incidence of sun glare with the user’s angle of vision is analyzed based on human vision. Third, sun ray intersections with near obstacles (vegetation, building, etc.) are calculated utilizing MLS point clouds. Finally, intersections with distant obstacles (mountains) are calculated utilizing ALS point clouds. MLS and ALS data are processed in order to combine both data types, remove outliers, and optimize computational time for intersection searches (point density reduction and Delaunay triangulation). The method was tested on two real case studies, covering roads with different bearings, slopes, and surroundings. The combination of MLS and ALS data, together with the solar geometry, identify areas of risk for the visibility of drivers. Consequently, the proposed method can be utilized to reduce sun glare, implementing warnings in navigation systems. Full article

The Kofun period of the history of Japan—between the 3rd and the 7th century AD—bears its name from the construction of huge, earth mound tombs called Kofun. Among them, the largest have a keyhole shape and are attributed to the first, semi-legendary emperors. The study of the orientation of ancient tombs is usually a powerful tool to better understand the cognitive aspects of religion and power in ancient societies. This study has never been carried out in Japan due to the very large number of Kofun and to the fact that access to the perimeter is usually forbidden. For these reasons, to investigate Kofun orientations, simple tools of satellite imagery are used here. Our results strongly point to a connection of all Kofun entrance corridors with the arc of the sky where the Sun and the Moon are visible every day of the year; additionally, these show an orientation of the keyhole Kofun to the arc of the rising/shining Sun, the goddess that the Japanese emperors put at the mythical origin of their dynasty. Full article