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Search Results (743)

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16 pages, 2558 KB  
Review
Applications and Uses of Moringa Oleifera Seeds for Water Treatment, Agricultural Fertilization, and Nutraceuticals
by Diana J. Moreno, Consuelo C. Romero and Daniel F. Lovera
Sustainability 2026, 18(1), 3; https://doi.org/10.3390/su18010003 - 19 Dec 2025
Abstract
Moringa oleifera has been recognized for its adaptability, nutritional richness, and multipurpose potential, particularly in resource-limited regions. While most research has focused on its leaves, moringa seeds remain underutilized despite their broad applicability in the environmental, agricultural, and food sectors. This review systematically [...] Read more.
Moringa oleifera has been recognized for its adaptability, nutritional richness, and multipurpose potential, particularly in resource-limited regions. While most research has focused on its leaves, moringa seeds remain underutilized despite their broad applicability in the environmental, agricultural, and food sectors. This review systematically and critically examines recent scientific literature on the use of M. oleifera seeds across these fields, emphasizing their functional value, applications, and challenges for sustainable use. The review follows the SALSA methodology (Search, Appraisal, Synthesis, and Analysis), a structured and iterative framework designed to identify, evaluate, and integrate scientific evidence from diverse sources. The analysis encompasses three main areas: (i) water treatment, where moringa seed extracts have achieved turbidity removal efficiencies above 90% and effective adsorption of dyes and potentially toxic elements; (ii) agriculture, where seed-derived fertilizers improve soil fertility, nutrient availability, and crop yield compared to conventional inputs; and (iii) the food industry, where moringa seed derivatives enhance the nutritional, functional, and antioxidant properties of bakery, beverage, and oil-based products. Overall, M. oleifera seeds emerge as a versatile and sustainable resource with proven potential as a natural coagulant, biofertilizer, and nutraceutical ingredient. By integrating findings from both English and Spanish language studies, this work highlights their contribution to sustainable water management, agricultural productivity, and food innovation, while emphasizing the need for further safety evaluation and process optimization to support large-scale application. Full article
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12 pages, 1543 KB  
Article
Seed-Carrying Ant Assemblages in a Fragmented Dry Forest Landscape: Richness, Composition, and Ecological Implications
by Rodrigo G. Pol, Mariana Pereyra and Leonardo Galetto
Diversity 2025, 17(12), 866; https://doi.org/10.3390/d17120866 - 17 Dec 2025
Abstract
Habitat fragmentation profoundly alters ecological processes such as seed predation and dispersal. Ants play a central role as seed removers and dispersers, yet the effects of fragmentation on seed-carrying ant assemblages in dry tropical forests remain insufficiently studied. In this work, we examined [...] Read more.
Habitat fragmentation profoundly alters ecological processes such as seed predation and dispersal. Ants play a central role as seed removers and dispersers, yet the effects of fragmentation on seed-carrying ant assemblages in dry tropical forests remain insufficiently studied. In this work, we examined the influence of forest fragmentation on seed-carrying ants in the Chaco forests of central Argentina. Ants were sampled across nine forest fragments of varying sizes and two continuous forests within an agroecosystem landscape, and species richness, composition, and occurrence were analyzed. Our results revealed that species richness did not vary significantly with fragment size; however, fragmentation caused pronounced shifts in species composition, with clear distinctions between continuous forests and fragments. Large-bodied specialist harvester ants declined in fragments, whereas small- to medium-sized generalist species from genera such as Pheidole and Solenopsis persisted. These compositional changes suggest that although overall seed removal rates may remain stable, the functional quality of seed dispersal likely diminishes. This study highlights the sensitivity of seed-carrying ant assemblages to habitat fragmentation and underscores the need for further research that integrates behavioral and landscape-scale approaches to better assess impacts on seed removal, dispersal, and forest regeneration in fragmented dry forests. Full article
(This article belongs to the Special Issue Systematics, Evolution and Diversity in Ants)
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16 pages, 2704 KB  
Article
Introduction Policy of the Botanical Garden of Southern Federal University and Problems of Managing Invasive Woody Plants
by Boris L. Kozlovsky, Olga I. Fedorinova, Mikhail V. Kuropyatnikov, Mikhail M. Sereda, Anastasiya A. Dmitrieva and Pavel A. Dmitriev
J. Zool. Bot. Gard. 2025, 6(4), 63; https://doi.org/10.3390/jzbg6040063 - 17 Dec 2025
Viewed by 44
Abstract
The Botanical Garden of Southern Federal University (SFedU Botanical Garden) is the first botanical garden in the steppe zone of southern Russia, founded in 1927. The priority task of the SFedU Botanical Garden was the introduction of woody plants for greenery and forestry. [...] Read more.
The Botanical Garden of Southern Federal University (SFedU Botanical Garden) is the first botanical garden in the steppe zone of southern Russia, founded in 1927. The priority task of the SFedU Botanical Garden was the introduction of woody plants for greenery and forestry. It has been shown that the introduction of woody plants was the root cause of their invasion in the region. A total of 24 species of invasive trees and shrubs have been identified in the Priazovsky district of the Rostov region. Using species with high seed reproductive capacity and resistance to climatic factors to expand the range of woody plants used for greenery in urban areas poses a real threat of invasion. Thus, 83 species spread spontaneously from the SFedU Botanical Garden collections across its territory, 50 of which are not currently found in the regional culture. An important step in the management of invasive woody plants is for municipalities to adopt basic assortment lists for greening purposes. The SFedU Botanical Garden’s collection policy for woody plants should focus on reducing the number of species in living plant collections by removing species that self-seed and currently have no scientific, educational, or practical use. These species can be stored in a seed bank for future use. The introduction policy of the SFedU Botanical Garden should be aimed at mobilizing and introducing species that are not only highly resilient and effective in providing ecosystem services, but also possess properties that limit their invasion. Full article
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15 pages, 1727 KB  
Article
Analysis of the Factors Affecting Germination of Cnidium monnieri Seeds and Its Endogenous Inhibitory Substances
by Qiantong Wei, Shulian Shan, Sirui Zhao, Chongyi Liu, Feng Ge, Hongying Cui and Fajun Chen
Plants 2025, 14(24), 3801; https://doi.org/10.3390/plants14243801 - 13 Dec 2025
Viewed by 178
Abstract
Cnidium monnieri is a valuable functional plant with significant potential for green pest control. However, its large-scale application is limited by its low and uneven seed germination in fields. To determine the factors that affect the germination of C. monnieri seeds, we examined [...] Read more.
Cnidium monnieri is a valuable functional plant with significant potential for green pest control. However, its large-scale application is limited by its low and uneven seed germination in fields. To determine the factors that affect the germination of C. monnieri seeds, we examined its seed viability, germination percentage and germination speed index (GSI) after seed-coat treatments, water permeability, and the types and activity of endogenous inhibitory substances in C. monnieri seeds. The results indicated that the seed viability of C. monnieri is 95%, but the germination percentage was relatively low (12.60%). Seed coat removal significantly enhanced both the germination percentage and the GSI, but had no significant effect on water absorption rate. Moreover, ethyl acetate extracts completely inhibited the seed germination of the control non-dormant Brassica rapa subsp. rapa, while diethyl ether extracts showed moderate suppression, and petroleum ether extracts exhibited the weakest effect. And the three endogenous inhibitory substances, i.e., dibutyl phthalate, 2,6-di-tert-butylphenol, and 2,4-di-tert-butylphenol significantly reduced the seed germination, seedling height and root length of B. rapa, indicating their high inhibitory efficiency on seed germination. Our study demonstrates that the mechanical barrier of the seed coat and the presence of potent endogenous germination inhibitory substances are the key factors influencing the germination of C. monnieri seeds. These findings provide a theoretical basis for promoting seed germination of C. monnieri, which enhance its application value as functional plant for green pest control. Full article
(This article belongs to the Section Plant Protection and Biotic Interactions)
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16 pages, 2998 KB  
Article
Development and Validation of a Selective Method to Quantify Low-Molecular-Mass Flavan-3-ols in Grapes and Wines
by Guzmán Favre, Gustavo González-Neves, Diego Piccardo, Yamila Celio-Ackermann, Florencia Pereyra-Farina and Alejandro Cammarota
Foods 2025, 14(24), 4257; https://doi.org/10.3390/foods14244257 - 10 Dec 2025
Viewed by 136
Abstract
Quantifying low-molecular-mass (LMM) flavanols in wines is relevant because these compounds, though typically minor, reflect flavanol structural composition (seed vs. skin contributions) and relate to cultivar and winemaking technique. Their determination is challenging because oligomeric and polymeric tannins interfere with standard spectrophotometric assays. [...] Read more.
Quantifying low-molecular-mass (LMM) flavanols in wines is relevant because these compounds, though typically minor, reflect flavanol structural composition (seed vs. skin contributions) and relate to cultivar and winemaking technique. Their determination is challenging because oligomeric and polymeric tannins interfere with standard spectrophotometric assays. This study introduces a coupled procedure that isolates and selectively quantifies LMM flavan-3-ols by combining the well-established methylcellulose precipitation assay (MCP) to remove oligomers and polymers with dimethylaminocinnamaldehyde (DMAC) determination of the MCP supernatant. The sequential workflow uses DMAC specificity and sensitivity and minimizes interference caused by higher-mass flavanols. Additionally, samples are quantified following dilution in the highly stable MCP supernatant medium. A Small Flavanol Index (SFI, %) is also introduced, expressing the LMM fraction relative to methylcellulose-precipitable tannins and providing a descriptor of flavanol composition. The method was validated in terms of linearity, limits of detection and quantification (LOQ in the supernatant, 1.58 mg L−1), precision, and recovery. Applicability is demonstrated in Marselan and Tannat (Vitis vinifera), resolving compositional differences by cultivar, grape tissue (skins vs. seeds), and maceration technique. Compatible with microplate formats and simple instrumentation, this robust analysis enables tandem determination of LMM flavanols and condensed tannins and represents an analytically valuable tool for commercial wineries and research. Full article
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17 pages, 1613 KB  
Article
Optimizing the Bleaching Conditions for Mechanically Extracted and Solvent-Extracted Hempseed Oil
by Preston C. Wilson, Md. Sanaul Huda, Roque Evangelista, Clairmont L. Clementson, Sean Liu, Bingcan Chen and Ewumbua Monono
ChemEngineering 2025, 9(6), 134; https://doi.org/10.3390/chemengineering9060134 - 2 Dec 2025
Viewed by 257
Abstract
Hemp (Cannabis sativa) seed oil is recognized as a valuable oil due to its beneficial fatty acid profile, which includes a favorable balance of omega-6 and omega-3 fatty acids, making it highly desirable for edible and bioproduct applications. Crude hempseed oil [...] Read more.
Hemp (Cannabis sativa) seed oil is recognized as a valuable oil due to its beneficial fatty acid profile, which includes a favorable balance of omega-6 and omega-3 fatty acids, making it highly desirable for edible and bioproduct applications. Crude hempseed oil contains high concentrations of chlorophyll, carotenoids, and other amphiphilic compounds that can negatively affect its appearance, stability, and downstream processing. Therefore, bleaching is a crucial step in removing these pigments after the degumming and neutralization processes. To optimize the bleaching process, a Box–Behnken response surface methodology was employed, focusing on three factors: time (15, 30, 45 min), temperature (100, 120, 140 °C), and bleaching earth concentration (2.5, 5, and 7.5% w/w). The key response variables were β-carotene, chlorophyll content, and antioxidant activity. For chlorophyll removal, bleaching earth concentration accounted for 83.82% and 81.84% of the variation in the solvent-extracted and mechanically extracted oils, respectively. For β-carotene, the bleaching earth concentration accounted for over 93% of the variation in both types of oil. The optimal bleaching earth concentrations were determined to be 4.87% and 5.36% for the solvent-extracted and mechanically extracted oils, respectively, to achieve the target chlorophyll level of ≤150 ppb. Mechanically extracted oil had lower antioxidant activity after bleaching compared to solvent-extracted oil. The addition of bleaching earth, up to 5%, removed polar antioxidants, further lowering the oil’s antioxidant capacity. These findings suggest that optimizing bleaching conditions can significantly affect both pigment removal and the antioxidant profile of the final product. Full article
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17 pages, 1632 KB  
Article
Adsorption of Imidazolium-Based ILs Combined on Activated Carbon Obtained from Grape Seeds
by Ismael F. Mena, Elena Diaz, Jose Palomar and Angel F. Mohedano
Molecules 2025, 30(23), 4595; https://doi.org/10.3390/molecules30234595 - 29 Nov 2025
Viewed by 222
Abstract
In this work, the adsorption of imidazolium-based ionic liquids containing the bis(trifluoromethanesulfonyl) imide anion (NTf2) from aqueous phase was evaluated using different activated carbons (ACs). Three commercial Acs and two Acs prepared from grape seeds (one produced by pyrolysis and [...] Read more.
In this work, the adsorption of imidazolium-based ionic liquids containing the bis(trifluoromethanesulfonyl) imide anion (NTf2) from aqueous phase was evaluated using different activated carbons (ACs). Three commercial Acs and two Acs prepared from grape seeds (one produced by pyrolysis and the other by hydrothermal carbonization (HTC), both activated with potassium hydroxide) were tested, assessing the adsorption of both the cation and the anion. For commercial ACs, similar adsorption performances were observed, with maximum adsorption capacities ranging from 0.85 to 1.08 mmol g−1. These values increased under acidic conditions (pH 4), reaching 1.74 mmol g−1 for the 1-butyl-3-methylimidazolium cation (Bmim+) and 1.87 mmol g−1 for NTf2. Among the prepared ACs, the HTC-derived AC showed slightly higher capacities than the commercial samples, while the pyrolysis-derived AC exhibited the highest adsorption capacity for BmimNTf2 (3.36 mmol g−1 at pH 4). In terms of reusability, the pyrolysis-derived AC maintained 84% of its initial adsorption capacity between the third and fifth regeneration cycles. These results highlight the high adsorption performance and recyclability of grape-seed-derived activated carbons, demonstrating their potential for the removal of ionic liquids from aqueous environments. Full article
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28 pages, 3279 KB  
Article
Early Stress Resilience in Turfgrass: Comparative Germination and Seedling Responses of Lolium perenne L. and Poa pratensis L. Under Osmotic and Salt Stress
by Ligia Craciun, Rodolfo J. Bacharach Sánchez, Diana M. Mircea, Adrián Sapiña-Solano, Radu E. Sestras, Monica Boscaiu, Adriana F. Sestras and Oscar Vicente
Agronomy 2025, 15(12), 2719; https://doi.org/10.3390/agronomy15122719 - 26 Nov 2025
Viewed by 363
Abstract
Seed germination and early seedling development represent critical stages for turfgrass establishment under increasingly frequent drought and salinity constraints. This study evaluated the germination performance of three cultivars of Lolium perenne L. and three cultivars of Poa pratensis L. exposed to iso-osmotic drought [...] Read more.
Seed germination and early seedling development represent critical stages for turfgrass establishment under increasingly frequent drought and salinity constraints. This study evaluated the germination performance of three cultivars of Lolium perenne L. and three cultivars of Poa pratensis L. exposed to iso-osmotic drought stress simulated with polyethylene glycol (PEG) and salt stress induced by NaCl. Germination percentage, mean germination time, germination index, seedling vigor index, and radicle and plumule elongation were quantified, and post-stress recovery tests assessed the reversibility of stress effects. Osmotic restriction imposed by PEG caused stronger inhibition of germination and seedling growth than NaCl at equivalent water potentials. L. perenne showed higher overall tolerance, maintaining faster emergence and greater seedling vigor across treatments, while P. pratensis was more sensitive but exhibited substantial germination recovery after stress removal. Cultivar-dependent variation was evident in both species, and multivariate analyses consistently differentiated tolerant and sensitive genotypes. The contrasting germination strategies, with rapid activation in L. perenne and delayed, recovery-oriented germination in P. pratensis, highlight species-specific adaptive responses to water and salt stress. These findings provide a physiological basis for selecting resilient turfgrass cultivars suited to drought- and salinity-prone environments, contributing to sustainable turfgrass establishment and management. Full article
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18 pages, 2184 KB  
Article
Nutrient Removal and Oxidative Response of Barley to Eutrophic Stress
by Jing Sun, Minghui Hou, Yanliang Sun, Shahbaz Khan, Kaixin Yang and Qianbing Zhang
Plants 2025, 14(23), 3595; https://doi.org/10.3390/plants14233595 - 25 Nov 2025
Viewed by 343
Abstract
Eutrophication caused by excessive nitrogen (N) and phosphorus (P) inputs threatens aquatic ecosystems and requires sustainable solutions. Barley (Hordeum vulgare L.) is a fast-growing forage crop with potential for removing nutrients in eutrophic waters; however, a comprehensive understanding of its physiological responses [...] Read more.
Eutrophication caused by excessive nitrogen (N) and phosphorus (P) inputs threatens aquatic ecosystems and requires sustainable solutions. Barley (Hordeum vulgare L.) is a fast-growing forage crop with potential for removing nutrients in eutrophic waters; however, a comprehensive understanding of its physiological responses across a wide gradient of concurrent N and P levels is still developing. To investigate this, a 7-day hydroponic experiment was conducted: six N + P enrichment levels, control (0), 70 + 7, 140 + 14, 280 + 28, 560 + 56, and 1120 + 112 mg·L–1 of total N and P (TN:TP fixed at 10:1), were prepared in hydroponic culture and their effect on seed germination, growth, nutritional quality, photosynthetic pigments, antioxidant activity, and nutrient removal efficiency were studied. Results showed that early germination was inhibited under nutrients and enriched conditions, but this recovered by day 3. A moderate nutrient supply (NP 70 + 7) promoted seedling growth, resulting in maximum plant height, fresh weight, crude protein (6.6%), ether extract (6.1%), and chlorophyll a (10.9%) compared to the control. Root growth was best in control, while high nutrient stress (NP 1120 + 112) led to the highest mortality (23.5%). This mortality was linked to a severe suppression of the enzymatic antioxidant system (SOD, POD, and CAT), indicating a collapse of primary oxidative defense under extreme stress. Nutritional quality improved under NP 140 + 14, which yielded the lowest NDF and ADF and the highest chlorophyll b (15%) and glutathione content (14.9%). Antioxidant enzymes (SOD, POD, and CAT) were most active in the control and declined with increasing N + P levels, while glutathione peaked under NP 140 + 14. This indicates a potential shift in the plant’s defense strategy, where glutathione plays a key role in mediating tolerance to moderate eutrophic stress. Nutrient removal analysis showed that N removal efficiency was highest under NP 70 + 7 (53.4%), whereas P removal decreased consistently with rising concentrations. Overall, barley grass seedlings tolerated N + P levels up to NP 280 + 28 while maintaining growth and nutrient uptake, a resilience facilitated by its dynamic antioxidant response, suggesting their potential role in phytoremediation of eutrophic waters. Full article
(This article belongs to the Section Plant Response to Abiotic Stress and Climate Change)
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17 pages, 4351 KB  
Article
Sequential Treatment of Domestic Wastewater in Rural Zones Applying Aloe Vera Extract as Coagulant (Preliminar), E. crassipes in a Horizontal Biofilter (Secondary), and Activated Carbon from Soursop Seeds (Tertiary)
by Franco Hernan Gomez, Maria Cristina Collivignarelli, Stefano Bellazzi, Kelly Cristina Torres, Alessandro Abbà and Sabrina Sorlini
Clean Technol. 2025, 7(4), 105; https://doi.org/10.3390/cleantechnol7040105 - 24 Nov 2025
Viewed by 434
Abstract
The absence of domestic wastewater (DWW) treatment in impoverished rural communities of the global south remains a pressing challenge for both public health and environmental sustainability. This study presents a simplified and decentralized treatment chain at laboratory-scale designed under the principles of nature-based [...] Read more.
The absence of domestic wastewater (DWW) treatment in impoverished rural communities of the global south remains a pressing challenge for both public health and environmental sustainability. This study presents a simplified and decentralized treatment chain at laboratory-scale designed under the principles of nature-based solutions (NBS) and the circular economy (CE), emphasizing the integration of the macrophyte Eichhornia crassipes (EC) and bioproducts derived from aloe vera waste (AVW) and soursop seed waste (SSW). The system comprises three sequential stages: (1) coagulation using AVW, which achieved up to 39.9% turbidity reduction; (2) a horizontal flow biofilter system (HFB) employing the aquatic macrophyte EC, which removed 97.9% of fecal coliforms, 82.4% of Escherichia coli, and 99.9% of heterotrophic bacteria; and (3) a tertiary treatment step employing adsorbent derived from SSW, which attained 99.7% methylene blue removal in preliminary tests and an average 97.5% turbidity reduction in DWW. The integrated configuration demonstrates a practical, effective, and replicable approach for decentralized domestic wastewater treatment, fostering local waste valorization, reducing reliance on commercial chemicals, and enhancing water quality in resource-limited rural areas, with potential for scaling to pilot applications in rural communities. Full article
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20 pages, 2773 KB  
Article
Synthesis and Characterization of Biochar Obtained by Partial Delignification of Waste Biomass
by Gabriel Vasilievici, Mia Sanda, Marian Băjan, Cristina Dușescu-Vasile, Ion Onuțu, Gheorghe Brănoiu, Dorin Bomboș, Abeer Baioun, Anca Florentina Borcea and Andra-Ioana Stănică
Molecules 2025, 30(23), 4505; https://doi.org/10.3390/molecules30234505 - 22 Nov 2025
Viewed by 513
Abstract
Biochar activation is achieved by removing tar formed in the pores during the thermal treatment of biomass, thereby increasing pore volume. This process typically involves entraining tar with steam at elevated temperatures for extended durations. In this study, a reduction in lignin content [...] Read more.
Biochar activation is achieved by removing tar formed in the pores during the thermal treatment of biomass, thereby increasing pore volume. This process typically involves entraining tar with steam at elevated temperatures for extended durations. In this study, a reduction in lignin content in grape seeds through partial solubilization, prior to thermal treatment, is proposed. Initially, grape seeds were treated with a basic sodium sulfide solution, followed by conditioning with either phosphoric acid or zinc chloride and then drying and calcination. The synthesized adsorbents were characterized using scanning electron microscopy (SEM), textural analysis, Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and evaluation of toluene adsorption capacity. Textural analysis indicated that conditioning with phosphoric acid or zinc chloride increased the specific surface area of biochar by over 20%, with a higher increase observed for phosphoric acid treatment. The toluene adsorption capacity of the adsorbents was assessed in a continuous fixed-bed system. Biochar pretreated with ZnCl2 exhibited an adsorption capacity of 0.11 cm3 of toluene per gram, while biochar pretreated with phosphoric acid demonstrated a capacity of 0.14 cm3 per gram. These results indicate that preliminary delignification of grape seed biomass maintains its adsorption capacity of toluene at levels comparable to other adsorbents, despite a lower activation temperature. Full article
(This article belongs to the Special Issue Advanced Removal of Emerging Pollutants and Its Mechanism)
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11 pages, 1965 KB  
Article
Removal of an Invasive Alien Mediterranean Herbaceous (Asphodelus fistulosus) in a Mexican Botanical Garden
by Oscar Sandino Guerrero-Eloisa, Jordan Golubov, María C. Mandujano and Beatriz Maruri-Aguilar
J. Zool. Bot. Gard. 2025, 6(4), 59; https://doi.org/10.3390/jzbg6040059 - 21 Nov 2025
Viewed by 330
Abstract
Botanical gardens promote the conservation of native species of the sites where they are located, showing the importance of preserving native flora. It is common to find invasive alien species (IAS) established intentionally or accidentally in these sites. In a patch of native [...] Read more.
Botanical gardens promote the conservation of native species of the sites where they are located, showing the importance of preserving native flora. It is common to find invasive alien species (IAS) established intentionally or accidentally in these sites. In a patch of native vegetation within the Cadereyta de Montes Regional Botanical Garden, the removal of the invasive alien Asphodelus fistulosus was carried out and during a subsequent 108-month period. The repopulation of the species was supervised by removing new individuals at each visit. More than 1000 individual plants of A. fistulosus were removed during the entire monitoring period, and through subsequent visits, no new individuals have been spotted. The monetary cost associated with the removal, monitoring and control of A. fistulosus was calculated over MXN 15,000.00. The removal and post-removal monitoring of species at sites of interest provide valuable information about control time and economic costs to consider in the control of IAS. Additionally, the germination experiments carried out with seeds from different years of collection showed a higher germination percentage that was not affected by the age of the seeds. Full article
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18 pages, 2742 KB  
Article
Chemical and Bio-Based Coagulation Coupled with Adsorption: Advancing Leachate Treatment Chemistry
by Maroua Almi, Nadia Chekir, Leila Merabti, Djilali Tassalit, Naima Sahraoui, Soumeya Bouchareb, Khadidja Benkraouche, Wissam Yanina and Seif El Islam Lebouachera
Appl. Sci. 2025, 15(22), 11948; https://doi.org/10.3390/app152211948 - 10 Nov 2025
Viewed by 560
Abstract
Leachate from the Magtaa Kheira landfill exhibits complex physicochemical characteristics that restrict the efficacy of single-treatment processes. This study assessed a sustainable two-stage treatment strategy combining coagulation–flocculation and adsorption. During the initial stage of the study, both aluminum sulfate (AS) and a bio-based [...] Read more.
Leachate from the Magtaa Kheira landfill exhibits complex physicochemical characteristics that restrict the efficacy of single-treatment processes. This study assessed a sustainable two-stage treatment strategy combining coagulation–flocculation and adsorption. During the initial stage of the study, both aluminum sulfate (AS) and a bio-based coagulant derived from Moringa oleifera seeds (MOS) were evaluated for their effectiveness in the pretreatment of leachate. Box–Behnken Design combined with Response Surface Methodology was used to optimize the coagulation process using aluminum sulfate (AS). The highest removal efficiencies were 91% for turbidity and 85% for chemical oxygen demand (COD) removal, achieved at an AS concentration of 1.44 g·L−1 and an initial pH of 8. In parallel, the performance of MOS extract was investigated as an eco-friendly alternative to AS. An FTIR analysis revealed the presence of protein-associated hydroxyl (3288 cm−1) and carboxyl and amine groups (1647 cm−1), which are integral to destabilization via hydrogen bonding, while SEM confirmed a surface morphology conducive to effective floc formation. MOS demonstrated comparable turbidity removal to AS, significantly reducing both sludge generation and chemical consumption. Following the coagulation stage, treated leachates were passed through a granular activated carbon (GAC) column, enhancing overall COD removal to over 94% to reach acceptable discharge and reuse levels. The coagulation–adsorption sequence, incorporating both chemical and bio-based coagulants, provides an efficient and sustainable approach for the treatment of complex leachate, addressing both performance and environmental considerations. Full article
(This article belongs to the Special Issue Water Pollution and Wastewater Treatment Chemistry)
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16 pages, 772 KB  
Article
Removal of Myclobutanil and Detoxification in Modified Biomixtures: Fungal Bioaugmentation and Biochar Amendment
by Paraskevas Parlakidis, Víctor Castro-Gutiérrez, Mario Masís-Mora, Zisis Vryzas and Carlos E. Rodríguez-Rodríguez
Sustain. Chem. 2025, 6(4), 40; https://doi.org/10.3390/suschem6040040 - 3 Nov 2025
Viewed by 616
Abstract
Biopurification systems are designed for the treatment of pesticide-containing agricultural wastewater; their biologically active matrix, the biomixture, can be modified to enhance the pesticide removal capacity. Two approaches, fungal bioaugmentation with Trametes versicolor and amendment with biochar, were applied for the potential improvement [...] Read more.
Biopurification systems are designed for the treatment of pesticide-containing agricultural wastewater; their biologically active matrix, the biomixture, can be modified to enhance the pesticide removal capacity. Two approaches, fungal bioaugmentation with Trametes versicolor and amendment with biochar, were applied for the potential improvement of biomixtures’ capacity to remediate myclobutanil-contaminated wastewater. The conventional biomixture (B) and its modifications, either bioaugmented with Trametes versicolor (biomixture BT) or supplemented with pineapple biochar (5% v/v) (biomixture BB), were spiked with myclobutanil at a very high concentration (10,000 mg/kg) to simulate extreme on-farm events such as the disposal or leakage of commercial formulations. The dissipation followed a bi-phasic behavior in every case. Both modifications of the conventional biomixture increased the dissipation rates, resulting in estimated DT50 values of 61.9 (BB) and >90 days (BT) compared to biomixture B (DT50 = 474 days). The assessment of biomixtures’ detoxification was carried out with two different bioindicators: a seed germination test in Lactuca sativa and an algal growth inhibition test. Some degree of detoxification was achieved for all biomixtures in both indicators, with the exception of the biochar-containing biomixture, which, despite showing the fastest myclobutanil dissipation, was unable to maintain a steady detoxification trend towards the algae over the course of the treatment, probably due to biochar adverse effects. This approach seems promising for removing persistent myclobutanil from agricultural wastewater and demonstrates the dissipation capacity of biomixtures at extremely high pesticide concentrations likely to take place at an on-farm level. Full article
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26 pages, 1513 KB  
Review
Functional Coatings for Fiber Bragg Gratings: A Critical Review of Deposition Techniques for Embedded and Harsh-Environment Applications
by Cristian Vendittozzi, Emilia Di Micco, Michele A. Caponero and Rosaria D’Amato
Coatings 2025, 15(11), 1268; https://doi.org/10.3390/coatings15111268 - 2 Nov 2025
Viewed by 692
Abstract
Fiber Bragg Grating (FBG) sensors facilitate compact, multiplexed, and electromagnetic interference-immune monitoring in embedded and harsh environments. The removal of the polymer jacket, a measure taken to withstand elevated temperatures or facilitate integration, exposes the fragile glass. This underscores the necessity of functional [...] Read more.
Fiber Bragg Grating (FBG) sensors facilitate compact, multiplexed, and electromagnetic interference-immune monitoring in embedded and harsh environments. The removal of the polymer jacket, a measure taken to withstand elevated temperatures or facilitate integration, exposes the fragile glass. This underscores the necessity of functional coatings, which are critical for enhancing durability, calibrating sensitivity, and improving compatibility with host materials. This review methodically compares coating materials and deposition routes for FBGs, encompassing a range of techniques including top-down physical-vapor deposition (sputtering, thermal/e-beam evaporation, cathodic arc), bottom-up chemical vapor deposition (CVD)/atomic layer deposition (ALD), wet-chemical methods (sensitization/activation, electroless plating (EL), electrodeposition (ED)), fusion-based processes (casting and melt coating), and hybrid stacks (e.g., physical vapor deposition (PVD) seed → electrodeposition; gradient interlayers). The consolidation of surface-preparation best practices and quantitative trends reveals a comprehensive understanding of the interrelationships between coating material/stack, thickness/microstructure, adhesion, and sensitivity across a range of temperatures, extending from approximately 300 K to cryogenic regimes. Practical process windows and design rules are distilled to guide method selection and reliable operation across cryogenic and high-temperature regimes. Full article
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