Search Results (11)

Excess concentrations of fecal indicator bacteria, nitrogen, and phosphorus have caused closure of shellfish growing waters, swimming advisories, eutrophication, and impairment of aquatic habitat in the Tar–Pamlico Estuary, North Carolina. Regulatory requirements to reduce nutrient and bacteria loading to the estuary were enacted more than two decades ago, but water quality problems persist. The goals of this study were to (1) assess the nutrient and bacteria concentrations and exports from Jacks Creek and Runyon Creek to the Tar–Pamlico Estuary in Coastal North Carolina, USA, and (2) recommend watershed-specific practices to reduce pollutant loadings and improve estuarine water quality. Stream water samples were collected for nutrient, bacteria, and physicochemical property (flow, pH, temperature, turbidity, and dissolved oxygen) analyses from five segments of Jacks Creek and six segments of Runyon Creek. Samples were collected between 8 and 10 times over a two-and-a-half-year period (2021–2024). Mean concentrations of total dissolved nitrogen, total dissolved phosphorus, and E. coli for Jacks Creek (1.55 mg/L, 0.10 mg/L, 502 MPN/100 mL) and Runyon Creek (1.70 mg/L, 0.07 mg/L, 262 MPN/100 mL) exceeded reference conditions or thresholds established by the US EPA (0.69 mg/L, 0.036 mg/L, 126 MPN/100 mL). Therefore, both watersheds have been contributing to the nutrient and bacteria problems of the estuary. Implementation of stormwater control measures in the urbanized Jacks Creek Watershed and agricultural best management practices in the Runyon Creek Watershed is encouraged. Some of the suggested practices have been installed, but additional remediation efforts are needed. Full article

Tyre wear particles (TWPs), generated from tyre-road abrasion, are a pervasive and under-regulated environmental pollutant, accounting for a significant share of global microplastic contamination. Recent estimates indicate that 1.3 million metric tons of TWPs are released annually in Europe, dispersing via atmospheric transport, stormwater runoff, and sedimentation to contaminate air, water, and soil. TWPs are composed of synthetic rubber polymers, reinforcing fillers, and chemical additives, including heavy metals such as zinc (Zn) and copper (Cu) and organic compounds like polycyclic aromatic hydrocarbons (PAHs) and N-(1,3-dimethylbutyl)-N′-phenyl-p-phenylenediamine (6PPD). These constituents confer persistence and bioaccumulative potential. While TWP toxicity in aquatic systems is well-documented, its ecological impacts on terrestrial environments, particularly in agricultural soils, remain less understood despite global soil loading rates exceeding 6.1 million metric tons annually. This review synthesizes global research on TWP sources, environmental fate, and ecotoxicological effects, with a focus on soil–plant systems. TWPs have been shown to alter key soil properties, including a 25% reduction in porosity and a 20–35% decrease in organic matter decomposition, disrupt microbial communities (with a 40–60% reduction in nitrogen-fixing bacteria), and induce phytotoxicity through both physical blockage of roots and Zn-induced oxidative stress. Human exposure occurs through inhalation (estimated at 3200 particles per day in urban areas), ingestion, and dermal contact, with epidemiological evidence linking TWPs to increased risks of respiratory, cardiovascular, and developmental disorders. Emerging remediation strategies are critically evaluated across three tiers: (1) source reduction using advanced tyre materials (up to 40% wear reduction in laboratory tests); (2) environmental interception through bioengineered filtration systems (60–80% capture efficiency in pilot trials); and (3) contaminant degradation via novel bioremediation techniques (up to 85% removal in recent studies). Key research gaps remain, including the need for long-term field studies, standardized mitigation protocols, and integrated risk assessments. This review emphasizes the importance of interdisciplinary collaboration in addressing TWP pollution and offers guidance on sustainable solutions to protect ecosystems and public health through science-driven policy recommendations. Full article

Water pollution, resulting from industrial effluents, agricultural runoff, and pharmaceutical residues, poses serious threats to ecosystems and human health, highlighting the need for innovative approaches to effective remediation, particularly for non-biodegradable emerging pollutants. This research work explores the influence of shape-controlled nanocrystalline titanium dioxide (TiO₂ NC), synthesized by a simple hydrothermal method, on the photodegradation efficiency of three different classes of emerging environmental pollutants: phenol, pesticides (methomyl), and drugs (sodium diclofenac). Experiments were conducted to assess the influence of the water matrix on treatment efficiency by using ultrapure water and stormwater (basic) collected from an urban drainage system as matrices. The size and shape of the nano-cuboids were accurately controlled during synthesis to assess their impact on photoactivity and selectivity. Regarding total organic carbon removal using TiO₂ nano-cuboids in basic environments, the results were particularly remarkable. TiO₂ nano-cuboids and truncated bipyramids synthesized in the 200–250 °C temperature range showed an enhanced photocatalytic efficiency when compared to alternative formulations. Diclofenac, methomyl, and phenol were fully mineralized from ultrapure water and basic stormwater. The TiO₂ nano-cuboids/nano-bipyramids demonstrated better selectivity and photoactivity in comparison to irregular TiO₂ nanoparticles. The differences in photoactivity and selectivity are explained in terms of charge carrier separation and trapping on the different crystal facets. Their performance demonstrates their potential as sustainable materials for the photodegradation of emerging pollutants in various water matrices. Full article

The production of plastics and associated products, including microplastics (MPs), has been surging over the past several decades and now poses a grave environmental threat. This is because when not appropriately recycled, incinerated, or disposed of in fully contained landfills, plastic waste manifests as a potent pollutant, with vast amounts finding their way into oceans annually, adversely impacting marine life and ecosystems. Additionally, research also confirms there are direct impacts from MPs on water, air, and soil, impacting ecosystem and human health. This study investigated all aspects of plastics and microplastics such as their generation and consumption, their presence in oceans, and their ultimate fate. Next, a comprehensive literature search was performed to identify impacts MPs have on watercourses and soils and eventually on the ocean, taking into consideration the coupled impacts of metals and emerging contaminants adsorbed onto MPs. Then, a model to estimate the number of MPs in oceans and then using toxicity of MPs to humans and aquatic life to estimate when oceans would become toxic to humanity is described. Utilizing the model, it is possible to estimate the year when MPs in the ocean could potentially become broadly toxic, for both humanity and marine life, under different emissions scenarios. The estimates conclude that with the current MP discharge growth, oceans would become toxic to humanity between 2398 and 2456, for MP discharge growth only until 2020, it could be reached between 2408 and 2472, and for emissions ending in 2020, oceans would not become toxic to the humanity. Finally, remediation strategies are described to prevent oceans from becoming toxic to humanity by focusing on various action items such as education and awareness, reducing the utilization of single-use plastic, and conventional and innovative strategies that can be used for the treatment of stormwater and wastewater. Full article

The increase in the quantity and variety of contaminants generated during routine airport infrastructure maintenance operations leads to a wider range of pollutants entering soil and surface waters through runoff, causing soil erosion and groundwater pollution. A significant developmental challenge is ensuring that airport infrastructure meets high-quality environmental management standards. It is crucial to have effective tools for monitoring and managing the volume and quality of stormwater produced within airports and nearby coastal areas. It is necessary to develop methodologies for determining a wide range of contaminants in airport stormwater samples and assessing their toxicity to improve the accuracy of environmental status assessments. This manuscript aims to showcase the latest advancements (2010–2024 update) in developing methodologies, including green analytical techniques, for detecting a wide range of pollutants in airport runoff waters and directly assessing the toxicity levels of airport stormwater effluent. An integrated chemical and ecotoxicological approach to assessing environmental pollution in airport areas can lead to precise environmental risk assessments and well-informed management decisions for sustainable airport operations. Furthermore, this critical review highlights the latest innovations in remediation techniques and various strategies to minimize airport waste. It shifts the paradigm of soil and water pollution management towards nature-based solutions, aligning with the sustainable development goals of the 2030 Agenda. Full article

In recent decades, the pollution of water with micropollutants has become an increasing environmental concern. Since 2019, increased stormwater pollution from chlorine-based disinfectants has been recorded due to the COVID-19 pandemic. Runoff from disinfected areas and the residual chlorine present in stormwater are transported to surface water bodies, posing a risk to aquatic flora and fauna. The objectives of this study were (1) to evaluate the efficiency of different low-cost and recyclable filter materials in removing residual chlorine, and (2) to test plants’ ability to reduce residual chlorine concentrations through phytoremediation. Experiments were conducted in the laboratory (column and batch) and in the field (raised garden bed) to assess the efficiency of various filter materials (peat, wood chips, sawdust and the lightweight aggregates) in retaining residual chlorine to be implemented in green infrastructure. The best retainers of chlorine were sawdust (96%) and the LWA Leca (76%). No harmful effects of residual chlorine (changes in growth, color, leaf size, etc.) on plants (Tagetes patula or Pisum savitum) were observed and the residual chlorine in the leachate samples was below the equipment’s detection limit. Our research results will contribute to future studies aiming to remove various micropollutants from stormwater using remediation technologies. Full article

Bioretention cells, or rain gardens, can effectively reduce many contaminants in polluted stormwater through phytoremediation and bioremediation. The vegetated soil structure develops bacterial communities both within the soil and around the vegetation roots that play a significant role in the bioremediative process. Prediction of a bioretention cell’s performance and efficacy is essential to the design process, operation, and maintenance throughout the design life of the cell. One of the key hurdles to these important issues and, therefore, to appropriate designs, is the lack of effective and inexpensive devices for monitoring and quantitatively assessing this bioremediative process in the field. This research reviews the available technologies for biomass monitoring and assesses their potential for quantifying bioremediative processes in rain gardens. The methods are discussed based on accuracy and calibration requirements, potential for use in situ, in real-time, and for characterizing biofilm formation in media that undergoes large fluctuations in nutrient supply. The methods discussed are microscopical, piezoelectric, fiber-optic, thermometric, and electrochemical. Microscopical methods are precluded from field use but would be essential to the calibration and verification of any field-based sensor. Piezoelectric, fiber-optic, thermometric, and some of the electrochemical-based methods reviewed come with limitations by way of support mechanisms or insufficient detection limits. The impedance-based electrochemical method shows the most promise for applications in rain gardens, and it is supported by microscopical methods for calibration and validation. Full article

Even though the common acknowledgment that vacant urban lands (VUL) can play a positive role in improving stormwater management, little synthesized literature is focused on understanding how VUL can take advantage of different stormwater control measures (SCMs) to advance urban water quality. The project aims to provide urban planners with information on the remediation of vacant lands using urban runoff pollutant removal techniques. To find the most effective removal method, relevant scholarly papers and case studies are reviewed to see what types of vacant land have many urban runoff pollutants and how to effectively remove contaminants from stormwater runoff in the city by SCMs. The results show that previously developed/used land (but now vacant) has been identified as contaminated sites, including prior residential, commercial, industrial, and parking lot land use from urban areas. SCMs are effective management approaches to reduce nonpoint source pollution problems runoff. It is an umbrella concept that can be used to capture nature-based, cost-effective, and eco-friendly treatment technologies and redevelopment strategies that are socially inclusive, economically viable, and with good public acceptance. Among these removal techniques, a bioretention system tends to be effective for removing dissolved and particulate components of heavy metals and phosphorus. Using different plant species and increasing filter media depth has identified the effectiveness of eliminating nitrate nitrogen (NO₃-N). A medium with a high hydraulic conductivity covers an existing medium with low hydraulic conductivity, and the result will be a higher and more effective decrease for phosphorus (P) pollutants. In addition, wet ponds were found to be highly effective at removing polycyclic aromatic hydrocarbons, with removal rates as high as 99%. For the removal of perfluoroalkyl acid (PFAA) pollutants, despite the implementation of SCMs in urban areas to remove PFAAs and particulate-related contaminants in stormwater runoff, the current literature has little information on SCMs’ removal of PFAAs. Studies have also found that VUL’s size, shape, and connectivity are significantly inversely correlated with the reduction in stormwater runoff. This paper will help planners and landscape designers make efficient decisions around removing pollutants from VUL stormwater runoff, leading to better use of these spaces. Full article

Porous Asphalt (PA) pavements are an increasingly adopted tool in the green stormwater infrastructure toolbox to manage stormwater in urbanized watersheds across the United States. This technology has seen particular interest in western Washington State, where permeable pavements are recognized as an approved best management practice per the National Pollutant Discharge Elimination System (NPDES) municipal stormwater permit. Stormwater effluent concentrations from six PA cells were compared with runoff concentrations from three standard impervious asphalt cells to quantify pollutant removal efficiencies by porous asphalt systems. Additionally, the effects of maintenance and pavement age on pollutant removal efficiencies were examined. Twelve natural and artificial storms were examined over a five-year period. Street dirt and pollutant spikes were added to the pavements prior to some storm events to simulate high loading conditions. Results from this work show that porous asphalt pavements are highly efficient at removing particulate pollutants, specifically coarse sediments (98.7%), total Pb ( 98.4%), total Zn (97.8%), and total suspended solids (93.4%). Dissolved metals and Polycyclic Aromatic Hydrocarbons (PAH) were not significantly removed. Removal efficiencies for total Pb, total Zn, motor oil, and diesel H. improved with the age of the system. Annual maintenance of the pavements with a regenerative air street sweeper did not yield significant pollutant removal efficiency differences between maintained and unmaintained PA cells. Full article

The City of Sydney is constructing more than 21,000 square metres of street biofilter units (raingardens) in terms of their Decentralised Water Master Plan (DWMP), for improving the quality of stormwater runoff to Port Jackson, the Cooks River, and the historical Botany Bay. Recharge of the Botany Sand Beds aquifer, currently undergoing remediation by extraction of industrial chlorinated hydrocarbon pollutants, is also envisaged. To anticipate the pollution removal efficiency of field biofilter designs, laboratory soil-column simulations were developed by Western Sydney University partnered with the City. Synthetic stormwater containing stoichiometric amounts of high-solubility pollutant salts in deionised water was passed through 104 mm columns that were layered to simulate monophasic and biphasic field designs. Both designs met the City’s improvement targets for total nitrogen (TN) and total phosphorus (TP), with >65% median removal efficiency. Prolonged release of total suspended solids (SS) on startup emphasised the need for specifications and testing of proprietary fills. Median removal efficiency for selected heavy metal ecotoxicants was >75%. The researchers suggested that Zinc be added to the targets as proxy for metals, polycyclic aromatic hydrocarbons (PAH) and oils/greases co-generated during road use. Simulation results suggested that field units will play an important role in meeting regional stormwater improvement targets. Full article

Adsorption is a key water pollution remediation measure used to achieve stormwater quality improvement in Sustainable urban Drainage Systems (SuDS). The level of contamination of detained sediment within SuDS assets is not well documented, with published investigations limited to specific contaminant occurrence in ponds, wetlands or infiltration devices (bioretention cells) and generally focused on solute or suspended sediment. Guidance on contamination threshold levels and potential deposited sediment contamination information is not included in current UK SuDS design or maintenance guidance, primarily due to a lack of evidence and understanding. There is a need to understand possible deposited sediment contamination levels in SuDS, specifically in relation to sediment removal maintenance activities and potential impact on receiving waterways of conveyed sediment. Thus, the objective of the research presented herein was to identify what major elements and trace metals were observable in (the investigated) SuDS assets detained sediment, the concentration of these major elements and trace metals and whether they met/surpassed ecotoxicity or contaminated land thresholds. The research presented here provides evidence of investigated SuDS sediment major element and trace metal levels to help inform guidance and maintenance needs, and presents a new methodology to identify the general cause (anthropocentric land use) and extent of detained SuDS fine urban sediment contamination through use of a contamination matrix. Full article