Search Results (486)

The thermodynamic instability and relatively low mechanical strength of γ/γ′ phase boundaries in Ni-based single-crystal superalloys compromise the service safety of these materials. The interfacial segregation behavior of alloying elements is expected to enhance the thermodynamic stability and mechanical strength of γ/γ′ phase boundaries. In the present research, first-principles computations grounded in density functional theory were performed to examine the unclarified cosegregation characteristics of W-Re/Cr solutes at the γ-Ni/γ′-Ni₃Al phase boundary, as well as the impacts of such cosegregation on interfacial formation heat and Griffith fracture work. The results indicated that Re and Cr atoms tend to segregate preferentially at the γ-L₁-3.52-cp site within the W-alloyed phase boundary. This phenomenon can be attributed to the attractive interactions between W and Re/Cr, along with the fact that this site exhibits the most negative segregation energy. The thermodynamic stability of W-Re and W-Cr cosegregated phase boundaries is significantly enhanced, being much higher than that of clean or W-segregated phase boundaries, which is ascribed to deeper pseudogaps at the Fermi level. Notably, the preferred fracture path remains in region-1 after cosegregation, as directly evidenced by its lower Griffith fracture work compared to region-2. This disparity is rationalized by charge density analysis, which reveals a pronounced charge accumulation and consequently stronger bonding in region-2. Our results may provide atomistic insights into the solute cosegregation behaviors and their interfacial strengthening and stabilizing effects, and also the interfacial composition manipulation of Ni-based single-crystal superalloys. Full article

Pipeline steels under cyclic loading in corrosive environments are prone to wear and corrosion–wear synergy. Low-dilution, high-reliability Ni-based Cold Metal Transfer (CMT) overlays are therefore required to ensure structural integrity. In this work, three overlay architectures were deposited on L415QS pipeline steel: a single-layer ERNiFeCr-1 coating, a double-layer ERNiFeCr-1/ERNiFeCr-1 coating, and an ERNiCrMo-3 interlayer plus ERNiFeCr-1 working layer. The microstructure, interfacial composition gradients, and dry sliding wear behavior were systematically characterized to clarify the role of interlayer design. The single-layer ERNiFeCr-1 coating shows a graded transition from epitaxial columnar grains to cellular/dendritic and fine equiaxed grains, with smooth Fe dilution, Ni–Cr enrichment, and a high fraction of high-angle grain boundaries, resulting in sound metallurgical bonding and good crack resistance. The double-layer ERNiFeCr-1 coating contains coarse, strongly textured columnar grains and pronounced interdendritic segregation in the upper layer, which promotes adhesive fatigue and brittle spalling and degrades wear resistance and friction stability. The ERNiCrMo-3 interlayer introduces continuous Fe-decreasing and Ni-Cr/Mo-increasing gradients, refines grains, suppresses continuous brittle phases, and generates dispersed second phases that assist crack deflection and load redistribution. Under dry sliding, the tribological performance ranks as follows: interlayer + overlay > single-layer > double-layer. The ERNiCrMo-3 interlayer system maintains the lowest and most stable friction coefficient due to the formation of a dense tribo-oxidative glaze layer. These results demonstrate an effective hierarchical alloy-process design strategy for optimizing Ni-based CMT overlays on pipeline steels. Full article

This study examines the fast pyrolysis of rosehip seed waste (RSW) in a fluidized bed reactor, evaluating its potential for syngas production and effective waste valorization. The fluidization behavior of sand/RSW mixtures was characterized by determining the minimum fluidization velocity (U_mf) from pressure drop measurements. U_mf increased with RSW content, ranging from 0.227 to 0.257 m/s. Fluid-dynamic tests conducted in an acrylic prototype assessed bed expansion and mixing, showing stable fluidization at 10% RSW concentration without axial slugging. The bed expanded to 68% above the fixed-bed height, while bubble formation promoted uniform mixing and prevented solid segregation. Pyrolysis experiments were performed in a steel reactor using a nitrogen flow three times the U_mf, an initial bed height of 2.5 cm, and a 10% RSW mixture. The reactor operated between 400 and 600 °C, and syngas composition was analyzed. At 600 °C, carbon monoxide and hydrogen yields reached 13.868 mmol/g_RSW and 7.914 mmol/g_RSW, respectively—values notably higher than those obtained under slow pyrolysis conditions. These findings demonstrate that high-efficiency fluidized bed technology provides a sustainable pathway to convert invasive biomass into clean syngas, integrating waste mitigation with renewable energy generation. Full article

The family Sisyridae, the Spongilla-flies, is notable for its phylogenetic position as a basal group within Neuroptera. Using the improved Schiff-Giemsa method, we analyzed the behavior of the sex chromosomes X and Y during male meiosis in Sisyra nigra (Retzius 1738). The diploid chromosome number in males was 2n = 12 + XY. In pachytene, X and Y chromosomes appeared positively heteropycnotic and loosely paired. In early diakinetic nuclei, autosomal bivalents typically exhibited one distally located chiasma, although bivalents with two chiasmata were occasionally observed. The X and Y univalents were isopycnotic with the autosomes, with the X considerably larger than the Y. During the first meiotic division, metaphase plates were radial, with autosomal bivalents forming a ring and X and Y univalents positioned centrally, well separated from each other. In metaphase cells, X and Y were located at the equator, strongly indicating their amphitelic orientation. However, they later formed a pseudobivalent from which X and Y segregated simultaneously with autosomal half bivalents at anaphase I. This achiasmatic segregation mechanism, touch-and-go pairing, has now been observed for the first time in a species carrying chromosomes with a localized centromere. At the second metaphase, two cell types were observed: one with the X chromosome and the other with the Y chromosome. The behavior of the sex chromosomes in S. nigra is notably different from that in other Neuroptera, where sex chromosomes exhibit syntelic orientation and distance pairing at metaphase I. The unusual mechanism of sex chromosome segregation in the family Sisyridae aligns well with molecular phylogenetic findings concerning the family’s basal position within the order Neuroptera. Full article

Electromigration (EM) presents a major reliability challenge in advanced electronic packaging as device scaling and rising power demands lead to higher current densities in solder joints. While eutectic Sn-58Bi solder is widely adopted as a low-temperature alternative for its energy efficiency and compatibility with heat-sensitive substrates, its heterogeneous microstructure renders it vulnerable to EM-induced degradation. This review summarizes recent progress in understanding the EM behavior of Sn-Bi solder joints. We first introduce lifetime prediction models based on Black’s law, emphasizing the influences of current density, Joule heating, and thermomigration. Subsequently, the microstructural mechanisms accelerating degradation, including phase segregation and the coarsening of intermetallic compounds (IMCs), are examined. Various alloying strategies are evaluated for their effectiveness in strengthening the solder matrix and suppressing atomic diffusion to improve EM resistance. The critical role of substrate metallization is also discussed, comparing how different surface finishes affect interfacial reactions and joint lifetimes. Additionally, operational methods such as current polarity reversal are explored as potential pathways to mitigate degradation. Finally, we conclude that the EM reliability of Sn-Bi solder joints depends on the combined effects of alloy chemistry, interfacial reactions, and operating conditions, and we suggest future research directions in advanced modeling and material design for next-generation electronic applications. Full article

Solidification cracking is a critical defect in Cu–steel dissimilar laser welding for cylindrical lithium-ion battery busbar assembly, yet the metallurgical role of phosphorus (P) in crack formation has not been quantitatively established. In this study, the influence of phosphorus in the coating layer on weld solidification behavior was clarified by preparing Cu substrates with four different coating conditions—Ni–P-coated Cu (10 and 50 μm) and pure Ni-coated Cu (10 and 50 μm)—and performing high-speed single-mode fiber-laser welding under identical heat-input conditions. Shear-tensile testing, EPMA-based microstructural analysis, and Thermo-Calc solidification calculations were combined to correlate P segregation with solidification cracking susceptibility. The Ni–P 10 μm coating generated severe solidification cracking compared with the pure Ni 50 μm coating, which was attributed to excessive P enrichment in the terminal liquid phase (up to 8.8 mass%). This enrichment significantly expanded the mushy-zone width to approximately 869 K, yielding a highly solidification crack-susceptible fusion zone. In contrast, 50 μm pure Ni coatings produced narrow mushy-zone widths (200–400 K) and extremely low residual P levels (~0.1 mass%), resulting in fully crack-free microstructures. The 50 μm Ni coating exhibited the highest shear-tensile strength and largest rupture displacement among all conditions, confirming that suppression of P segregation directly improves both structural integrity and mechanical performance. Overall, this study demonstrates that phosphorus enrichment critically governs the solidification-cracking susceptibility of Cu–steel dissimilar welds by widening the solidification temperature range. Eliminating P from the coating layer and applying an adequately thick pure Ni coating constitute highly effective strategies for achieving crack-free, mechanically robust welds in lithium-ion battery busbar manufacturing. Full article

This study investigates the influence of iron dilution on the microstructure and corrosion behavior of Inconel 625 weld overlays deposited on carbon steel. Different deposition strategies were employed to control dilution and to evaluate its effect on elemental segregation. The overlays were characterized in terms of microstructural evolution, chemical distribution, and corrosion performance under standardized testing conditions. The results show that increasing iron dilution enhances chemical segregation within the dendritic structure, which governs the initiation of localized corrosion. A critical dilution condition associated with the onset of pitting was identified. These findings advance the understanding of dilution-controlled corrosion mechanisms in nickel-based alloy overlays. Full article

Titanium matrix composites (TMCs), characterized by low density, high strength, and excellent high-temperature mechanical properties, are becoming preferred materials for key components in aerospace engines. However, conventional casting methods for preparing TMCs often encounter issues such as composition segregation and coarse reinforcement phases, hindering their engineering application. In this study, we fabricated TiC/TC4 titanium matrix composites via hot isostatic pressing (HIP). The composites exhibited room-temperature tensile strength of 1058 ± 8 MPa, yield strength of 958 ± 12 MPa, and total elongation of 17.0 ± 0.5%. Furthermore, the TiC/TC4 composites demonstrated favorable high-temperature mechanical properties, with a tensile strength of about 500 MPa at 600 °C. Investigation into plastic deformation and fracture behavior revealed that at room temperature, tensile cracks initiated predominantly around the reinforcing TiC particles, whereas at high temperatures, cracks primarily originated within the matrix. The strengthening mechanisms of the TiC particle-reinforced TC4 composites included particle strengthening, solid solution strengthening, and load-transfer strengthening. Additionally, the precipitation of nano-acicular secondary α (αs) phases within the β phase during high-temperature tensile deformation was observed, contributing to the superior high-temperature mechanical performance of the composites. Full article

(1) Background: Each generation’s approach to private-sphere environmentalism is shaped by distinct historical and socio-economic contexts, values, educational opportunities, and living conditions. The aim of this article is to identify differences on this issue among four generations (BB, X, Y, Z) of Poles. (2) Methods: An online survey was conducted on a quota sample of 1000 individuals, with each generation represented by 250 participants. The sample was balanced across generations in terms of gender, education, and place of residence. (3) Results: The top private-sphere environmental behavior was waste segregation (M = 5.1, SD = 1.23), followed by using reusable bags (M = 4.92, SD = 1.2) and reducing energy use (M = 4.57, SD = 1.2). The older the generation, the higher the score in the private-sphere environmentalism index (F = 33.3 (3, 996), p < 0.001). Significant predictors of the private-sphere environmental behaviors (PSE) index were age, gender, environmental concern, and perceived self-impact on the environment, and the final hierarchical regression model explained 38% of the variance in the PSE index. (4) Conclusions: These results underscores the need to account for generational contexts when developing behavior-change strategies and sustainability policies aligned with SDG 12. Full article

This study investigates the effects of welding current on the microstructure, mechanical properties, and corrosion behavior of 7075/7075 pulsed metal inert gas (P-MIG) welded joints. Welding experiments were conducted at currents of 190 A, 200 A, and 210 A using ER5356 filler wire, with the joints analyzed through optical microscopy (OM), scanning electron microscopy (SEM/EDS), and tensile and hardness testing, as well as intergranular and electrochemical corrosion evaluations. The results reveal that increasing welding current alters the solidification dynamics and precipitation behavior in the WZ. At 190 A, refined and uniformly distributed dendrites were obtained, whereas at 210 A, grains coarsened and elemental segregation was more pronounced. The weld hardness exhibited a trend of first increasing and then slightly decreasing with increasing welding current, with a maximum value of 99.5 HV0.1 obtained at 200 A. Similarly, the tensile strength improved with increasing welding current, reaching 257.7 MPa with 8% elongation at 210 A. Corrosion resistance exhibited a non-monotonic trend, with the best performance observed at 200 A, as indicated by the shallowest intergranular corrosion depth, the most positive open-circuit potential, and the highest charge transfer resistance in electrochemical impedance spectroscopy. The findings demonstrate that welding current is a critical parameter controlling the balance between microstructural refinement, mechanical strengthening, and corrosion resistance, and that 200 A represents the optimal condition under the investigated parameters. These insights provide theoretical guidance and experimental evidence for process optimization in the welding of high-strength aluminum alloys. Full article

The distinct solidification behavior of additively manufactured (AM) Inconel 718 (IN718) produces a unique microstructure and precipitation response compared with its conventionally forged counterpart, leading to fundamentally different responses to heat treatment and intermediate-temperature deformation behaviors. In this work, the intermediate-temperature (450–750 °C) deformation mechanisms of laser powder bed fusion (LPBF)-fabricated and forged IN718 alloys were systematically compared under various heat-treatment conditions. Overall, under solution treatment state, the LPBF alloy exhibited fine columnar grains, a high dislocation density, and retained δ phases along the grain boundaries, whereas the forged alloy showed coarse equiaxed γ grains without the δ phase. Under solution + aging (STA) treatment, the δ phase in the LPBF alloy effectively pinned grain boundaries and enhanced flow stress, while in the forged alloy, strengthening was dominated by the uniform precipitation of γ″ and γ′ phases. Owing to Nb consumption by δ-phase formation, the STA-treated LPBF alloy contained fewer γ″/γ′ precipitates and exhibited slightly lower strength than the STA-treated forged alloy. This study demonstrates that the inherent δ phase retention and Nb segregation in LPBF-built IN718 critically influence its precipitation behavior and deformation resistance, distinguishing it from conventionally processed alloys and providing valuable insights for microstructure design in AM-built high-temperature superalloys. Full article

Particle shape is a critical factor governing the macroscopic behavior of granular materials. While the Discrete Element Method (DEM) has proven to be a powerful tool for modeling these materials, the accurate representation of particles with realistic geometries remains a significant challenge. Numerous shape description techniques have been developed to address this, including sphere-clustering, polyhedral, spheropolyhedral, and superquadric approaches. However, these methods often introduce artificial surface roughness or are limited to highly regular geometries, particularly when modeling general-shaped particles with rounded features. The proposed method reformulates collision detection in the Metaball Discrete Element Method (MDEM) as a constrained optimization problem, ensuring stable and physically consistent contact handling. Validation results show excellent agreement with analytical solutions and significantly improved robustness over unconstrained MDEM approaches. Finally, the model is applied to analyze the effects of particle shape on compaction and segregation, demonstrating that the proposed MDEM effectively captures the influence of complex shapes on macroscopic behavior and offers strong potential for engineering and scientific applications. Full article

Chronic stress alters hypothalamic–pituitary–adrenal (HPA) axis function, affecting corticosterone regulation and adaptive responses. Understanding individual variability in stress adaptation requires identifying distinct HPA axis response patterns. Here, we assessed HPA axis sensitivity in male C57BL6 mice exposed to 30 days of chronic social defeat stress (CSDS). Negative feedback integrity was evaluated using the dexamethasone suppression test (DST), with corticosterone measured after saline or low-dose dexamethasone administration at days 10 and 30. Behavioral testing (open field, elevated plus maze, social interaction test, partition, social defeat, forced swimming test, sucrose preference test) and qPCR analysis of HPA-axis-related genes in the hypothalamus (Crh, Crhr1, Crhbp, Fkbp5, Nr3c1), pituitary (Pomc, Crhr1, Nr3c1, Nr3c2), and adrenal glands (Cyp11a1, Cyp11b1, Hsd11b1, Mc2r, Star, Fkbp5, Nr3c1) were performed. K-means cluster analysis identified three distinct response profiles differing in baseline and dexamethasone-suppressed corticosterone levels. Clusters also exhibited differences in behavioral phenotypes and HPA axis gene expression. Cluster 1 showed low basal corticosterone and an abnormal dexamethasone suppression response, without significant Crh or Crhbp dysregulation in the hypothalamus. Cluster 2 exhibited elevated basal corticosterone, a blunted dexamethasone response, anhedonia, and reduced immobility in the forced swim test; increased Crh and reduced Fkbp5 suggested enhanced glucocorticoid receptor sensitivity and sustained hypercortisolemia. Cluster 3, characterized by normal basal corticosterone and normal dexamethasone response, displayed upregulation of Crh and Crhbp, consistent with balanced and potentially adaptive HPA axis regulation under chronic stress. These results demonstrate that corticosterone response heterogeneity reflects distinct adaptive trajectories under chronic stress. Identifying behavioral and molecular markers of these strategies may advance understanding of stress vulnerability and resilience mechanisms, with implications for stress-related disorders. Full article

Municipal solid waste (MSW) is a rapidly escalating global challenge, with Thailand exemplifying the persistence of a policy–practice gap in zero-waste transitions. Despite national initiatives such as Zero Waste Thailand, household segregation and recycling rates remain modest, particularly in semi-rural municipalities. This study addresses this gap by introducing and validating the ARUN Model, a competency-based governance framework for community-level zero-waste management. Using a mixed-methods sequential explanatory design, quantitative data from 300 households were analyzed using exploratory factor analysis and regression modeling, complemented by focus group interviews with local leaders to interpret behavioral mechanisms. The findings revealed that Responsibility and Nurturing competencies exert the strongest positive effects on household zero-waste behavior, confirming the model’s reliability and construct validity. These results empirically demonstrate how community competencies shape sustainable waste practices and bridge the structural–behavioral divide in waste governance. This research provides the first empirical validation of a competency-based governance framework in a semi-rural Thai context, extending beyond participatory and capacity-based models. By integrating statistical rigor with community insight, the ARUN Model advances theoretical and practical understanding of competency-driven sustainability transitions. This study provides actionable insights for policymakers and supports the achievement of SDGs 11, 12, and 13, offering a locally rooted yet globally relevant pathway toward circular economy governance. Full article

Tragacanth gum (GT) was mixed with whey protein concentrate (WPC80), whey protein isolate (WPI) or rice protein (RP) across pH 3.0–7.2 in order to clarify the effect of protein type and pH on controlling association and bulk behavior. Turbidimetry at 600 nm by photographic validation, oscillatory and steady-shear rheology, dynamic light scattering (DLS), FTIR spectroscopy, and AutoDock Vina docking were employed and compared. Whey systems reflected a clear, mildly acidic window: low-strain elasticity (G′) reached near pH ~5, with increased A600 and dominant sub-100 nm DLS modes, reflecting associative complexation near the isoelectric region. WPI also reflected a secondary turbidity/viscosity rise at pH 7.2, consistent with segregative aggregationafter the associative window. RP was variable, featuring broadly increased turbidity with viscosity/DLS maxima at pH 6.4, reflecting glutelin-facilitated solubility/aggregation rather than an acid optimum. FTIR changes in the amide band and GT bands (COO⁻ ~1400–1406 cm⁻¹; 1015–1040 cm⁻¹) supplemented enhanced coupling at pH 3–5. Superimposition through docking of multivalent hot-spots (Lys/Arg and H-bonding neighborhoods) corresponded to the phase-level readouts. Together, the data establish protein-dependent, pH-selective windows for GT–protein systems and uncover a mechanistic dichotomy: associative complexation in whey vs. neutral-side, solubility-regulated aggregation in RP. Full article