Search Results (78)

Swirl spray combustion has attracted significant attention due to its common usage in gas turbines. However, the high pressure in many practical applications remains a major obstacle to the deep understanding of flame stability and pollutant formation. To address this concern, this study investigated a swirl spray flame fueled with n-decane at elevated pressure. Planar laser-induced fluorescence (PLIF) of OH and polycyclic aromatic hydrocarbons (PAHs) were used simultaneously, enabling the distinction of the locations of OH, PAHs, and mixtures of them, providing detailed information on flame structure and evolution of PAHs. The effects of swirl number and ambient pressure on reaction zone characteristics and PAHs’ formation were studied, with the swirl number ranging from 0.30 to 1.18 and the pressure ranging from 1 to 3 bar. The data suggest that the swirl number changes the flame structure from V-shaped to crown-shaped, as observed at both atmospheric and elevated pressures. Additionally, varying swirl numbers lead to the initiation of flame divergence at distinct pressure levels. Moreover, PAHs of different molecular sizes exhibit significant overlap, with larger PAHs able to further extend downstream. The relative concentration of PAH increased with pressure, and the promoting effect of pressure on producing larger PAHs was significant. Full article

The physical and chemical properties of methanol differ significantly from those of conventional diesel, and its injection strategy plays a critical role in engine performance. In this study, a three-dimensional simulation model of a methanol–diesel dual-fuel engine integrated with chemical reaction kinetics was developed using CONVERGE software. The effects of methanol injection position and angle on combustion characteristics, emission performance, and engine economy were systematically investigated through numerical simulation and theoretical analysis, leading to the optimization of the methanol injection strategy. By varying the distance between the methanol nozzle and the cylinder head as well as the methanol injection angle, changes in temperature, pressure, heat release rate (HRR), and other engine parameters were analyzed. Additionally, the impact on emissions, including soot, HC, CO, and NOx, was evaluated, providing a theoretical foundation for optimizing dual-fuel engine performance and enhancing methanol utilization efficiency. The results indicate that the methanol injection position minimally affects engine performance. When the methanol spray is positioned 3 mm from the cylinder head, it facilitates the formation of a homogeneous mixture, resulting in optimal power output and enhanced environmental performance. In contrast, the injection angle has a more pronounced effect on combustion and emission characteristics. At a methanol injection angle of 65°, the mixture homogeneity reaches its optimal level, leading to a significant enhancement in combustion efficiency and engine power performance. Excessive injection angles may lead to combustion deterioration and reduced engine performance. The primary reason is that an excessive spray angle may cause methanol spray to impinge on the cylinder wall. This leads to wall wetting, which adversely affects mixture formation and combustion. Full article

The spray pyrolysis deposition of nanostructured Pb_1−xSn_xSe alloy films, x = 0.0 to 1.0, from as-prepared Pb_1−xSn_xSe alloy colloids as the starting solution is reported. The colloidal dispersions were prepared by dissolving selenium in an amine–thiol mixture, reacted with the Sn and Pb precursors in propylene glycol, and subsequently sprayed onto glass substrates at 300 °C. Structural characterization indicated the formation of the alloyed rock-salt cubic phase for 0.0 ≤ x ≤ 0.75, oxidized Pb and Se phases produced during the deposition, and only orthorhombic SnSe for x = 1.0 with Se and SnSe₂ as impurities. Nanocrystalline films ranging from 16 to 16.5 nm in size were obtained. The films displayed a shift in their optical structure and a non-monotonic variation in the band gap energy, first a decrease, reaching the minimum at x = 0.30 and a further increase in the Sn content. The decrease in the optical band gap resembles that of a topological insulator behavior. The morphology of the alloyed films confirmed the large nanocrystal formation by self-assembly processes in both the PbSe and SnSe phases and segregated PbSnSe platelets for x ≥ 0.30. Seebeck coefficient revealed that a typical semiconductor behavior dominated by bipolar transport, and p-type conductivity, but only for x = 0.0 n-type conductivity was exhibited. The maximal Seebeck coefficient magnitude behaved similarly to the band gap energy, evidencing the influence of energy band structure and the topological character. Full article

In this article, the structure formation and phase composition of coatings containing Cr₂AlC MAX phase under the conditions of plasma spraying were studied. Mechanical mixtures of commercially available Cr₃C₂ and Al powders were used as a material for spraying. The amount of aluminium in the mixtures was 9 and 18 wt.%. As a result of studying physicochemical processes occurring during plasma spraying of mechanical mixtures of selected compositions, the formation of coatings containing Cr₂AlC MAX phase was established, the synthesis of which occurs both at the stage of the particles flight of initial components in the plasma jet as a result of the collision and coagulation, and at the stage of a coating layer formation as a result of layering particles deformed during the collision–splats. It is shown that for the formation of a denser coating with a higher MAX phase content for spraying, it is rational to use a mixture of chromium carbide powders with 9 wt.% of aluminium. A coating with the composition 91Cr₃C₂-9Al (wt.%) has high corrosion resistance in operation conditions in a chloride-acetate solution, and by its indicators of corrosion resistance, is not inferior to the Cr₃C₂-NiCr coating, which is widely used in industry to protect parts from corrosion and wear. The obtained results show the possibility and feasibility of using mechanical mixtures of commercially available powders for the formation of coatings containing Cr₂AlC MAX phase instead of expensive synthesized MAX-Cr₂AlC powders. Full article

In this study, we examined the impact of droplet size and laser energy on droplet fragmentation and the resulting species composition due to laser irradiation of an acoustically levitated heptane droplet. Using shadowgraphy and spatially resolved laser-induced breakdown spectroscopy (LIBS), we observed two different fragmentation regimes for the conditions studied. The experiments demonstrated that low laser energy densities (<~70 mJ/mm³), designated as regime 1, resulted in a single plasma breakdown event accompanied by broadband emission and C₂ Swan bands, suggesting weak plasma formation. Conversely, high energy densities (>~70 mJ/mm³), designated as regime 2, resulted in multiple plasma breakdowns that resulted in the emission of H_α, O, and N, implying a full laser breakdown in the gaseous reactive mixture. Additionally, in regime 2, we calculated the electron density using Stark broadening of the H_α line and temperature using Boltzmann analysis of O lines at 715 nm and 777 nm. We found that the electron densities and temperatures within the air spark and heptane droplets are quite similar. The findings from this research could impact the design of spray ignition systems and may also aid in validating the modeling efforts of aerosols, droplet breakdown, and ignition. Full article

The process of osteointegration depends significantly on the surface roughness, structure, chemical composition, and mechanical characteristics of the coating. In this regard, an important direction in the development of medical materials is the development of new techniques of surface modification and the creation of bioactive ceramic coatings. Calcium-phosphate materials based on hydroxyapatite have been proposed as bioactive ceramic coatings on titanium implants for the effective acceleration of bone tissue healing. To obtain bioactive ceramic coatings, pulse power sources are best suited, namely detonation spraying, in which the energy of the explosion of gas mixtures is used as a source of pulse action. The pulse mode of operation in the detonation spraying method is preferable for the formation of bioactive ceramic coatings. It provides a high velocity of hydroxyapatite particles, which promotes their effective fixation on the titanium substrate, while minimizing the heating of the material. This approach preserves the substrate structure and improves the coating adhesion. Four different types of coatings with varying O₂/C₂H₂ molar ratios, ranging from 2.6 to 3.7, were obtained using detonation spraying. Powders and obtained coatings of hydroxyapatite were studied by Raman spectroscopy and XRD structural analysis. The results of XRD phase analysis showed the partial conversion of the hydroxyapatite phase to the α-tricalcium phosphate (α-TCP) phase during the detonation spraying process. The results obtained by Raman spectroscopy indicate that hydroxyapatite is the main phase in coatings. All hydroxyapatite-based coatings exhibited hydrophobic properties, which was confirmed by contact-angle values above 90° in wettability tests, characteristic of hydrophobic surfaces. The adhesive strength of the coatings was measured by the scratch test method. Tribological tests were conducted using the ball-on-disk method under both dry conditions and in Ringer’s solution. This approach enabled the evaluation of wear resistance and friction coefficient of the coatings in different environments, simulating both lubrication-free conditions and those resembling physiological environments. Full article

The article investigates the potential for producing hydrogen by combining the methods of water splitting under cavitation and the chemical activation of aluminum in a high-speed cavitation–jet flow generated by a specialized hydrodynamic reactor. The process of cavitation and water spraying causes the liquid heating itself until it reaches saturated vapor pressure, resulting in the creation of vapor–gaseous products from the splitting of water molecules. The producing of vapor–gaseous products can be explained through the theory of non-equilibrium low-temperature plasma formation within a high-speed cavitation–jet flow of fluid. Special focus is also given to the interactions occurring at the interface boundary phase of aluminum and liquid under cavitation condition. The primary solid products formed on aluminum surfaces are bayerite, copper oxides (I and II), iron carbide, and a compound of magnesium oxides and aluminum hydroxide. A high hydrogen yield of 60% was achieved when using a 0.1% sodium hydroxide solution as a working liquid compared to demineralized water. Moreover, hydrogen methane was also detected in the volume of the vapor–gas mixture, which could be utilized to address the challenges of decarbonization and the recycling of aluminum-containing solid industrial and domestic waste. This work provides a contribution to the study of the mechanism of hydrogen generation by cavitation–jet processing of water and aqueous alkali solutions, in which conditions are created for double cavitation in the cavitation–jet chamber of the hydrodynamic reactor. Full article

The process of obtaining powders from the 5–50 μm fraction of a W-Ni-Fe system consisting of particles with predominantly spherical shapes was investigated. Experimental studies on the plasma–chemical synthesis of a nanopowder composed of WNiFe-90 were carried out in a plasma reactor with a confined jet flow. A mixture of tungsten trioxide, nickel oxide, and iron oxide powders interacted with a flow of hydrogen-containing plasma generated in an electric-arc plasma torch. The parameters of the spray-drying process and the composition of a suspension consisting of WNiFe-90 nanoparticles were determined, which provided mechanically strong nanopowder microgranules with a rounded shape and a homogeneous internal structure that contained no cavities. The yield of the granule fraction under 50 μm was 60%. The influence of the process parameters of the plasma treatment of the nanopowder microgranules in the thermal plasma flow on the degree of spheroidization and the microstructure of the obtained particles, seen as their bulk density and fluidity, was established. It was shown that the plasma spheroidization of the microgranules of the W-Ni-Fe system promoted the formation of a submicron internal structure in the obtained spherical particles, which were characterized by an average tungsten grain size of 0.7 μm. Full article

Amorphous carbon coatings are widely used due to their beneficial friction and wear characteristics. A detailed understanding of their behavior during running-in, apart from model tribosystems, has yet to be obtained. Multiple analytical methods were used to detect the physical and chemical changes in a ta-C coating and its thermally sprayed, metallic counterpart after a running-in procedure with pin-on-disk experiments. Both coatings exhibited changes in their surface and near-surface chemistry. The mechanisms in and on the metallic coating were identified to be a mixture of the third-body type, with the formation of gradients in the microstructure and chemistry and an additional carbon-rich tribofilm formation on top. The ta-C coating’s changes in chemistry with sp² enrichment and lubricant element inclusions proved to be too complex to allocate them to tribofilm or third-body formation. Full article

A system combining gas-phase oxidation and liquid-phase collision absorption for removing NO from marine diesel engine exhaust was proposed. This method was the first to utilize different physical states of the same mixed solution to achieve both pre-oxidation and impingement reduction absorption of exhaust gases. During the pre-oxidation stage, a mixture of (NH₄)₂S₂O₈ and urea solution was atomized into a spray using an ultrasonic nebulizer to increase the contact area between the oxidant and the exhaust gas, thereby efficiently pre-oxidizing the exhaust gas in the gas phase. In the liquid-phase absorption stage, the (NH₄)₂S₂O₈ and urea solution was used in an impingement absorption process, which not only enhanced gas–liquid mass transfer efficiency but also effectively inhibited the formation of nitrates. Experimental results showed that, without increasing the amount of absorbent used, the maximum NO removal efficiency of this method reached 97% (temperature, 343 K; (NH₄)₂S₂O₈ concentration, 0.1 mol/L; urea concentration, 1.5 mol/L; NO concentration, 1000 ppm; pH, 7; impinging stream velocity, 15 m/s), compared to 72% using the conventional liquid-phase oxidation absorption method. Additionally, this method required only the addition of a nebulizer and two opposing nozzles to the existing desulfurization tower to achieve simultaneous removal of sulfur and nitrogen oxides from the exhaust gas, with low retrofitting costs making it favorable for practical engineering applications. Full article

An arc glow discharge device was used to prepare a helical carbon fiber skeleton with helical carbon fibers hooked to each other by spraying a hydrogen and ethanol mixture onto the iron wire substrate through the discharge area, using anhydrous ethanol as the carbon source. The samples were characterized by SEM, EDS, Raman and XPS. A growth mechanism of helical carbon fiber driven by C sp3 was proposed. The various growth modes of carbon fiber during the formation of carbon fiber skeleton were investigated. A ring appearance that indicated a change in the direction of carbon fiber growth was observed. And double helical carbon fiber was constructed from single helical carbon fiber in two ways. Super-large carbon fiber with a diameter of about 13 μm was observed, and it was speculated that this super-large carbon fiber is the backbone of the carbon fiber skeleton. The mechanical properties of the carbon fiber skeleton are isotropic. Full article

Clean-burning oxygenated and synthetic fuels derived from renewable power, so-called e-fuels, are a promising pathway to decarbonize compression–ignition engines. Polyoxymethylene dimethyl ethers (PODEs or OMEs) are one candidate of such fuels with good prospects. Their lack of carbon-to-carbon bonds and high concentration of chemically bound oxygen effectively negate the emergence of polycyclic aromatic hydrocarbons (PAHs) and even their precursors like acetylene (C₂H₂), enabling soot-free combustion without the soot-NO_x trade-off common for diesel engines. The differences in the spray combustion process for OMEs and diesel-like reference fuels like n-dodecane and their potential implications on engine applications include discrepancies in the observed ignition delay, the stabilized flame lift-off location, and significant deviations in high-temperature flame morphology. For CFD simulations, the accurate modeling and prediction of these differences between OMEs and n-dodecane proved challenging. This study investigates the spray combustion process of an OME_{3 − 5} mixture and n-dodecane with advanced optical diagnostics, Reynolds-Averaged Navier–Stokes (RANS), and Large-Eddy Simulations (LESs) within a constant-volume vessel. Cool-flame and high-temperature combustion were measured simultaneously via high-speed (50 kHz) imaging with formaldehyde (CH₂O) planar laser-induced fluorescence (PLIF) representing the former and line-of-sight OH* chemiluminescence the latter. Both RANS and LES simulations accurately describe the cool-flame development process with the formation of CH₂O. However, CH₂O consumption and the onset of high-temperature reactions, signaled by the rise of OH* levels, show significant deviations between RANS, LES, and experiments as well as between n-dodecane and OME. A focus is set on the quality of the simulated results compared to the experimentally observed spatial distribution of OH*, especially in OME fuel-rich regions. The influence of the turbulence modeling is investigated for the two distinct ambient temperatures of 900 K and 1200 K within the Engine Combustion Network Spray A setup. The capabilities and limitations of the RANS simulations are demonstrated with the initial cool-flame propagation and periodic oscillations of CH₂O formation/consumption during the quasi-steady combustion period captured by the LES. Full article

In diesel engines, emission formation inside the combustion chamber is a complex phenomenon. The combustion events inside the chamber occur in microseconds, affecting the overall engine performance and emissions characteristics. This study opted for using computational fluid dynamics (CFD) to investigate the combustion patterns and how these events affect nitrogen oxide (NO_x) emissions. In this study, a diesel engine model with a flat combustion chamber (FCC) was developed for the simulation. The simulation result of the heat release rate (HRR) and cylinder pressure was validated with the experimental test data (the engine test was conducted at 1500 rpm at full load conditions). The validated model and its respective boundary conditions were used to investigate the effect of modified combustion chamber profiles on NO_x emissions. Modified chambers, such as a bathtub combustion chamber (BTCC) and a shallow depth chamber (SCC), were developed, and their combustion events were analysed with respect to the FCC. This study revealed that combustion events such as fuel distribution, unburnt mass fractions, temperature and turbulent zones directly impact NO_x emissions. The modified chambers controlled the spread of combustion and provided better fuel distribution, improving engine performance and combustion rates. The SCC (63.2 bar) showed peak pressure rates compared to the FCC (63.02 bar) and BTCC (62.72 bar). This study concluded that the SCC showed better results than other chambers. This study further recommends conducting lean fuel mixture combustion with chamber modifications and optimising fuel spray, such as by adjusting the fuel injection profile, spray angle and injection timing, which has a better tendency to create complete combustion. Full article

Laser processing is an effective post-treatment method for modifying the structure and improving the properties of cold-sprayed coatings. In the present work, the possibility of fabricating a hard and wear-resistant Ti-based cermet coating by cold spray followed by laser remelting was studied. A mixture of titanium and chromium carbide powders in a ratio of 60/40 wt.% was deposited by cold spray onto a titanium alloy substrate, which ensured the formation of a composite coating with a residual chromium carbide content of about 12–13 wt.%. The optimal values of laser beam power (2 kW) and scanning speed (75 mm/s) leading to the qualitative fusion of the coating with the substrate with minimal porosity and absence of defects were revealed. The microstructure and phase composition of as-sprayed and remelted coatings were examined with SEM, EDS and XRD analysis. It was shown that the phase composition of the as-sprayed coating did not change compared to the feedstock mixture, while the remelted coating was transformed into a β-Ti(Cr) solid solution with uniformly distributed nonstoichiometric TiC_x particles. Due to the change in microstructure and phase composition, the remelted coating was characterized by an attractive combination of higher microhardness (437 HV_0.1) and lower specific wear rate (0.25 × 10⁻³ mm³/N × m) under dry sliding wear conditions compared to the as-sprayed coating and substrate. Laser remelting of the coating resulted in a change in the dominant wear mechanism from oxidative–abrasive to oxidative–adhesive with delamination. Full article

Coatings with high hardness were successfully obtained using low-pressure cold spray (LPCS) technology from nanocrystalline powders based on the aluminum alloy AlMg6, which were multi-reinforced with 0.3 wt.% fullerenes and 10–50 wt.% AlN. The powders were synthesized through a two-stage high-energy ball milling process, resulting in a complex mechanical mixture consisting of agglomerates and micro-sized ceramic particles of AlN. The agglomerates comprise particles of the nanocomposite material AlMg6/C₆₀ with embedded and surface-located, micro-sized ceramic particles of AlN. Scanning electron microscopy and EDS analyses demonstrated a uniform distribution of reinforcing particles throughout the coating volume. An X-ray diffraction (XRD) analysis of the coatings revealed a change in the predominant orientation of matrix alloy grains to a more chaotic state during deformation over the course of cold gas dynamic spraying. A quantitative determination of AlN content in the coating was achieved through the processing of XRD data using the reference intensity ratio (RIR) method. It was found that the proportion of transferred ceramic particles from the multi-reinforced powder to the coating did not exceed ~65%. Experimental evidence indicated that LPCS processing of mono-reinforced nanocrystalline powder composite AlMg6/C₆₀ practically did not lead to the formation of a coating on the substrate and was limited to a monolayer with a thickness of ~10 µm. The microhardness of the monolayer coating obtained from the deposition of AlMg6/C₆₀ powder was 181 ± 12 HV. Additionally, the introduction of 10 to 50 wt.% AlN into the powder mixture contributed to the enhancement of growth efficiency and an increase in coating microhardness by ~1.4–1.7 times. The obtained results demonstrate that the utilization of agglomerated multi-reinforced powders for cold gas dynamic spraying can be an effective strategy for producing coatings and bulk materials based on aluminum and its alloys with high microhardness. Full article