Search Results (25)

Vanadium-bearing beryl is a vanadium-bearing variety of green beryl (distinct from emerald) that exhibits an “electro-optical” green (blue-green) color, which has led to its commercial popularity. However, the underlying coloration mechanism remains unclear. The present study adopted standard gemological tests and non-destructive spectroscopic tests, such as X-ray fluorescence, UV-visible-near infrared (UV-Vis-NIR), infrared and Raman spectroscopy, to analyze the vanadium-bearing beryl from Nigeria. The results of these tests indicated the presence of Fe as the predominant chromogenic element of vanadium-bearing beryl, followed by V, at a level exceeding that of Cr. Furthermore, the samples displayed lower levels of alkali and magnesium when compared to other beryls, accompanied by lower refractive indices and specific gravities. Spectroscopic analysis indicates that the structural channels are dominated by type I H₂O, with CO₂, HDO, and D₂O molecules also present. The inclusions observed in vanadium-bearing beryl bear a resemblance to those found in typical aquamarines, which are raindrop-shaped inclusions, and to those found in emeralds of various origins, which are irregular, jagged, gas–liquid two-phase/three-phase inclusions. The broad UV-Vis-NIR absorption bands at 427 and 610 nm are characteristic of V³⁺ (and a minor amount of Cr³⁺). Charge transfer between Fe²⁺ and Fe³⁺ may also contribute to the 610 nm band, which is superimposed on the absorption bands of V³⁺ and Cr³⁺. These factors primarily contribute to the blue-green coloration of beryl. The absorption induced by V³⁺ in the visible violet-blue region exhibits stronger intensity and a greater tendency towards the blue region compared to Cr³⁺. Consequently, the resultant vanadium-bearing beryl acquires the yellow-green hue (induced by V) overlaid with the light blue (induced by charge transfer between Fe²⁺-Fe³⁺ pairs), resulting in the so-called “electro-optical” green (blue-green) beryl. Full article

Approximately 71% of the Earth’s surface is covered by vast oceans. With the exacerbation of global climate change, high-precision monitoring of sea surface height variations is of vital importance for constructing global ocean gravity fields and preventing natural disasters in the marine system. Global Navigation Satellite System Interferometry Reflectometry (GNSS-IR) sea surface altimetry is a method of inferring sea surface height based on the signal-to-noise ratio of satellite signals. It enables the retrieval of sea surface height variations with high precision. However, navigation satellite signals are influenced by the ionosphere during propagation, leading to deviations in the measured values of satellite elevation angles from their true values, which significantly affects the accuracy of GNSS-IR sea surface altimetry. Based on this, the contents of this paper are as follows: Firstly, a new ionospheric stratified elevation angle correction model (ISEACM) was developed by integrating the International Reference Ionosphere Model (IRI) and ray tracing methods. This model aims to improve the accuracy of GNSS-IR sea surface altimetry by correcting the ionospheric refraction effects on satellite elevation angles. Secondly, four GNSS stations (TAR0, PTLD, GOM1, and TPW2) were selected globally, and the corrected sea surface height values obtained using ISEACM were compared with observed values from tide gauge stations. The calculated average Root Mean Square Error (RMSE) and Pearson Correlation Coefficient (PCC) were 0.20 m and 0.83, respectively, indicating the effectiveness of ISEACM in sea surface height retrieval. Thirdly, a comparative analysis was conducted between sea surface height retrieval before and after correction using ISEACM. The optimal RMSE and PCC values with tide gauge station observations were 0.15 m and 0.90, respectively, representing a 20.00% improvement in RMSE and a 4.00% improvement in correlation coefficient compared to traditional GNSS-IR retrieval heights. These experimental results demonstrate that correction with ISEACM can effectively enhance the precision of GNSS-IR sea surface altimetry, which is crucial for accurate sea surface height measurements. Full article

The application of starlight refraction navigation to spacecraft and space weapons is a significant development. However, the irregular stratospheric atmosphere can cause fluctuations in relative light intensity and refraction angles of refracted stars, which need to be analyzed to provide guidance for system design and simulation verification. The internal gravity wave (IGW) is an important component of the irregular atmosphere. Based on the Rytov approximation, closed-form approximations were obtained, which can more intuitively reveal the relationship between the IGW parameters and the star signals’ statistical characteristics. From the GOMOS observations, the influence of the stratosphere from 25 km to 35 km on the fluctuations in relative intensity and refraction angles was analyzed in this study. As the height increased, the fluctuations in starlight signals gradually weakened. Compared with the numerical solution, the error of the closed-form approximations for relative intensity fluctuations was no more than 10%, and the error for refraction angle fluctuations was 1.0%. Compared with the measured data, the error of the closed-form approximations for relative intensity was 6.3%. The proposed approximations better reflect the relationship between IGW parameters and star signal fluctuations compared to the existing approximation. The research in this article can provide a reference for application assessment based on starlight refraction navigation. Full article

Nephrite is a very precious gemstone material. As a non-renewable resource, the discovery of new nephrite deposits and the study of the genesis of nephrite have aroused great interest. A new occurrence of nephrite known as Xinyu nephrite was discovered in Xinyu Country, Jiangxi province, China. Field investigations reveal that nephrite appears in a contact zone between the Mengshan composite granitic pluton and Permian carbonate rock. The carbonate rock is calcic marble that underwent diopsidization and tremolitization. Nephrites have a light yellow-green color, weak greasy luster, are slightly-translucent to translucent, and are fine-grained. Their refractive index (RI) ranges from 1.60 to 1.61, and their specific gravity (SG) value ranges from 2.90 to 2.91, falling within the range of nephrites from Xinjiang, China. Their Mohs hardness (Hm) ranges from 5.78 to 5.83. Petrographic observations and electron probe micro analyzer (EPMA) data indicated that analyzed nephrites mainly comprise tremolite, with minor diopside, calcite, quartz, and apatite. Tremolite has a ratio of Mg/(Mg + Fe²⁺) greater than 0.99. The tremolite grains show microscopic fibrous-felted and columnar textures. Scanning electron microscope (SEM) images show some tremolite fibers interwoven in different crystallographic orientations, and some arranged in parallel. Fourier transform infrared and Raman spectroscopy features reveal the bands of minerals typical for nephrite composition. The petrographic characteristics and geological background of the Mengshan area indicate that nephrite formed through a replacement of calcic marble, which differs from the two known types (D-type: dolomite-related; S-type: serpentinite-related). Mineral replacements were common in nephrite, including diopside by tremolite, calcite by tremolite, and recrystallization of coarse by fine tremolite grains. The discovery of Xinyu nephrite occurrence complements the resource and provides an updated case for the in-depth study of the diversity of nephrite deposits. Full article

If visible matter alone is present in the Universe, general relativity (GR) and its Newtonian weak field limit (WFL) cannot explain several pieces of evidence, from the largest to the smallest scales. The most investigated solution is the cosmological model $\mathsf{\Lambda }$ cold dark matter ($\mathsf{\Lambda }$CDM), where GR is valid and two dark components are introduced, dark energy (DE) and dark matter (DM), to explain the ∼70% and ∼25% of the mass–energy budget of the Universe, respectively. An alternative approach is provided by modified gravity theories, where a departure of the gravity law from $\mathsf{\Lambda }$CDM is assumed, and no dark components are included. This work presents refracted gravity (RG), a modified theory of gravity formulated in a classical way where the presence of DM is mimicked by a gravitational permittivity $ϵ\left(\rho \right)$ monotonically increasing with the local mass density $\rho$, which causes the field lines to be refracted in small density environments. Specifically, the flatter the system the stronger the refraction effect and thus, the larger the mass discrepancy if interpreted in Newtonian gravity. RG presented several encouraging results in modelling the dynamics of disk and elliptical galaxies and the temperature profiles of the hot X-ray emitting gas in galaxy clusters and a covariant extension of the theory seems to be promising. Full article

Our main goal here is to conduct a comparative analysis between the well-known MOND theory and a more recent model called the $\kappa$-model. An additional connection, between the $\kappa$-model and two other novel MOND-type theories, Newtonian Fractional-Dimension Gravity (NFDG) and Refracted Gravity (RG), is likewise presented. All these models are built to overtake the DM paradigm, or at least to strongly reduce the dark matter content. Whereas they rely on different formalisms, however, all four seem to suggest that the universal parameter, $a_0$, appearing in MOND theory could intrinsically be correlated to either the sole baryonic mean mass density (RG and $\kappa$-model) and/or to the dimension of the object under consideration (NFDG and $\kappa$-model). We then confer to parameter $a_0$ a more flexible status of multiscale parameter, as required to explain the dynamics together in galaxies and in galaxy clusters. Eventually, the conformal gravity theory (CFT) also seems to have some remote link with the $\kappa$-model, even though the first one is an extension of general relativity, and the second one is Newtonian in essence. The $\kappa$-model has been tested on a small sample of spiral galaxies and in galaxy clusters. Now, we test this model on a large sample of galaxies issued from the SPARC database. Full article

Titanite is a widespread accessory mineral in igneous, metamorphic, and hydrothermal rocks, but few comply with gem-grade requirements. Previous studies on Moroccan titanite focused on elementary composition and U-Pb dating. In this study, two gem-grade titanites (MA-1 and MA-2) from the Moroccan Central High Atlas were investigated through gemological and chemical studies, including infrared spectrum, Raman spectrum, SEM-EDS, and LA-ICP-MS. Two titanite samples are yellow, transparent–translucent with a greasy luster, 3.5 and 2.5 mm long. MA-1 and MA-2 have similar gemological properties, the refractive index (RI) is beyond the range of the refractometer (>1.78), the specific gravity (SG) values fall in the range of 3.52~3.54 and both are inert to short-wave and long-wave UV radiation. The spectral characteristics have high consistency with the RRUFF database. The major elements’ composition shows a negative correlation between Al, Fe, V, and Ti, suggesting the titanites underwent substitutions such as (Al, Fe³⁺) + (F, OH) ↔ Ti + O. The titanite samples, characterized by a low abundance of REE (802~4088 ppm) and enriched in LREE, exhibit positive Eu (δEu: 1.53~7.79) and Ce (δCe: 1.08~1.33) anomalies, indicating their formation in a hydrothermal environment with low oxygen fugacity. The ²³⁸U/²⁰⁶Pb and ²⁰⁷Pb/²⁰⁶Pb ratios of the titanites yield lower intercept ages of 152.6 ± 2.2 and 151.4 ± 5.3 Ma (1s), consistent with their weighted average ²⁰⁶Pb/²³⁸U ages of 152.3 ± 2.0 and 150.7 ± 3.2 Ma (1s) respectively. The results of U-Pb dating are matched with the second main magmatic activities in the High Atlas intracontinental belt of Morocco during the Mesozoic to Cenozoic period. Moreover, the two titanite samples have almost no radiational damage. All the results show that the titanite from High Atlas, Morocco, has the potential to be a reference material for LA-ICP-MS U–Pb dating, but further experiments are needed to be sure. Full article

The paper presents the problem of generation and validation of Velocity Interval Depth (VID) models with the application of non-seismic geophysical and geological data. The study area is a part of the Carpathian Foredeep located close to its contact with the Carpathian Overthrust. In this area of complicated geological structure, hydrocarbon deposits have been successfully explored for decades with seismic methods and drilling. The research applied the Simultaneous Joint Inversion (SJI) of independent geophysical data, which is a modern methodology of geophysical data processing, that is still under development. Such an attempt was necessary due to the lack of a sufficiently dense grid of wells in the study area, in which seismic velocities would be correctly recorded. Such data would be then applied for the generation of relevant VID models, which in turn, could be used to perform the Prestack Depth Migration (PreSDM) procedures. The application of procedures taking advantage of independent geophysical and geological data enabled researchers to control the generation process of the spatial VID model in the areas without wells. The analyses aimed to verify the correctness of VID model evaluation and its influence on the quality of seismic imaging in the area of the Carpathian Overthrust. Precisely, the influence was tested of such non-standard generation procedure of seismic velocity fields, not only on the PreSDM results but also on the geological interpretation of both the Rączyna and the Jodłówka gas deposits. The latter aspect of the presented results seems to be crucial to the effectiveness of petroleum exploration in the transition zone between the Carpathian Orogen and the Carpathian Foredeep. Full article

We present a quaternion representation of quantum mechanics that allows its ontological interpretation. The correspondence between classical and quaternion quantum equations permits one to consider the universe (vacuum) as an ideal elastic solid. Elementary particles would have to be standing or soliton-like waves. Tension induced by the compression and twisting of the elastic medium would increase energy density, and as a result, generate gravity forcing and affect the wave speed. Consequently, gravity could be described by an index of refraction. Full article

Purple scapolite is a precious gemstone. In this paper, we compared the crystal structure and spectral characteristics of purple scapolite before and after heat treatment with conventional gemological tests, EPMA, XRF, LA-ICP-MS, infrared spectroscopy, Raman spectroscopy, UV–vis spectrophotometer, EPR, and other tests. The XRD results showed that the structure of purple scapolite fits perfectly with that of marialite. Compositional analyses indicate that purple scapolite has an average Me value of 16.85 and belongs to the subspecies marialite, and thus its specific gravity and refractive index are low. The absorption peak at 1045 cm⁻¹ in the infrared spectra has a direct relationship with the Me value, which is blue-shifted with increasing Me value. After heating at 400 °C for 2 h, the purple scapolite changed to colorless, and no phase transformation or significant structural changes occurred during this process. But this process is accompanied by the disappearance of the signal at g = 2.011 in the EPR spectra, which indicates the presence of oxygen hole centers, thus proving that the color of purple scapolite is caused by oxygen hole centers rather than Fe³⁺. The chlorine in the marialite structure occupies the structural center, which provides for the appearance of oxygen hole centers, and thus purple scapolite always has a high marialite content. This further leads to the refractive index and specific gravity always being lower. That is a new explanation for the relationship between scapolite coloration mechanism, specific gravity, and refractive index. Full article

The refractive index is an important physical property that is used to estimate the structural characteristics, thermodynamic, and transport properties of petroleum fluids, and to determine the onset of asphaltene flocculation. Unfortunately, the refractive index of opaque petroleum fluids cannot be measured unless special experimental techniques or dilution is used. For that reason, empirical correlations, and metaheuristic models were developed to predict the refractive index of petroleum fluids based on density, boiling point, and SARA fraction composition. The capability of these methods to accurately predict refractive index is discussed in this research with the aim of contrasting the empirical correlations with the artificial neural network modelling approach. Three data sets consisting of specific gravity and boiling point of 254 petroleum fractions, individual hydrocarbons, and hetero-compounds (Set 1); specific gravity and molecular weight of 136 crude oils (Set 2); and specific gravity, molecular weight, and SARA composition data of 102 crude oils (Set 3) were used to test eight empirical correlations available in the literature to predict the refractive index. Additionally, three new empirical correlations and three artificial neural network (ANN) models were developed for the three data sets using computer algebra system Maple, NLPSolve with Modified Newton Iterative Method, and Matlab. For Set 1, the most accurate refractive index prediction was achieved by the ANN model, with %AAD of 0.26% followed by the new developed correlation for Set 1 with %AAD of 0.37%. The best literature empirical correlation found for Set 1 was that of Riazi and Daubert (1987), which had %AAD of 0.40%. For Set 2, the best performers were the models of ANN, and the new developed correlation of Set 2 with %AAD of refractive index prediction was 0.21%, and 0.22%, respectively. For Set 3, the ANN model exhibited %AAD of refractive index prediction of 0.156% followed by the newly developed correlation for Set 3 with %AAD of 0.163%, while the empirical correlations of Fan et al. (2002) and Chamkalani (2012) displayed %AAD of 0.584 and 0.552%, respectively. Full article

This paper describes the potential industrial use of zircon from Nigeria (Plateau, Nasarawa, Kano, Kaduna, Bauchi, and Adamawa states). Different techniques, equipment, and indices such as scanning electron microscope, energy dispersive X-ray fluorescence, X-ray diffraction, Fourier transform infrared spectroscopy, specific gravity, refractive index, pH, and hardness were used to examine the samples. The X-ray diffraction showed predominantly quartz, zirconium oxide, and other heavy minerals. All twelve samples showed the presence of Zr-O, ${\mathrm{SiO}}_4^{2-}$, Zr-OH, and OH, with pH values ranging from 7.3 to 7.8. Six of the zircon samples had a refractive index between 1.4 and 12.5. The hardness values ranged from 0.0021 to 0.0703 GPa, while the elastic moduli were between 0.00558 and 0.9593 GPa. Four of the twelve untreated zircon samples with specific gravities above 4.2 g/cm³, which is the United States Geological Survey minimum recommended standard for zircon sand, needed to be upgraded to increase the ZrO2 weight percentages and purity toward improving their suitability for zircon-reinforced composites applications in aerospace and also for ceramic, foundry, building and construction, and refractory industries. The study’s findings can be incorporated by the industries into their businesses for the development of novel industrial materials as well as the processing methods and procedures for beneficiation of the mineral for value-addition. Full article

A microwave hot pressing machine (MHPM) was used to heat the colander to produce fixed oils from each of castor, sunflower, rapeseed, and moringa seed and compared them to those obtained using an ordinary electric hot pressing machine (EHPM). The physical properties, namely the moisture content of seed (MCs), the seed content of fixed oil (S_cfo), the yield of the main fixed oil (Y_mfo), the yield of recovered fixed oil (Y_rfo), extraction loss (EL), six Efficiency of fixed oil extraction (E_foe), specific gravity (SG_fo), refractive index (RI) as well as chemical properties, namely iodine number (IN), saponification value (SV), acid value (AV), and the yield of fatty acid (Y_fa) of the four oils extracted by the MHPM and EHPM were determined. Chemical constituents of the resultant oil were identified using GC/MS after saponification and methylation processes. The Ymfo and SV obtained using the MHPM were higher than those for the EHPM for all four fixed oils studied. On the other hand, each of the SG_fo, RI, IN, AV, and pH of the fixed oils did not alter statistically due to changing the heating tool from electric band heaters into a microwave beam. The qualities of the four fixed oils extracted by the MHPM were very encouraging as a pivot of the industrial fixed oil projects compared to the EHPM. The prominent fatty acid of the castor fixed oil was found to be ricinoleic acid, making up 76.41% and 71.99% contents of oils extracted using the MHPM and EHPM, respectively. In addition, the oleic acid was the prominent fatty acid in each of the fixed oils of sunflower, rapeseed, and moringa species, and its yield by using the MHPM was higher than that for the EHPM. The role of microwave irradiation in facilitating fixed oil extrusion from the biopolymeric structured organelles (lipid bodies) was protruded. Since it was confirmed by the present study that using microwave irradiation is simple, facile, more eco-friendly, cost-effective, retains parent quality of oils, and allows for the warming of bigger machines and spaces, we think it will make an industrial revolution in oil extraction field. Full article

Currently, Zambia is one of the world’s major emerald-producing countries. In this study, emerald samples from Kamakanga, Zambia, were systematically analyzed by standard gemological tests, microscopic observation, Raman spectroscopy test of mineral inclusions, and fluid inclusions. The study found Kamakanga emeralds have higher RI (refractive index) and SG (specific gravity) than average. The common inclusions in Kamakanga emeralds are pseudo-hexagonal, dark green, brownish, or oval platelet phlogopite; red spot or skeletal hematite; black spot, platelet, or dendritic oxide inclusions (pyrolusite, magnetite, ilmenite); or schorl. The common paragenetic mineral is schorl. Other mineral inclusions are fluorapatite, tremolite, and calcite. All Kamakanga emeralds contain at least two kinds of common mineral inclusions that are described above, and the characteristic mineral inclusions are pseudo-hexagonal dark green platelet phlogopite and a large quantity of fluorapatite. The fluorapatite inclusions with colorless transparent rims and greyish hazy interiors are reported for the first time. Most fluid inclusions in Kamakanga emeralds are rectangular two- or three-phase inclusions, containing gas phase (CO₂ + CH₄ + H₂O or CO₂), aqueous fluid, and sometimes solid phase (carbonate). A small number of hexagonal three-phase fluid inclusions can be seen in Kamakanga emeralds, containing gas phase (CO₂ + CH₄), aqueous fluid, and daughter crystals (siderite). Full article

General relativity and its Newtonian weak field limit are not sufficient to explain the observed phenomenology in the Universe, from the formation of large-scale structures to the dynamics of galaxies, with the only presence of baryonic matter. The most investigated cosmological model, the $\mathsf{\Lambda }$CDM, accounts for the majority of observations by introducing two dark components, dark energy and dark matter, which represent ∼95% of the mass-energy budget of the Universe. Nevertheless, the $\mathsf{\Lambda }$CDM model faces important challenges on the scale of galaxies. For example, some very tight relations between the properties of dark and baryonic matters in disk galaxies, such as the baryonic Tully–Fisher relation (BTFR), the mass discrepancy–acceleration relation (MDAR), and the radial acceleration relation (RAR), which see the emergence of the acceleration scale $a_0\simeq 1.2\times {10}^{-10}$ m s${}^{-2}$, cannot be intuitively explained by the CDM paradigm, where cosmic structures form through a stochastic merging process. An even more outstanding coincidence is due to the fact that the acceleration scale $a_0$, emerging from galaxy dynamics, also seems to be related to the cosmological constant $\mathsf{\Lambda }$. Another challenge is provided by dwarf galaxies, which are darker than what is expected in their innermost regions. These pieces of evidence can be more naturally explained, or sometimes even predicted, by modified theories of gravity, that do not introduce any dark fluid. I illustrate possible solutions to these problems with the modified theory of gravity MOND, which departs from Newtonian gravity for accelerations smaller than $a_0$, and with Refracted Gravity, a novel classical theory of gravity introduced in 2016, where the modification of the law of gravity is instead regulated by a density scale. Full article