Search Results (174)

Lignocellulosic biomass—the non-edible fraction of plants composed of cellulose, hemicellulose, and lignin—is the most abundant renewable carbon resource and a key lever for shifting from fossil to bio-based production. Agro-industrial residues (straws, cobs, shells, bagasse, brewery spent grains, etc.) offer low-cost, widely available feedstocks but are difficult to process because their polymers form a tightly integrated, three-dimensional matrix. Within this matrix, lignin provides rigidity, hydrophobicity, and defense, yet its heterogeneity and recalcitrance impede saccharification and upgrading. Today, most technical lignin from pulping and emerging biorefineries is burned for energy, despite growing opportunities to valorize it directly as a macromolecule (e.g., adhesives, foams, carbon precursors, UV/antioxidant additives) or via depolymerization to low-molecular-weight aromatics for fuels and chemicals. Extraction route and severity strongly condition lignin structure linkages (coumaryl-, coniferyl-, and sinapyl-alcohol ratios), determining reactivity, solubility, and product selectivity. Advances in selective fractionation, reductive/oxidative catalysis, and hybrid chemo-biological routes are improving yields while limiting condensation. Remaining barriers include feedstock variability, solvent and catalyst recovery, hydrogen and energy intensity, and market adoption (e.g., low-emission adhesives). Elevating lignin from fuel to product within integrated biorefineries can unlock significant environmental and economic benefits. Full article

With the global ageing population and the increasing prevalence of mobility impairments, the demand for effective and comfortable rehabilitation and assistive solutions has grown rapidly. Soft exoskeletons have emerged as a key direction in the development of wearable rehabilitation devices. This review examines how these systems are designed and controlled, as well as how they differ from the rigid exoskeletons that preceded them. Made from flexible fabrics and lightweight components, soft exoskeletons use pneumatic or cable mechanisms to support movement while keeping close contact with the body. Their compliant structure helps to reduce joint stress and makes them more comfortable for long periods of use. The discussion in this paper covers recent work on lower-limb designs, focusing on actuation, power transmission, and human–robot coordination. It also considers the main technical barriers that remain, such as power supply limits, the wear and fatigue of soft materials, and the challenge of achieving accurate tracking performance, low latency, and resilience to external disturbances. Studies reviewed here show that these systems help users regain functionality and improve rehabilitation, while also easing caregivers’ workload. The paper ends by outlining several priorities for future development: lighter mechanical layouts, better energy systems, and adaptive control methods that make soft exoskeletons more practical for everyday use as well as clinical therapy. Full article

This scoping review examines how workplace language proficiency and corporate language policies function as dimensions of human capital, shaping employee mobility and organisational outcomes in multilingual contexts. Drawing on 12 empirical studies (2010–2025), supplemented by one influential review work used for context, the review integrates two analytical lenses: (1) language ceilings and walls, which capture invisible barriers to vertical and horizontal mobility, and (2) the Language Needs Analysis (LANA) framework, which categorises language demands at the individual, organisational, and operational levels. Findings indicate that language proficiency and inclusive language policies act as strategic resources that enhance employability, cross-border collaboration, and knowledge transfer. Conversely, rigid monolingual policies often reproduce inequalities and limit career progression. The review highlights the role of language-sensitive HRM in developing sustainable talent pipelines, advancing diversity and inclusion, and strengthening workforce resilience. Methodologically, this study applies PRISMA-ScR guidelines to ensure transparency and rigour, while offering a framework for future research at the intersection of human capital theory, language policy, and global HRM. By reframing communicative competence as career capital, the review underscores the need to integrate language training and policy design into broader human capital development strategies. Full article

Nanoparticle superlattices—periodic assemblies of uniformly spaced nanocrystals—bridge the nanoscale precision of individual particles with emergent collective properties akin to those of bulk materials. Recent advances demonstrate that multivalent ions and charged polymers can guide the co-assembly of nanoparticles, imparting electrostatic gating and enabling semiconductor-like behavior. However, the specific roles of anion geometry, valency, and charge density in mediating ion transport remain unclear. Here, we employ coarse-grained molecular dynamics simulations to investigate how applied electric fields (0–0.40 V/nm) modulate ionic conductivity and spatial distribution in trimethylammonium-functionalized gold nanoparticle superlattices assembled with four phosphate anions of distinct geometries and charges. Our results reveal that linear anions outperform ring-shaped analogues in conductivity due to higher charge densities and weaker interfacial binding. Notably, charge density exerts a greater influence on ion mobility than size alone. Under strong fields, anions accumulate at nanoparticle interfaces, where interfacial adsorption and steric constraints suppress transport. In contrast, local migration is governed by geometrical confinement and field strength. Analyses of transition probability and residence time further indicate that the rigidity and delocalized charge of cyclic anions act as mobility barriers. These findings provide mechanistic insights into the structure–function relationship governing ion transport in superlattices, offering guidance for designing next-generation ion conductors, electrochemical sensors, and energy storage materials through anion engineering. Full article

This study develops an ontology-based decision support framework to enhance sustainable polymer recycling within the circular economy. The framework, constructed in Protégé (OWL 2), systematically captures polymer categories with emphasis on polyethylene terephthalate (PET), polylactic acid (PLA), and rigid polyvinyl chloride (PVC) as well as recycling processes, waste classifications, and sustainability indicators such as carbon footprint. Semantic reasoning was implemented using the Semantic Web Rule Language (SWRL) and SPARQL Protocol and RDF Query Language (SPARQL) to infer optimal material flows and sustainable pathways. Validation through a UK industrial case study confirmed both the framework’s applicability and highlighted barriers to large-scale recycling, including performance gaps between virgin and recycled polymers. The comparative analysis showed carbon footprints of 2.8 kg CO₂/kg for virgin PET, 1.5 kg CO₂/kg for PLA, and 2.1 kg CO₂/kg for PVC, underscoring material-specific sustainability challenges. Validation through a UK industrial case study further highlighted additive complexity in PVC as a major barrier to large scale recycling. Bibliometric and thematic analyses conducted in this study revealed persistent gaps in sustainability metrics, lifecycle assessment, and semantic support for circular polymer systems. By integrating these insights, the proposed framework provides a scalable, data-driven tool for evaluating and optimising polymer lifecycles, supporting industry transitions toward resilient, circular, and net-zero material systems. Full article

The persistence of a binary biomedical framework in healthcare has become increasingly inadequate to address the realities of human diversity. Recent literature highlights how this dichotomous model reinforces inequities for transgender and intersex populations, sustaining barriers to access, stigmatisation, and poorer health outcomes. In this Perspective, I critically reflect on the limitations of the binary paradigm and draw on developments in science, clinical practice, education, and policy to propose a future-oriented approach to health equity. Emerging evidence underscores the complexity of sexual development as a spectrum and the urgent need to move from pathological frameworks toward affirming care based on rights. Key advances include the adoption of affirmative care models, reforms in medical curriculum, and the rise of inclusive research methodologies that capture gender diversity beyond binaries. However, structural barriers—such as rigid clinical protocols, outdated educational content, and insufficient policy alignment—continue to hinder meaningful change. This article advocates for systemic transformation in healthcare education, practice, and research. I outline strategic priorities for the field are the implementation of gender diversity in medical training, the implementation of rights-based clinical guidelines, and the design of inclusive methodologies that remove structural discrimination. These actions are essential to build a more precise, ethical and universally inclusive health system. Ultimately, ensuring sustainable and equitable outcomes requires bridging scientific innovation with human rights principles and focussing on the lived experiences of transgender and intersex individuals. Full article

This qualitative study investigates how academic faculty in a UK university conceptualise and implement alternative assessment practices aimed at fostering critical 21st-century skills—such as problem-solving, collaboration, and creativity—in an increasingly diverse higher education context. Drawing on in-depth interviews with six academic faculty members, the study explores the extent to which inclusive and alternative assessment practices are embedded in teaching and examines the institutional and cultural barriers that shape these practices. Thematic analysis reveals that while staff broadly value critical skills, there is considerable variation in how these skills are understood and operationalised in assessment. Many staff face structural constraints, including rigid assessment policies and market-driven accountability frameworks, that limit their ability to innovate. Furthermore, the findings highlight a disjunction between staff awareness of inclusive pedagogies and their capacity to enact them systematically in assessment design. The study contributes to the literature by foregrounding the complex interplay between institutional logics, assessment practices, and inclusive pedagogical aims. It argues that advancing genuinely inclusive and skills-oriented assessment requires systemic change at both institutional and policy levels. Full article

This article presents the results of a rockfall analysis conducted for the limestone walls of a former quarry that is now used as an urban park. The performed simulations (2D statistical analysis using Rigid Body Impact Mechanics—RBIM and Discrete Element Modelling—DEM) enabled the determination of the maximum displacement range during the ballistic phase and the maximum rebound height at the slope base, which facilitated the delineation of a safe land-use zone. A hazard zone was also identified, within which public access must be strictly prohibited due to the risk posed by flying debris. Based on slope stability assessments (safety factor values and rockfall trajectories), recommendations were formulated for slope reinforcement measures and appropriate management actions for designated sections to ensure safe operation of the site. Three mitigation strategies were proposed: (1) no protective measures, (2) no structural reinforcements but with installation of a rockfall barrier, and (3) full-scale stabilisation to allow unrestricted access to the quarry walls. The first option—leaving slopes unsecured with only designated safety buffers—is not recommended. Full article

Home-compostable, biobased films were developed by blending poly(lactic acid) (PLA) with poly(butylene succinate-co-adipate) (PBSA). Among the formulations, the PLA/PBSA 60/40 blend demonstrated strong potential for industrial film production due to its enhanced flexibility and tear resistance. Thanks to their thermoplastic nature, these films can be applied to various substrates—such as paper or paperboard—and are easily recyclable within industrial processing environments. In this study, nanostructured clay and talc were incorporated into PLA/PBSA 60/40-based films to produce composites, which were evaluated for their effectiveness in limiting the diffusion of moisture from high-humidity soft cheeses. The materials’ melt fluidity and tensile properties were also characterized, and the composite morphology was examined using electron microscopy. The results revealed that the filler type significantly affected both the morphological structure and barrier performance, highlighting the critical role of material composition in the development of effective and environmentally sustainable packaging solutions. The biobased PLA/PBSA (60/40) films, particularly those filled with talc, exhibited high processability, flexibility, and effectiveness as a moisture barrier for dairy packaging. Although not yet feasible as a direct LDPE substitute without increasing their thickness, their low mass loss points to their strong potential for sustainable applications—especially when paired with paperboard in rigid packaging. Full article

This study evaluates the eco-efficiency and eco-productivity of 141 countries using data-driven analytical frameworks over the period 2018–2023, covering the pre-COVID, COVID, and post-COVID phases. We employ an input-oriented Slack-Based Measure Data Envelopment Analysis (SBM-DEA) under variable returns to scale (VRS), combined with the Malmquist Productivity Index (MPI), to assess both static and dynamic performance. The analysis incorporates three inputs—labor force, gross fixed capital formation, and energy consumption—one desirable output (gross domestic product, GDP), and one undesirable output (CO₂ emissions). Eco-efficiency (the joint performance of energy and carbon efficiency) and eco-productivity (labor and capital efficiency) are evaluated to capture complementary dimensions of sustainable performance. The results reveal significant but temporary gains in eco-efficiency during the peak pandemic years (2020–2021), followed by widespread post-crisis reversals, particularly in labor productivity, energy efficiency, and CO₂ emission efficiency. These reversals were often linked to institutional and structural barriers, such as rigid labor markets and outdated infrastructure, which limited the translation of technological progress into operational efficiency. The MPI decomposition indicates that, while technological change improved in many countries, efficiency change declined, leading to overall stagnation or regression in eco-productivity for most economies. Regression analysis shows that targeted policy stringency in 2022 was positively associated with eco-productivity, whereas broader restrictions in 2020–2021 were less effective. We conclude with differentiated policy recommendations, emphasizing green technology transfer and institutional capacity building for lower-income countries, and the integration of carbon pricing and innovation incentives for high-income economies. Full article

Coral reefs are among the most important marine habitats but face significant threats from anthropogenic sources, including climate change. This paper reviews and compares the modern Great Barrier Reef Province and the 360-million-year-old Devonian Great Barrier Reef of western Australia. Despite occurring at times with different climates, biota (both marine and terrestrial), weathering processes and marine chemistry, similar reefs were constructed under certain circumstances. Major differences in global temperature, marine carbonate saturation, sea level behavior and reef community constituents were evaluated. The comparison highlights the integration of, and interdependencies within, reef communities and the need for both carbonate producers and significant binders, whether skeletal or microbial, to construct a reef in a high-energy setting. Devonian communities with abundant corals and skeletal sponges were incapable of making modern reef types without competent binders to unify framework into rigid substrate. The current strong focus on corals and bleaching in modern reef conservation may be obscuring the equally significant issue of ocean acidification, which impacts on equally crucial framework unification, i.e., hard binding by coralline algae and microbialites and early cementation. The comparison also supports the idea that ‘empty bucket’ carbonate platform morphologies require increased accommodation from high-amplitude icehouse sea level oscillations. Full article

Electrospun nanofiber membranes (ESNFMs) are exceptional biomaterials for tissue engineering, closely mimicking the native extracellular matrix. However, their inherent fragility poses significant handling, processing, and integration challenges, limiting their widespread application in advanced 3D tissue models and biofabricated devices. This study introduces a novel and on-mat framing technique utilizing extrusion-based printing of a UV-curable biocompatible resin (Biotough D90 MF) to create rigid, integrated support structures directly on chitosan–polyethylene oxide (PEO) ESNFMs. We demonstrate fabrication of these circular frames via precise 3D printing and a simpler manual stamping method, achieving robust mechanical stabilization that enables routine laboratory manipulation without membrane damage. The resulting framed ESNFMs maintain structural integrity during subsequent processing and exhibit excellent biocompatibility in standardized extract assays (116.5 ± 12.2% normalized cellular response with optimized processing) and acceptable performance in direct contact evaluations (up to 78.2 ± 32.4% viability in the optimal configuration). Temporal assessment revealed characteristic cellular adaptation dynamics on nanofiber substrates, emphasizing the importance of extended evaluation periods for accurate biocompatibility determination of three-dimensional scaffolds. This innovative biofabrication approach overcomes critical limitations of previous handling methods, transforming delicate ESNFMs into robust, easy-to-use components for reliable integration into complex cell culture applications, barrier tissue models, and engineered systems. Full article

Floating offshore wind turbines (FOWTs) unlock superior wind resources and reduce operational barriers. The dynamics of FOWT platforms present added engineering challenges and opportunities. While the motion of the floating platform due to wind and wave disturbances can worsen power quality and increase structural loading, certain movements of the floating platform can be exploited to improve power capture. Consequently, active FOWT platform control methods using conventional and innovative actuation systems are under investigation. This paper develops a novel framework to design nonlinear control laws for six degrees-of-freedom platform motion. The framework uses simplified rigid-body analytical models of the FOWT. Lyapunov’s direct method is used to develop actuator-agnostic unconstrained control laws for platform translational and rotational control. A model based on the NREL-5MW reference turbine on the OC3-Hywind spar-buoy platform is utilized to test the control framework for an ideal actuation scenario. Possible applications using traditional and novel turbine actuators and future research directions are presented. Full article

In the Hexaflex model of Acceptance and Commitment Therapy (ACT), psychological flexibility refers to the ability to openly embrace difficult thoughts and emotions while acting in alignment with personal values. In contrast, psychological inflexibility involves rigid avoidance and control strategies that hinder adaptive functioning. Although previously studied, more culturally relevant evidence is needed to inform interventions that promote well-being and mental health among Latin American students. This study explored manifestations of psychological flexibility and inflexibility in 15 undergraduate students from the University of Magdalena in Colombia (mean age = 20.13 years; 53.33% female) through semi-structured, face-to-face interviews (~45 min each). Data were analyzed using Interpretative Phenomenological Analysis (IPA), focusing on how participants described and made sense of their experiences. A total of 25 emergent themes were identified and grouped into 12 subordinate themes, mapped onto the 6 core ACT processes. The participants reported efforts to control or avoid distressing internal experiences, often resulting in difficulty acting in accordance with their values. The findings highlight a recurring ambivalence between avoidance and acceptance, and barriers to committed action, underscoring the dynamic interplay between flexibility and inflexibility. These results support the relevance of ACT-based interventions, such as structured group sessions that foster acceptance, mindfulness, and values-based behavior. Integrating this training into counseling and academic support services could enhance students’ well-being and performance. Future research should examine these dynamics longitudinally and across diverse contexts. Full article

Mining by-products present both an environmental challenge and a resource opportunity. This review investigates their potential application in road pavement construction, focusing on materials such as fly ash, slag, sulphur, red mud, tailings, and silica fume. Drawing from laboratory and field studies, the review examines their roles across pavement layers—subgrade, base, subbase, asphalt mixtures, and rigid pavements—emphasising mechanical properties, durability, moisture resistance, and ageing performance. When properly processed or stabilised, many of these wastes meet or exceed conventional performance standards, contributing to reduced use of virgin materials and greenhouse gas emissions. However, issues such as variability in composition, leaching risks, and a lack of standardised design protocols remain barriers to adoption. This review aims to consolidate current research, evaluate practical feasibility, and identify directions for future studies that would enable the responsible and effective reuse of mining waste in transportation infrastructure. Full article