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Keywords = shallow-water hydrothermal activity

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28 pages, 5040 KiB  
Article
Formation and Evolution Mechanisms of Geothermal Waters Influenced by Fault Zones and Ancient Lithology in the Yunkai Uplift, Southern China
by Xianxing Huang, Yongjun Zeng, Shan Lu, Guoping Lu, Hao Ou and Beibei Wang
Water 2025, 17(13), 1885; https://doi.org/10.3390/w17131885 - 25 Jun 2025
Viewed by 462
Abstract
Geothermal systems play a crucial role in understanding Earth’s heat dynamics. The Yunkai Uplift in southern China exemplifies a geothermally rich region characterized by ancient lithologies and high heat flow. This study investigates the geochemical characteristics of geothermal waters in the Yunkai Uplift. [...] Read more.
Geothermal systems play a crucial role in understanding Earth’s heat dynamics. The Yunkai Uplift in southern China exemplifies a geothermally rich region characterized by ancient lithologies and high heat flow. This study investigates the geochemical characteristics of geothermal waters in the Yunkai Uplift. Both geothermal and non-thermal water samples were collected along the Xinyi–Lianjiang (XL) Fault Zone and the Cenxi–Luchuan (CL) Fault Zone flanking the core of the Yunkai Mountains. Analytical techniques were applied to examine major ions, trace elements, and dissolved CO2 and H2, as well as isotopic characteristics of O, H, Sr, C, and He in water samples, allowing for an investigation of geothermal reservoir temperatures, circulation depths, and mixing processes. The findings indicate that most geothermal waters are influenced by water–rock interactions primarily dominated by granites. The region’s diverse lithologies, change from ancient Caledonian granites and medium–high-grade metamorphic rocks in the central hinterland (XL Fault Zone) to low-grade metamorphic rocks and sedimentary rocks in the western margin (CL Fault Zone). The chemical compositions of geothermal waters are influenced through mixing contacts between diverse rocks of varying ages, leading to distinct geochemical characteristics. Notably, δ13CCO2 values reveal that while some samples exhibit significant contributions from metamorphic CO2 sources, others are characterized by organic CO2 origins. Regional heat flow results from the upwelling of mantle magma, supplemented by radioactive heat generated from crustal granites. Isotopic evidence from δ2H and δ18O indicates that the geothermal waters originate from atmospheric sources, recharged by precipitation in the northern Yunkai Mountains. After infiltrating to specific depths, meteoric waters are heated to temperatures ranging from about 76.4 °C to 178.5 °C before ascending through the XL and CL Fault Zones under buoyancy forces. During their upward migration, geothermal waters undergo significant mixing with cold groundwater (54–92%) in shallow strata. As part of the western boundary of the Yunkai Uplift, the CL Fault Zone may extend deeper into the crust or even interact with the upper mantle but exhibits weaker hydrothermal activities than the XL Fault Zone. The XL Fault Zone, however, is enriched with highly heat-generating granites, is subjected more to both the thermal and mechanical influences of upwelling mantle magma, resulting in a higher heat flow and tension effect, and is more conducive to the formation of geothermal waters. Our findings underscore the role of geotectonic processes, lithological variation, and fault zone activity in shaping the genesis and evolution of geothermal waters in the Yunkai Uplift. Full article
(This article belongs to the Section Hydrogeology)
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22 pages, 12751 KiB  
Article
Seismic Signals of the Wushi MS7.1 Earthquake of 23 January 2024, Viewed Through the Angle of Hydrogeochemical Characteristics
by Zhaojun Zeng, Xiaocheng Zhou, Jinyuan Dong, Jingchao Li, Miao He, Jiao Tian, Yuwen Wang, Yucong Yan, Bingyu Yao, Shihan Cui, Gaoyuan Xing, Han Yan, Ruibing Li, Wan Zheng and Yueju Cui
Appl. Sci. 2025, 15(9), 4791; https://doi.org/10.3390/app15094791 - 25 Apr 2025
Viewed by 548
Abstract
On 23 January 2024, a MS7.1 earthquake struck Wushi County, Xinjiang Uygur Autonomous Region, marking the largest seismic event in the Southern Tianshan (STS) region in the past century. This study investigates the relationship between hydrothermal fluid circulation and seismic activity [...] Read more.
On 23 January 2024, a MS7.1 earthquake struck Wushi County, Xinjiang Uygur Autonomous Region, marking the largest seismic event in the Southern Tianshan (STS) region in the past century. This study investigates the relationship between hydrothermal fluid circulation and seismic activity by analyzing the chemical composition and origin of fluids in natural hot springs along the Maidan Fracture (MDF). Results reveal two distinct hydrochemical water types (Ca-HCO3 and Ca-Mg-Cl). The δD and δ18O values indicating spring water are influenced by atmospheric precipitation input and altitude. Circulation depths (621–3492 m) and thermal reservoir temperatures (18–90 °C) were estimated. Notably, the high 3He/4He ratios (3.71 Ra) and mantle-derived 3He content reached 46.48%, confirming that complex gas–water–rock interactions occur at fracture intersections. Continuous monitoring at site S13 (144 km from the epicenter of the Wushi MS7.1 earthquake) captured pre-and post-seismic hydrogeochemical fingerprints linked to the Wushi MS7.1 earthquake. Stress accumulation along the MDF induced permeability changes, perturbing hydrogeochemical equilibrium. At 42 days pre-Wushi MS7.1 earthquake, δ13C DIC exceeded +2σ thresholds (−2.12‰), signaling deep fracture expansion and CO2 release. By 38 days pre-Wushi MS7.1 earthquake, Na+, SO42−, and δ18O surpassed 2σ levels, reflecting hydraulic connection between deep-seated and shallow fracture networks. Ion concentrations and isotope values showed dynamic shifts during the earthquake, which revealed episodic stress transfer along fault asperities. Post-Wushi MS7.1 earthquake, fracture closure reduced deep fluid input, causing δ13C DIC to drop to −4.89‰, with ion concentrations returning to baseline within 34 days. Trace elements such as Be and Sr exhibited anomalies 12 days before the Wushi MS7.1 earthquake, while elements like Li, B, and Rb showed anomalies 24 days after the Wushi MS7.1 earthquake. Hydrochemical monitoring of hot springs captures such critical stress-induced signals, offering vital insights for earthquake forecasting in tectonically active regions. Full article
(This article belongs to the Section Earth Sciences)
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22 pages, 7574 KiB  
Article
Evaluating Depositional Environment and Organic Matter Accumulation of Datangpo Formation in Central Hunan Province, South China
by Peng Jiao, Rong Xiao, Shimin Tan, Yu Xie, Hanqi Fang, Zhigang Wen and Zhanghu Wang
Minerals 2025, 15(4), 366; https://doi.org/10.3390/min15040366 - 31 Mar 2025
Viewed by 501
Abstract
The interglacial period of the Cryogenian glaciation is a pivotal interval in geological history, marked by two “Snowball Earth” events and the emergence of early animals. Currently, there is considerable debate regarding the paleo-oceanic environment and the dominant factors controlling organic matter enrichment. [...] Read more.
The interglacial period of the Cryogenian glaciation is a pivotal interval in geological history, marked by two “Snowball Earth” events and the emergence of early animals. Currently, there is considerable debate regarding the paleo-oceanic environment and the dominant factors controlling organic matter enrichment. Here, based on inorganic geochemical data and mineral composition from the Datangpo Formation in Xiangtan (South China), combined with previous research, we have analyzed the paleo-climate, redox condition, seawater restriction, and primary productivity across different sedimentary facies during this critical interval. The results exhibit that the Datangpo Formation can be divided into three members (Da1–Da3) based on lithology. Paleoclimatic proxies suggest the environment was relatively cold during the deposition of the Da-1 Member, while it was relatively warm and humid during the deposition of the Da 2–3 members. Compared to shallow water areas, deep-water areas experienced a more rapid transition in paleotemperature following the Sturtian glaciation event. Combining Mo-U elements, CeN/Ce*N, and Corg/P ratios, the environment was characterized by an oxic environment during the early deposition period of the Datangpo Formation, then gradually transitioned to suboxic, and finally anoxic conditions. Furthermore, the decompression of terrestrial magma chambers led to intense volcanic/hydrothermal activity during the deglaciation period. Hydrothermal activity was most intense during the Da-1 depositional period, followed by Da-2, and gradually declined during Da-3 depositional period. Hydrothermal activity not only provided essential materials for the formation of Mn carbonate ores but also significantly enhanced the primary productivity by introducing large amounts of nutrients in the paleo-ocean. The primary productivity indicators (Ni/Al, Cu/Al) exhibited an obvious coupling with CeN/Ce*N and Corg/P ratios in the Datangpo Formation, indicating that oxygen-rich environments were favorable for biological proliferation, thereby providing abundant organic matter. Anoxic conditions further facilitated the preservation of organic matter, which may be the primary factor driving organic matter enrichment in the Datangpo Formation. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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36 pages, 9140 KiB  
Article
The Geochemical Characteristics of Ore-Forming Fluids in the Jebel Stah Fluorite Deposit in Northeast Tunisia: Insights from LA-ICP-MS and Sr Isotope Analyses
by Chaima Somrani, Fouad Souissi, Radhia Souissi, Giovanni De Giudici, Eduardo Ferreira da Silva, Dario Fancello, Francesca Podda, José Francisco Santos, Tamer Abu-Alam, Sara Ribeiro and Fernando Rocha
Minerals 2025, 15(4), 331; https://doi.org/10.3390/min15040331 - 21 Mar 2025
Cited by 1 | Viewed by 1137
Abstract
The Zaghouan Fluorite Province (ZFP) encloses F-Ba(Pb-Zn) ores hosted within Jurassic carbonate series, in northeastern Tunisia. Critical breakthroughs on the Jebel Stah fluorite deposits, an MVT-style F-mineralization, have been made within the Lower Jurassic limestones along the Zaghouan Fault, which is a major [...] Read more.
The Zaghouan Fluorite Province (ZFP) encloses F-Ba(Pb-Zn) ores hosted within Jurassic carbonate series, in northeastern Tunisia. Critical breakthroughs on the Jebel Stah fluorite deposits, an MVT-style F-mineralization, have been made within the Lower Jurassic limestones along the Zaghouan Fault, which is a major target for mineralization. This study presents the first REE-Y analyses conducted by LA-ICP-MS on fluorites in Tunisia, and specifically on the fluorites of Jebel Stah deposit. This analytical technique provides highly accurate insights into the geochemical regime of mineralizing fluids and the related scavenging sources. Distinct geochemical characteristics between two fluorite generations (G1 and G2) were revealed. Fluorites (Fl2) from the early generation (G1) showed low ΣREE + Y (36.3 and 39.73 ppm, respectively). When normalized to chondrites, early fluorite G1 displayed a bell-shaped REE + Y pattern with a depletion in LREE relative to HREE and a slight MREE hump. Late fluorite (Fl3) generation (G2) displayed higher ΣREE + Y concentrations (77.43 ppm), but an almost similar REE pattern. Ce/Ce* ratios demonstrated strong negative Ce anomalies in all fluorites, while Eu/Eu* ratios indicated weak negative Eu anomalies. The positive Y anomaly observed in the REE + Y patterns of fluorites G1 and G2 suggests Y-Ho fractionation in the fluid system. Moreover, significant degrees of differentiation between terbium (Tb) and lanthanum (La) have been observed in all fluorite samples. The plot of fluorites from both fluorite generations on the Tb/La–Tb/Ca diagram gives evidence of the sedimentary hydrothermal origin of the ore-forming fluids in the Jebel Stah F-deposit. Sr isotopes show that the mineralizing fluids are radiogenic and deeply sourced basinal brines, whereas the small variation in 87Sr/86Sr ratios suggests a similar source for Sr in fluorites G1 and G2. These results allow us to conclude that the economic fluorite (G1) ore of Jebel Stah was deposited due to the interaction of the deeply sourced hydrothermal fluid with the carbonated host rocks (dolomitization, an increase in pH, and Ca activity), whereas the late fluorite (G2) is an accessory and could have resulted from the mixing of the hydrothermal fluid with shallow meteoric waters. Full article
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27 pages, 29442 KiB  
Article
Sinking Particle Fluxes at the Jan Mayen Hydrothermal Vent Field Area from Short-Term Sediment Traps
by Alexey A. Klyuvitkin, Marina D. Kravchishina, Dina P. Starodymova, Anton V. Bulokhov and Alla Yu. Lein
J. Mar. Sci. Eng. 2024, 12(12), 2339; https://doi.org/10.3390/jmse12122339 - 20 Dec 2024
Viewed by 946
Abstract
The mixing of hydrothermal vent fluids with deep ocean water and near-vent pelagic matter results in particle populations with a complex composition consisting of hydrothermally derived, rock-forming, and biogenic particles. This study is the first investigation of deep sediment trap material collected at [...] Read more.
The mixing of hydrothermal vent fluids with deep ocean water and near-vent pelagic matter results in particle populations with a complex composition consisting of hydrothermally derived, rock-forming, and biogenic particles. This study is the first investigation of deep sediment trap material collected at the Jan Mayen hydrothermal vent field area at 71° N and 6° W of the southernmost Mohns Ridge in the Norwegian–Greenland Sea. This area is characterized by high magmatic activity, axial volcanic ridges, and mafic-hosted volcanogenic massive sulfide deposits. Data on sinking particle fluxes from two hydrothermal settings, the Troll Wall and Soria Moria vent fields, located about 4 km apart, are discussed in the article. In particular, the study emphasize the differences between two hydrothermal settings from each other that demonstrate the geodiversity of hydrothermal processes within the relatively shallow Jan Mayen hydrothermal vent field area affected by the Iceland and Jan Mayen hotspots. The fluxes of sinking hydrothermally derived particles (barite, gypsum, non-crystalline Fe-Si oxyhydroxides, and Fe, Zn, and Cu sulfides) obtained at the Jan Mayen hydrothermal vents made it possible to elucidate the characteristic features of their buoyancy plumes and compare them with similar data reported for other submarine hydrothermal systems. In terms of the composition of the deep-sea hydrothermal particles from buoyant plumes, the studied vent fields are most similar to the Menez Gwen and Lucky Strike vent fields affected by the Azores hotspot. The supply of hydrothermally derived matter is accompanied by normal pelagic/hemipelagic sedimentation, which is dominated by biogenic particles, especially in the upper water layers. Full article
(This article belongs to the Section Geological Oceanography)
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18 pages, 13198 KiB  
Article
Microfacies and Evolution of the Carbonate Factory During the Middle Permian in Northwest Sichuan Basin, China
by Siyu Zhou, Dakang Zhong, Haitao Sun, Xiaojie Huang, Chenguang Wang and Xuanwei Liu
Minerals 2024, 14(10), 1037; https://doi.org/10.3390/min14101037 - 17 Oct 2024
Viewed by 1428
Abstract
Located in the eastern Paleo-Tethys Ocean and near the equator, carbonate sedimentation widely developed in the Sichuan Basin in the Permian Guadalupian period. Although the growth and decline of carbonate particles are closely related to the surrounding sedimentary environment, the relationships between the [...] Read more.
Located in the eastern Paleo-Tethys Ocean and near the equator, carbonate sedimentation widely developed in the Sichuan Basin in the Permian Guadalupian period. Although the growth and decline of carbonate particles are closely related to the surrounding sedimentary environment, the relationships between the grain composition and distribution of the northwest Sichuan Basin and the sedimentary environment are not clear. This study explored the particle type, particle content, and sedimentary structure of 300 thin sections from 19 wells and seven field profiles of the Guadalupian period in the northwest Sichuan Basin, identified seven microfacies and four microfacies associations, analyzed the sedimentary environment, and established a sedimentary evolution model. The results show that there was a warm-water Dasycladaceae-dominated and foraminifera-dominated open platform developed in the early Roadian era in the research area. As the climate cooled during the late Roadian era, the warm-water carbonate sedimentary environment was replaced by a cold-water bryozoan-dominated and echinoid-dominated marginal sedimentary environment. As the climate continued to cool and the sea level dropped, the platform margin grain beach sediment underwent further development in the early Wordian era. In the late Wordian era stage, the sedimentary environment was influenced by the Dongwu movement, resulting in sea level changes and acidification caused by hydrothermal activities, which reduced the degree of grain beach development. During the Capitanian era, the climate became warmer due to the eruption of the ELIP. The uplift caused by the Dongwu movement resulted in a relative shallowing of the platform margin region, and hence, the grain beach sediment only developed in the southwest, while the northeast was dominated by deepwater basin sediments. The sudden transition from a warm-water, autotroph-dominated carbonate open platform to a cold-water, heterozoan-dominated carbonate platform margin resulted from a combination of tectonic movements, rapid sea level changes, and sedimentary environment changes during the Guadalupian era. Full article
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30 pages, 13193 KiB  
Article
Revisiting the Concealed Zn-Pb±(Ag,Ge) VMS-Style Ore Deposit, Molai, Southeastern Peloponnese, Greece
by Elias Kevrekidis, Stavros Savvas Triantafyllidis, Stylianos Fotios Tombros, Sotirios Kokkalas, Joan Papavasiliou, Konstantinos Kappis, Konstantinos Papageorgiou, Ioannis Koukouvelas, Michalis Fitros, Dimitrios Zouzias, Panagiotis Voudouris, Degao Zhai and Karen St Seymour
Minerals 2024, 14(9), 885; https://doi.org/10.3390/min14090885 - 30 Aug 2024
Viewed by 2428
Abstract
The concealed Molai Zn-Pb±(Ag,Ge) stratiform deposit in southeastern Peloponnese is hosted in Triassic intermediate tuffs, ignimbrites and subaerial andesitic flows. The host rocks display trace element signatures of a Supra-Subduction Zone (SSZ) setting. Three ore-forming stages are recognized, with stages I and II [...] Read more.
The concealed Molai Zn-Pb±(Ag,Ge) stratiform deposit in southeastern Peloponnese is hosted in Triassic intermediate tuffs, ignimbrites and subaerial andesitic flows. The host rocks display trace element signatures of a Supra-Subduction Zone (SSZ) setting. Three ore-forming stages are recognized, with stages I and II related to formation of the epigenetic, stratiform, massive-to-semi-massive ore and a late stage III associated with vein-type mineralization. The O and D isotope geochemistry of gangue chlorite and epidote reveal mixing with fresh meteoric water during the weaning stages of the hydrothermal activity of the late stage II due to uplifting of the hydrothermal system. Sphalerite is the major ore phase, with three different varieties formed during stages I (Sp-I) and II (Sp-II and Sp-III). All sphalerite varieties coexist, depicting gradual change in the chemistry of the ore-forming fluids. Molai ores are characterized by elevated Ag and Ge contents. Tetrahedrite is the major Ag carrier, while among the three sphalerite varieties, early Sp-I comprises the highest Ge contents. The Molai Zn-Pb±(Ag,Ge) deposit is characterized by intermediate features between bimodal felsic massive sulfides and subaerial epithermal systems based on the shallow formation depth, the presence of hydraulic breccias associated with phase separation, the ore formation along high-angle faults, the relatively low ore-forming temperatures below 250 °C obtained from geothermometry, and the absence of the typical structure of bimodal felsic type ores. Full article
(This article belongs to the Special Issue Mineralization and Geochemistry of VMS Deposits)
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21 pages, 5270 KiB  
Article
Mimicking Marine Conditions to Improve Prodigiosin Yields in Bioreactor
by Ricardo F. S. Pereira and Carla C. C. R. de Carvalho
Processes 2024, 12(9), 1794; https://doi.org/10.3390/pr12091794 - 23 Aug 2024
Cited by 2 | Viewed by 1724
Abstract
Prodigiosin is a red bacterial pigment with great potential as a natural dye and drug precursor, while presenting several pharmacological properties, including antimicrobial and anticancer activities. Its commercialization for biomedical applications, however, remains scarce. The major limitations are related to the lack of [...] Read more.
Prodigiosin is a red bacterial pigment with great potential as a natural dye and drug precursor, while presenting several pharmacological properties, including antimicrobial and anticancer activities. Its commercialization for biomedical applications, however, remains scarce. The major limitations are related to the lack of efficient bioprocesses and scaling up from laboratory to production. In the present work, the upstream process for prodigiosin production was developed using a marine Serratia rubidaea isolated from a sample collected near a shallow-water hydrothermal vent. The yield of product per biomass was found to be influenced by the cell concentration in the inoculum. The system was scaled up to 2 L stirred tank reactors with two different vessel geometries. It was shown that the vessel geometry and a cascade control mode for regulating the dissolved oxygen concentration influenced the volumetric oxygen mass transfer coefficient (kLa) and thus prodigiosin production. To improve product yields, strategies to mimic the aeration conditions found at the sampling site were tested. When the inoculum was grown for 5 h at 200 rpm and for 19 h at 25 rpm, which significantly decreased the oxygen available, the cells produced 588.2 mgproduct/gbiomass, corresponding to a production of 1066.2 mg of prodigiosin in 24 h and a productivity of 36.1 mgproduct/(L.h). This is a 3.7-fold increase in prodigiosin yield and a 4.5-fold increase in productivity in relation to when no particular strategy was promoted. Additionally, it was shown that lipid analysis and flow cytometry may be used as reliable at-line analytical tools, allowing the monitoring of cell condition and prodigiosin production during fermentation. Full article
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12 pages, 4386 KiB  
Article
Deep Structure of Epithermal Deposits in Youxi Area: Insights from CSAMT and Dual-Frequency IP Data
by Huanyin He, Jinrong Wang, Wu Wen, Rencong Tian, Jiansui Lin, Weiqiang Huang and Yabin Li
Minerals 2024, 14(1), 27; https://doi.org/10.3390/min14010027 - 25 Dec 2023
Cited by 5 | Viewed by 1735
Abstract
Epithermal deposits represent a significant category of gold occurrences, with their subsurface structure playing a key role in reserve assessments. Fujian Province, characterized by extensive Mesozoic volcanic activities, stands out as a noteworthy region for shallow hydrothermal mineralization in China. This paper focus [...] Read more.
Epithermal deposits represent a significant category of gold occurrences, with their subsurface structure playing a key role in reserve assessments. Fujian Province, characterized by extensive Mesozoic volcanic activities, stands out as a noteworthy region for shallow hydrothermal mineralization in China. This paper focus on the Youxi area within Fujian Province, employing the dual-frequency induced polarization method (DFIP) and controlled-source audio-frequency magnetotelluric method (CSAMT) to investigate the target ore. The DFIP results revealed predominant northeast-oriented zones with high polarizability and notable apparent resistivity. The CSAMT data were inverted using the SCS2D software. Two-dimensional resistivity profiles reveal a three-layer electrical structure, comprising subsurface banded rhyolites influenced by fault zones, intermediate-low resistivity sandstone layers, and deep-seated high-resistivity conglomerates. The resistivity gradient zones and highly polarizable locations align closely with known local faults. We interpreted these resistivity gradient zones as prospective target areas for mineralization, a hypothesis subsequently validated by drilling results. Combining geochemical analyses of epithermal gold deposits with the electrical resistivity structure, we propose an explanatory model for the mechanism of the formation of epithermal gold–silver deposits in the Youxi area. The magmatic hydrothermal fluids ascended along the fault, underwent convection-driven interaction with meteoric waters, and subsequently metasomatized the host rocks. This integrated approach provides valuable insights into the geological processes governing epithermal gold–silver deposit formation in the Youxi region. Full article
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15 pages, 21449 KiB  
Article
First Documentation of Large Submarine Sinkholes on the Ganquan Carbonate Platform in the Xisha Islands, South China Sea
by Wenbo Du, Chupeng Yang, Huodai Zhang, Jinwei Gao, Mingming Wen, Xiaosan Hu, Ziying Xu, Xin Nie and Rongwei Zhu
J. Mar. Sci. Eng. 2023, 11(11), 2171; https://doi.org/10.3390/jmse11112171 - 15 Nov 2023
Cited by 4 | Viewed by 1540
Abstract
Submarine sinkholes are unique and important geomorphological features with a typical cavity structure that are of great scientific value. Submarine sinkholes were discovered for the first time in the isolated Ganquan carbonate platform on the Xisha Islands, the northwestern South China Sea. Based [...] Read more.
Submarine sinkholes are unique and important geomorphological features with a typical cavity structure that are of great scientific value. Submarine sinkholes were discovered for the first time in the isolated Ganquan carbonate platform on the Xisha Islands, the northwestern South China Sea. Based on high-resolution multibeam bathymetric data and seismic profile data, we identified 37 submarine sinkholes at water depths ranging from 550 to 1267 m. They are subcircular to circular negative-relief features, and most of them are V- or compound V-shaped in the cross-section. Their average diameters range from 57 to 667 m, and the depth of the depression ranges from 2.5 to 241 m. By comparing submarine sinkholes in the Ganquan platform with those in other carbonate platforms worldwide, we can infer that the Ganquan platform submarine sinkholes are the largest sinkholes developed on an isolated carbonate platform. Remotely operated vehicle (ROV) “Haima 2” images revealed that the inner walls of submarine sinkholes are characterized by stalactite-like structures, possible dikes, flow marks, and corroded holes, which are typical karstic landscape features. The temperature within submarine sinkholes is 2 °C higher than that of the open ocean at the same water depth. Based on the results of the shallow formation profile and multichannel seismic profiles, we propose that the submarine sinkholes in the Ganquan platform probably formed via the dissolution of the carbonate platform via acidic hydrothermal fluids that originated from magmatic activity and migrated along faults. Full article
(This article belongs to the Section Geological Oceanography)
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14 pages, 3885 KiB  
Article
Novel Insights on the Bacterial and Archaeal Diversity of the Panarea Shallow-Water Hydrothermal Vent Field
by Erika Arcadi, Emanuela Buschi, Eugenio Rastelli, Michael Tangherlini, Pasquale De Luca, Valentina Esposito, Rosario Calogero, Franco Andaloro, Teresa Romeo and Roberto Danovaro
Microorganisms 2023, 11(10), 2464; https://doi.org/10.3390/microorganisms11102464 - 30 Sep 2023
Cited by 4 | Viewed by 1755
Abstract
Current knowledge of the microbial diversity of shallow-water hydrothermal vents is still limited. Recent evidence suggests that these peculiar and heterogeneous systems might host highly diversified microbial assemblages with novel or poorly characterized lineages. In the present work, we used 16S rRNA gene [...] Read more.
Current knowledge of the microbial diversity of shallow-water hydrothermal vents is still limited. Recent evidence suggests that these peculiar and heterogeneous systems might host highly diversified microbial assemblages with novel or poorly characterized lineages. In the present work, we used 16S rRNA gene metabarcoding to provide novel insights into the diversity of the bacterial and archaeal assemblages in seawater and sediments of three shallow-water hydrothermal systems of Panarea Island (Tyrrhenian Sea). The three areas were characterized by hot, cold, or intermediate temperatures and related venting activities. Microbial biodiversity in seawater largely differed from the benthic one, both in α-diversity (i.e., richness of amplicon sequence variants—ASVs) and in prokaryotic assemblage composition. Furthermore, at the class level, the pelagic prokaryotic assemblages were very similar among sites, whereas the benthic microbial assemblages differed markedly, reflecting the distinct features of the hydrothermal activities at the three sites we investigated. Our results show that ongoing high-temperature emissions can influence prokaryotic α-diversity at the seafloor, increasing turnover (β-)diversity, and that the intermediate-temperature-venting spot that experienced a violent gas explosion 20 years ago now displays the highest benthic prokaryotic diversity. Overall, our results suggest that hydrothermal vent dynamics around Panarea Island can contribute to an increase in the local heterogeneity of physical–chemical conditions, especially at the seafloor, in turn boosting the overall microbial (γ-)diversity of this peculiar hydrothermal system. Full article
(This article belongs to the Special Issue Microbial Diversity in Extreme Environments 2.0)
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23 pages, 14269 KiB  
Article
Genetic Mechanism of Structurally Controlled Dolomites Derived from Seawater-Hydrothermal Mixed Fluids—A Case Study from Middle Permian, Central Sichuan Basin, South China
by Jinliang Gao, Haofu Zheng, Bo Liu, Lei Pan, Rangbin Li, Junfeng Wu, Xiangyang Yang, Hailei Tang and Yixin Dong
Minerals 2023, 13(6), 758; https://doi.org/10.3390/min13060758 - 31 May 2023
Cited by 3 | Viewed by 1917
Abstract
Dolomite bodies in the Middle Permian of the central Sichuan Basin have been reported as favorable natural gas reservoirs. The Middle Permian dolomite consists of three types of recrystallized dolomite (Rd1, Rd2, and Rd3) and one type of dolomite cement (Sd). Rd1 might [...] Read more.
Dolomite bodies in the Middle Permian of the central Sichuan Basin have been reported as favorable natural gas reservoirs. The Middle Permian dolomite consists of three types of recrystallized dolomite (Rd1, Rd2, and Rd3) and one type of dolomite cement (Sd). Rd1 might be formed as the primary mineral along the calcite in the original sea-water. Its δ13C value and 87Sr/86Sr ratio, consistent with those of marine limestone and Permian seawater, support that the dolomitizing fluid for Rd1 was Permian seawater preserved in the strata. Rd2 consists of fine to medium (50 μm to 250 μm) and planar to curved crystals. Geochemical indicators (slightly high 87Sr/86Sr ratio, similar rare earth element patterns, negative δ18O, slightly high salinity) confirm that the dolomitizing fluid of Rd2 was mainly Permian seawater during shallow burial, with a small number of hydrothermal fluids. Rd3 and Sd are featured by very large (>250 μm), curved crystals, and high-temperature, high-salinity, and obviously positive Eu anomalies, suggesting that their diagenetic fluids were mainly hydrothermal fluids from deep. Additionally, inherited carbon sources and the 87Sr/86Sr ratios of some samples fall within the range of Permian seawater distribution, confirming the contribution of Permian seawater. ELIP activity caused the formation of this dolomite through the mixing of seawater and hydrothermal fluids. The main fluid circulation channels were activated basement faults, epigenetic karst pores, and shallowly buried high-permeability strata. During the peak period of ELIP activity, the continuous upwelling of deep hydrothermal fluids led to the continuous formation of Rd2, Rd3, and Sd. The dolomitization fluid of Rd2 was mainly composed of seawater and featured a certain lateral extension, which was away from faults. Rd3 and Sd are mainly distributed along the fault system, and excessive dolomitization caused by the hydrothermal activity, to some extent, inhibited the lateral movement of hydrothermal fluids. This study provides a good example for exploring the genetic mechanism and distribution pattern of structurally controlled dolomites under a volcanic activity background. Full article
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33 pages, 34009 KiB  
Article
Hydrothermal Alteration in the Nevados de Chillán Geothermal System, Southern Andes: Multidisciplinary Analysis of a Fractured Reservoir
by Diego Morata, Romina Gallardo, Santiago Maza, Gloria Arancibia, Camila López-Contreras, Valentina Mura, Claudia Cannatelli and Martin Reich
Minerals 2023, 13(6), 722; https://doi.org/10.3390/min13060722 - 25 May 2023
Cited by 8 | Viewed by 3234
Abstract
The interplay between a heat source, primary plus secondary permeability, and hydrothermal fluids makes geothermal systems a highly dynamic environment where evolving physico-chemical conditions are recorded in alteration mineralogy. A comprehensive characterization of hydrothermal alteration is therefore essential to decipher the major processes [...] Read more.
The interplay between a heat source, primary plus secondary permeability, and hydrothermal fluids makes geothermal systems a highly dynamic environment where evolving physico-chemical conditions are recorded in alteration mineralogy. A comprehensive characterization of hydrothermal alteration is therefore essential to decipher the major processes associated with geothermal system development. In this study, we defined the hydrothermal mineralogical evolution of the Nevados de Chillán Geothermal System (NChGS), located in the Southern Volcanic Zone (SVZ) of the central Andes, where the regional framework of the system is formed by a direct association with a currently active volcanic complex, a favorable structural control, and vertically inhibited fluid circulation. To characterize the secondary mineralogy present in the NChGS, we integrated optical petrography, Scanning Electron Microscopy (SEM) observations, X-ray Diffraction (XRD) analysis, and microthermometric measurements along a drill core with a depth of 1000 m at the Nieblas-1 well. These mineralogical approaches were combined with a structural field analysis to highlight the relevance of multidisciplinary study in understanding active geothermal systems. The results indicated that the evolution of the system involved four paragenetic stages, with the main processes in each phase being the heating, boiling, and mixing of fluids and re-equilibration to new physico-chemical conditions. Additionally, three hydrothermal zones were recognized: an upper argillic section, an intermediate sub-propylitic zone, and a deep propylitic domain. Sampled thermal springs are characterized by pH values of 2.4–5.9 and high SO4= concentrations (>290 ppm). These acid-sulfate steam-heated waters suggest the contribution of primary magmatic volatiles to the hydrothermal system. Alunite recorded in the alteration halos of veinlets presents at depths of 170–230 m denote the circulation of acidic fluids at these levels which were favored by reverse faults. These findings indicate that, at this depth range, the condensation of magmatic volatiles into shallow aquifers controls the recharge area of the superficial thermal manifestations. Conversely, deep-seated hydrothermal fluids correspond to near-neutral chloride fluids, with salinities ranging from 0.1 to 6.9 wt.% NaCl eq. The distribution of illite/smectite and chlorite/smectite mixed-layered minerals outline the presence of a significant clay cap, which, in this system, separates the steam-heated domain from the deep hydrothermal realm and restricts fluid circulation to existing permeable channels. Our mineralogical and structural study provides critical data for the interpretation of heat–fluid–rock interaction processes in the NChGS. The interplay between hydrothermal fluids and active faults is also discussed in the context of the complex of geological processes in active geothermal systems along the Chilean Southern Volcanic Zone. Full article
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21 pages, 25501 KiB  
Article
Origin and Paleoenvironmental Conditions of the Köprüağzı Evaporites (Eastern Anatolia, Turkey): Sedimentological, Mineralogical and Geochemical Constraints
by Pelin Güngör Yeşilova and Ozan Baran
Minerals 2023, 13(2), 282; https://doi.org/10.3390/min13020282 - 17 Feb 2023
Cited by 3 | Viewed by 3511
Abstract
Köprüağzı evaporites mainly consist of primary (selenite and gypsarenite) and secondary (massive, laminated and satin-spar) gypsum lithofacies, as well as minor anhydrite, and are interbedded with clastic and carbonate units. Sedimentological-mineralogical and geochemical findings reveal that the depositional basin extends from a lagoon [...] Read more.
Köprüağzı evaporites mainly consist of primary (selenite and gypsarenite) and secondary (massive, laminated and satin-spar) gypsum lithofacies, as well as minor anhydrite, and are interbedded with clastic and carbonate units. Sedimentological-mineralogical and geochemical findings reveal that the depositional basin extends from a lagoon to the hinterland. These data confirm that too much detrital input was transported into the basin with multiple salinity and pH value fluctuations, organic matter activity and reducing conditions. Geochemical data point out the shallow environment and the mixing of hydrothermal fluids and fresh waters. The investigated evaporites were exposed to diagenesis and alteration under the influence of a hot—dry and minor humid climate, tectonism and pressure. The 87Sr/86Sr, δ34S and δ18O isotope values of Köprüağzı evaporites reveal that they are of Miocene marine sulfate origin. Full article
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25 pages, 3603 KiB  
Article
Hydrogeochemistry of Fault-Related Hot Springs in the Qaidam Basin, China
by Jie Tang, Xiaocheng Zhou, Yongxian Zhang, Jiao Tian, Miao He, Jingchao Li, Jinyuan Dong, Yucong Yan, Fengli Liu, Shupei Ouyang and Kaiyi Liu
Appl. Sci. 2023, 13(3), 1415; https://doi.org/10.3390/app13031415 - 20 Jan 2023
Cited by 11 | Viewed by 2909
Abstract
Hydrogeochemical characterization studies are regarded as an important method for determining the origin of hot springs. The major elements, trace elements, and stable isotopes of four groups of hot spring water samples and two groups of gas samples collected from the intersection of [...] Read more.
Hydrogeochemical characterization studies are regarded as an important method for determining the origin of hot springs. The major elements, trace elements, and stable isotopes of four groups of hot spring water samples and two groups of gas samples collected from the intersection of the Altyn Tagh fault zone and the East Kunlun fault belt were investigated in this study. The hot spring water temperature ranged between 6 °C and 14 °C. The water chemistry types of the hot springs were Na·Mg-Cl, Mg·Na-Cl·HCO3, Na-Cl·SO4, and Na-Cl·HCO3. The δD values ranged from −50.00% to −68.60%, while the δ18O values ranged from −6.90% to −8.60%. The hot spring water was recharged mainly by infiltrating precipitation, with a recharge elevation of 3390~3676 m. The heat storage temperature ranged from 66.7 to 164.9 °C. The circulation depth was estimated to range between 1043 and 2679 m. The strontium isotopic composition of the water samples in response to the main weathering sources comprised carbonate and sulfate. CO2 was the main component in the hot spring gas in the study region, and its content was over 95%. The 3He/4He-R/Ra relationship diagram revealed that the mantle-sourced helium from the Yitunbulake spring was 3.06%. In comparison, that from the Aiken spring was 7.38%, which indicated an intrusion of mantle-source material mixed into the hot springs in the study region. The crustal marine limestone contributed significantly to the carbon inventory of the hot spring gas samples (>75%). The dissolution of the marl aquifer resulted in the release of CO2. Carbon was primarily obtained through metamorphism and hydrothermal reactions in the basement lithologies. The Yitunbulake and Aiken hot springs are found near the intersection of the Arjin and East Kunlun fractures, where the water–rock response is relatively strong and the depth of circulation and thermal storage temperature are both high. This causes relatively high ambient pressure to be released from the deep fluid, resulting in microseismic activity in this region. The continuous observation of Aiken spring water chemistry allows for the monitoring of fracture activity in the region. The results of the study could serve as a foundation for further exploration of the relationship between geothermal water and deep faults, shallow geological formations, hydrogeological conditions, and geothermal resource development in the region. Full article
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