Search Results (1,143)

Accelerated oxidation experiments on Chinese 0# diesel fuel were performed with a self-designed aging reactor system. Five experimental conditions covering pressures ranging from atmospheric pressure to 0.8 MPa, temperatures ranging from room temperature (25 °C) to 80 °C, and their synergistic effects were adopted to simulate the long-term oxidation of diesel fuel. The extent of deterioration was evaluated based on the measurement of three key indicators, i.e., oxidation stability, wear scar diameter, and viscosity. Thermogravimetric analysis (TGA) tests were performed, and the measured thermogravimetric (TG) curves and derivative thermogravimetric (DTG) curves were used to evaluate the effects of reactor material, heating rate, bath gas, and reactive gas on the deterioration and vaporization processes of diesel fuel. Based on a comparison of the deterioration indicators of diesel fuel collected from the accelerated oxidation experiments and oil depots serving actual operating emergency diesel generators (EDGs), a rapid assessment method of real-time diesel deterioration was explored. Based on the experimental observations, the affecting mechanisms of the increases in temperature and oxygen partial pressure were discussed. Two test methods of accelerated oxidation, with the respective conditions of 0.8 MPa/80 °C and atmospheric pressure/80 °C, were proposed, which could effectively compress the time needed for long-term storage simulations (e.g., 200 h lab aging equals three years of actual operation). The optional temperature and pressure windows for acceleration oxidation were confirmed (40–80 °C/0.3–0.8 MPa). These results are valuable for the further understanding of the processes of deterioration and vaporization of diesel fuel. Full article

Integrating bioluminescent organisms as passive lighting sources in the built environment is currently a hot topic. However, there are several limitations facing the implementation and up-scaling of these naturally bioluminescent organisms in the built environment on architectural and urban scales, such as the scale, sensitivity, enclosure, and difficulty of maintenance. Moreover, there are complex technicalities and operational aspects of conventional bioreactors that host these bioluminescent agents, especially in terms of managing their recharge and effluent, not to mention their high maintenance cost. The current work offers a sustainable, stand-alone, bioluminescent urban screen system employing Aliivibrio fischeri CECT 524 bioink on 3D-printed customized scaffolds as bioreceptive panel design based on a field-diffusion pattern to host the bioluminescent bacterial bioink. The field-diffusion pattern was employed thanks to its proven efficiency in entrapment of the various microbial cultures. Three different growth media were tested for culturing Aliivibrio fischeri CECT 524, including Luria Bertani Broth (LB), the Tryptone Soy Broth (TSB), and the standard Marine Broth (MB). The results revealed that the Marine Broth (MB) media achieved the highest bioluminescent intensity and duration. The maximum light emission typically in range of ~490 nm of blue–green light captured by a conventional reflex camera (human eye vision) was observed for 10 consecutive days in complete darkness after 3–10 s, at a room temperature of 25 °C. This was visible mainly at the thin curvilinear peaks of the 3D-printed field pattern. P1 achieved the highest performance in terms of visible blue–green light, and a duration of 10 days of active bioluminescence was achieved without the need for refilling, thanks to the high number of peaks and narrow wells at <0.5 cm of its field-diffusion pattern. This study proves the efficiency of this biomimetic pattern in terms of the bioreceptivity of the bioluminescent bacterial bioink. Furthermore, the proposed 3D-printed urban screens proved their economic sustainability in terms of affordability and their minimized production processes, in addition to their easy maintenance and recharge. These results qualify these 3D-printed bioluminescent urban screens for easy and decentralized adoption and application on an architectural and urban scale. Full article

The subject of this paper is an analysis of the use of wall heating and cooling modules with heat pipes for efficient space heating and cooling. The modules under consideration constitute a structural element installed in the room’s partition structure and consist of heat pipes embedded in a several-centimeter layer of concrete. Water-based central heating and chilled water systems were used as the heat and cooling source. The heat pipes are filled with a thermodynamic medium that changes state in repeated gas–liquid cycles. The advantage of this solution is the use of heat pipes as a heating and cooling element built into the wall, instead of a traditional water system. This solution offers many operational benefits, such as reduced costs for pumping the heat medium. This paper presents an analysis of the potential of using heat pipe modules for heating and cooling in real-world buildings in Poland. Taking into account the structural characteristics of the rooms under consideration (i.e., internal wall area, window area), an analysis was conducted to determine the potential use of the modules for space heating and cooling. The analysis was based on rooms where, according to the authors, the largest possible use of internal and external wall surfaces is possible, such as hotels and schools. Based on the simulations and calculations, it can be concluded that the modules can be effectively used in Poland as a real heating and cooling element: standalone, covering the entire heating and cooling demand of a room, e.g., a hotel room, or as a component working with an additional system, e.g., air cooling and heating in school buildings. The changes in outdoor air temperature, during the year analyzed in the article, were in the range of −24/+32 °C. Full article

This paper describes two low-cost, modular instruments developed for rapid room-temperature characterization of mainly thermoelectrics. The first instrument measures the Seebeck coefficient across diverse sample geometries and incorporates a four-point probe configuration for simultaneous electrical conductivity measurement, including disk-shaped samples. The second instrument implements the Van der Pauw method, enabling detailed investigation of charge carrier behavior within materials. Both devices prioritize accessibility, constructed primarily from 3D-printed components, basic hardware, and readily available instrumentation, ensuring ease of reproduction and modification. A unique calibration protocol using pure elemental disks and materials with well-established properties was employed for both instruments. Validation against comparable systems confirmed reliable operation. Control and data acquisition software for both devices was developed in-house and is fully documented and does not require an experienced operator. We demonstrate the utility of these instruments by characterizing the electronic properties of polycrystalline SnSe thermoelectric materials doped with Bi, Ag, and In. The results reveal highly complex charge carrier behavior significantly influenced by both dopant type and concentration. Full article

The prompt and reliable detection of NH₃ leakage at room temperature (RT) is considered important for safety assurance and sustainable production. Although chemiresistive NH₃ sensors feature low cost and structural simplicity, their practical application is hindered by high operating temperatures and inadequate selectivity. Metal–organic frameworks (MOFs) and their derivatives offer a promising approach to address these limitations. In this work, Ce-BDC precursors with tunable particle sizes and crystallinity were synthesized by adjusting the raw material concentration. Controlled pyrolysis yielded a series of CeO₂-C-X (X = 0.5, 1, 1.5, 2) materials with nanosized particles. Among them, the CeO₂-C-1 sensor delivered a high response of 82% toward NH₃ under 40% relative humidity at RT. Moreover, it possessed excellent selectivity, repeatability, and rapid response-recovery behavior compared with the other samples. CeO₂-C-1 also remained stable under varying oxygen and humidity conditions, demonstrating high applicability. The superior sensing properties may be attributed to its high specific surface area and optimized mesoporous structure, which facilitated efficient gas adsorption and reaction. These findings demonstrated that precise control of MOF precursors and the structure in CeO₂ nanomaterials was critical for achieving high-performance gas sensing and established Ce-MOF-derived CeO₂ as a promising sensing material for NH₃ detection at RT. Full article

In metallurgy, the quenching process often induces changes in certain material properties, such as hardness and ductility, through the rapid cooling of a workpiece in water, gas, oil, polymer, air, or other fluids. Given that lithium-ion batteries operate under relatively benign conditions, conventional rapid cooling does not significantly affect the property variations in their internal electrode materials during normal use. However, thermal runaway presents an exception due to its dramatic temperature fluctuations from room temperature to several hundred degrees Celsius. In this study, we investigated NCM811 cathodes in 18,650 batteries subjected to transient thermal runaway followed by rapid cooling using several advanced analytical techniques. The results reveal a phenomenon characterized by intergranular cracking within NCM811 cathode materials when exposed to rapid cooling during transient thermal runaway. Furthermore, lithium-ion cells utilizing reused NCM-182.4 electrodes in fresh electrolyte demonstrate a reversible capacity of 231.4 mAh/g after 30 cycles at 0.1 C, highlighting the potential for reusing NCM811 cathodes in the lithium-ion battery recycling process. These findings not only illustrate that NCM811 particles may experience intergranular cracking when subjected to rapid cooling during transient thermal runaway, but also the rapidly cooled NCM811 electrodes exhibit potential for reuse. Full article

The building sector plays a key role in the transition toward climate neutrality, with national regulations across the EU requiring the construction of nearly zero-energy buildings (nZEBs). However, while energy performance has been extensively studied, less attention has been given to the problem of ensuring user comfort—both indoors and in the surrounding outdoor areas—under nZEB design constraints. This gap raises two key research objectives: (1) to evaluate whether a well-designed nZEB with extensive glazing maintains acceptable indoor thermal comfort and (2) to assess whether residents experience greater outdoor thermal comfort and satisfaction in small, sun-exposed private gardens or in larger, shaded communal green spaces. To address these objectives, a newly built residential estate near Kraków (Poland) was analyzed. The investigation included simulation-based assessments during the design phase and in situ measurements during building operation, complemented by a user survey on spatial preferences. Indoor comfort was evaluated for rooms with large glazed façades, as well as rooms with standard-sized windows, while outdoor comfort was assessed in both private gardens and a shared green courtyard. Results show that shading the southwest-oriented glazed façade with an overhanging terrace provided slightly lower temperatures in ground-floor rooms compared to rooms with standard unshaded windows. Outdoors, users experienced lower thermal comfort in small, unshaded gardens than in the larger, vegetated communal area (pocket park), which demonstrated greater capacity for temperature moderation and thermal stress reduction. Survey responses further indicate that potential future residents prefer the inclusion of a shared green–blue infrastructure area, even at the expense of building some housing units in semi-detached form, instead of maximizing the number of detached units with unshaded individual gardens. These findings emphasize the importance of addressing both indoor and outdoor comfort in residential nZEB design, showing that technological efficiency must be complemented by user-centered design strategies. This integrated approach can improve the well-being of residents while supporting climate change adaptation in the built environment. Full article

Invasive cases of Mycobacterium chimaera have been found in Europe, and beyond, and have been associated with the use of heater–cooler units necessary to regulate the temperature of blood in extracorporeal circulation during cardiac surgery, mostly due to contamination of patients by aerosol coming from the water in the tanks of the devices. An outbreak of five cases of M. chimaera infection associated with heater–cooler units Stockert 3T (LivaNova) was also identified in the Piedmont region (Italy). M. chimaera strains isolated from 10 Stockert 3T heater–cooler units used in 3 regional cardiac surgery operating rooms were subjected to whole-genome sequencing. The results were analysed according to van Ingen’s criteria. M. chimaera was isolated from 59% of heater–cooler units Stockert 3T (LivaNova) monitored. By whole-genome sequencing analysis performed on M. chimaera strains obtained from 10 heater–cooler units, four strains were classified as subgroup 1.1 or 1.8, which are the two subgroups associated with the HCU-related outbreak worldwide. Our data and their comparisons with global heater–cooler unit isolates provide further evidence of the hypothesis that contamination occurs at the production site of LivaNova following exposure to M. chimaera-contaminated factory plumbing systems. Full article

This work presents a novel Gallium Nitride (GaN) high-electron-mobility transistor (HEMT)-based ultraviolet (UV) photodetector architecture that integrates advanced material and structural design strategies to enhance detection performance and stability under room-temperature operation. This study is conducted as a fully numerical simulation using the Silvaco Atlas platform, providing detailed electrothermal and optoelectronic analysis of the proposed device. The device is constructed on a high-thermal-conductivity silicon carbide (SiC) substrate and incorporates an n-GaN buffer, an indium nitride (InN) channel layer for improved electron mobility and two-dimensional electron gas (2DEG) confinement, and a dual-passivation scheme combining silicon nitride (SiN) and hexagonal boron nitride (h-BN). A p-GaN layer is embedded between the passivation interfaces to deplete the 2DEG in dark conditions. In the device architecture, the metal contacts consist of a 2 nm Nickel (Ni) adhesion layer followed by Gold (Au), employed as source and drain electrodes, while a recessed gate embedded within the substrate ensures improved electric field control and effective noise suppression. Numerical simulations demonstrate that the integration of a hexagonal boron nitride (h-BN) interlayer within the dual passivation stack effectively suppresses the gate leakage current from the typical literature values of the order of ${10}^{-8}$ A to approximately ${10}^{-10}$ A, highlighting its critical role in enhancing interfacial insulation. In addition, consistent with previous reports, the use of a SiC substrate offers significantly improved thermal management over sapphire, enabling more stable operation under UV illumination. The device demonstrates strong photoresponse under 360 nm ultraviolet (UV) illumination, a high photo-to-dark current ratio (PDCR) found at approximately ${10}^6$, and tunable performance via structural optimization of p-GaN width between 0.40 μm and 1.60 μm, doping concentration from $5\times {10}^{16}$ ${\mathrm{cm}}^{-3}$ to $5\times {10}^{18}$ ${\mathrm{cm}}^{-3}$, and embedding depth between 0.060 μm and 0.068 μm. The results underscore the proposed structure’s notable effectiveness in passivation quality, suppression of gate leakage, and thermal management, collectively establishing it as a robust and reliable platform for next-generation UV photodetectors operating under harsh environmental conditions. Full article

P92 martensitic heat-resistant steel is widely used in ultra-supercritical (USC) thermal power units due to its excellent creep resistance and high-temperature strength. However, prolonged exposure to high temperatures induces significant microstructural degradation, compromising mechanical properties and operational safety. This study investigates the evolution of microstructure and mechanical properties in P92 steel extracted from main steam pipelines after service durations of 30,000 h, 47,000 h, 56,000 h, 70,000 h, and 93,000 h. Comparative analyses of impact toughness, tensile strength, and creep strength were conducted and advanced characterization of SEM and TEM was used to investigate the microstructural evolution. The results reveal a progressive decline in mechanical properties with increasing service time. Specifically, impact toughness decreased by approximately 66.8%, room-temperature tensile strength reduced by 9.62%, and high-temperature tensile strength at 610 °C declined by 31.6%. Notably, the 10⁵ hour creep rupture strength exhibited a 10.4% decrease compared to as-received material. This decline is attributed to microstructural changes including precipitate coarsening, martensite lath boundary degradation, dislocation reconfiguration, and severe grain coarsening. The coarsening of precipitates weakens their bonding with the matrix, while the widening of martensite laths reduces resistance to crack propagation and dislocation movement, jointly contributing to strength deterioration. Full article

The Ni-Fe coatings modified with AuNPs were deposited on the flexible copper-coated polyimide (Cu/PI) surface using electroless metal plating, while the galvanic displacement technique was applied to modify the surface of NiFe coatings by a small content of AuNPs in the range of 16.5 µg_Au cm⁻². AuNPs of a few nanometers in size were deposited on the NiFe/Cu/PI surface by immersing it in a solution containing AuCl₄⁻ ions. The electrooxidation of sodium borohydride was evaluated in a 1 M NaOH solution containing 0.05 M of sodium borohydride using cyclic voltammetry, chronoamperometry, and chronopotentiometry. In addition, the performance and stability of the NiFe/Cu/PI and AuNPs-NiFe/Cu/PI catalysts were evaluated for potential use in a direct NaBH₄-H₂O₂ fuel cell. The NiFe coating modified with AuNPs demonstrated significantly higher electrocatalytic activity towards the oxidation of sodium borohydride as compared to bare Au or unmodified NiFe/Cu/PI. Furthermore, it exhibited a superior power density of 89.7 mW cm⁻² at room temperature and operational stability under alkaline conditions, while the NiFe anode exhibited 73.1 mW cm⁻². These results suggest that the AuNPs-modified NiFe coating has great potential as a material for use in direct borohydride fuel cells (DBFCs) applications involving the oxidation of sodium borohydride. Full article

Room-temperature (RT) gas sensors for nitrogen dioxide (NO₂) detection face persistent challenges, including reliance on high operating temperatures and inefficient charge carrier utilization under UV activation. To address these limitations, we engineered a p-n nano-heterojunction (NHJ) gas sensor by integrating p-type nickel oxide (NiO) nanoparticles onto n-type zinc oxide (ZnO) nanorods. This architecture leverages UV-driven carrier generation and interfacial electric fields at the NHJ to suppress recombination, enabling unprecedented RT performance. By optimizing thermal annealing conditions, we achieved a well-defined heterojunction with uniform NiO distribution on the top of the ZnO nanorods, validated through electron microscopy and X-ray photoelectron spectroscopy. The resulting sensor exhibits a 5.4-fold higher normalized response to 50 ppm NO₂ under 365 nm UV illumination compared to pristine ZnO, alongside rapid recovery and stable cyclability. The synergistic combination of UV-assisted carrier generation and heterojunction-driven interfacial modulation offers a promising direction for next-generation RT gas sensors aimed at environmental monitoring. Full article

We examined the effect of SiO₂ passivation on the parameters of mesa heterostructure InAs/InAsSbP photodiodes with a spectral responsivity 50% cut off at 3.5 µm at 295 K, specific to the InAs absorber layer. The R₀A product was found to increase by 30% after passivation of the devices of 113 µm in diameter, up to 0.9 Ωcm², while for those with a diameter of 1.13 mm, R₀A of 2.2 Ωcm² was achieved, with a value of D* > 3 × 10⁹ cmHz^1/2/W at the peak of the spectrum, 1 kHz, 0 V bias, 295 K. To the best of our knowledge, this is the highest R₀A value at room temperature reported to date for a photodiode with an InAs absorber. Full article

In nondestructive evaluation of concrete structures, the far-infrared region, including terahertz waves, which can penetrate concrete and measure the amount of corrosion in the internal steel, has attracted much attention. Magnetite has the potential to be used as a far-infrared detection device that meets the requirements for nondestructive evaluation devices, such as room temperature operation and portability, while also having a low environmental impact. In this study, the sensitivity of magnetite thin films with different concentrations of Pt to electromagnetic waves at a wavelength of 10.6 μm was evaluated and compared: a nanocomposite with Pt nanocrystals dispersed in magnetite thin films was prepared by radio frequency sputtering, electrodes were prepared by a photoresist process, and the resistance variation was recorded after irradiation with 10.6 μm pulse electromagnetic waves. As a result, it was experimentally confirmed that the peak of response was the maximum at the amount of Pt added, where the electrical resistivity reached 12,000 µΩcm, and the S/N ratio was the maximum at the amount of Pt added, where the electrical resistivity reached 14,000 µΩcm. This indicates that Pt-doped magnetite with a Pt content of 14,000 µΩcm electrical resistivity is suitable as a far-infrared detector element material. Full article

Field emission (FE) cold-cathodes have some important characteristics, including instant turn-on, room temperature operation, miniaturization, low power consumption, and nonlinearity. As emitters, Carbon nanotubes (CNTs) exhibit a high field enhancement factor, low turn-on voltage, high current density, high thermal conductivity, and temporal stability. These properties make them highly suitable for applications in FE cold-cathodes. In addition, Carbon nanotube (CNT) cold cathodes have specialized applications in electron beams, which are modulated by high-frequency electric fields and exhibit low energy dispersion. There have been substantial studies on CNT-based cold cathode electron guns with diverse structural configurations. These studies have laid the foundation for the applications of microwave vacuum electron devices, X-ray equipments, flat-panel displays, and scanning electron microscopes. The review primarily introduces cold cathode electron guns based on CNT emitters with diverse morphologies, including disordered CNTs, aligned CNTs, CNT paste, and other CNTs with special surface morphologies. Additionally, the research results of microwave electron guns based on CNT cathodes are also mentioned. Finally, the problems that need to be resolved in the practical applications of CNT cold cathode electron guns are summarized, and some suggestions for future development are provided. Full article