Search Results (77)

This research paper provides new insights into the impact of accelerated mineralization of alkaline waste materials on the physical and mechanical behavior of low-carbon cement-based mortars. Standardized eco-cement mortars were prepared by replacing Portland cement with 7% and 20% proportions of three alkaline waste materials (white ladle furnace slag, biomass ash, and fine concrete waste fraction) that had been previously carbonated in a static reactor at predefined humidity and CO₂ concentration. The mortars’ physical (total/capillary water absorption, electrical resistivity) and mechanical properties (compressive strength up to 90 d of curing) were analyzed, and their microstructures were examined using mercury intrusion porosimetry and computed tomography. The results reveal that carbonated waste materials generate a greater heat of hydration and have a lower total and capillary water absorption capacity, while the electrical resistivity and compressive strength tests generally indicate that they behave similarly to mortars not containing carbonated minerals. Mercury intrusion porosimetry (microporosity) indicates an increase in total porosity, with no clear refinement versus non-carbonated materials, while computed tomography (macroporosity) reveals a refinement of the pore structure with a significant reduction in the number of larger pores (>0.09 mm³) and intermediate pores (0.001–0.09 mm³) when carbonated residues are incorporated that varies depending on waste material. The construction and demolition waste (CCDW-C) introduced the best physical and mechanical behavior. These studies confirm the possibility of recycling carbonated waste materials as low-carbon supplementary cementitious materials (SCMs). Full article

This study investigates the use of Glass Fine Aggregate (GFA) and Fly Ash (FA) in mortar for Alkali–Silica Reaction (ASR) mitigation through a multidimensional evaluation. GFA was used to replace river sand in 20% increments up to 100%, while FA replaced cement at 10%, 20%, and 30%. Three GFA size ranges were considered: <1.18 mm, 1.18–4.75 mm, and a combined fraction of <4.75 mm. At 100% replacement, <1.18 mm GFA reduced ASR expansion to 0.07%, compared to 0.2% for <4.75 mm and 0.46% for 1.18–4.75 mm GFA. It also improved long-term strength by 25% from 28 days to 6 months due to pozzolanic activity. However, refining GFA to below 1.18 mm increased environmental impacts and resulted in a 4.2% increase in energy demand due to the additional drying process. Incorporating 10% FA reduced ASR expansion to 0.044%, had no significant effect on strength, and decreased key environmental burdens such as toxicity by up to 18.2%. These findings indicate that FA utilisation offers greater benefits for ASR mitigation and environmental sustainability than further refining GFA size. Therefore, combining <4.75 mm GFA with 10% FA is identified as the optimal strategy for producing durable and sustainable mortar with recycled waste glass. Full article

This article provides a comprehensive analysis of the acoustic properties of recycled rubber crumb, examined in two forms—loose granular and compacted specimens. The aim was to compare their acoustic properties depending on the size of the fraction, the thickness of the sample, and the degree of compaction, with measurements performed using a model BSWA SW433 impedance tube in the frequency band 100–2500 Hz. Experimental samples of recycled rubber crumb were prepared with various thicknesses (2, 4.5, and 7 cm) and of various fractions (0–4 mm), and the granular samples were compacted under a pressure of 250–750 kPa. The results showed that the highest transmission loss (TL) is achieved by fine fractions at higher pressure and with greater sample thickness; Fraction 1 (below 1 mm) at a pressure of 750 kPa and a thickness of 7 cm had the best acoustic properties. Through regression analysis, mathematical models of the dependence of transmission loss on the monitored parameters for all types of samples (granular/compacted) were created. The regression analysis confirmed that the thickness, pressure, and size of the fraction significantly affect the acoustic properties of the material. Recycled rubber crumb therefore represents an efficient and environmentally sustainable alternative to traditional insulation materials, and optimizing its parameters enables a wide range of practical acoustic applications in construction, transport infrastructure, and manufacturing industries. Full article

Geopolymer recycled aggregate concrete (GRAC) is an eco-friendly material utilizing industrial byproducts (slag, fly ash) and substituting natural aggregates with recycled aggregates (RA). Incorporating steel-polypropylene hybrid fibers into GRAC to produce hybrid-fiber-reinforced geopolymer recycled aggregate concrete (HFRGRAC) can bridge cracks across multi-scales and multi-levels to synergistically improve its mechanical properties. This paper aims to investigate the mechanical properties of HFRGRAC with the parameters of steel fiber (SF) volume fraction (0%, 0.5%, 1%, 1.5%) and aspect ratio (40, 60, 80), polypropylene fiber (PF) volume fraction (0%, 0.05%, 0.1%, 0.15%), and RA substitution rate (0%, 25%, 50%, 75%, 100%) considered. Twenty groups of HFRGRAC specimens were designed and fabricated to evaluate the compressive splitting tensile strengths and flexural behavior emphasizing failure pattern, load–deflection curve, and toughness. The results indicated that adding SF enhances the specimen ductility, mechanical strength, and flexural toughness, with improvements proportional to SF content and aspect ratio. In contrast, a higher percentage of RA substitution increased fine cracks and reduced mechanical performance. Moreover, the inclusion of PF causes cracks to exhibit a jagged profile while slightly improving the concrete strength. The significant synergistic effect of SF and PF on mechanical properties of GRAC is observed, with SF playing a dominant role due to its high elasticity and crack-bridging capacity. However, the hydrophilic nature of SF combined with the hydrophobic property of PF weakens the bonding of the fiber–matrix interface, which degrades the concrete mechanical properties to some extent. Full article

Tunnel Boring Machine (TBM) excavation materials were recycled by sieving and separating particles into sizes 5–10 mm (coarse aggregates) and below 5 mm (manufactured sand) to explore their potential as aggregates in shotcrete production, with the aim of reducing environmental harm from waste disposal. Mix proportion experiments were conducted to evaluate the mechanical properties—including failure patterns, compressive strength, flexural strength, and deflection—of the shotcrete specimens through cubic axial compression and four-point bending tests; furthermore, rebound tests were conducted on shotcrete mixed with the recycled TBM aggregates in foundation pit engineering. These tests assessed the effects of key parameters (water–binder ratio, sand ratio, fly ash content, synthetic fibers, and liquid alkali-free accelerator) on shotcrete composed of recycled TBM sand and gravel. The results indicated that crushing and grading flaky TBM-excavated rock fragments, and subsequently blending them with pre-screened fine aggregates in a 4:1 ratio, yielded manufactured sand with an optimized particle gradation and controlled stone powder content (18%). Adjusting the water–binder ratio (0.4–0.5), fly ash dosage (mixed with 0–20%), and sand ratio (0.5–0.6) are feasible steps in preparing shotcrete with a compressive strength of 29.1 MPa to 50.4 MPa and slump of 9 cm to 20 cm. Moreover, the rebound rate of the shotcrete reached 11.3% by applying polyoxymethylene (POM) fibers with a 0.15% volume fraction and a liquid-state alkali-free setting accelerator (8% dosage), demonstrating that the implemented approach enables a decrease in the rebound rate of shotcrete. Full article

In the context of sustainable construction, recycled concrete aggregates (RCAs), including both fine and coarse fractions derived from construction and demolition waste (CDW), are gaining traction due to their potential to mitigate environmental impacts by reducing reliance on natural aggregates and minimizing waste. This paper provides a comprehensive review of the effects of RCAs on the mechanical and durability properties of concrete, including compressive and tensile strengths, modulus of elasticity, and resistance to environmental degradation. The review highlights that the presence of adhered mortar and higher porosity in RCAs generally leads to reduced mechanical performance and durability. However, pretreatment methods—mechanical, chemical, and thermal—along with optimized mix designs and the use of supplementary cementitious materials (SCMs) have shown to significantly improve the concrete properties of RCAs. Additionally, recent studies on carbon dioxide (CO₂) capture through the accelerated carbonation of RCAs offer promising environmental benefits. Life cycle assessment (LCA) analyses reveal reductions in energy use, CO₂ emissions, and material costs when RCAs are properly processed and locally sourced. Despite challenges related to RCA quality variability, the review identifies pathways for the effective use of RCAs in structural applications. Full article

Recycled aggregate concrete (RAC), which is made by replacing all natural coarse and fine aggregates with recycled aggregate, plays a significant role in improving the recycling rate of construction materials, reducing carbon emissions from construction, and alleviating ecological degradation issues. However, due to its low strength and significant shrinkage and deformation problems, RAC has limited application. The effort of fiber type, fiber admixture, and fiber hybridization on autogenous shrinkage were studied to improve the structural safety of building materials and broaden the application of RAC. Test results indicate that the shrinkage of RAC decreases with an increase in fiber admixture, and steel fiber-reinforced RAC is more resistant to shrinkage deformation than polypropylene fiber-reinforced RAC. The shrinkage deformation of the hybrid fiber group is smaller than that of the single fiber group, and the inhibition of shrinkage deformation is most effective when the volume fraction of steel fiber is 0.5% and the polypropylene fiber content is 1.5 kg/m³. At 120 days, the PF15SF05 mixture showed a 65.3% reduction in shrinkage compared with ordinary RAC. By merging the shrinkage deformation characteristics of fiber-reinforced RAC and introducing the fiber influence coefficient, three theoretical calculation models for autogenous shrinkage applicable to single and hybrid fiber-reinforced RAC were established based on the experimental data. Full article

Concrete manufacturing and recycling must evolve to meet sustainability and carbon reduction demands. While the focus is often on reusing coarse aggregates, fine fractions are also produced during recycling. This study explores using ground fine fractions (0/2) as a partial cement substitute. The fines were characterized for their mineralogical, chemical, and physical properties, and experiments were conducted on pastes and mortars with 0% to 30% cement substitution, including isothermal calorimetry and strength tests. Two concrete mixes—a reference mix with natural aggregates and CEM I, and a mix with 10% concrete fines replacing CEM I—using recycled sand and coarse aggregates were tested for compressive strength, carbonation, shrinkage, and freeze–thaw resistance. The results indicated that the recycled concrete had a comparable strength to the reference and a slightly reduced durability in freeze–thaw conditions. In terms of shrinkage, recycled concrete with 10% concrete fines had an increased drying shrinkage and a lower autogenous shrinkage due to the water retention capacity of the recycled aggregates. Full article

Sustainable development relies on the circularity in the built environment, which, in turn, includes recycling construction and demolition waste and using recycled materials. However, using fine recycled fractions is challenging, especially considering the requirements for new building applications. Yet, producing more widely applied recycled coarse aggregates usually leads to the simultaneous generation of recycled sand fraction, which contains many fines that pose potential problems. This work presents the direct incorporation of concrete and mixed waste-based recycled sand and recycled fines in masonry mortars, on the one hand, as a complete aggregate replacement and, on the other, only replacing the finest aggregate fraction. Such mortars are assessed based on the fresh and hardened mortar properties and are compared to natural aggregate-containing mortars. In the fresh state, the mortars with recycled fines and recycled sand required more mixing water to produce comparable consistency and workability. In a hardened state, mortars with recycled mixed waste sand and fines have demonstrated increased mechanical strength compared to natural aggregate mortars. In contrast, those containing recycled concrete aggregates and fines were inferior in that regard. This indicates the potential of using recycled mixed waste fractions to improve masonry mortar performance, although both types might be important in enhancing the sustainability of masonry construction. Full article

The modern metallurgical industry produces approximately 90% of the volume of all produced steel; for this, integrated technology based on fossil materials such as coal, fluxes, and especially iron ore is used. This industry generates large amounts of waste and by-products at almost all stages of production. Alternative iron and steel production technologies based on iron ore, methane, or pure hydrogen are also not waste-free. To ensure sustainable waste management, efforts are made to seal processes as well as capture and recycle dusty waste. This work presents the results of research on the processing of sludge resulting from the dedusting of the basic oxygen furnace (BOF) process and landfilling in a lagoon. The work discusses the treatment of fine dusty sludge hydrated to 26–60% H₂O, to which various amounts of caking agents were added; also discussed are the rheological characteristics of the tested suspension systems, the possibility of forming these systems into larger fractions, and rapid drying using 100–600 W microwaves with a drying time of 1–9 min. The aim was to identify, describe, and characterize the parameters of the agglomeration process and obtain a product that was durable enough to transport and dose into slag baths in order to reduce iron oxides in liquid phases. During the research, completely dried briquettes with an appropriate strength were obtained. The study demonstrates that microwave drying at 300 W for 6 min achieved complete drying with a weight loss of 35%, whereas a higher-power treatment at 750 W for 2 min enhanced compressive strength by up to 95% and reached 15 N/psc, which was comparable with green iron ore pellets. This approach offers a sustainable alternative to traditional methods, but with a reduced drying time. Full article

Kazakhstan is embarking on a fresh approach to managing waste, aiming to recycle and repurpose solid household waste while integrating innovative, eco-friendly technologies for its treatment and disposal. The main goal is to reduce the amount of waste sent to landfills and instead convert it into more stable forms, lessening its harmful impact on the environment. This effort requires a comprehensive strategy, especially as existing landfills still need to be managed and rehabilitated when they reach capacity. It is essential to use municipal solid waste as a resource for producing various goods, which not only helps in landfill management but also aligns with principles of sustainability. This approach aligns with circular economic principles and helps to reduce the technological impact of landfills on the surrounding environment. The main types of waste in the Aktas landfill were identified as a result of this research: it is glass, of which only 3% is recycled. In our results, the setup allowed for the extraction of valuable components from the fine fraction, which can then be recycled. This enriches the organic material ready for composting (organo-mineral raw material mixture) with food waste. Full article

This study investigates the reactivity of municipal solid waste incineration residues to aqueous carbonation, focusing on CO₂ absorption rates, uptakes, and heavy metal (HM) leachability. Various combinations of boiler, electrofilter, and bag filter residues were assessed under typical incineration conditions. Bag filter residues from lime-sorbent plants exhibited the highest CO₂ uptake (244.5 gCO₂/kg), while bottom ash (BA) fine fraction, boiler/electrofilter fly ash (FA), and other mixed air pollution control residue (APCr) demonstrated uptakes of 101, 0, 93, and 167 gCO₂/kg, respectively. Carbonation kinetics revealed that high calcium content FA and APCr, followed similar CO₂ absorption trends. Notably, BA carbonation was predominantly driven by Ca-aluminates rather than lime. Carbonation reduces leaching of Al, As, Cd, Co, Cu, Ni, Pb and Zn compared to water washing, though significant concerns arise with anions such as Sb and Cr. In BA, critical behaviours of Cr, Mn, and Fe were observed, with Cr leaching likely controlled by Fe-Mn-Cr oxide particle dissolution. These findings highlight the potential of integrating enhanced metal recovery (EMR) through density or magnetic separation in BA prior to carbonation to reduce HM leaching and recycle critical metals (Ag, Cu, Cr, Ni, Mn, etc). Full article

Cement-bonded particle boards are gaining popularity globally due to their durability, strength, and, more importantly, environmental sustainability. The increasing demand for these materials has also created the necessity for the sustainable recycling of these materials. In this study, the potential to recycle wood-wool cement board (WWCB) waste into new lightweight insulation biocomposite material was examined. The waste WWCBs were crushed and separated into a fine aggregate fraction, and WWCB production line residues were also collected and compared. The crushed WWCBs were used to produce biocomposites with various compaction ratios and different binder-to-aggregate ratios. To improve their thermal properties and reduce their density, hemp shives were used to partially replace the recycled WWCB aggregate. Their physical, mechanical (compressive and flexural strength), and thermal properties were evaluated, and the drying process of the biocomposites was characterized. The results showed that the density of the produced biocomposites ranged from 390 to 510 kg/m³. The reduction in density was limited due to the presence of cement particles in the aggregate. The incorporation of hemp shives allowed us to reduce the density below 200 kg/m³. The thermal conductivity of the biocomposites ranged from 0.054 to 0.084 W/(mK), placing the material within the effective range of natural biocomposites. This research has demonstrated that industrially produced WWCBs can be successfully recycled to produce sustainable lightweight cement-bonded insulation materials. Full article

The recent COVID-19 emergency has led to an impressive increase in the production of pharmaceutical vials. This has led to a parallel increase in the amounts of waste glass; manufacturers typically recover material from faulty containers by crushing, giving origin to an unrecyclable fraction. Coarse fragments are effectively reused as feedstock for glass melting; on the contrary, fine powders (<100 microns), contaminated by metal and ceramic particles due to the same crushing operations, are landfilled. Landfilling is also suggested for pharmaceutical containers after medical use. This study aims at proposing new opportunities for the recycling of fine glass particles, according to recent findings concerning alkali activation of pharmaceutical glass, combined with novel processing, i.e., binder jetting printing. It has already been shown that pharmaceutical glass, immersed in low-molarity alkaline solution (not exceeding 2.5 M NaOH), undergoes surface dissolution and hydration; cold consolidation is later achieved, upon drying at 40–60 °C, by a condensation reaction occurring at hydrated layers of adjacent particles. Binder jetting printing does not realize a full liquid immersion of the glass powders, as the attacking solution is selectively sprayed on a powder bed. Here, we discuss the tuning of key parameters, such as the molarity of the attacking solution (from 2.5 to 10 M) and the granulometry of the waste glass, to obtain stable printed blocks. In particular, the stability depends on the formation of bridges between adjacent particles consisting of strong T-O bonds (Si-O-Si, Al-O-Si, B-O-Si), while degradation products (concentrating Na ions) remain as a secondary phase, solubilized by immersion in boiling water. Such stability is achieved by operating at 5 M NaOH. Full article

Excessive consumption of natural resources to meet the growing demands of building and infrastructure projects has put enormous stress on these resources. On the other hand, a significant quantity of soil is excavated for development activities across the globe and is usually treated as waste material. This study explores the potential of excavated soils in the Brittany region of France for its reuse as earthen construction materials. Characterization of soil recovered from building sites was carried out to classify the soils and observe their suitability for earthen construction materials. These characteristics include mainly Atterberg limits, granulometry, organic matter and optimum moisture content. Soil samples were separated into fine and coarse particles through wet sieving. The percentage of fines (particles smaller than 0.063 mm) in studied soil samples range from 28% to 65%. The methylene blue value (MBV) for Lorient, Bruz and Polama soils is 1, 1.2 and 1.2 g/100 g, and French classification (Guide de terrassements des remblais et des couches de forme; GTR) of soil samples is A1, B5 and A1, respectively. The washing of soils with lower fine content helps to recover excellent-quality sand and gravel, which are a useful and precious resource. However, residual fine particles are a waste material. In this study, three soil formulations were used for manufacturing earth blocks. These formulations include raw soil, fines and restructured soil. In restructured soil, a fine fraction of soil smaller than 0.063 mm was mixed with 15% recycled sand. Restructuring of soil fine particles helps to improve soil matrix composition and suitability for earth bricks. Compressed-earth blocks of 4 × 4 × 16 cm were manufactured at a laboratory scale for flexural strength testing by using optimum molding moisture content and compaction through Proctor normal energy. Compressive strength tests were performed on cubic blocks of size 4 × 4 × 4 cm. Mechanical testing of bricks showed that bricks with raw soil had higher resistance with a maximum of 3.4 MPa for Lorient soil. Removal of coarse particles from soil decreased the strength of bricks considerably. Restructuring of fines with recycled sand improves their granular skeleton and increases the compressive strength and durability of bricks. Full article