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Keywords = short-glass fiber reinforced composite

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12 pages, 6639 KiB  
Article
Study of Space Micro Solid Thruster Using 3D-Printed Short Glass Fiber Reinforced Polyamide
by Haibo Yang, Zhongcan Chen, Xudong Yang, Chang Xu and Hanyu Deng
Aerospace 2025, 12(8), 663; https://doi.org/10.3390/aerospace12080663 - 26 Jul 2025
Viewed by 229
Abstract
To meet the rapid maneuverability and lightweight demands of micro-nano satellites, a space micro solid thruster using 3D-printed short glass fiber reinforced polyamide 6 (PA6GF) composites was developed. Thruster shells with wall thicknesses of 4, 3, and 2.5 mm were designed, and ground [...] Read more.
To meet the rapid maneuverability and lightweight demands of micro-nano satellites, a space micro solid thruster using 3D-printed short glass fiber reinforced polyamide 6 (PA6GF) composites was developed. Thruster shells with wall thicknesses of 4, 3, and 2.5 mm were designed, and ground ignition tests were conducted to monitor chamber pressure and shell temperature. Compared with conventional metallic thrusters, PA6GF composites have exhibited excellent thermal insulation and sufficient mechanical strength. Under 8 MPa and 2773 K ignition conditions, the shell thickness was reduced to 2.5 mm and could withstand pressures up to 10.37 MPa. These results indicate that PA6GF composites are well-suited for space micro solid thrusters with inner diameters of 15–70 mm, offering new possibilities for lightweight space propulsion system design. Full article
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36 pages, 2504 KiB  
Article
Long-Term Durability of CFRP Strips Used in Infrastructure Rehabilitation
by Karunya Kanagavel and Vistasp M. Karbhari
Polymers 2025, 17(13), 1886; https://doi.org/10.3390/polym17131886 - 7 Jul 2025
Viewed by 487
Abstract
Prefabricated unidirectional carbon fiber reinforced polymer (CFRP) composite strips are extensively used as a means of infrastructure rehabilitation through adhesive bonding to the external surface of structural concrete elements. Most data to date are from laboratory tests ranging from a few months to [...] Read more.
Prefabricated unidirectional carbon fiber reinforced polymer (CFRP) composite strips are extensively used as a means of infrastructure rehabilitation through adhesive bonding to the external surface of structural concrete elements. Most data to date are from laboratory tests ranging from a few months to 1–2 years providing an insufficient dataset for prediction of long-term durability. This investigation focuses on the assessment of the response of three different prefabricated CFRP systems exposed to water, seawater, and alkaline solutions for 5 years of immersion in deionized water conducted at three temperatures of 23, 37.8 and 60 °C, all well below the glass transition temperature levels. Overall response is characterized through tensile and short beam shear (SBS) testing at periodic intervals. It is noted that while the three systems are similar, with the dominant mechanisms of deterioration being related to matrix plasticization followed by fiber–matrix debonding with levels of matrix and interface deterioration being accelerated at elevated temperatures, their baseline characteristics and distributions are different emphasizing the need for greater standardization. While tensile modulus does not degrade appreciably over the 5-year period of exposure with final levels of deterioration being between 7.3 and 11.9%, both tensile strength and SBS strength degrade substantially with increasing levels based on temperature and time of immersion. Levels of tensile strength retention can be as low as 61.8–66.6% when immersed in deionized water at 60 °C, those for SBS strength can be 38.4–48.7% at the same immersion condition for the three FRP systems. Differences due to solution type are wider in the short-term and start approaching asymptotic levels within FRP systems at longer periods of exposure. The very high levels of deterioration in SBS strength indicate the breakdown of the materials at the fiber–matrix bond and interfacial levels. It is shown that the level of deterioration exceeds that presumed through design thresholds set by specific codes/standards and that new safety factors are warranted in addition to expanding the set of characteristics studied to include SBS or similar interface-level tests. Alkali solutions are also shown to have the highest deteriorative effects with deionized water having the least. Simple equations are developed to enable extrapolation of test data to predict long term durability and to develop design thresholds based on expectations of service life with an environmental factor of between 0.56 and 0.69 for a 50-year expected service life. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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19 pages, 2511 KiB  
Article
Exploring the Thermal and Mechanical Properties of Thermoset-Based Composites Reinforced with New Continuous and Chopped Phosphate Glass Fibers
by Iliass Daki, Nezha Saloumi, Mohamed Yousfi, Caroline Parajua-sejil, Vivien Truchot, Jean-François Gérard, Omar Cherkaoui, Hassan Hannache, Mehdi El Bouchti and Mina Oumam
Polymers 2025, 17(12), 1627; https://doi.org/10.3390/polym17121627 - 11 Jun 2025
Viewed by 1208
Abstract
Currently, the main drivers for the production of phosphate glass fiber-reinforced composites are the growing demand for lightweight materials, reduced energy consumption, improved durability, and minimized environmental impact. This study aims to develop thermoset-based composites using chopped and continuous phosphate glass fibers (PGFs) [...] Read more.
Currently, the main drivers for the production of phosphate glass fiber-reinforced composites are the growing demand for lightweight materials, reduced energy consumption, improved durability, and minimized environmental impact. This study aims to develop thermoset-based composites using chopped and continuous phosphate glass fibers (PGFs) combined with polyester and epoxy matrices, processed via contact molding. Physical, mechanical, thermal, and morphological characterizations were conducted. The addition of PGFs led to a steady increase in density and fiber volume fraction. For polyester composites with short PGFs, density rose from 1.60 g/cm3 (0 wt%) to 1.77 g/cm3 (22.8 wt%), with a corresponding volume fraction increase from 0% to 14.4%. Similarly, epoxy composites showed density values from 1.70 g/cm3 to 1.87 g/cm3 and volume fractions up to 15.2%. Thermogravimetric analysis (TGA) showed that as the fiber content increased, the thermal degradation of the resin was delayed, as evidenced by a rise in onset degradation temperature and greater residual mass—indicating improved thermal stability of the composites. Tensile strength increased from 20.8 MPa to 71.3 MPa (polyester) and from 26.8 MPa to 75.9 MPa (epoxy) with chopped fibers, reaching 145.7 MPa and 187.9 MPa, respectively, with continuous fibers. Flexural strength reached 167.9 MPa (polyester) and 218.0 MPa (epoxy) in continuous-fiber configurations. Young’s modulus values closely matched Hirsch model predictions. These findings confirm the potential of PGF-reinforced thermoset composites for high-performance and sustainable material applications. Full article
(This article belongs to the Section Polymer Fibers)
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25 pages, 12421 KiB  
Article
Fluid–Structure Interaction of a Darrieus-Type Hydrokinetic Turbine Modified with Winglets
by Emerson Escobar Nunez, Diego García González, Omar Darío López, Juan Pablo Casas Rodríguez and Santiago Laín
J. Mar. Sci. Eng. 2025, 13(3), 548; https://doi.org/10.3390/jmse13030548 - 12 Mar 2025
Viewed by 754
Abstract
The growing demand for electricity in developing countries has called attention and interest to renewable energy sources to mitigate the adverse environmental effects caused by energy generation through fossil fuels. Among different renewable energy sources, such as photovoltaic, wind, and biomass, hydraulic energy [...] Read more.
The growing demand for electricity in developing countries has called attention and interest to renewable energy sources to mitigate the adverse environmental effects caused by energy generation through fossil fuels. Among different renewable energy sources, such as photovoltaic, wind, and biomass, hydraulic energy represents an attractive solution to address the demand for electricity in rural areas of Colombia that are not connected to the electrical grid. In the current paper, the fluid–structure interaction (FSI) of a recently designed Vertical-Axis Hydrokinetic Turbine (VAHT) Straight-Bladed (SB) Darrieus-type, modified with symmetric winglets, was studied by implementing the sliding mesh method (SMM). By coupling with Computational Fluid Dynamics (CFD) numerical simulations, the FSI study demonstrated that the hydrodynamic loads obtained can cause potential fatigue damage in the blades of the Straight-Bladed (SB) Darrieus VAHT. Fatigue life was assessed using the stress–life (S-N) approach, and materials such as structural steel, short glass fiber reinforced composites (SGFRC), and high-performance polymers (HPP), such as PEEK, were studied as potential materials for the construction of the blades. FSI results showed that the biaxiality index (BI) provides a good understanding of the dominant stresses in the blades as the azimuth angle changes. It was also shown that structural steel and PEEK are good materials for the manufacturing of the blades, both from a fatigue resistance and modal perspective. Full article
(This article belongs to the Section Marine Energy)
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15 pages, 8198 KiB  
Article
Differential Effects of Adding Graphene Nanoplatelets on the Mechanical Properties and Crystalline Behavior of Polypropylene Composites Reinforced with Carbon Fiber or Glass Fiber
by Hiroki Satoh, Ayumu Morita and Yoshihiko Arao
Materials 2025, 18(5), 926; https://doi.org/10.3390/ma18050926 - 20 Feb 2025
Cited by 2 | Viewed by 711
Abstract
Short fiber-reinforced thermoplastic composites (SFRTPs) have excellent recyclability and processability, but their mechanical properties are weak compared to continuous fiber products. Various studies have reported that the addition of GNPs improves the mechanical properties of SFRTPs, but it is unclear what effect different [...] Read more.
Short fiber-reinforced thermoplastic composites (SFRTPs) have excellent recyclability and processability, but their mechanical properties are weak compared to continuous fiber products. Various studies have reported that the addition of GNPs improves the mechanical properties of SFRTPs, but it is unclear what effect different types of reinforcing fibers have on a hybrid composite system. In this study, the effect of adding a small amount (1 wt%) of graphene nanoplatelets (GNPs) to fiber-reinforced polypropylene composites on their mechanical properties was investigated from a crystallinity perspective. GNPs were mixed with polypropylene (PP)/carbon fiber (CF) or PP/glass fiber (GF) using a melt blending process, and composites were molded by injection molding. The results of mechanical property characterization showed no significant effect when GNPs were added to PP/CF, but when GNPs were added to PP/GF, this increased the composite’s tensile strength and Young’s modulus by approximately 20% and 10%, respectively. The interfacial shear strength (IFSS) predicted using the modified Kelly–Tyson equation did not change much before and after the addition of GNPs to PP/CF. On the other hand, the IFSS increased from 10.8 MPa to 19.2 MPa with the addition of GNPs to PP/GF. The increase in IFSS led to an increase in the tensile strength of PP/GF with the incorporation of GNPs. Differential scanning calorimetry (DSC) indicated that GNPs accelerated the crystallization rate, and the X-ray diffraction (XRD) results confirmed that GNPs acted as a crystal nucleating agent. However, CF was also shown to be a nucleating agent, limiting the effect of GNP addition. In other words, it can be said that the addition of GNPs to PP/GF is more effective than their addition to PP/CF due to the differential crystallization effects of each fiber. Full article
(This article belongs to the Special Issue Advanced Resin Composites: From Synthesis to Application)
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13 pages, 8060 KiB  
Article
Research on the Quality of Composite Pipe Components in Fluid-Powered Projectile-Assisted Injection Molding
by Tangqing Kuang, Chuixin Kong, Hesheng Liu and Fan Yang
Polymers 2025, 17(4), 489; https://doi.org/10.3390/polym17040489 - 13 Feb 2025
Viewed by 775
Abstract
Composite pipe fittings with an outer layer of 20% long glass fiber-reinforced polypropylene (LGFR-PP) and an inner layer of polypropylene (PP) were prepared via water-powered projectile-assisted co-injection molding short-shot (W-PACIM-S), water-powered projectile-assisted co-injection molding overflow (W-PACIM-O), gas-powered projectile-assisted co-injection molding short-shot (G-PACIM-S), and [...] Read more.
Composite pipe fittings with an outer layer of 20% long glass fiber-reinforced polypropylene (LGFR-PP) and an inner layer of polypropylene (PP) were prepared via water-powered projectile-assisted co-injection molding short-shot (W-PACIM-S), water-powered projectile-assisted co-injection molding overflow (W-PACIM-O), gas-powered projectile-assisted co-injection molding short-shot (G-PACIM-S), and gas-powered projectile-assisted co-injection molding overflow (G-PACIM-O)techniques. The effects of different injection molding processes on the wall thickness, inner surface roughness, glass fiber orientation, and pressure resistance of pipe fittings were studied to evaluate the quality of the pipe fittings formed by each process. Compared with the short-shot method, the overflow method results in pipes with thinner walls in each layer, a more uniform distribution, smoother inner wall surfaces, and better orientation of glass fibers along the axial direction in the near boundary layer, resulting in better pressure resistance. Under the same injection method, the difference in fluid medium did not significantly change the trend of wall thickness variation in each layer. However, compared with gas, high-pressure water improves the uniformity of the pipe wall thickness and inner wall quality. In addition, the introduction of the warhead is more conducive to improving the degree of glass fiber orientation of the pipe fittings, and the thickness of the residual wall thickness of the pipe fittings has a great influence on the pressure resistance of the pipe fittings. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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19 pages, 13944 KiB  
Article
Fracture Resistance of Glass-Fiber-Reinforced Direct Restorations on Endodontically Treated Molar Teeth with Furcal Perforation
by Ecehan Hazar and Ahmet Hazar
Polymers 2025, 17(3), 370; https://doi.org/10.3390/polym17030370 - 29 Jan 2025
Cited by 2 | Viewed by 1409
Abstract
This in vitro study evaluated short-fiber-reinforced composite materials and fiber-reinforced restorations of endodontically treated molars with furcal perforation. The endodontic treatment and mesio-occlusal–distal cavity preparation of 126 two-rooted mandibular third molars were performed. Eighteen non-perforated teeth were restored with resin composite as the [...] Read more.
This in vitro study evaluated short-fiber-reinforced composite materials and fiber-reinforced restorations of endodontically treated molars with furcal perforation. The endodontic treatment and mesio-occlusal–distal cavity preparation of 126 two-rooted mandibular third molars were performed. Eighteen non-perforated teeth were restored with resin composite as the control group. Furcal perforations and repair were performed on 108 teeth that were divided into six experimental groups: resin composite (RC), everX Flow (EXF), everX Posterior (EXP), Bioblock (BB), modified transfixed (MT), and horizontal glass-fiber (HGF) groups (n = 18). Fracture resistance tests were performed at an angle of 30◦ using a universal testing machine under static loading, and fracture patterns were classified. Welch’s analysis of variance, Pearson chi-square, and Tamhane post hoc tests (p = 0.05) were used to analyze the data (p = 0.05). The highest fracture resistance values were seen with the HGF (596.305 N), followed by MT (540.365 N), BB (477.906 N), EXP (476.647 N), EXF (414.462 N), control (413.811 N), and RC (335.325 N) groups (p < 0.001). There was no significant difference between the BB and EXP groups or between the EXF and control groups (p > 0.05). In terms of the dominant fracture pattern, the HGF and MT groups were repairable and possibly repairable, whereas the control, RC, and EXP groups were unrepairable. The EXF and BB groups were almost equally divided between possibly repairable and unrepairable. Restorations using horizontal fiber techniques and short-fiber-reinforced materials increased the fracture resistance of endodontically treated teeth with furcal perforation. Full article
(This article belongs to the Special Issue High-Performance Fiber-Reinforced Polymer Composites)
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18 pages, 9183 KiB  
Article
Short-Glass-Fiber Aspect Ratios in Polyamide-6 Composites: Homogenization and Deep Learning-Based Scanning Image-Microscope Segmentation Comparison
by Evgenii Kurkin, Vladislava Chertykovtseva, Andry Sedelnikov, Evgenii Minaev, Ekaterina Kurkina and Andrey Gavrilov
Appl. Sci. 2024, 14(23), 11464; https://doi.org/10.3390/app142311464 - 9 Dec 2024
Cited by 1 | Viewed by 1601
Abstract
This paper presents a comparative analysis of fiber aspect ratios using scanning electron microscopy (SEM) and the mean field homogenization approach. The novelty of this work lies in an effective fiber length evaluation based on a comparative analysis of fiber aspect ratios using [...] Read more.
This paper presents a comparative analysis of fiber aspect ratios using scanning electron microscopy (SEM) and the mean field homogenization approach. The novelty of this work lies in an effective fiber length evaluation based on a comparative analysis of fiber aspect ratios using scanning electron microscopy (SEM) and the mean field homogenization approach. This makes it possible to use an electron microscope to image fiber samples corresponding to the sample size using microtomography. Molded samples and pellets of four polyamide-6 short-glass fiber-reinforced composites with mass fractions of 15%, 30%, and 50% were considered. The aspect ratio distribution measured by SEM for the investigated materials was 20.25 with a coefficient of variation of 5.1%. The fiber aspect ratio obtained based on mean field homogenization theory and the tensile curve approximation was underestimated at 13.698 with a coefficient of variation of 5.2%. The deviation between the micro- and macro-estimates can be represented as a mean effective aspect ratio of 68% with a coefficient of variation of 8.5%. The developed technology for preparing samples for SEM and automated image processing can be used to study other short-reinforced polymer composite materials. The obtained estimates can serve as a useful reference when calibrating other models of short-fiber-reinforced polymer materials. Full article
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13 pages, 3036 KiB  
Article
On the Hydrodynamic and Structural Performance of Thermoplastic Composite Ship Propellers Produced by Additive Manufacturing Method
by Erkin Altunsaray, Serkan Turkmen, Ayberk Sözen, Alperen Doğru, Pengfei Liu, Akile Neşe Halilbeşe and Gökdeniz Neşer
J. Mar. Sci. Eng. 2024, 12(12), 2206; https://doi.org/10.3390/jmse12122206 - 2 Dec 2024
Viewed by 1631
Abstract
In the marine industry, the search for sustainable methods, materials, and processes, from the product’s design to its end-of-life stages, is a necessity for combating the negative consequences of climate change. In this context, the lightening of products is essential in reducing their [...] Read more.
In the marine industry, the search for sustainable methods, materials, and processes, from the product’s design to its end-of-life stages, is a necessity for combating the negative consequences of climate change. In this context, the lightening of products is essential in reducing their environmental impact throughout their life. In addition to lightening through design, lightweight materials, especially plastic-based composites, will need to be used in new and creative ways. The material extrusion technique, one of the additive manufacturing methods, is becoming more widespread day by day, especially in the production of objects with complex forms. This prevalence has not yet been reflected in the marine industry. In this study, the performances of plastic composite propellers produced by the material extrusion technique is investigated and discussed comparatively with the help of both hydrodynamic and structural tests carried out in a cavitation tunnel and mechanical laboratory. The cavitation tunnel test and numerical simulations were conducted at a range of advance coefficients (J) from 0.3 to 0.9. The shaft rate was kept at 16 rps. The thrust and torque data were obtained using the tunnel dynamometer. Digital pictures were taken to obtain structural deformation and cavitation dynamics. The structural performance of the propellers shows that an aluminum propeller is the most rigid, while a short carbon fiber composite propeller is the most flexible. Continuous carbon fiber composite has high strength and stiffness, while continuous glass fiber composite is more cost-effective. In terms of the hydrodynamic performance of the propellers, flexibility reduces the loading on the blade, which can result in thrust and torque reduction. Overall, the efficiency of the composite propellers was similar and less than that of the rigid aluminum propeller. In terms of weight, the composite carbon propeller containing continuous fiber, which is half the weight of the metal propeller, is considered as an alternative to metal in production. These propellers were produced from a unique composite consisting of polyamide, one of the thermoplastics that is a sustainable composite material, and glass and carbon fiber as reinforcements. The findings showed that the manufacturing method and the new composites can be highly successful for producing ship components. Full article
(This article belongs to the Special Issue Marine Technology: Latest Advancements and Prospects)
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15 pages, 5505 KiB  
Article
Design and Characterization of Poly(ethylene oxide)-Based Multifunctional Composites with Succinonitrile Fillers for Ambient-Temperature Structural Sodium-Ion Batteries
by Vasan Iyer, Jan Petersen, Sebastian Geier and Peter Wierach
Polymers 2024, 16(19), 2806; https://doi.org/10.3390/polym16192806 - 3 Oct 2024
Cited by 2 | Viewed by 2184
Abstract
A new approach to developing structural sodium batteries capable of operating in ambient-temperature conditions has been successfully achieved. The developed multifunctional structural electrolyte (SE) using poly(ethylene oxide) (PEO) as a matrix integrated with succinonitrile (SN) plasticizers and glass-fiber (GF) reinforcements identified as GF_PEO-SN-NaClO [...] Read more.
A new approach to developing structural sodium batteries capable of operating in ambient-temperature conditions has been successfully achieved. The developed multifunctional structural electrolyte (SE) using poly(ethylene oxide) (PEO) as a matrix integrated with succinonitrile (SN) plasticizers and glass-fiber (GF) reinforcements identified as GF_PEO-SN-NaClO4 showed a tensile strength of 32.1 MPa and an ionic conductivity of 1.01 × 10−4 S cm−1 at room temperature. It displayed a wide electrochemical stability window of 0 to 4.9 V and a high sodium-ion transference number of 0.51 at room temperature. The structural electrode (CF|SE) was fabricated by pressing the structural electrolyte with carbon fibers (CFs), and it showed a tensile strength of 72.3 MPa. The fabricated structural battery half-cell (CF||SE||Na) demonstrated good cycling stability and an energy density of 14.2 Wh kg−1, and it retained 80% capacity at the end of the 200th cycle. The cycled electrodes were observed using scanning electron microscopy, which revealed small dendrite formation and dense albeit uniform deposition of the sodium metal, helping to avoid a short-circuit of the cell and providing more cycling stability. The developed multifunctional matrix composites demonstrate promising potential for developing ambient-temperature sodium structural batteries. Full article
(This article belongs to the Special Issue Multifunctional Polymer Composite Materials)
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10 pages, 713 KiB  
Article
Influence of Processing Parameters in Injection Molding on the Properties of Short Carbon and Glass Fiber Reinforced Polypropylene Composites
by Thomas Höftberger, Gernot Zitzenbacher and Christoph Burgstaller
Polymers 2024, 16(19), 2745; https://doi.org/10.3390/polym16192745 - 28 Sep 2024
Cited by 3 | Viewed by 1757
Abstract
Short-fiber reinforcement is a potent approach to improving the material properties of injection-molded parts. The main consideration in such reinforced materials is to preserve the fiber length, as this is the major influence on the properties of a given composite. The aim of [...] Read more.
Short-fiber reinforcement is a potent approach to improving the material properties of injection-molded parts. The main consideration in such reinforced materials is to preserve the fiber length, as this is the major influence on the properties of a given composite. The aim of this work was to investigate the different influencing parameters in injection molding processing on the properties of short carbon and glass fiber-reinforced polypropylene. We investigated parameters like melt temperature and back pressure, but also machine size and pre-heating regarding their influence on the tensile properties. We found that adjustments of melt temperature and back pressure only yield small improvements in the fiber length and the tensile properties, also depending on machine size, but a pre-heating step of the granules can significantly improve the properties. Full article
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20 pages, 15194 KiB  
Article
Effect of High Fiber Content on Properties and Performance of CFRTP Composites
by Saeed Ziaee, Eric Kerr-Anderson, Aaron Johnson, David Eastep and Beckry Abdel-Magid
J. Compos. Sci. 2024, 8(9), 364; https://doi.org/10.3390/jcs8090364 - 17 Sep 2024
Cited by 4 | Viewed by 2525
Abstract
Continuously reinforced thermoplastic composites are widely used in structural applications due to their toughness, light weight, and shorter process cycle. Moreover, they provide flexibility in design and material selection. Unlike thermoset composites, continuous fiber content to maximize mechanical properties in thermoplastic composites has [...] Read more.
Continuously reinforced thermoplastic composites are widely used in structural applications due to their toughness, light weight, and shorter process cycle. Moreover, they provide flexibility in design and material selection. Unlike thermoset composites, continuous fiber content to maximize mechanical properties in thermoplastic composites has not been well investigated. In this paper, three thermoplastic systems are investigated to study the optimum content of continuous fiber reinforcement. These systems include carbon fiber/polyphenylene sulfide (PPS), glass fiber/PPS, and glass fiber/high-density polyethylene (HDPE). Tapes were made at several fiber contents, and samples were compression molded and tested using thermo-gravimetric analysis (TGA), differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), tensile, 3-point flexure, and short-beam shear tests. Results revealed that higher fiber content led to an increase in the glass transition and melt transition temperatures of the polymer. Some mechanical properties increased with fiber content and then began to decrease upon further addition of fibers, while other properties, such as ductility and interfacial bond strength, decreased with more reinforcement. Furthermore, the optimum fiber contents to maximize mechanical properties are different for different properties and different materials. Full article
(This article belongs to the Special Issue Advances in Continuous Fiber Reinforced Thermoplastic Composites)
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18 pages, 6151 KiB  
Article
Enhancing the Fire Resistance of Ablative Materials: Role of the Polymeric Matrix and Silicon Carbide Reinforcement
by Juana Abenojar, Sara López de Armentia and Miguel Angel Martínez
Polymers 2024, 16(17), 2454; https://doi.org/10.3390/polym16172454 - 29 Aug 2024
Cited by 1 | Viewed by 1252
Abstract
The primary characteristic of ablative materials is their fire resistance. This study explored the development of cost-effective ablative materials formed into application-specific shapes by using a polymer matrix reinforced with ceramic powder. A thermoplastic (polypropylene; PP) and a thermoset (polyester; UPE) matrix were [...] Read more.
The primary characteristic of ablative materials is their fire resistance. This study explored the development of cost-effective ablative materials formed into application-specific shapes by using a polymer matrix reinforced with ceramic powder. A thermoplastic (polypropylene; PP) and a thermoset (polyester; UPE) matrix were used to manufacture ablative materials with 50 wt% silicon carbide (SiC) particles. The reference composites (50 wt% SiC) were compared to those with 1 and 3 wt% short glass fibers (0.5 mm length) and to composites using a 1 and 3 wt% glass fiber mesh. Fire resistance was tested using a butane flame (900 °C) and by measuring the transmitted heat with a thermocouple. Results showed that the type of polymer matrix (PP or UPE) did not influence fire resistance. Composites with short glass fibers had a fire-resistance time of 100 s, while those with glass fiber mesh tripled this resistance time. The novelty of this work lies in the exploration of a specific type of material with unique percentages of SiC not previously studied. The aim is to develop a low-cost coating for industrial warehouses that has improved fire-protective properties, maintains lower temperatures, and enhances the wear and impact resistance. Full article
(This article belongs to the Special Issue Flame-Retardant Polymer Composites II)
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22 pages, 40119 KiB  
Article
Improving the Tribological Performance of POM through the Incorporation of Bio-Based Materials
by Lucas M. Kneissl, Roberts Joffe, Mitjan Kalin and Nazanin Emami
Polymers 2024, 16(16), 2310; https://doi.org/10.3390/polym16162310 - 15 Aug 2024
Cited by 1 | Viewed by 1562
Abstract
Polyoxymethylene (POM), an engineering polymer commonly used in tribological applications, is often reinforced with fossil-based fibers such as carbon and/or glass fibers to improve its properties. To find more sustainable solutions, in this study, the tribological performance of POM/short cellulose fiber composites at [...] Read more.
Polyoxymethylene (POM), an engineering polymer commonly used in tribological applications, is often reinforced with fossil-based fibers such as carbon and/or glass fibers to improve its properties. To find more sustainable solutions, in this study, the tribological performance of POM/short cellulose fiber composites at different sliding conditions is investigated. An improvement in the wear coefficient of roughly 69% is observed at the harshest conditions of 5 MPa and 1 m · s−1 with only 10 wt.% cellulose fibers. The friction behavior is furthermore stabilized through fiber addition, as the unfilled polymer did not show a steady state. No signs of thermo-oxidative degradation are found after tribological testing. This study presents promising results for sustainable wear-resistant polymer materials in tribological applications. Full article
(This article belongs to the Special Issue Biodegradable Polymers for Sustainable Development)
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23 pages, 3480 KiB  
Article
Influence of Montmorillonite Organoclay Fillers on Hygrothermal Response of Pultruded E-Glass/Vinylester Composites
by Vistasp M. Karbhari
Polymers 2024, 16(15), 2157; https://doi.org/10.3390/polym16152157 - 29 Jul 2024
Cited by 1 | Viewed by 1028
Abstract
Pultruded fiber reinforced polymer composites used in civil, power, and offshore/marine applications use fillers as resin extenders and for process efficiency. Although the primary use of fillers is in the form of an extender and processing aid, the appropriate selection of filler can [...] Read more.
Pultruded fiber reinforced polymer composites used in civil, power, and offshore/marine applications use fillers as resin extenders and for process efficiency. Although the primary use of fillers is in the form of an extender and processing aid, the appropriate selection of filler can result in enhancing mechanical performance characteristics, durability, and multifunctionality. This is of special interest in structural and high voltage applications where the previous use of specific fillers has been at levels that are too low to provide these enhancements. This study investigates the use of montmorillonite organoclay fillers of three different particle sizes as substitutes for conventional CaCO3 fillers with the intent of enhancing mechanical performance and hygrothermal durability. The study investigates moisture uptake and kinetics and reveals that uptake is well described by a two-stage process that incorporates both a diffusion dominated initial phase and a second slower phase representing relaxation and deterioration. The incorporation of the organoclay particles substantially decreases uptake levels in comparison to the use of CaCO3 fillers while also enhancing stage I, diffusion, dominated stability, with the use of the 1.5 mm organoclay fillers showing as much as a 41.5% reduction in peak uptake as compared to the CaCO3 fillers at the same 20% loading level (by weight of resin). The mechanical performance was characterized using tension, flexure, and short beam shear tests. The organoclay fillers showed a significant improvement in each, albeit with differences due to particle size. Overall, the best performance after exposure to four different temperatures of immersion in deionized water was shown by the 4.8 mm organoclay filler-based E-glass/vinylester composite system, which was the only one to have less than a 50% deterioration over all characteristics after immersion for a year in deionized water at the highest temperature investigated (70 °C). The fillers not only enhance resistance to uptake but also increase tortuosity in the path, thereby decreasing the overall effect of uptake. The observations demonstrate that the use of the exfoliated organoclay particles with intercalation, which have been previously used in very low amounts, and which are known to be beneficial in relation to enhanced thermal stability, flame retardancy, and decreased flammability, provide enhanced mechanical characteristics, decreased moisture uptake, and increased hygrothermal durability when used at particle loading levels comparable to those of conventional fillers, suggesting that these novel systems could be considered for critical structural applications. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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