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15 pages, 1745 KiB  
Article
A Prediction Method for Technically Recoverable Reserves Based on a Novel Relationship Between the Relative Permeability Ratio and Saturation
by Dongqi Wang, Jiaxing Wen, Yang Sun and Daiyin Yin
Eng 2025, 6(8), 182; https://doi.org/10.3390/eng6080182 (registering DOI) - 2 Aug 2025
Abstract
Upon reaching stabilized production in waterflooded reservoirs, waterflood performance curves are conventionally used to predict technically recoverable reserves (TRRs). However, as reservoirs enter high water-cut stages, the relationship between the relative permeability ratio and saturation becomes nonlinear, causing deflection in waterflood performance curves. [...] Read more.
Upon reaching stabilized production in waterflooded reservoirs, waterflood performance curves are conventionally used to predict technically recoverable reserves (TRRs). However, as reservoirs enter high water-cut stages, the relationship between the relative permeability ratio and saturation becomes nonlinear, causing deflection in waterflood performance curves. This leads to systematic overestimation of both predicted TRR and ultimate recovery factors. To overcome these limitations in conventional TRR prediction methods, this study establishes a novel relative permeability ratio-saturation relationship based on characteristic relative permeability curve behaviors. The proposed model is validated for three distinct fluid-rock interaction types. We further develop a permeability-driven forecasting model for oil production rates and water cuts. Comparative analyses with a conventional waterflood curve methodology demonstrate significant accuracy improvements. The results show that while traditional methods predict TRR ranging from 78.40 to 92.29 million tons, our model yields 70.73 million tons—effectively resolving overestimation issues caused by curve deflection during high water-cut phases. This approach establishes a robust framework for determining critical development parameters, including economic field lifespan, strategy adjustments, and ultimate recovery factor. Full article
(This article belongs to the Section Chemical, Civil and Environmental Engineering)
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15 pages, 5152 KiB  
Article
Assessment of Emergy, Environmental and Economic Sustainability of the Mango Orchard Production System in Hainan, China
by Yali Lei, Xiaohui Zhou and Hanting Cheng
Sustainability 2025, 17(15), 7030; https://doi.org/10.3390/su17157030 (registering DOI) - 2 Aug 2025
Abstract
Mangoes are an important part of Hainan’s tropical characteristic agriculture. In response to the requirements of building an ecological civilization pilot demonstration zone in Hainan, China, green and sustainable development will be the future development trend of the mango planting system. However, the [...] Read more.
Mangoes are an important part of Hainan’s tropical characteristic agriculture. In response to the requirements of building an ecological civilization pilot demonstration zone in Hainan, China, green and sustainable development will be the future development trend of the mango planting system. However, the economic benefits and environmental impact during its planting and management process remain unclear. This paper combines emergy, life cycle assessment (LCA), and economic analysis to compare the system sustainability, environmental impact, and economic benefits of the traditional mango cultivation system (TM) in Dongfang City, Hainan Province, and the early-maturing mango cultivation system (EM) in Sanya City. The emergy evaluation results show that the total emergy input of EM (1.37 × 1016 sej ha−1) was higher than that of TM (1.32 × 1016 sej ha−1). From the perspective of the emergy index, compared with TM, EM exerted less pressure on the local environment and has better stability and sustainability. This was due to the higher input of renewable resources in EM. The LCA results showed that based on mass as the functional unit, the potential environmental impact of the EM is relatively high, and its total environmental impact index was 18.67–33.19% higher than that of the TM. Fertilizer input and On-Farm emissions were the main factors causing environmental consequences. Choosing alternative fertilizers that have a smaller impact on the environment may effectively reduce the environmental impact of the system. The economic analysis results showed that due to the higher selling price of early-maturing mango, the total profit and cost–benefit ratio of the EM have increased by 55.84% and 36.87%, respectively, compared with the TM. These results indicated that EM in Sanya City can enhance environmental sustainability and boost producers’ annual income, but attention should be paid to the negative environmental impact of excessive fertilizer input. These findings offer insights into optimizing agricultural inputs for Hainan mango production to mitigate multiple environmental impacts while enhancing economic benefits, aiming to provide theoretical support for promoting the sustainable development of the Hainan mango industry. Full article
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24 pages, 9564 KiB  
Article
Linking Optimization Success and Stability of Finite-Time Thermodynamics Heat Engines
by Julian Gonzalez-Ayala, David Pérez-Gallego, Alejandro Medina, José M. Mateos Roco, Antonio Calvo Hernández, Santiago Velasco and Fernando Angulo-Brown
Entropy 2025, 27(8), 822; https://doi.org/10.3390/e27080822 (registering DOI) - 2 Aug 2025
Abstract
In celebration of 50 years of the endoreversible Carnot-like heat engine, this work aims to link the thermodynamic success of the irreversible Carnot-like heat engine with the stability dynamics of the engine. This region of success is defined by two extreme configurations in [...] Read more.
In celebration of 50 years of the endoreversible Carnot-like heat engine, this work aims to link the thermodynamic success of the irreversible Carnot-like heat engine with the stability dynamics of the engine. This region of success is defined by two extreme configurations in the interaction between heat reservoirs and the working fluid. The first corresponds to a fully reversible limit, and the second one is the fully dissipative limit; in between both limits, the heat exchange between reservoirs and working fluid produces irreversibilities and entropy generation. The distance between these two extremal configurations is minimized, independently of the chosen metric, in the state where the efficiency is half the Carnot efficiency. This boundary encloses the region where irreversibilities dominate or the reversible behavior dominates (region of success). A general stability dynamics is proposed based on the endoreversible nature of the model and the operation parameter in charge of defining the operation regime. For this purpose, the maximum ecological and maximum Omega regimes are considered. The results show that for single perturbations, the dynamics rapidly directs the system towards the success region, and under random perturbations producing stochastic trajectories, the system remains always in this region. The results are contrasted with the case in which no restitution dynamics exist. It is shown that stability allows the system to depart from the original steady state to other states that enhance the system’s performance, which could favor the evolution and specialization of systems in nature and in artificial devices. Full article
(This article belongs to the Special Issue The First Half Century of Finite-Time Thermodynamics)
23 pages, 5280 KiB  
Article
Seismic Damage Pattern Analysis of Long-Span CFST Arch Bridges Based on Damper Configuration Strategies
by Bin Zhao, Longhua Zeng, Qingyun Chen, Chao Gan, Lueqin Xu and Guosi Cheng
Buildings 2025, 15(15), 2728; https://doi.org/10.3390/buildings15152728 (registering DOI) - 2 Aug 2025
Abstract
Variations in damper configuration strategies have a direct impact on the seismic damage patterns of long-span deck-type concrete-filled steel tube (CFST) arch bridges. This study developed an analysis and evaluation framework to identify the damage category, state, and progression sequence of structural components. [...] Read more.
Variations in damper configuration strategies have a direct impact on the seismic damage patterns of long-span deck-type concrete-filled steel tube (CFST) arch bridges. This study developed an analysis and evaluation framework to identify the damage category, state, and progression sequence of structural components. The framework aims to investigate the influence of viscous dampers on the seismic response and damage patterns of long-span deck-type CFST arch bridges under near-fault pulse-like ground motions. The effects of different viscous damper configuration strategies and design parameters on seismic responses of long-span deck-type CFST arch bridges were systematically investigated, and the preferred configuration and parameter set were identified. The influence of preferred viscous damper configurations on seismic damage patterns of long-span deck-type CFST arch bridges was systematically analyzed through the established analysis and evaluation frameworks. The results indicate that a relatively optimal reduction in bridge response can be achieved when viscous dampers are simultaneously installed at both the abutments and the approach piers. Minimum seismic responses were attained at a damping exponent α = 0.2 and damping coefficient C = 6000 kN/(m/s), demonstrating stability in mitigating vibration effects on arch rings and bearings. In the absence of damper implementation, the lower chord arch foot section is most likely to experience in-plane bending failure. The piers, influenced by the coupling effect between the spandrel construction and the main arch ring, are more susceptible to damage as their height decreases. Additionally, the end bearings are more prone to failure compared to the central-span bearings. Implementation of the preferred damper configuration strategy maintains essentially consistent sequences in seismic-induced damage patterns of the bridge, but the peak ground motion intensity causing damage to the main arch and spandrel structure is significantly increased. This strategy enhances the damage-initiation peak ground acceleration (PGA) for critical sections of the main arch, while concurrently reducing transverse and longitudinal bending moments in pier column sections. The proposed integrated analysis and evaluation framework has been validated for its applicability in capturing the seismic damage patterns of long-span deck-type CFST arch bridges. Full article
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23 pages, 3817 KiB  
Article
Experimental and Numerical Study on the Restitution Coefficient and the Corresponding Elastic Collision Recovery Mechanism of Rapeseed
by Chuandong Liu, Haoping Zhang, Zebao Li, Zhiheng Zeng, Xuefeng Zhang, Lian Gong and Bin Li
Agronomy 2025, 15(8), 1872; https://doi.org/10.3390/agronomy15081872 (registering DOI) - 1 Aug 2025
Abstract
In this study, we aimed to address the lack of systematic research on key collision dynamics parameters (elastic restitution coefficient) in the full mechanization of rapeseed operations, which hinders the development of precision agriculture. In this present work, the restitution coefficient of rapeseed [...] Read more.
In this study, we aimed to address the lack of systematic research on key collision dynamics parameters (elastic restitution coefficient) in the full mechanization of rapeseed operations, which hinders the development of precision agriculture. In this present work, the restitution coefficient of rapeseed was systematically investigated, and a predictive model (R2 = 0.959) was also established by using Box–Behnken design response surface methodology (BBD-RSM). The results show that the collision restitution coefficient varies in the range of 0.539–0.649, with the key influencing factors ranked as follows: moisture content (Mc) > material layer thickness (L) > drop height (H). The EDEM simulation methodology was adopted to validate the experimental results, and the results show that there is a minimal relative error (−1% < δ < 1%) between the measured and simulated rebound heights, indicating that the established model shows a reliable prediction performance. Moreover, by comprehensively analyzing stress, strain, and energy during the collision process between rapeseed and Q235 steel, it can be concluded that the process can be divided into five stages—free fall, collision compression, collision recovery, rebound oscillation, and rebound stabilization. The maximum stress (1.19 × 10−2 MPa) and strain (6.43 × 10−6 mm) were observed at the beginning of the collision recovery stage, which can provide some theoretical and practical basis for optimizing and designing rapeseed machines, thus achieving the goals of precise control, harvest loss reduction, and increased yields. Full article
(This article belongs to the Section Precision and Digital Agriculture)
19 pages, 3765 KiB  
Article
Mathematical Study of Pulsatile Blood Flow in the Uterine and Umbilical Arteries During Pregnancy
by Anastasios Felias, Charikleia Skentou, Minas Paschopoulos, Petros Tzimas, Anastasia Vatopoulou, Fani Gkrozou and Michail Xenos
Fluids 2025, 10(8), 203; https://doi.org/10.3390/fluids10080203 (registering DOI) - 1 Aug 2025
Abstract
This study applies Computational Fluid Dynamics (CFD) and mathematical modeling to examine uterine and umbilical arterial blood flow during pregnancy, providing a more detailed understanding of hemodynamic changes across gestation. Statistical analysis of Doppler ultrasound data from a large cohort of more than [...] Read more.
This study applies Computational Fluid Dynamics (CFD) and mathematical modeling to examine uterine and umbilical arterial blood flow during pregnancy, providing a more detailed understanding of hemodynamic changes across gestation. Statistical analysis of Doppler ultrasound data from a large cohort of more than 200 pregnant women (in the second and third trimesters) reveals significant increases in the umbilical arterial peak systolic velocity (PSV) between the 22nd and 30th weeks, while uterine artery velocities remain relatively stable, suggesting adaptations in vascular resistance during pregnancy. By combining the Navier–Stokes equations with Doppler ultrasound-derived inlet velocity profiles, we quantify several key fluid dynamics parameters, including time-averaged wall shear stress (TAWSS), oscillatory shear index (OSI), relative residence time (RRT), Reynolds number (Re), and Dean number (De), evaluating laminar flow stability in the uterine artery and secondary flow patterns in the umbilical artery. Since blood exhibits shear-dependent viscosity and complex rheological behavior, modeling it as a non-Newtonian fluid is essential to accurately capture pulsatile flow dynamics and wall shear stresses in these vessels. Unlike conventional imaging techniques, CFD offers enhanced visualization of blood flow characteristics such as streamlines, velocity distributions, and instantaneous particle motion, providing insights that are not easily captured by Doppler ultrasound alone. Specifically, CFD reveals secondary flow patterns in the umbilical artery, which interact with the primary flow, a phenomenon that is challenging to observe with ultrasound. These findings refine existing hemodynamic models, provide population-specific reference values for clinical assessments, and improve our understanding of the relationship between umbilical arterial flow dynamics and fetal growth restriction, with important implications for maternal and fetal health monitoring. Full article
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17 pages, 3738 KiB  
Article
Beyond Spheres: Evaluating Gold Nano-Flowers and Gold Nano-Stars for Enhanced Aflatoxin B1 Detection in Lateral Flow Immunoassays
by Vinayak Sharma, Bilal Javed, Hugh J. Byrne and Furong Tian
Biosensors 2025, 15(8), 495; https://doi.org/10.3390/bios15080495 (registering DOI) - 1 Aug 2025
Abstract
The lateral flow immunoassay (LFIA) is a widely utilized, rapid diagnostic technique characterized by its short analysis duration, cost efficiency, visual result interpretation, portability and suitability for point-of-care applications. However, conventional LFIAs have limited sensitivity, a challenge that can be overcome by the [...] Read more.
The lateral flow immunoassay (LFIA) is a widely utilized, rapid diagnostic technique characterized by its short analysis duration, cost efficiency, visual result interpretation, portability and suitability for point-of-care applications. However, conventional LFIAs have limited sensitivity, a challenge that can be overcome by the introduction of gold nanoparticles, which provide enhanced sensitivity and selectivity (compared, for example, to latex beads or carbon nanoparticles) for the detection of target analytes, due to their optical properties, chemical stability and ease of functionalization. In this work, gold nanoparticle-based LFIAs are developed for the detection of aflatoxin B1, and the relative performance of different morphology particles is evaluated. LFIA using gold nano-labels allowed for aflatoxin B1 detection over a range of 0.01 ng/mL–100 ng/mL. Compared to spherical gold nanoparticles and gold nano-flowers, star-shaped gold nanoparticles show increased antibody binding efficiency of 86% due to their greater surface area. Gold nano-stars demonstrated the highest sensitivity, achieving a limit of detection of 0.01ng/mL, surpassing the performance of both spherical gold nanoparticles and gold nano-flowers. The use of star-shaped particles as nano-labels has demonstrated a five-fold improvement in sensitivity, underscoring the potential of integrating diverse nanostructures into LFIA for significantly improving analyte detection. Moreover, the robustness and feasibility of gold nano-stars employed as labels in LFIA was assessed in detecting aflatoxin B1 in a wheat matrix. Improved sensitivity with gold nano-stars holds promise for applications in food safety monitoring, public health diagnostics and rapid point-of-care diagnostics. This work opens the pathway for further development of LFIA utilizing novel nanostructures to achieve unparallel precision in diagnostics and sensing. Full article
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22 pages, 8105 KiB  
Article
Extraction of Sparse Vegetation Cover in Deserts Based on UAV Remote Sensing
by Jie Han, Jinlei Zhu, Xiaoming Cao, Lei Xi, Zhao Qi, Yongxin Li, Xingyu Wang and Jiaxiu Zou
Remote Sens. 2025, 17(15), 2665; https://doi.org/10.3390/rs17152665 (registering DOI) - 1 Aug 2025
Abstract
The unique characteristics of desert vegetation, such as different leaf morphology, discrete canopy structures, sparse and uneven distribution, etc., pose significant challenges for remote sensing-based estimation of fractional vegetation cover (FVC). The Unmanned Aerial Vehicle (UAV) system can accurately distinguish vegetation patches, extract [...] Read more.
The unique characteristics of desert vegetation, such as different leaf morphology, discrete canopy structures, sparse and uneven distribution, etc., pose significant challenges for remote sensing-based estimation of fractional vegetation cover (FVC). The Unmanned Aerial Vehicle (UAV) system can accurately distinguish vegetation patches, extract weak vegetation signals, and navigate through complex terrain, making it suitable for applications in small-scale FVC extraction. In this study, we selected the floodplain fan with Caragana korshinskii Kom as the constructive species in Hatengtaohai National Nature Reserve, Bayannur, Inner Mongolia, China, as our study area. We investigated the remote sensing extraction method of desert sparse vegetation cover by placing samples across three gradients: the top, middle, and edge of the fan. We then acquired UAV multispectral images; evaluated the applicability of various vegetation indices (VIs) using methods such as supervised classification, linear regression models, and machine learning; and explored the feasibility and stability of multiple machine learning models in this region. Our results indicate the following: (1) We discovered that the multispectral vegetation index is superior to the visible vegetation index and more suitable for FVC extraction in vegetation-sparse desert regions. (2) By comparing five machine learning regression models, it was found that the XGBoost and KNN models exhibited relatively lower estimation performance in the study area. The spatial distribution of plots appeared to influence the stability of the SVM model when estimating fractional vegetation cover (FVC). In contrast, the RF and LASSO models demonstrated robust stability across both training and testing datasets. Notably, the RF model achieved the best inversion performance (R2 = 0.876, RMSE = 0.020, MAE = 0.016), indicating that RF is one of the most suitable models for retrieving FVC in naturally sparse desert vegetation. This study provides a valuable contribution to the limited existing research on remote sensing-based estimation of FVC and characterization of spatial heterogeneity in small-scale desert sparse vegetation ecosystems dominated by a single species. Full article
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20 pages, 16348 KiB  
Article
The Recent Extinction of the Carihuairazo Volcano Glacier in the Ecuadorian Andes Using Multivariate Analysis Techniques
by Pedro Vicente Vaca-Cárdenas, Eduardo Antonio Muñoz-Jácome, Maritza Lucia Vaca-Cárdenas, Diego Francisco Cushquicullma-Colcha and José Guerrero-Casado
Earth 2025, 6(3), 86; https://doi.org/10.3390/earth6030086 (registering DOI) - 1 Aug 2025
Abstract
Climate change has accelerated the retreat of Andean glaciers, with significant recent losses in the tropical Andes. This study evaluates the extinction of the Carihuairazo volcano glacier (Ecuador), quantifying its area from 1312.5 m2 in September 2023 to 101.2 m2 in [...] Read more.
Climate change has accelerated the retreat of Andean glaciers, with significant recent losses in the tropical Andes. This study evaluates the extinction of the Carihuairazo volcano glacier (Ecuador), quantifying its area from 1312.5 m2 in September 2023 to 101.2 m2 in January 2024, its thickness (from 2.5 m to 0.71 m), and its volume (from 2638.85 m3 to 457.18 m3), before its complete deglaciation in February 2024; this rapid melting and its small size classify it as a glacierette. Multivariate analyses (PCA and biclustering) were performed to correlate climatic variables (temperature, solar radiation, precipitation, relative humidity, vapor pressure, and wind) with glacier surface and thickness. The PCA explained 70.26% of the total variance, with Axis 1 (28.01%) associated with extreme thermal conditions (temperatures up to 8.18 °C and radiation up to 16.14 kJ m−2 day−1), which probably drove its disappearance. Likewise, Axis 2 (21.56%) was related to favorable hydric conditions (precipitation between 39 and 94 mm) during the initial phase of glacier monitoring. Biclustering identified three groups of variables: Group 1 (temperature, solar radiation, and vapor pressure) contributed most to deglaciation; Group 2 (precipitation, humidity) apparently benefited initial stability; and Group 3 (wind) played a secondary role. These results, validated through in situ measurements, provide scientific evidence of the disappearance of the Carihuairazo volcano glacier by February 2024. They also corroborate earlier projections that anticipated its extinction by the middle of this decade. The early disappearance of this glacier highlights the vulnerability of small tropical Andean glaciers and underscores the urgent need for water security strategies focused on management, adaptation, and resilience. Full article
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21 pages, 670 KiB  
Article
I-fp Convergence in Fuzzy Paranormed Spaces and Its Application to Robust Base-Stock Policies with Triangular Fuzzy Demand
by Muhammed Recai Türkmen and Hasan Öğünmez
Mathematics 2025, 13(15), 2478; https://doi.org/10.3390/math13152478 - 1 Aug 2025
Abstract
We introduce I-fp convergence (ideal convergence in fuzzy paranormed spaces) and develop its core theory, including stability results and an equivalence to I*-fp convergence under the AP Property. Building on this foundation, we design an adaptive base-stock policy for a single-echelon [...] Read more.
We introduce I-fp convergence (ideal convergence in fuzzy paranormed spaces) and develop its core theory, including stability results and an equivalence to I*-fp convergence under the AP Property. Building on this foundation, we design an adaptive base-stock policy for a single-echelon inventory system in which weekly demand is expressed as triangular fuzzy numbers while holiday or promotion weeks are treated as ideal-small anomalies. The policy is updated by a simple learning rule that can be implemented in any spreadsheet, requires no optimisation software, and remains insensitive to tuning choices. Extensive simulation confirms that the method simultaneously lowers cost, reduces average inventory and raises service level relative to a crisp benchmark, all while filtering sparse demand spikes in a principled way. These findings position I-fp convergence as a lightweight yet rigorous tool for blending linguistic uncertainty with anomaly-aware decision making in supply-chain analytics. Full article
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16 pages, 3753 KiB  
Article
Elevational Patterns and Seasonal Dynamics of Soil Organic Carbon Fractions and Content in Rice Paddies of Yuanyang Terrace, Southwest China
by Haitao Li, Linxi Chang, Yonglin Wu, Yang Li, Xinran Liang, Fangdong Zhan and Yongmei He
Agronomy 2025, 15(8), 1868; https://doi.org/10.3390/agronomy15081868 - 1 Aug 2025
Abstract
Soil organic carbon (SOC) is an important part of the global C pool and is sensitive to climate change. The SOC content and fractions of rice paddies along four elevations (250, 1150, 1600 and 1800 m) on the same slope in four seasons [...] Read more.
Soil organic carbon (SOC) is an important part of the global C pool and is sensitive to climate change. The SOC content and fractions of rice paddies along four elevations (250, 1150, 1600 and 1800 m) on the same slope in four seasons (spring, summer, autumn and winter) at Yuanyang Terrace in southwest China were investigated, and their relationship with environmental factors was analyzed. The contents of SOC, unprotected SOC (uPOM), physically protected SOC (pPOM) and biochemically protected SOC (bcPOM) in rice paddies at a low elevation (250 m), were significantly lower by 49–51% than those at relatively high elevations (1600 m and 1800 m). Among the SOC fractions, the highest proportion (33–50%) was uPOM, followed by pPOM and bcPOM (accounting for 17–40%), and the lowest proportion was chemically protected SOC (cPOM). In addition, there were interseasonal differences among the contents of SOC fractions, with a significantly higher content of SOC, uPOM and pPOM at an elevation of 1600 m in summer than in the other three seasons, whereas the cPOM content at an elevation of 250 m in spring was significantly higher than in the other three higher elevations. According to the redundancy analysis (RDA), total nitrogen was the key environmental factor, with an explanatory degree of 56% affecting the contents of SOC and its fractions. Thus, the SOC content increased with increasing elevation, and physical and biochemical protection were potential stabilization mechanisms responsible for their stability in the rice paddy of Yuanyang Terrace. These results provides empirical evidence for the elevational distribution patterns and seasonal dynamics of SOC fractions in rice paddies across Yuanyang Terrace. These findings highlight the importance of physical and biochemical protection mechanisms in stabilizing SOC in rice paddies, which could enhance long-term C sequestration and contribute to climate change mitigation in terraced agroecosystems. Full article
(This article belongs to the Section Soil and Plant Nutrition)
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15 pages, 1987 KiB  
Article
Threshold Effects of Straw Returning Amounts on Bacterial Colonization in Black Soil
by Genzhu Wang, Wei Qin, Zhe Yin, Ziyuan Zhou, Jian Jiao, Xiaohong Xu, Yu Zhang and Xing Han
Microorganisms 2025, 13(8), 1797; https://doi.org/10.3390/microorganisms13081797 - 31 Jul 2025
Abstract
Straw returning (ST) significantly improves soil quality and profoundly impacts soil microorganisms. However, the effects of different ST application amounts on the soil bacterial community remain unclear, and more studies on optimal ST application amounts are warranted. This study aimed to investigate the [...] Read more.
Straw returning (ST) significantly improves soil quality and profoundly impacts soil microorganisms. However, the effects of different ST application amounts on the soil bacterial community remain unclear, and more studies on optimal ST application amounts are warranted. This study aimed to investigate the bacterial diversity and composition, as well as physicochemical properties, of soil in a corn field with 5-year ST amounts of 0, 3, 4.5, 5, and 6 t/hm2, respectively. The results indicated that ST significantly reduced soil bulk density and increased soil pH and nutrients. Meanwhile, ST had a significant effect on the bacterial composition, and the bacterial diversity increased significantly after ST. The relative abundance of Proteobacteria and Acidobacteria increased dramatically, whereas that of Actinobacteria significantly decreased after ST. The amount of ST had threshold effects on soil physicochemical properties and the dominant bacterial phyla. Moreover, the co-occurrence networks indicated that bacterial stability first increased and then decreased with the increase in ST amounts. Soil organic carbon and total nitrogen concentrations were the main drivers of bacterial diversity, whereas soil pH and total nitrogen concentrations were the main drivers of bacterial composition. This study strengthens the fact that ST amounts have threshold effects on the soil physicochemical properties and soil microorganisms, and ST amounts of 3–5 t/hm2 were appropriate. Full article
(This article belongs to the Section Environmental Microbiology)
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29 pages, 14993 KiB  
Article
Microclimate Monitoring Using Multivariate Analysis to Identify Surface Moisture in Historic Masonry in Northern Italy
by Elisabetta Rosina and Hoda Esmaeilian Toussi
Appl. Sci. 2025, 15(15), 8542; https://doi.org/10.3390/app15158542 (registering DOI) - 31 Jul 2025
Abstract
Preserving historical porous materials requires careful monitoring of surface humidity to mitigate deterioration processes like salt crystallization, mold growth, and material decay. While microclimate monitoring is a recognized preventive conservation tool, its role in detecting surface-specific moisture risks remains underexplored. This study evaluates [...] Read more.
Preserving historical porous materials requires careful monitoring of surface humidity to mitigate deterioration processes like salt crystallization, mold growth, and material decay. While microclimate monitoring is a recognized preventive conservation tool, its role in detecting surface-specific moisture risks remains underexplored. This study evaluates the relationship between indoor microclimate fluctuations and surface moisture dynamics across 13 historical sites in Northern Italy (Lake Como, Valtellina, Valposchiavo), encompassing diverse masonry typologies and environmental conditions. High-resolution sensors recorded temperature and relative humidity for a minimum of 13 months, and eight indicators—including dew point depression, critical temperature–humidity zones, and damp effect indices—were analyzed to assess the moisture risks. The results demonstrate that multivariate microclimate data could effectively predict humidity accumulation. The key findings reveal the impact of seasonal ventilation, thermal inertia, and localized air stagnation on moisture distribution, with unheated alpine sites showing the highest condensation risk. The study highlights the need for integrated monitoring approaches, combining dew point analysis, mixing ratio stability, and buffering performance, to enable early risk detection and targeted conservation strategies. These insights bridge the gap between environmental monitoring and surface moisture diagnostics in porous heritage materials. Full article
(This article belongs to the Special Issue Advanced Study on Diagnostics for Surfaces of Historical Buildings)
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21 pages, 5466 KiB  
Article
Evaluation of Bending Stress and Shape Recovery Behavior Under Cyclic Loading in PLA 4D-Printed Lattice Structures
by Maria Pia Desole, Annamaria Gisario and Massimiliano Barletta
Appl. Sci. 2025, 15(15), 8540; https://doi.org/10.3390/app15158540 (registering DOI) - 31 Jul 2025
Abstract
This study aims to analyze the bending behavior of polylactic acid (PLA) structures made by fusion deposition modeling (FDM) technology. The investigation analyzed chiral structures such as lozenge and clepsydra, as well as geometries with wavy patterns such as roller and Es, in [...] Read more.
This study aims to analyze the bending behavior of polylactic acid (PLA) structures made by fusion deposition modeling (FDM) technology. The investigation analyzed chiral structures such as lozenge and clepsydra, as well as geometries with wavy patterns such as roller and Es, in addition to a honeycomb structure. All geometries have a relative density of 50%. After being subjected to three-point bending tests, the capacity to spring back with respect to the bending angle and the shape recovery of the structures were measured. The roller and lozenge structures demonstrated the best performance, with shape recovery assessed through three consecutive hot water immersion cycles. The lozenge structure exhibits 25% higher energy absorption than the roller, but the latter ensures better replicability and shape stability. Additionally, the roller absorbs 15% less energy than the lozenge, which experiences a 27% decrease in absorption between the first and second cycle. This work provides new insights into the bending-based energy absorption and recovery behavior of PLA metamaterials, relevant for applications in adaptive and energy-dissipating systems. Full article
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15 pages, 1889 KiB  
Article
Influence of Mixing Duration and Absorption Characteristics of Superabsorbent Polymers on the Fresh and Hardened Properties of High-Performance Concrete
by Yu-Cun Gu and Kamal H. Khayat
Materials 2025, 18(15), 3609; https://doi.org/10.3390/ma18153609 (registering DOI) - 31 Jul 2025
Abstract
This study investigates the combined influence of superabsorbent polymers (SAPs) with distinct absorption kinetics and extended mixing sequences on the rheological, mechanical, and transport properties of high-performance concrete (HPC). Two SAPs—an ionic acrylamide-co-acrylic acid copolymer (SAP-P) and a non-ionic acrylamide polymer (SAP-B)—were incorporated [...] Read more.
This study investigates the combined influence of superabsorbent polymers (SAPs) with distinct absorption kinetics and extended mixing sequences on the rheological, mechanical, and transport properties of high-performance concrete (HPC). Two SAPs—an ionic acrylamide-co-acrylic acid copolymer (SAP-P) and a non-ionic acrylamide polymer (SAP-B)—were incorporated at an internal curing level of 100%. The impact of extended mixing times (3, 5, and 7 min) following SAP addition was systematically evaluated. Results showed that longer mixing durations led to increased superplasticizer demand and higher plastic viscosity due to continued water absorption by SAPs. However, yield stress remained relatively stable owing to the dispersing effect of the added superplasticizer. Both SAPs significantly enhanced the static yield stress and improved fresh stability, as evidenced by reduced surface settlement. Despite the rheological changes, mechanical properties—including compressive and flexural strengths and modulus of elasticity—were consistently improved, regardless of mixing duration. SAP incorporation also led to notable reductions in autogenous and drying shrinkage, as well as enhanced electrical resistivity, indicating better durability performance. These findings suggest that a 3 min extended mixing time is sufficient for effective SAP dispersion without compromising performance. Full article
(This article belongs to the Special Issue Characterization and Optimization of Cement-Based Materials)
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