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25 pages, 1286 KB  
Review
Progress and Challenges in Joining for Precision Endoscope Fabrication
by Peiquan Xu, Xiaohao Zheng, Leijun Li and Ziyi Wang
Sensors 2026, 26(9), 2828; https://doi.org/10.3390/s26092828 - 1 May 2026
Viewed by 857
Abstract
This review summarizes the base materials, joining methods, filler materials, and principal technical challenges in endoscope joining fabrication, and proposes practical strategies to improve joint reliability under clinical constraints. We conducted a comprehensive search in multiple databases, including Web of Science, Google Scholar, [...] Read more.
This review summarizes the base materials, joining methods, filler materials, and principal technical challenges in endoscope joining fabrication, and proposes practical strategies to improve joint reliability under clinical constraints. We conducted a comprehensive search in multiple databases, including Web of Science, Google Scholar, patent databases, Scopus databases, and Medline (via PubMed), for articles on the joining for precision endoscope fabrication, covering the period from 1950 to 2026. We employed the combinations of keywords, “endoscopy”, “minimally invasive surgery”, “welding”, “joining”, “sealing”, “soldering”, “bonding”, and “brazing”. Approximately 500 references were retrieved. After excluding duplicates and irrelevant studies, 158 publications met the inclusion criteria. Data on base materials, joining, processes, filler materials, and technical issues related to sterilization, corrosion, and microstructural evolution were extracted and analyzed. Endoscopes are multi-material systems, involving metallic biomaterials (stainless steels (SSs), titanium alloys, nickel-based alloys, etc.), optical functional materials (glass, sapphire, quartz, etc.), engineering plastics, ceramics, composite materials, and coatings. Joining, sealing, and functional integration have been achieved via adhesive bonding, laser soldering, laser brazing, wave soldering, reflow soldering, fusion welding, and other joining techniques. The main challenges include how to reliably join highly mismatched dissimilar materials, how to fabricate low-residual-stress joints, and how to increase the long-term resistance to sterilization-induced degradation and thermal aging over repeated 100–200 °C thermal cycles. Conventional joining techniques struggle to balance mechanical integrity, joint hermeticity, and long-term stability under such harsh cyclic conditions. The resulting joints may suffer surface yellowing, interfacial debonding, microcracking, delamination, or progressive property degradation during service. We propose the following three strategies to achieve reliable, low-residual-stress, and sterilization-resistant joining of dissimilar materials for endoscopes: (1) A synergistic design that combines thin-film engineering (including evaporation, sputtering, and electroplating) with silver anti-oxidation layers is proposed to reduce residual stresses and to enhance the joint hermeticity. (2) To develop principles for the selection of multi-joining processes to achieve the multi-material integration and functional assembly of dissimilar material components. (3) To develop the laser-based joining methods (fusion, brazing, or braze-welding) for precision control of heat input, bonding quality, and the least damage to the heat-sensitive components. Full article
(This article belongs to the Section Biomedical Sensors)
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19 pages, 3717 KB  
Article
Molecular Dynamics Study of the Sintering Behavior and Mechanical Properties of Cu@Ag Core–Shell Nanoparticle Solder Paste
by Xuezhi Zhang, Jian Gao and Lanyu Zhang
Materials 2026, 19(8), 1612; https://doi.org/10.3390/ma19081612 - 17 Apr 2026
Viewed by 1196
Abstract
Silver-coated copper (Cu@Ag) core–shell nanoparticles are promising interconnect materials for electronic packaging due to their high conductivity, oxidation resistance, and reduced use of precious metals. However, the key factors governing their sintering behavior and mechanical performance are not fully understood. In this study, [...] Read more.
Silver-coated copper (Cu@Ag) core–shell nanoparticles are promising interconnect materials for electronic packaging due to their high conductivity, oxidation resistance, and reduced use of precious metals. However, the key factors governing their sintering behavior and mechanical performance are not fully understood. In this study, molecular dynamics simulations were performed to examine the effects of sintering pressure (300–700 MPa), temperature (500–700 K), particle size, and silver shell thickness on atomic diffusion, microstructural evolution, and mechanical properties. Results show that higher pressure improves particle contact, accelerates densification, and strengthens interfacial bonding, with optimal performance achieved at 600–700 MPa. Elevated temperatures enhance atomic mobility, promoting neck growth and pore elimination, with the most active diffusion observed between 650 K and 700 K. Particle size and shell thickness also affect sintering: the Ag6Cu3 configuration exhibits the highest atomic mobility and a balanced combination of strength and ductility. Moderately thick silver shells facilitate surface diffusion and interfacial interdiffusion, while mechanisms such as the Kirkendall effect and local plastic relaxation reduce defect density, yielding stable sintered structures. These findings provide atomic-scale insights into the sintering mechanisms of Cu@Ag nanoparticle solder pastes and offer guidance for optimizing processing parameters in high-performance electronic packaging applications. Full article
(This article belongs to the Section Advanced Nanomaterials and Nanotechnology)
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15 pages, 3813 KB  
Article
Strengthening Copper Nano-Solder Pastes with Group IV 2D Materials: A Molecular Dynamics Insight
by Xuezhi Zhang, Jian Gao and Lanyu Zhang
Materials 2026, 19(7), 1418; https://doi.org/10.3390/ma19071418 - 2 Apr 2026
Viewed by 480
Abstract
This study investigates the effects of three group IV two-dimensional (2D) materials (graphene, silicene, and germanene) on the sintering process and tensile properties of copper nanoparticle pastes for electronic packaging. Using atomic-scale simulations, we constructed models of pure copper and composite pastes, tracking [...] Read more.
This study investigates the effects of three group IV two-dimensional (2D) materials (graphene, silicene, and germanene) on the sintering process and tensile properties of copper nanoparticle pastes for electronic packaging. Using atomic-scale simulations, we constructed models of pure copper and composite pastes, tracking particle rearrangement, neck formation, and pore closure under identical sintering conditions, followed by uniaxial tensile testing. All composites formed continuous copper networks, with densification rates increasing in the order: graphene < silicene < germanene. The yield strength of the pure copper paste was 2.41 GPa and increased to 2.96, 4.39, and 5.46 GPa with graphene, silicene, and germanene, respectively, corresponding to gains of about 23%, 82%, and 127% relative to pure copper. Increasing the sintering temperature led to a monotonic increase in the tensile strength of the germanene composite, with the highest value being obtained at 650 K. Dislocation and stress field analyses revealed that silicene and germanene strengthen the material by promoting pronounced plastic accommodation in neck regions, whereas graphene mainly redistributes strain along the interfaces and produces a more moderate increase in strength. These findings demonstrate that the strength and deformation mode of copper nano-solder joints can be effectively tuned by selecting the type of 2D filler and optimizing the sintering temperature. Full article
(This article belongs to the Section Advanced Nanomaterials and Nanotechnology)
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12 pages, 2619 KB  
Article
Effects of Al Element on the Microstructure and Properties of Sn-9Zn Solder Alloy
by Jiaojiao Yang, Yuanqi You, Gaohua Jiang and Caiju Li
Materials 2026, 19(6), 1159; https://doi.org/10.3390/ma19061159 - 16 Mar 2026
Viewed by 471
Abstract
The application of microalloying technology has significantly improved the mechanical properties, oxidation resistance, and corrosion resistance of the Sn-9Zn-xAl-series solder. The effects of Al addition on microstructural evolution and service-related performance of the solders were systematically investigated using a combination of characterization techniques, [...] Read more.
The application of microalloying technology has significantly improved the mechanical properties, oxidation resistance, and corrosion resistance of the Sn-9Zn-xAl-series solder. The effects of Al addition on microstructural evolution and service-related performance of the solders were systematically investigated using a combination of characterization techniques, including scanning electron microscopy/energy-dispersive X-ray spectroscopy (SEM/EDX), differential scanning calorimetry (DSC), tensile testing, spreading testing, thermogravimetry (TG), and potentiodynamic polarization measurements. Microstructural characterization reveals that an optimal content of Al reacts with the Sn-Zn matrix to form AlZnSn intermetallic compounds (IMCs), which effectively refines the Zn-rich precipitates and eutectic lamellar structure. Concomitantly, the formation of second-phase strengthening contributes to a significant enhancement in the tensile strength of the solder alloys. Specifically, the Sn-9Zn-0.8Al solder exhibits a tensile strength of 87 MPa, corresponding to a 37% increment compared to the base Sn-9Zn alloy, whereas the elongation is reduced to 14.1%. Moreover, the in situ-formed Al2O3 passive film provides effective protection for the solder matrix, inhibiting oxidation induced by oxygen atoms and corrosion caused by chlorine ions, thereby remarkably improving the oxidation and corrosion resistance of the alloy. Collectively, these findings demonstrate that Al microalloying can substantially enhance the strength, oxidation resistance, and corrosion resistance of Sn-9Zn solder; however, a trade-off between wettability and ductility needs to be carefully considered for practical applications. Full article
(This article belongs to the Section Metals and Alloys)
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16 pages, 2588 KB  
Article
Prediction of Activity of Au-Sn-Based Lead-Free Solder Using Modified Molecular Interaction Volume Model
by Hai Wu, Liangliang Chen, Liguo Zhu, Lingxin Kong, Ganggang Liu, Bin Yang and Yong Deng
Metals 2026, 16(3), 330; https://doi.org/10.3390/met16030330 - 16 Mar 2026
Viewed by 340
Abstract
Controlling thermodynamic properties is critical for the rational design and development of advanced lead-free solders, especially in high-temperature applications. Au–Sn-based alloys have emerged as promising candidates for high-performance electronic packaging, yet reliable thermodynamic descriptions of their multicomponent systems remain limited. The Modified Molecular [...] Read more.
Controlling thermodynamic properties is critical for the rational design and development of advanced lead-free solders, especially in high-temperature applications. Au–Sn-based alloys have emerged as promising candidates for high-performance electronic packaging, yet reliable thermodynamic descriptions of their multicomponent systems remain limited. The Modified Molecular Interaction Volume Model (M-MIVM) provides a effective approach for characterizing strongly asymmetric liquid alloys that are typical in Au–Sn-based systems. This work focuses on the thermodynamic modeling of Au–Sn-containing ternary and quaternary solder systems within a physically consistent and computationally efficient framework. The study aims to support the database development, composition design, and optimization of next-generation high-temperature lead-free solders. Full article
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77 pages, 14413 KB  
Review
Welding Techniques and Microstructural Control for Dissimilar Cu/Al Joints
by Dong Jin, Juan Pu, Xiaohui Shi, Xiangping Xu, Zhaoqi Zhang and Fei Long
Crystals 2026, 16(3), 172; https://doi.org/10.3390/cryst16030172 - 2 Mar 2026
Viewed by 1629
Abstract
Welding copper (Cu) and aluminum (Al) is highly demanded for lightweight and cost-effective manufacturing. However, it faces significant challenges. First, substantial differences in physical properties may lead to high residual stresses and distortion. Second, brittle intermetallic compounds (IMCs) readily form at the interface, [...] Read more.
Welding copper (Cu) and aluminum (Al) is highly demanded for lightweight and cost-effective manufacturing. However, it faces significant challenges. First, substantial differences in physical properties may lead to high residual stresses and distortion. Second, brittle intermetallic compounds (IMCs) readily form at the interface, severely compromising the joint’s mechanical properties and electrical conductivity. Third, the native oxide film on Al impedes effective wetting and bonding. Therefore, effective control over the interfacial microstructure of the welded joint is essential. This review provides a critical analysis and comparison of several typical welding techniques, including laser welding (LW), friction stir welding (FSW), ultrasonic welding (UW), brazing and soldering, and welding–brazing. These analyses focus on their process characteristics, joint microstructures, and corresponding formation mechanisms. Furthermore, this review synthesizes key strategies for enhancing joint quality, including process parameter optimization, introduction of functional interlayers, and external assistance, aimed at optimizing joint microstructure and minimizing defects. Based on the analysis, this work provides comparative insights into process selection and microstructure control, and highlights future directions: advancing novel methods such as magnetic pulse welding and transient liquid phase bonding; developing intelligent real-time process control to suppress brittle IMCs and associated defects; promoting sustainable practices and establishing standardized performance evaluation; and systematically investigating long-term reliability to support the industrial application of robust Cu/Al joints. Full article
(This article belongs to the Special Issue Surface Modification Treatments of Metallic Materials (2nd Edition))
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23 pages, 8890 KB  
Article
Anand Model and Finite Element Analysis of Sn-0.3Ag-0.7Cu-3Bi Lead-Free Solder Joints in BGA Packages
by Junchen Liu, Abdullah Aziz Saad, Yuezong Zheng, Hongchao Ji and Zuraihana Bachok
Materials 2026, 19(3), 636; https://doi.org/10.3390/ma19030636 - 6 Feb 2026
Viewed by 1014
Abstract
Bi-doped low-silver Sn-Ag-Cu solders are increasingly gaining attention in advanced electronic packaging due to their cost-effectiveness and enhanced mechanical properties. However, the thermo-mechanical reliability mechanisms of such modified solders, particularly Sn-0.3Ag-0.7Cu-3Bi (SAC0307-3Bi) within Ball Grid Array (BGA) assemblies, remain insufficiently understood. To address [...] Read more.
Bi-doped low-silver Sn-Ag-Cu solders are increasingly gaining attention in advanced electronic packaging due to their cost-effectiveness and enhanced mechanical properties. However, the thermo-mechanical reliability mechanisms of such modified solders, particularly Sn-0.3Ag-0.7Cu-3Bi (SAC0307-3Bi) within Ball Grid Array (BGA) assemblies, remain insufficiently understood. To address this gap, this research proposes a comprehensive assessment framework integrating constitutive parameter calibration with finite element analysis (FEA) to accurately characterize the mechanical behavior and fatigue durability of SAC0307-3Bi solder joints under cyclic thermal loads. The Anand viscoplastic parameters were first calibrated via the Norton creep law and virtual tensile tests. Subsequently, a 3D quarter-symmetry model was constructed to replicate thermal cycling conditions between 25 °C and 125 °C. Simulation data reveal a strong correlation between stress concentration and the Distance to Neutral Point (DNP), pinpointing the chip-side interface of the corner joint as the critical failure site. Moreover, creep strain was observed to accrue in a “step-wise” pattern, predominantly during the heating and cooling ramps, reflecting distinct temperature sensitivity. Utilizing the Syed model, the fatigue life was estimated at approximately 2239 cycles. These insights serve as a crucial benchmark for designing robust packages using Bi-doped, low-silver lead-free solders. Full article
(This article belongs to the Special Issue Research on Metal Cutting, Casting, Forming, and Heat Treatment)
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16 pages, 9806 KB  
Article
Structure and Properties of Stainless Steel–Thermoplastic Joints Made Using Resistance Element Soldering Technology
by Pavol Sejč, Pavol Švec, Peter Gogola, Branislav Vanko, Zuzana Gábrišová, Alexander Schrek and Miroslav Zelina
Metals 2026, 16(1), 6; https://doi.org/10.3390/met16010006 - 20 Dec 2025
Viewed by 703
Abstract
This study investigated the microstructure and properties of soldered joints of AISI 304 stainless steel and PMMA thermoplastic or AW-1050A aluminum alloys made using Resistance Element Soldering (RES) technology. The bimetallic element used in RES provided a mechanical joint with a thermoplastic or [...] Read more.
This study investigated the microstructure and properties of soldered joints of AISI 304 stainless steel and PMMA thermoplastic or AW-1050A aluminum alloys made using Resistance Element Soldering (RES) technology. The bimetallic element used in RES provided a mechanical joint with a thermoplastic or aluminum alloy and a soldered joint with AISI 304 steel using Sn60Pb40 solder in the core of the element. The solder in combination with the Chemet CHM-A-014 flux wetted the AISI 304 steel surface very well at a temperature of 225 °C with a contact angle of 14°. During the production of the joints, the solder melted in the bimetallic element on the AISI 304 steel side, while solid solder was retained at the point of contact with the welding electrode. The strength of the joints ranged from 25.5 to 36.4 MPa, which was less than the strength of the solder, and the joints failed at the AISI 304 steel–Sn60Pb40 solder interface. The fracture surface was predominantly formed by the solder. An intermetallic phase of FeSn2 was identified at the interface. Full article
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9 pages, 3241 KB  
Proceeding Paper
Finite Element Simulation of Surface-Mount Resistor Solder Joint Quarter Models Under Thermomechanical Loading
by Yashveer Dunputh, Norbert Kiss, Matthew Joshua Sandy, Dániel Székely, Mahmud M. D. Firoz and Antal Bakonyi
Eng. Proc. 2025, 113(1), 50; https://doi.org/10.3390/engproc2025113050 - 11 Nov 2025
Viewed by 620
Abstract
Virtual lifetime estimation is growing in importance, as replacing physical tests by simulations leads to cost reductions in the development of microelectronics assemblies. However, the predictions made by fatigue models often differ significantly from the lifetimes recorded in physical tests. Tuning these models [...] Read more.
Virtual lifetime estimation is growing in importance, as replacing physical tests by simulations leads to cost reductions in the development of microelectronics assemblies. However, the predictions made by fatigue models often differ significantly from the lifetimes recorded in physical tests. Tuning these models is not straightforward, and results are often accurate only in specific test cases. Deviations may arise from manufacturing tolerances in the soldering process which can lead to deviations in the solder joint geometry. These include variations in the size of the copper pad area or in the volume of solder material. These factors, which have impacts on estimated lifetimes, are not fully understood. This paper assesses the impact of solder geometry in parallel with that of thermal cycling properties on estimated lifetimes. It is demonstrated that the shape and thermocycling properties of the solder joint significantly affect the thermomechanical lifetimes of surface-mounted resistors. Full article
(This article belongs to the Proceedings of The Sustainable Mobility and Transportation Symposium 2025)
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14 pages, 2248 KB  
Article
Effect of Laser Scanning Parameters on Surface Morphology and Topography of Glass Solder-Coated Zirconia Substrate
by Fiona Hartung, Christian Moss, Hermann Seitz and Georg Schnell
J. Funct. Biomater. 2025, 16(9), 324; https://doi.org/10.3390/jfb16090324 - 3 Sep 2025
Cited by 1 | Viewed by 1342
Abstract
Surface roughness and morphology, along with surface chemistry, are key features for improving ingrowth behavior and combating peri-implantitis after the insertion of dental implants. Using femtosecond laser texturing, this study aims to control both morphological and topographical surface properties of a glass solder [...] Read more.
Surface roughness and morphology, along with surface chemistry, are key features for improving ingrowth behavior and combating peri-implantitis after the insertion of dental implants. Using femtosecond laser texturing, this study aims to control both morphological and topographical surface properties of a glass solder coating on a zirconia substrate for dental applications. Experiments with varying laser and scanning parameters on the upper glass solder layer show the occurrence of two different surface morphologies. On the one hand, periodic wave-like structures are generated at relatively low pulse energy, with a high scanning pulse overlap of 80 to 90% and a scanning line overlap of 50%. On the other hand, a cauliflower-like structure can be observed at high pulse energies and a line overlap of up to 90%. Both surface morphologies represent a potential way to modify the glass solder surface to customize hard- and soft-tissue ingrowth, while realizing anti-adhesive properties for pathogenic bacteria in dental applications. Full article
(This article belongs to the Special Issue Advanced Technologies for Processing Functional Biomaterials)
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19 pages, 5923 KB  
Article
Microstructure and Properties of Bi-Sn, Bi-Sn-Sb, and Bi-Sn-Ag Solder Alloys for Electronic Applications
by Andrei-Alexandru Ilie, Florentina Niculescu, Gheorghe Iacob, Ion Pencea, Florin Miculescu, Robert Bololoi, Dumitru-Valentin Drăguț, Alexandru-Cristian Matei, Mihai Ghiţă, Adrian Priceputu and Constantin Ungureanu
Metals 2025, 15(8), 915; https://doi.org/10.3390/met15080915 - 18 Aug 2025
Cited by 6 | Viewed by 4314
Abstract
The Bi-Sn, Bi-Sn-Ag, and Bi-Sn-Sb solder alloy systems represent lead-free, environmentally friendly alternatives for reliable electronic assembly. These alloys comply with increasingly strict environmental and health regulations, while offering low melting points suitable for soldering temperature-sensitive components. Microstructural analysis revealed distinct phase segregation [...] Read more.
The Bi-Sn, Bi-Sn-Ag, and Bi-Sn-Sb solder alloy systems represent lead-free, environmentally friendly alternatives for reliable electronic assembly. These alloys comply with increasingly strict environmental and health regulations, while offering low melting points suitable for soldering temperature-sensitive components. Microstructural analysis revealed distinct phase segregation in all alloys, with Sb promoting coarse Sn2Sb3 intermetallic compounds and Ag inducing fine needle-like Ag3Sn precipitates. Eutectic refinement and compositional contrast were confirmed by SEM-BSE and EDS mapping. Vickers microhardness measurements revealed increased hardness in Sb- and Ag-modified Bi–Sn alloys, with Ag3Sn dispersion yielding the highest strengthening effect, indicating enhanced mechanical potential. This study also reports the thermal and electrical conductivities of Bi60Sn40, Bi60Sn35Ag5, and Bi60Sn35Sb5 alloys over the 25–140 °C range. Bi60Sn40 showed an increase in thermal conductivity across the full temperature range from 16.93 to 26.93 W/m·K, while Bi60Sn35Ag5 reached 18.28 W/m·K at 25 °C, and Bi60Sn35Sb5 exhibited 13.90 W/m·K. These findings underline the critical influence of alloying elements on microstructure, phase stability, and thermophysical behavior, supporting their application in low-temperature soldering technologies. Full article
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19 pages, 6626 KB  
Article
Evaluation of the Quality of Welded Joints After Repair of Automotive Frame Rails
by Andrzej Augustynowicz, Mariusz Prażmowski, Wiktoria Wilczyńska and Mariusz Graba
Materials 2025, 18(16), 3849; https://doi.org/10.3390/ma18163849 - 16 Aug 2025
Viewed by 1451
Abstract
Passenger cars have unibody constructions, which means that their collision damage often involves key structural components. Successful repair requires the selection of appropriate technology and adherence to quality standards, which directly affects the safety of the vehicle’s continued operation. A commonly used method [...] Read more.
Passenger cars have unibody constructions, which means that their collision damage often involves key structural components. Successful repair requires the selection of appropriate technology and adherence to quality standards, which directly affects the safety of the vehicle’s continued operation. A commonly used method is a system of replacing damaged components with new ones, while repair by molding and forming is also possible—provided the original structural features are preserved. Automotive body repairs require advanced welding techniques and high precision. Methods such as MIG, TIG, as well as brazing and soldering have replaced older techniques, providing more efficient joining of HSS and HSLA components. Maintaining quality workmanship is crucial, as repair errors can weaken a vehicle’s structure and compromise passenger safety. This article presents the results of a study on the evaluation of the quality, microstructure, and mechanical properties of welded joints of a passenger car frame rail section made of high-strength, low-alloy steel—HSLA 320. The joints were made by three welding methods: MMA, MAG, and TIG, using different technological parameters. Microstructural analysis, non-destructive testing, and microhardness measurements made it possible to assess the impact of the chosen technology on the quality and strength of the joints. The best results were obtained for the TIG method, characterized by the highest repeatability and precision. Full article
(This article belongs to the Section Mechanics of Materials)
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16 pages, 4578 KB  
Article
Corrosion Behavior Analysis of Novel Sn-2.5Ag-1.0Bi-0.8Cu-0.05Ni and Sn-1.8Bi-0.75Cu-0.065Ni Pb-Free Solder Alloys via Potentiodynamic Polarization Test
by Sang Hoon Jung and Jong-Hyun Lee
Metals 2025, 15(6), 670; https://doi.org/10.3390/met15060670 - 17 Jun 2025
Cited by 2 | Viewed by 1983
Abstract
The corrosion behaviors of newly developed solder alloys with excellent mechanical properties, Sn-2.5 Ag-1.0 Bi-0.8 Cu-0.05 Ni (SABC25108N) and Sn-1.5 Bi-0.75 Cu-0.065 Ni (SBC15075N), are analyzed to supplement the corrosion behavior of the limited corrosion data in Pb- and Zn-free solder compositions. A [...] Read more.
The corrosion behaviors of newly developed solder alloys with excellent mechanical properties, Sn-2.5 Ag-1.0 Bi-0.8 Cu-0.05 Ni (SABC25108N) and Sn-1.5 Bi-0.75 Cu-0.065 Ni (SBC15075N), are analyzed to supplement the corrosion behavior of the limited corrosion data in Pb- and Zn-free solder compositions. A potentiodynamic polarization test is conducted on these compositions in a NaCl electrolyte solution, the results of which are compared with those of conventional Sn-3.0 (wt%) Ag-0.5Cu and Sn-1.2Ag-0.5Cu-0.05Ni alloys. The results indicate that SBC15075N exhibits the lowest corrosion potential and highest corrosion current density, thus signifying the lowest corrosion resistance. By contrast, SABC25108N exhibits the lowest corrosion current density and highest corrosion resistance. Notably, SABC25108N shows a slower corrosion progression in the active state and exhibits the longest passive state. The difference in corrosion resistance is affected more significantly by the formation and distribution of the Ag3Sn intermetallic compound phase owing to the high Ag content instead of by the presence of Bi or Ni. This uniform dispersion of Ag3Sn IMC phases in the SABC25108N alloy effectively suppressed corrosion propagation along the grain boundaries and reduced the formation of corrosion products, such as Sn3O(OH)2Cl2, thereby enhancing the overall corrosion resistance. These findings provide valuable insights into the optimal design of solder alloys and highlight the importance of incorporating sufficient Ag content into multicomponent compositions to improve corrosion resistance. Full article
(This article belongs to the Special Issue New Welding Materials and Green Joint Technology—2nd Edition)
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20 pages, 16156 KB  
Article
Impact of Annealing Treatment on the Microstructure and Micromechanical Properties of Pb-Containing and Pb-Free Solder Alloys
by Wen Jiang, Changwei Wang, Kangning Han, Yaxin Zhu, Chuantao Hou and Ruisi Xing
Materials 2025, 18(11), 2596; https://doi.org/10.3390/ma18112596 - 2 Jun 2025
Cited by 5 | Viewed by 1404
Abstract
This study investigates the microstructural changes and micromechanical responses of Pb-containing and Pb-free solder alloys subjected to various annealing conditions, with the goal of elucidating the relationship between microstructure evolution and micromechanical properties. Results indicate that grain size in SAC0307 and SAC305 significantly [...] Read more.
This study investigates the microstructural changes and micromechanical responses of Pb-containing and Pb-free solder alloys subjected to various annealing conditions, with the goal of elucidating the relationship between microstructure evolution and micromechanical properties. Results indicate that grain size in SAC0307 and SAC305 significantly increases with annealing temperature, while that of Sn63Pb37 remains relatively stable. In Sn63Pb37, the Pb-rich phase coarsens and its area fraction increases with higher annealing temperatures, whereas in SAC0307, the intermetallic compounds (IMCs) phase coarsens but its area fraction decreases. Nano-indentation tests show that the hardness of Sn63Pb37 significantly increases with rising annealing temperature, whereas the hardness of SAC0307 decreases, and that of SAC305 remains relatively unchanged. These variations in these alloys induced by annealing are closely related to the changes in the hardness of individual phases within the grains. For Sn63Pb37, higher annealing temperatures increase the hardness of both the Sn matrix and Pb-rich phases, enhancing overall hardness. Conversely, in SAC0307, increased temperatures reduced the hardness of both the Sn matrix and IMCs phases, resulting in lower overall hardness. The differing trends in mechanical property of individual phases in three alloy are attributed to their distinct evolutions under annealing treatment. This study provides insights into the micromechanical behavior of solder alloys under annealing and offers guidance for optimizing their performance. Full article
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22 pages, 14262 KB  
Article
Comparison of the Self-Healing Behaviour of 60Sn40Pb and 99.3Sn0.7Cu Solder Alloy Reinforced Al6061 MMCs’
by Subrahmanya Ranga Viswanath Mantha, Gonal Basavaraja Veeresh Kumar, Ramakrishna Pramod, Chilakalapalli Surya Prakasha Rao, Mohd Shahneel Saharudin and Santosh Kumar Sahu
J. Manuf. Mater. Process. 2025, 9(5), 141; https://doi.org/10.3390/jmmp9050141 - 24 Apr 2025
Viewed by 1882
Abstract
The self-healing characteristics of Al6061 reinforced with CuO have been examined experimentally. The solder alloys 60Pb40Sn and 99.3Sn0.7Cu with low melting points are incorporated to strengthen the Al6061 MMCs’; the self-healing properties have been investigated. Developed self-healing samples have undergone testing for hardness, [...] Read more.
The self-healing characteristics of Al6061 reinforced with CuO have been examined experimentally. The solder alloys 60Pb40Sn and 99.3Sn0.7Cu with low melting points are incorporated to strengthen the Al6061 MMCs’; the self-healing properties have been investigated. Developed self-healing samples have undergone testing for hardness, tensile, and impact characteristics in accordance with ASTM standard test protocols. The findings demonstrate how the solder filling affects the mechanical characteristics of self-healed Al6061 alloy and its MMCs’. The results showed that the composites formed a decent bond between the solder and matrix, confirming successful fabrication. Pb-Sn filled samples demonstrated higher self-healing efficiency for tensile and impact of 90.02% and 90.30% with 6 wt.% of CuO, respectively, and Sn-Cu filled samples witnessed higher self-healing efficiency for tensile and impact of 91.81% and 91.09% with 6 wt.% of CuO respectively. However, the self-healed composite did not split in two when subjected to Charpy impact and tensile strength tests, and the healing efficiency of Sn-Cu-filled composites is higher than that of the Pb-Sn-filled composites. Full article
(This article belongs to the Special Issue Advances in Dissimilar Metal Joining and Welding)
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