Search Results (1,167)

Quantum beams-including X-rays, synchrotron radiation, electrons, neutrons, ions, and ultrafast photon sources-are indispensable tools for probing the structure, dynamics, and electronic properties of matter. The excitation time scale ${\tau }_{exc}$ is defined operationally as the characteristic temporal interval governing externally imposed energy deposition events within the interaction volume, such as pulse duration, bunch spacing, or beam dwell time. Interpretation of beam–matter interactions has traditionally relied on steady-state or quasi-equilibrium assumptions, implicitly presuming that intrinsic material relaxation processes can accommodate externally imposed excitation. Recent advances in high-brightness synchrotron sources, X-ray free-electron lasers (XFELs), and pulsed electron beams increasingly operate in regimes where this assumption is strained, and systematic nonequilibrium effects, radiation damage, and irreversible transformations are reported even under routine experimental conditions. This work examines the role of time-scale mismatch between beam-driven energy deposition and intrinsic material relaxation as a governing constraint in beam–matter interactions. Analyzing the hierarchy of excitation, electronic relaxation, phonon coupling, and thermal diffusion time scales, the analysis introduces a dimensionless mismatch parameter $\mathsf{\Lambda }={\displaystyle \frac{{\tau }_{rel}}{{\tau }_{exc}}}$, which quantifies the competition between externally imposed excitation and intrinsic relaxation processes in beam–matter interactions. The resulting framework provides a unified physical interpretation of beam-induced damage, signal distortion, dose dependence, and nonlinear response across quantum beam modalities, framing these effects as consequences of forced nonequilibrium dynamics rather than technique-specific artifacts. Full article

The use of additive manufacturing in structural applications has increased in industry; however, reliable material selection criteria remain limited when printed components must withstand real service loads. The following study provides a comprehensive evaluation of polymeric materials (PLA filament, ABS filament, and ABS-like resin) used in additive manufacturing technologies for the production of footwear heels. Consequently, five heel models were designed using reverse engineering based on real industry references and analyzed within a decision framework based on the Input–Transformation–Output (ITO) model. Within this framework, each material was subjected to static mechanical tests (tensile, compression, flexural and hardness), scanning electron microscopy (SEM) analysis and numerical simulations. In addition, functional tests were carried out by mounting the printed heels on real sandals, allowing for evaluation of their performance under service conditions. Significant differences in surface morphology were observed, attributable to the physical state and consolidation mechanism of each material. Uncontrolled environmental conditions during printing and testing were identified as a limitation affecting reproducibility. The ABS-like resin showed the highest compressive load capacity (10.8 kN), together with a tensile strength of 14.99 MPa and a deformation at break of 0.076 mm/mm. SEM analysis revealed a more homogeneous surface morphology and greater structural continuity after curing, consistent with the numerical simulations, which predicted stresses between 19.98 and 196.23 MPa, displacements up to 8.917 mm and unit strains up to 0.1378. The integrated interpretation of the experimental, microstructural and functional results provides technical criteria for material selection in reverse-engineered footwear components and structural elements manufactured by additive manufacturing. Full article

Anisogrid lattice structures are gaining increasing attention due to their high strength-to-weight ratios, which make them ideal for the production of lightweight mechanical components. This study presents a finite element model developed to evaluate stress distribution in an anisogrid sandwich panel with an octahedral core. The Taguchi method and analysis of variance (ANOVA) were employed to identify the geometric parameters that mostly influence the stress state and, consequently, the structural strength. The radius of the inclined ribs and the thickness of the skins were identified as the most critical factors, while the influence of the horizontal rib cross-sectional area was found to be minimal. The stiffness and strain energy of different cell geometries were also evaluated, and the results are consistent with the stress-based analysis. These findings offer valuable guidance for optimizing anisogrid geometry, improving load-bearing performance and advancing the design of high-efficiency structures. Full article

The current study explored the martensite structures of Fe₃Pt alloys, specifically $Cmmm$-Fe₃Pt, $P{6}_3/mmc$-Fe₃Pt, $P4/mmm$-Fe₃Pt, and $R\overline{3}m$-Fe₃Pt, aiming to provide a comprehensive understanding of the mechanisms that govern their physical and chemical properties. We have focused on their structural, thermodynamical, magnetic, electronic, mechanical, and dynamical characteristics, utilizing the density functional theory (DFT) technique. Our study revealed that in addition to the previously reported austenitic cubic $Pm\overline{3}m$-Fe₃Pt and martensite tetragonal $I4/mmm$-Fe₃Pt with L1₂ structure, there exist additional Fe₃Pt phases that exhibit excellent structural, thermodynamic, magnetic, and mechanical properties. The calculated enthalpies of formation were found to be negative and less than −0.39 eV in all the structures considered, indicating thermodynamic stability and formation under experimental synthetic conditions. Moreover, the computed magnetic moments are in the range 2.94 to 3.04 ${\mathsf{\mu }}_{\mathrm{B}}$, which is relatively comparable to 3.24 ${\mathsf{\mu }}_{\mathrm{B}}$ of the widely reported $Pm\overline{3}m$-Fe₃Pt alloy. The analysis of the electronic structure also revealed strong magnetism due to the presence of asymmetry in the spin-up and -down states of the density of states (DOS) plots. To determine the mechanical response of Fe₃Pt structures under loading conditions, we computed the independent elastic constants, macroscopic properties, and stress–strain relationship under hydrostatic stress. All four phases were studied, but the hypothetical $P{6}_3/mmc$-Fe₃Pt showed excellent mechanical stability at ambient conditions and exceptional hardness and resistance to compression in the elastic region 0% ≤ strain ≤ 10%. This evidence is provided by satisfying the Born necessary stability conditions, large bulk modulus, and a strong linear relationship fit ($R^2$) of greater than 0.94. Moreover, the phonon dispersion curves revealed dynamical stability for $Cmmm$-Fe₃Pt and $R\overline{3}m$-Fe₃Pt, and metastability for $P4/mmm$-Fe₃Pt, while the hypothetical $P{6}_3/mmc$-Fe₃Pt is unstable. Full article

This study investigates the transient wheel–rail contact mechanics of welded joints in heavy-haul rails via a validated 3D finite element model, and analyzes the stick-slip behavior, dynamic response and elastoplastic characteristics in the base material zone, heat-affected zone and weld bead zone. Results show a distinct contact state transition from stick-slip in the base material to predominant slip within the welded zones, indicating higher wear susceptibility. Dynamic response analysis reveals the highest and lowest contact-point acceleration amplitudes in the base material and heat-affected zone, respectively, due to material heterogeneity. Plastic deformation consistently initiates at the rail surface, where stress and strain concentrate, establishing it as the primary site for damage nucleation. A systematic parametric study shows that plastic deformation can be effectively mitigated by increasing the yield strength and elastic modulus of the welded joint material, or reducing the wheelset velocity, unsprung mass and wheel–rail friction coefficient. In contrast, adjusting the primary suspension and fastener parameters exerts a negligible influence on plastic deformation control. These findings provide a mechanistic basis for optimizing the performance and maintenance of welded joints in heavy-haul rail operations. This study reveals the coupling law of multiple mechanisms among contact behavior, dynamic response and material failure during the damage initiation process of rail welded joints from the mechanistic perspective, which provides a theoretical basis for the structural optimization, condition assessment and maintenance of rail welded joints in heavy-haul railways. Full article

Limosilactobacillus fermentum KUB-D18 is a probiotic strain with significant potential in food fermentation and health promotion, yet the systems-level mechanisms underlying its physiological robustness remain elusive. To elucidate the metabolic remodeling strategies operating across growth phases, we developed an integrated framework combining genome-scale metabolic modeling (GSMM) with transcriptomics. A high-quality metabolic model for L. fermentum KUB-D18, designated iYH640 and comprising 640 genes, 1530 metabolites, and 1922 reactions, was constructed and validated against experimental growth data. Specifically, in vitro assays measuring biomass and glucose concentrations showed a maximum specific growth rate of 0.2696 h⁻¹ and a glucose uptake rate of 11.75 mmol gDCW⁻¹ h⁻¹, providing physiological constraints for the model. Using transcriptome-regulated flux balance analysis (TR-FBA), gene expression profiles from the logarithmic phase (L-phase) and stationary phase (S-phase) were integrated to quantify growth phase-specific metabolic flux distributions. These simulations revealed a distinct transcription-driven metabolic shift, in which the organism moves from a proliferation-oriented metabolic state with active central carbon metabolism and macromolecule synthesis to a maintenance-oriented state. This S-phase is characterized by reduced flux through anabolic pathways together with the selective preservation of redox balance and nucleotide homeostasis. Collectively, these results provide a quantitative explanation of how L. fermentum KUB-D18 balances growth and maintenance, offering a mechanistic basis for improving its stability and functional performance in industrial probiotic applications. Full article

Achieving the EU 2030 target of a 30% CO₂ reduction requires transitioning intercity buses to CNG- or fuel-cell-driven vehicles, and urban buses to electric vehicles. The increasing mass of roof-mounted energy systems, such as battery packs, creates additional loads on the body frame. This study investigates the integration of a welded handrail system into the bus body frame as an additional load-bearing element. A combined approach based on dynamic modeling and finite element analysis was applied to evaluate the structural body response under the UNECE R100 and R110 regulations. The results demonstrate that the structural concept significantly improves the stress–strain state of the body frame. Maximum roof displacements under 5g loading decreased by 34% for the gas-powered model and by 50% for the electric model, enhancing passive safety by reducing window-rack intrusion. Maximum stress decreased by 20%, shifting the stress state below the ultimate strength of S235 steel and preventing rupture. Uniform strength under vertical loading increased significantly (by 58%) due to a more favorable stress distribution within the structure. Overall, the results indicate that integrating a welded handrail truss into the bus body frame can effectively improve structural stiffness and redistribute loads within the frame. Full article

Background: Parents of school-age children with neurodevelopmental and conduct difficulties face elevated stress, reduced self-efficacy and relational strain, yet evidence for scalable, school-embedded support remains limited. Drawing on mentalization theory—which emphasises parents’ capacity to understand behaviour in terms of underlying mental states—this mixed-methods study evaluated a weekly parent learning group integrating psychoeducation, mentalization-based practice and peer support, delivered within an alternative provision school. Methods: A group of twelve parents who attended at least six sessions completed retrospective pretest–posttest questionnaires assessing parental reflective functioning (PRFQ) and parenting self-efficacy (PSOC). Semi-structured interviews explored parents’ subjective experiences and perceived changes in parent–child interactions and parent–school relationships. Quantitative outcomes were analysed using paired t-tests and effect sizes; qualitative data underwent reflexive thematic analysis. Results: Quantitative analyses revealed statistically significant improvements in parental reflective functioning and self-efficacy. Pre-mentalizing scores decreased substantially (d = 1.34), indicating reductions in non-mentalizing, while interest and curiosity about children’s mental states increased markedly (d = 1.83). Parenting self-efficacy improved significantly (d = 1.61). Although a reduction in excessive certainty about mental states approached significance (d = 0.63, p = 0.053), trends suggested greater epistemic balance. Qualitative analysis identified six themes elucidating mechanisms of change, including enhanced mentalizing capacity, reduced parental stress, transformed parent–child interactions and facilitation style as a critical active ingredient. Integration of findings suggests that psychoeducational content provided conceptual grounding for understanding behaviour, facilitator modelling scaffolded reflective practice, and relational safety within the group enabled authentic engagement with challenging experiences. Conclusions: These preliminary findings indicate that a school-based parent learning group combining psychoeducation, mentalization-based practice and peer support is feasible and associated with meaningful improvements in parental reflective functioning and self-efficacy. Parent narratives of transformed relational practices and shifts from reactive to reflective engagement echo broader literature demonstrating that group-delivered mentalization-oriented programmes can enhance reflective capacities and caregiving quality in diverse family contexts. The school setting may extend the reach of such interventions to families not engaged with clinical services and support collaborative parent–school partnerships. Future research should employ larger, controlled designs, incorporate observational and child outcome measures, and explore scalability across educational contexts. Full article

Low-velocity impacts during manufacturing and maintenance (e.g., tool drops) can induce barely visible impact damage in composite aircraft structures, motivating sensing-assisted approaches for rapid post-event assessment. This study proposes and validates a strain-based structural health monitoring framework for carbon-fiber-reinforced polymer (CFRP) panels by combining surface-mounted strain gauges with explicit finite element analysis (FEA). Drop-weight tests were con-ducted in accordance with ASTM D7136 using a 1.0 kg hemispherical impactor at drop heights of 250–400 mm. Three strain gauges were positioned at 1.25 mm, 32.5 mm, and 52.5 mm from the impact point to quantify the spatial attenuation of peak surface strain. The measured peak strains exhibited clear-dependent decay and increased with impact energy up to 350 mm, whereas the 400 mm case showed a non-monotonic response and a pronounced deviation from an elastic energy-scaling baseline, consistent with a transition to damage-dominated energy dissipation. Dedicated MSC Apex/Nastran Implicit simulations reproduced experimental trends and provided a physics-based digital twin for interpreting strain signatures in elastic regions, correlating them with likely damage states. Full article

Improving the flavour of soybean-based ingredients remains challenging as soybeans naturally contain compounds that generate green and beany notes. This study evaluated how the surface-growing food-grade fungus Penicillium nalgiovense (PN), alone and together with selected yeasts and lactic acid bacteria, alters the chemistry and sensory attributes of soybeans during solid-state fermentation. PN showed strong proteolytic activity in the monoculture fermentation, producing the highest accumulation of free amino acids (1324 mg/100 g), while its combination with Lactiplantibacillus plantarum (LP) further increased this to 1487 mg/100 g due to acid-assisted protease action. Sugar and organic acid profiles reflected distinct metabolic roles among the strains; for example, PNLP and PN-Debaryomyces hansenii (DH) depleted sucrose and glucose completely by 72 h, whereas DH retained substantial sucrose. Fermentation also altered the lipid profiles, where PN-Kluyveromyces marxianus (KM) showed the highest increase in polyunsaturated fatty acids, with linoleic and α-linolenic acid increasing more than twofold and threefold, respectively. Volatile analysis showed a significant decrease in hexanal (from 18.3 µg/g in control to <2.0 µg/g post fermentation) and an increase in esters, floral alcohols, and savoury compounds depending on the microbial pairing. Electronic tongue profiling showed that PN-fermented samples produced the strongest savoury taste signals. Overall, the work highlights how specific PN-yeast or PN-LAB combinations can be used to modulate flavour development in fermented soy-based substrates. Full article

The performance of polymer nanocomposites is governed primarily by the structure and properties of the matrix–filler interphase. This study presents a quantitative Raman spectroscopy analysis of interphase evolution in epoxy nanocomposites reinforced with two-dimensional WS₂, whose surface chemistry was systematically tuned via grafting of aminoacetic acid (AA) at concentrations of 2.5, 5.0, and 7.5 wt.%. By tracking peak shifts, linewidths, intensity ratios, and integrated areas of the characteristic WS₂ phonon modes (2LA(M) + E₂g¹, A₁g, and defect-related bands), we establish a non-linear, concentration-dependent interfacial response. Minor spectral variations at 2.5 wt.% AA indicate limited interfacial interaction. At 5.0 wt.% AA, suppression of the A₁g mode and significant band broadening reflect increased structural disorder. At 7.5 wt.% AA, coordinated red shifts (~−1.8 cm⁻¹) and the appearance of an additional band near 432.8 cm⁻¹ suggest the development of a strain-mediated interfacial state. Overall, increasing AA concentration leads to a non-linear evolution of the WS₂–epoxy interface, as reflected in peak positions, linewidths and intensity ratios. These Raman-derived descriptors correlate directly with enhanced mechanical properties (flexural and tensile strength) and thermal stability (Vicat softening point) of the composites. The results demonstrate that effective interfacial coupling requires a critical surface coverage and that Raman spectroscopy serves as a powerful tool for non-destructively probing and optimizing interphase architecture in TMD/polymer systems. Full article

To give more insight into the microstructural evolution and deformation mechanisms governing the long-term service performance of additively manufactured TiAl-based composites at elevated temperatures, this study investigated the high-temperature compressive creep behavior of a laser powder bed-fused LaB₆ reinforced high-Nb TiAl-based composite after hot isostatically pressing (HIP), with emphasis on the creep response and dynamic recrystallization (DRX) mechanisms under different applied stress levels. The results showed that, as the applied stress increased from 200 MPa to 450 MPa, the steady-state creep rate rose from 2.88 × 10⁻⁸ s⁻¹ to 3.85 × 10⁻⁷ s⁻¹. Stress exponent analysis indicated that creep deformation was predominantly controlled by dislocation climb, and no tertiary creep stage was observed within the investigated stress range. At 200 MPa and 300 MPa, a certain fraction of recrystallized grains formed during prolonged creep exposure. When the stress increased to 400 MPa, the recrystallization process was restricted due to the limited creep duration. In contrast, at 450 MPa, the accelerated accumulation of strain energy significantly promoted recrystallization. Both continuous dynamic recrystallization (CDRX) and discontinuous dynamic recrystallization (DDRX) were identified, jointly governing the microstructural evolution. Superior creep resistance can be attributed to multiple synergistic strengthening mechanisms, including the refined α₂/γ lamellar structure induced by HIP treatment, the strong pinning effect of dispersed La₂O₃ nanoparticles on dislocation motion, and the suppression of diffusion-controlled dislocation climb by Nb addition. These combined effects enhance the high-temperature creep performance of the TiAl composite and provide important insights for the application of LPBF-fabricated TiAl-based composites under elevated-temperature service conditions. Full article

Pear scab, caused by Venturia pyrina, poses a threat to pear cultivation, with particularly severe consequences for Portugal’s high-value Rocha pear industry. Despite its economic impact, few biological control agents are currently available. In this work, the phenotypic and genomic characterization of Pseudomonas capeferrum NFX1 is performed and its role as an effective biocontrol agent against V. pyrina is reported. Detailed genomic analysis revealed that strain NFX1 and other members of the Pseudomonas capeferrum species contain key biosynthetic gene clusters involved in pathogen antagonism, including the cyclic lipopeptide putisolvin. Phenotypic assays showed that strain NFX1 significantly inhibited V. pyrina growth, spore germination, and reduced pear scab lesion severity and fungal colonization in detached leaf assays. Moreover, strain NFX1 reprogrammed the Rocha pear leaf transcriptome to be consistent with a priming state and induced systemic resistance. A novel image-based method quantifying lesion darkening as a proxy for pear scab severity in detached leaves and a qPCR assay targeting the V. pyrina ef1-α gene and optimized for fungal DNA detection in infected pear leaves were also developed, thereby establishing a laboratory workflow specifically tailored to biocontrol evaluation against V. pyrina. Ultimately, the obtained results demonstrated the potential of P. capeferrum NFX1 for sustainable pear scab control. Full article

To address the challenge of identifying damage in the hangers and bridge deck systems of long-span suspension bridges, this paper proposes a non-contact monitoring method based on video image recognition. This method extracts structural vibration displacement responses through video acquisition and image analysis, and combined with the strain mode change rate index, it achieves damage localization, type identification, and severity assessment. The principle of extracting displacement time-history data from video images is first elaborated, and MATLAB-based computational code is developed, including pixel tracking and time-history curve generation methods. The eigensystem realization algorithm is used to identify displacement mode shapes, which are then converted into strain mode shapes via the central difference method. The strain mode change rate and its deviation rate are proposed as damage indicators: under undamaged conditions, the curve is smooth; at damage locations, peaks appear; the distribution range of peaks can distinguish between hanger damage and bridge deck cracks; the deviation rate quantifies damage severity. The feasibility of the method is validated through finite element simulations and physical model experiments. The results show that hanger damage causes broad peaks, while bridge deck cracks present narrow peaks; the deviation rate increases monotonically with damage severity. Applied to an in-service suspension bridge, the method successfully identified hanger bending and weld cracking, with assessment results consistent with on-site inspections. This study demonstrates that the strain mode change rate analysis based on video images enables damage identification without prior knowledge of the structural health state, relying solely on the damaged state response. Offering advantages such as non-contact measurement, full-field monitoring, and no need for sensor deployment, it provides a new technical approach for the long-term monitoring of suspension bridge hanger systems. Full article

In the current numerical simulation study of high-strength steel welding, ignoring the phase transformation plasticity effect in the coupling analysis led to a significant deviation between the simulated value of residual stress and the experimentally measured value. To investigate the influence mechanism of the Welding Residual Stresses (WRSs) of 30MnCrNiMo armor steel, the transformation plasticity (TP) coefficient (7.81 × 10⁻⁵ MPa⁻¹) was measured via a Gleeble 3500, and a Finite Element Model (FEM) of thermal–metallurgical–mechanical coupling considering yield strength, volumetric strain and TP behavior in Solid-State Phase Transformation (SSPT) was developed. The results show that the volume expansion during the SSPT is the main factor for the shift in WRS from tensile to compressive. In contrast, the TP effect reduces the peak longitudinal tensile stress in the Heat-Affected Zone (HAZ) by 51 MPa. It also ultimately neutralizes the compressive component in this region. When the martensite fraction ranges from 0.12 to 0.45, transformation plastic strain becomes the dominant factor, leading to a characteristic evolution of longitudinal stress that initially decreases and subsequently increases. The FEM incorporating the TP effect successfully captures the dual reversals of residual stress in the HAZ. The average relative error between the simulated longitudinal stress and the experimental data obtained via X-ray diffraction (cosα method) is 8.8%. The TP coefficient database and the developed multi-field coupling model markedly enhance the predictive accuracy for WRS in 30MnCrNiMo steel, offering a robust theoretical foundation for the design of stress corrosion resistance and the service life assessment of welded joints in armored vehicles. Full article