Search Results (1,968)

Nuclear power is a low-emission and economically competitive energy source, yet the effective disposal and management of its associated radioactive waste can be challenging. Radioactive waste can be categorised as high-level waste (HLW), intermediate-level waste (ILW), and low-level waste (LLW). LLW primarily comprises materials contaminated during routine clean-up, such as mop heads, paper towels, and floor sweepings. While LLW is less radioactive compared to HLW and ILW, the management of LLW poses significant challenges due to the large volume that requires processing and disposal. The volume of LLW can be significantly reduced through sorting, which is typically performed manually in a labour-intensive way. Smart management techniques, such as computer vision (CV) and machine learning (ML), have great potential to help reduce the workload and human errors during LLW sorting. This paper provides a comprehensive review of previous research related to LLW sorting and a summative review of existing applications of CV in solid waste management. It also discusses state-of-the-art CV and ML algorithms and their potential for automating LLW sorting. This review lays a foundation for and helps facilitate the applications of CV and ML techniques in LLW sorting, paving the way for automated LLW sorting and sustainable LLW management. Full article

This paper presents a comprehensive review of dealuminated metakaolin (DK), a hazardous industrial by-product generated by the aluminium sulphate (alum) industry and evaluates its potential as a component in cementitious systems for the partial or full replacement of Portland cement (PC). Positioned within the context of waste valorisation in concrete, the review aims to establish a critical understanding of DK formation, properties, and reactivity, particularly its pozzolanic potential, to assess its suitability for use as a supplementary cementitious material (SCM), or as a precursor in alkali-activated cement (AAC) systems for concrete. A systematic methodology is used to extract and synthesise relevant data from existing literature concerning DK and its potential applications in cement and concrete. The collected information is organised into thematic sections exploring key aspects of DK, beginning with its formation from kaolinite ores, followed by studies on its pozzolanic reactivity. Applications of DK are then reviewed, focusing on its integration into SCMs and alkali-activated cement (AAC) systems. The review consolidates existing knowledge related to DK, identifying scientific gaps and practical challenges that limit its broader adoption for cement and concrete applications, and outlines future research directions to provide a solid foundation for future studies. Overall, this review highlights the potential of DK as a low-carbon, circular-economy material and promotes its integration into efforts to enhance the sustainability of construction practices. The findings aim to support researchers’ and industry stakeholders’ strategies to reduce cement clinker content and mitigate the environmental footprint of concrete in a circular-economy context. Full article

Biodiesel, as one of the alternatives to fossil fuels, faces significant challenges in large-scale industrial production due to its high production costs. In addition to raw material costs, catalyst costs are also a critical factor that cannot be overlooked. This review summarizes various methods for preparing biodiesel catalysts from solid waste. These methods not only enhance the utilization rate of waste but also reduce the production costs and environmental impact of biodiesel. Finally, the limitations of waste-based catalysts and future research directions are discussed. Research indicates that solid waste can serve as a catalyst carrier or active material for biodiesel production. Methods such as high-temperature calcination, impregnation, and coprecipitation facilitate structural modifications to the catalyst and the formation of active sites. The doping of metal ions not only alters the catalyst’s acid-base properties but also forms stable metal bonds with functional groups on the carrier, thereby maintaining catalyst stability. The application of microwave-assisted and ultrasound-assisted methods reduces reaction parameters, making biodiesel production more economical and sustainable. Overall, this study provides a scientific basis for the reuse of solid waste and ecological protection, emphasizes the development potential of waste-based catalysts in biodiesel production, and offers unique insights for innovation in this field, thereby accelerating the commercialization of biodiesel. Full article

For the first time, electrospinning has been used to recycle polyacrylonitrile terpolymer (PAN) waste following the solid-phase N-methylmorpholine-N-oxide (NMMO) process from PAN solutions in DMSO into nonwoven materials. The morphology of the obtained material has been studied. The material derived from secondary raw materials was compared to the material from the original PAN using IR spectroscopy, X-ray diffraction, scanning electron microscopy, and atomic force microscopy. It has been demonstrated that the chemical changes of PAN that occur during NMMO processing do not interfere with nonwoven material manufacture. Spun PAN nonwovens with different histories have similar morphology. It has been shown that the elastic modulus of ultrafine fibers depends on the history of PAN. Single monofilaments produced from initial PAN have a threefold greater elastic modulus than fibers spun from NMMO-recycled polymer. The revealed structure and properties of PAN fibers allow them to be considered as filter materials, as well as precursors of carbon nonwoven fabrics. Full article

The sustainable management of Municipal Solid Waste (MSW) relies heavily on community participation in separating it at the source and delivering it to collection systems. These practices are crucial for reducing pollution, protecting ecosystems, and maximizing resource recovery. However, in the Global South context, with conditions of socioeconomic vulnerability, community participation in the sustainable management of MSW remains limited, highlighting the need to generate context-specific interventions. MSW includes items such as household appliances, batteries, and electronic devices, which require specialized handling due to their size, hazardous components, or material complexity. This study implemented a Community-Based Social Marketing approach during the research and design phases of an intervention focused on promoting source separation and management of hard-to-manage MSW in five municipalities within the administrative region of Norte de Santander (Colombia), which borders Venezuela. Using a mixed-methods approach, we collected data from 1775 individuals (63.83% women; M _age = 33.48 years; SD = 17.25), employing social mapping, focus groups, semi-structured interviews, participant observation, and a survey questionnaire. The results show that the source separation and delivery of hard-to-manage MSW to collection systems are limited by a set of psychosocial, structural, and institutional barriers that interact with each other, affecting communities’ willingness and capacity for action. Furthermore, a prediction model of willingness to engage in separation and delivery behaviors showed a good fit (R2 = 0.83). The strongest predictors were awareness of the negative consequences of non-participation and perceived environmental benefits, with subjective norms contributing to a lesser extent. Based on these results, we designed a context-specific intervention focused on reducing these barriers and promoting community engagement in the sustainable management of hard-to-manage MSW. Full article

The increasing need for sustainable valorization of fossil-based and waste-derived materials has gained interest in converting complex organic matrices such as kerogen into valuable chemicals. This study explores a two-step oxidative strategy to decompose and valorize kerogen-rich oil shale, aiming to develop a locally based source of aliphatic dicarboxylic acids (DCAs). The method combines air oxidation with subsequent nitric acid treatment to enable selective breakdown of the organic structure under milder conditions. Air oxidation was conducted at 165–175 °C using 1% KOH as an alkaline promoter and 40 bar oxygen pressure (or alternatively 185 °C at 30 bar), targeting 30–40% carbon conversion. The resulting material was then subjected to nitric acid oxidation using an 8% HNO₃ solution. This approach yielded up to 23% DCAs, with pre-oxidation allowing a twofold reduction in acid dosage while maintaining efficiency. However, two-step oxidation was still accompanied by substantial degradation of the structure, resulting in elevated CO₂ formation, highlighting the need to balance conversion and carbon retention. The process offers a possible route for transforming solid fossil residues into useful chemical precursors and supports the advancement of regionally sourced, sustainable DCA production from unconventional raw materials. Full article

Cattle manure accounts for approximately one-third of the total livestock manure produced in the Republic of Korea and is typically composted. To elucidate its feasibility as a renewable resource, this study evaluated the conversion of cattle manure into a solid biofuel and the nutrient recovery potential of its combustion residues. Solid fuel was prepared from cattle manure collected in Gyeongsangbuk-do, Korea, and its fuel characteristics and ash composition were analyzed after combustion. Combustion tests conducted using a dedicated solid fuel boiler showed that an average lower heating value of 13.27 MJ/kg was achieved, meeting legal standards. Under optimized combustion, CO and NO_x emissions (129.9 and 41.5 ppm) were below regulatory limits (200 and 90 ppm); PM was also within the 25 mg/Sm³ standard. The bottom ash contained high concentrations of P₂O₅ and K, and its heavy metal content was below the regulatory threshold, suggesting its potential reuse as a fertilizer material. Although the Zn concentration in the fly ash exceeded the standard, its quantity was negligible. Therefore, the solid fuel conversion of cattle manure can become a viable and environmentally sustainable solution for both bioenergy production and nutrient recycling, contributing to improved waste management in livestock operations. Full article

The concept of the circular economy aims to develop systems for reusing, recovering, and recycling products and services, pursuing both economic growth and sustainability. In many countries, legislation has been enacted to create frameworks ensuring environmental protection and fostering initiatives to implement the circular economy across various sectors. The wind energy industry is no exception, with industries and institutions adopting strategies to address the forthcoming challenge of repowering or dismantling a significant quantity of wind turbines in the coming years reaching a total of global wind power capacity by 2024. This also involves managing the resulting waste, which includes materials with high economic value as well as others that have considerable environmental impacts but that can be reused, recycled, or converted. In parallel, the research activity in this field has increased significantly in response to this challenge, leading to a vast body of work in the literature, especially in the last three years. The aim of this paper is to conduct a bibliometric study to provide a global perspective on the current literature in the field, covering the period from 2009 to 2024. A total of 670 publications were retrieved from Web of Science and Scopus, with 57% of them published in the last three years, highlighting the growing interest in the field. This study analyzes the research product, the most relevant journal, the most cited authors and institutions, their collaborative patterns, emerging trends, and gaps in the literature. This contribution will provide an up-to-date analysis of the field, fostering better understanding of the direction of the research and establishing a solid foundation for future studies Full article

Boehmite has been widely used in theoretical research and industry, especially for hazardous material processing. For the liquid-phase treating process, the interfacial properties of boehmite are believed to be affected by pH conditions, which change its physicochemical behavior. However, molecular-level detection on cluster ions is challenging when using bulk approaches. Herein we employ in situ vacuum ultraviolet single-photon ionization mass spectrometry (VUV SPI-MS) coupled with a vacuum-compatible microreactor system for analysis at the liquid–vacuum interface (SALVI) to investigate the solute molecular composition of boehmite under different pH conditions for the first time. The mass spectral results show that more complex clustering of solute molecules exists at the solid–liquid (s–l) interface than conventionally perceived in a “simple” aqueous solution. Besides solute ions, such as boehmite molecules and fragments, the composition and appearance energies of these newly discovered solvated cluster ions are determined by VUV SPI-MS in different pH solutions. We offer new results for the pH-dependent effect of boehmite and provide insights into a more detailed solvation mechanism at the s–l interface. By comparing the key products under different pH conditions, fundamental understanding of boehmite dissolution is revealed to assist the engineering design of waste processing and storage solutions. Full article

This study developed a full solid waste-based cementitious material (ISWs-CM) using steel slag (SS), ground granulated blast furnace slag (GGBFS), phosphorus slag (PS), carbide slag (CS), and desulfurized gypsum (DG) to completely replace cement. A two-layer optimization strategy, combining three chemical moduli and simplex lattice experiments, was employed to determine the proportion and to investigate the impact of proportions on the uniaxial compressive strength of mortar. As an application case, the ISWs-CM with the optimal proportion was employed to stabilize aeolian sand, and its effectiveness as a cement substitute and the underlying mechanisms were investigated. The results indicated that the ISW proportion that maximized the strength of the mortar was SS:GGBFS:PS:CS = 5:20:20:40. The strength of the mortar was enhanced when the proportion of GGBFS exhibiting the highest reactivity was increased and also increased initially and then decreased with an increase in CS when the dosage of GGBFS was fixed. The aeolian sand stabilized by ISW-CM exhibited higher strength than that stabilized with cement. The greater number and variety of hydration products resulted in denser connections and encapsulation of sand particles, which highlights the synergistic effect of ISWs and the potential of ISW-CM as a cement replacement across diverse applications including aeolian sand stabilization. Full article

Agriculture and its related industries produce annually a vast amount of byproducts and waste which comprise a large proportion of global waste. Only a small percentage is managed with environmentally acceptable procedures, while a large proportion is either incinerated or discarded into nearby open fields, causing serious environmental burdens. Since these byproducts exhibit a rich nutritional and phytochemical content, they may be considered as raw materials for various industrial applications, initiating the need for the development of sustainable and eco-friendly methods for their valorization. Among the various methods considered, Solid-State Fermentation (SSF) constitutes an intriguing eco-friendly bioprocess, being suitable for water-insoluble mixtures and providing products with improved stability and depleted catabolic suppression. Thus, there are several literature studies highlighting the aspects and efficacy of SSF for improving the nutritional and phytochemical contents of diverse agro-industrial waste. The review herein aspires to summarize these literature results with a special focus on the enhancement of their antioxidant potency. For this purpose, specific keywords were used for searching multiple scientific databases with an emphasis on the most recent studies and higher impact journals. The presented data establish the usefulness and efficacy of the SSF bioprocess to obtain fermentation products with enhanced antioxidant profiles. Full article

In this study, to solidify the silt in an expressway, a stabilizing agent composed of industrial wastes, such as ordinary Portland cement (OPC), calcium based alkaline activator (CAA), silicate solid waste material (SISWM) and sulfate solid waste material (SUSWM) was developed. Orthogonal experiments and comparative experiments were carried out to analyze the strength and water stability of the stabilized silt, and get the optimal proportion of each component in the stabilizing agent. A series of laboratory tests, including unconfined compressive strength (UCS), water stability (WS), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD) analyses, were conducted on solidified silt samples treated with the stabilizing agent at optimal mixing ratios of OPC, CAA, SISWM, and SUSWM to elucidate the evolution of mineral composition and microstructure. Full article

To address the limitations of traditional hardened concrete road surfaces in coal mine tunnels, which are prone to damage and entail high maintenance costs, this study proposes using modular concrete blocks composed of fly ash and coal gangue as an alternative to conventional materials. These blocks offer advantages including ease of construction and rapid, straightforward maintenance, while also facilitating the reuse of substantial quantities of solid waste, thereby mitigating resource wastage and environmental pollution. Initially, the mineral composition of the raw materials was analyzed, confirming that although the physical and chemical properties of Liangshui Well coal gangue are slightly inferior to those of natural crushed stone, they still meet the criteria for use as concrete aggregate. For concrete blocks incorporating 20% fly ash, the steam curing process was optimized with a recommended static curing period of 16–24 h, a temperature ramp-up rate of 20 °C/h, and a constant temperature of 50 °C maintained for 24 h to ensure optimal performance. Orthogonal experimental analysis revealed that fly ash content exerted the greatest influence on the compressive strength of concrete, followed by the additional water content, whereas the aggregate particle size had a comparatively minor effect. The optimal mix proportion was identified as 20% fly ash content, a maximum aggregate size of 20 mm, and an additional water content of 70%. Performance testing indicated that the fabricated blocks exhibited a compressive strength of 32.1 MPa and a tensile strength of 2.93 MPa, with strong resistance to hydrolysis and sulfate attack, rendering them suitable for deployment in weakly alkaline underground environments. Considering the site-specific conditions of the Liangshuijing coal mine, ANSYS 2020 was employed to simulate and analyze the mechanical behavior of the blocks under varying loads, thicknesses, and dynamic conditions. The findings suggest that hexagonal coal gangue blocks with a side length of 20 cm and a thickness of 16 cm meet the structural requirements of most underground mine tunnels, offering a reference model for cost-effective paving and efficient roadway maintenance in coal mines. Full article

The sustainable valorization of electrolytic manganese residue (EMR) and fly ash (FA) presents critical environmental challenges. This study systematically investigates the performance optimization of EMR-FA ceramic composites through the coordinated regulation of raw material ratios, sintering temperatures, and additive effects. While the composite with 85 g FA exhibits the highest mechanical strength, lowest porosity, and minimal water absorption, the formulation consisting of 45 wt% EMR, 40 wt% FA, and 15 wt% kaolin is identified as a balanced composition that achieves an effective compromise between mechanical performance and solid waste utilization efficiency. Sintering temperature studies revealed temperature-dependent property enhancement, with controlled sintering at 1150 °C preventing the over-firing phenomena observed at 1200 °C while promoting phase evolution. XRD-SEM analyses confirmed accelerated anorthite formation and the morphological transformations of FA spherical particles under thermal activation. Additive engineering demonstrated that 8 wt% CaO addition enhanced structural densification through hydrogrossular crystallization, whereas Na₂SiO₃ induced sodium-rich calcium silicate phases that suppressed anorthite development. Contrastingly, ZrO₂ facilitated zircon nucleation, while TiO₂ enabled progressive performance enhancement through amorphous phase modification. This work establishes fundamental phase–structure–property relationships and provides actionable engineering parameters for sustainable ceramic production from industrial solid wastes. Full article

To reveal the long-term deformation behavior of high-volume fly ash-based backfill under continuous mining and backfilling, a fly ash–cement backfill material with 73.0% fly ash content was developed, and creep characteristic tests considering initial damage were conducted. The results demonstrate that: (1) A calculation method for the initial damage of backfill based on stress–strain hysteresis loop cycles is proposed, with cumulative characteristics of initial damage across mining phases analyzed; (2) Creep behaviors of backfill affected by initial damage are investigated, revealing the weakening effect of initial damage on long-term bearing capacity; (3) An enhanced, nonlinear plastic damage element is developed, enabling the construction of an HKBN constitutive model capable of characterizing the complete creep behavior of backfill materials. The research establishes a theoretical framework for engineering applications of backfill materials with early-age strength below 5 MPa, while significantly enhancing the utilization efficiency of coal-based solid wastes. Full article