Search Results (1,058)

Polymeric electrolyte membranes based on a low equivalent-weight Aquivion^® commercial dispersion (D72-25BS; EW = 720 g eq⁻¹, Syensqo) were fabricated using a standardized in-house doctor-blade casting technique for application in proton exchange membrane fuel cells (PEMFCs). The low equivalent-weight (EW) Aquivion^® dispersion is a copolymer of tetrafluoroethylene (TFE) and sulfonyl fluoride vinyl ether (SFVE), commonly referred to as a short-side-chain (SSC) ionomer, which exhibits higher ion-exchange capacity (IEC) and proton conductivity than long-side-chain (LSC) perfluorosulfonic membranes. A home-made 30 wt.% Pt/CeO₂ radical scavenger (denoted syn-scavenger) was synthesized via a colloidal method and incorporated into the Aquivion^® membranes to investigate its mitigating effect on chemical degradation induced by peroxide radicals, a role typically associated with Ce-based scavengers. Particularly, the unique aspects of the Pt/CeO₂ scavenger synthesis could be summarized in the following points: (i) the mild aqueous deposition approach enabling highly dispersed Pt species on CeO₂ without the use of organic ligands; and (ii) the tailored redox interaction between Pt and ceria that enhances radical scavenging activity. Two Aquivion^® membranes (denoted Aqu) containing different syn-scavenger loadings (1.0 and 1.5 wt.%) were prepared and compared with a pristine Aquivion^® membrane and a membrane containing commercial CeO₂ (1.0 wt.%). Physicochemical characterization of the scavenger was performed using transmission electron microscopy (TEM), BET surface area analysis, and X-ray diffraction (XRD). The membranes were characterized by micro-Raman spectroscopy, water uptake and hydration number (λ), IEC, and proton conductivity measurements. To assess membrane stability, exsitu chemical oxidative degradation tests were conducted using Fenton’s reagent. Overall, the membrane containing 1.0 wt.% syn-scavenger emerged as the most promising candidate, exhibiting favourable chemical–physical properties and the lowest reductions in IEC and proton conductivity following the degradation test. Full article

This study examined the geopolymerization behavior of granite waste powder and reactive silica powder (GWS), utilizing granite waste powder as a sustainable precursor material, to develop an environmentally friendly substitute for Ordinary Portland cement. To obtain this objective, a total of three different mixes of calcined granite waste with reactive silica (1:1, 3:2, 7:3) were cast to evaluate the aim of this study. Due to low inherent reactivity of granite waste powder, the alkali activation was achieved using a combined solution of alkali activators consisting of 8 mol/L concentration of NaOH and Na₂SiO₃ solution at mass ratio of 1:1.2 prepared 24 h in advance to ensure complete dissolution and stabilization prior to pouring it into the GWS paste. The finest particle size distribution for optimal reactivity performance was achieved by choosing lowest median particles size from 4.0 μm–4.2 μm among all mixtures. ICP-MS analysis of granite waste and reactive silica showed the presence of silica (0.11% and 0.26% respectively) and calcium (49.61% and 38.92% respectively) content adequate for effective geopolymerization of the paste. The elemental composition, new phase formation and microstructural analysis were examined using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR) techniques and Scanning Electron Microscopy (SEM) analysis. XRD analysis revealed that all GWS mixes were predominantly amorphous, with crystalline quartz, feldspar and minor α-cristobalite peaks diminishing from GWS50 to GWS70 confirming increased reactivity due to enormous reactive silica content. FTIR spectra of GWS mixes displayed characteristics of O-H (3375 cm⁻¹), H-O-H (1645 cm⁻¹), and Si-O-T (982–1000 cm⁻¹) bands, with the main Si-O-T peak shifting to higher wavenumbers from GWS50 to GWS70 due to increased GW content, indicating reduced geopolymerization effect in GWS50. SEM analysis revealed that among all mixes, GWS70 exhibited the most ideal dense matrix with increasing content of granite waste along with strong N-A-S-H gel formation. Compressive strength at 28 days increased from 11.2 MPa for GWS50 to 14.2 MPa for GWS60 and 13.8 MPa for GWS70, demonstrating that higher reactive silica powder content significantly enhanced the mechanical performance of the alkali-activated paste. These findings demonstrated that alkali-activated geopolymers of GSW offer a viable alternative to Ordinary Portland cement with optimized mixes by valorizing industrial waste and reducing reliance on high-carbon cement production. Full article

Medium-entropy alloys (MEAs) with a simple phase structure and nanoprecipitates have excellent mechanical properties and considerable potential for advanced structural applications. The current study investigated the effect of boron microalloying and thermomechanical treatment on the microstructure evolution and mechanical properties of Co₄₃Cr₁₅Ni₃₀Al₅Ti₇ and (Co₄₃Cr₁₅Ni₃₀Al₅Ti₇)_99.7B_0.3 MEAs. X-ray diffraction analysis revealed a single phase of face-centered cubic (FCC) structure in all as-cast samples. After cold rolling and recrystallization annealing were completed, a clear ordered FCC (L1₂) phase was observed concurrently with the FCC matrix. In the alloy doped with 0.3 at.% B, the grain size was refined from 600 to 200 nm. TEM analysis revealed a nano-sized L1₂ phase coherently embedded in the FCC matrix. Analysis of the mechanical properties of boron-doped MEA samples revealed that cold rolling to 80% thickness followed by annealing at 900 °C for 2 h and aging at 750 °C for 4 h yielded the best mechanical performance. Among all samples, the alloy doped with 0.3 at.% boron achieved an optimal combination of mechanical properties (yield strength: 1817 MPa; ultimate tensile strength: 2313 MPa; ductility: 14.5%). Full article

Despite the promising exploration potential of the tight bioclastic limestone in the Carboniferous Shiqiantan Formation (Shiqiantan Sag, Junggar Basin), its reservoir characteristics remain poorly constrained. In particular, the macro and microscopic features and the key factors controlling reservoir development are still not well understood. We combined core observation, cast thin-section analysis, scanning electron microscopy (SEM), X-ray diffraction (XRD), high-pressure mercury intrusion, nitrogen adsorption, and nuclear magnetic resonance (NMR) to systematically characterize the Carboniferous bioclastic limestone reservoirs and identify the factors controlling their development in the Shiqiantan Sag. This study develops a multi-scale quantitative framework that integrates mercury intrusion–withdrawal behavior, nitrogen adsorption, and NMR T₂ spectra to constrain pore connectivity and the contribution of microfractures in tight carbonate reservoirs, providing a transferable approach for reservoir evaluation beyond the study area. The results categorize three rock microfacies in the study area: Bioclastic micrite, Micritic bioclastic limestone, and Sparry Bioclastic Limestone. The reservoir space is predominantly composed of secondary pores, including intragranular dissolution pores, intercrystalline clay pores, and microfractures. The pore structures exhibit a marked contrast across the lithofacies: the sparry bioclastic limestone develops the most optimal pore-fracture composite system, The pore structures exhibit a marked contrast across the lithofacies, directly correlating with hydrocarbon accumulation. Specifically, the sparry bioclastic limestone develops a pore-fracture composite system characterized by 25–100 nm pore throats, corresponding to the primary oil-bearing intervals observed in drilling. In contrast, the bioclastic micrite limestone and micritic bioclastic limestone, despite exhibiting localized nanoscale pores, lack effective connectivity (pore throats < 25 nm) and predominantly act as tight, dry layers with poor or no oil and gas shows, which endow them with the anomalous characteristic of relatively low porosity yet high permeability. This study reveals an integrated control on the development of tight bioclastic limestone reservoirs, in which sedimentary microenvironment and paleogeomorphology jointly determine the initial reservoir framework, while subsequent structural fractures and associated diagenetic dissolution play a critical role in modifying pore structures and enhancing reservoir quality. Sedimentary microfacies distribution, controlled by paleogeomorphologic variations, dictated the initial reservoir fabric. Subsequently, fracture systems generated by tectonic uplift, coupled with dissolution from meteoric freshwater leaching and organic acids, facilitated the development of secondary pores. Ultimately, the resulting optimization of the pore structure governs the final reservoir quality. The sparry bioclastic limestone is identified as the most promising exploration target in the study area. Its favorable reservoir quality is mainly attributed to its development on palaeogeomorphic and structural highs, where enhanced hydrodynamic energy and subsequent fracture-related dissolution significantly improved pore connectivity. These high-quality reservoirs are widely developed on gentle slope profiles and similar high-quality reservoirs may also locally occur at isolated palaeogeomorphic highs within steep-slope settings, as demonstrated by individual wells. Full article

The increasing demand for bricks has raised environmental concerns related to natural clay depletion, land degradation, and agricultural waste disposal. To address these challenges, this study utilizes rice husk ash (RHA) as a sustainable partial replacement for clay in fired clay bricks. Brick mixtures were casted with varying RHA dosages (up to 80%), and the effect of 2% lime addition was also examined. Mixtures were fired at 1000 °C and 1200 °C and were tested for compressive strength, flexural strength, and water absorption. Microstructural and mineralogical characteristics were investigated using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). At 1000 °C, increasing RHA content and lime addition increased porosity and reduced mechanical strength due to limited vitrification. In contrast, firing at 1200 °C promoted extensive verification and densification, resulting in improved strengths surpassing the severe-weathering requirements of ASTM C62. Compressive strengths of 74.62 MPa and 52.55 MPa were achieved for bricks containing 20% and 40% RHA, respectively, exceeding ASTM C62 severe weather grade requirements. Results demonstrate that RHA can be utilized at high replacement levels when appropriate firing conditions are applied, supporting sustainable fired brick production and agricultural waste valorization. Full article

Developing safe and effective hemostatic materials is critical for rapid bleeding control and wound management. However, traditional hemostatic materials using chemical crosslinking often fall short in hemostatic efficiency and carry risks of secondary injury from reagent residues. This study introduced an irradiation-fabricated composite collagen sponge based on fish skin collagen, chitosan, and soluble starch. The sponge was prepared via material solution blending, followed by cobalt-60 gamma irradiation at various doses, with casting and freeze-drying. Its functionality and safety were systematically evaluated. The results show that low-dose gamma irradiation (1–3 kGy) applied to a precursor solution prior to freeze-drying promoted intermolecular crosslinking, improving mechanical strength, elongation, and biostability, while higher doses (6 kGy) slightly reduced crosslinking due to the partial degradation of collagen, chitosan, and starch. With low-dose irradiation, the proposed hemostatic sponges show enhanced water absorption, blood cell adsorption, swelling, and antibacterial properties, indicating effective hemostatic performance. Spectroscopic characterization confirmed chemical bond modifications with no loss of crystallinity. Cytotoxicity and in vivo tests demonstrated biocompatibility and effective hemostatic performance. Compared with the commercial HSD sponge, the irradiated sponges exhibited superior hemostatic efficacy. This study presents that a collagen-based synergistic matrix prepared by gamma-ray irradiation can produce a hemostatic sponge with enhanced absorbency, bioactivity, and antibacterial properties, highlighting its great potential in rapid hemostasis and wound care applications. Full article

Scandium (Sc), when added together with magnesium (Mg), forms a highly effective synergistic pair in aluminum (Al) alloys, enhancing their performance in various applications. While the thermomechanical processing and heat treatment of such Al-Mg-Sc alloys have been well investigated, the behavior and features of their as-cast state remain less understood. In particular, the evolution of cellular/dendritic microstructures and the formation of phases at submicrometric and nanometric scales, especially those developing during solid-state cooling, require further elucidation. The present study employs a combination of conventional and advanced characterization techniques in the Al-5 wt.%Mg-0.4 wt.% Sc alloy, including CALPHAD, optical microscopy, scanning electron microscopy (SEM), transmission and scanning transmission electron microscopy (TEM/STEM) with energy-dispersive spectroscopy (EDS), x-ray diffractometry (XRD), tensile testing, and fractographic analysis. Al-rich dendrites surrounded by Al₃Sc, AlFe, and β-Al₃Mg₂ phases and the formation of primary submicrometric clusters containing AlFe and Al₃Sc have been identified, revealing important microstructural features that depend strongly on the solidification conditions. Moreover, nanometric Al₃Sc precipitates mainly in the form of rod-like structures with sizes in the order of 50–200 nm have been observed within the α-Al matrix during solid-state cooling stage. At higher solidification rates, such as 15.3 °C/s, these precipitates remain predominantly in solid solution, indicating strong solidification rate dependence in the precipitation behavior. Comparisons between alloys containing 0.1 Sc and 0.4 Sc have demonstrated that the morphology, size, and distribution of Sc-rich phases significantly affect the stress–strain tensile response and underlying strengthening mechanisms. Distinct Portevin–Le Chatelier (PLC) effects have been observed, corresponding to very different serration activities in the stress–strain curves comparing both Al-5%Mg-0.4%Sc and Al-5%Mg-0.1%Sc alloy samples. Among the compositions and conditions studied, the Al–5Mg–0.4Sc alloy samples solidified under the fast-cooling condition (11.2 °C/s) exhibited the most improved mechanical performance, attaining a strength of 306 MPa and an elongation of 22.6%, underscoring the pivotal role of Sc content and solidification rate in achieving optimized mechanical properties. Full article

Accurate extraction of the centroid axes of beams with variable cross-sections is critical for infrastructure health monitoring. While 3D laser scanning provides dense point clouds, existing methods face challenges due to fixed slicing directions, sparse or incomplete boundaries, and inaccurate centroid calculations for concave sections. This study proposes a robust framework to overcome these issues. An improved k-d tree ordering algorithm enhances boundary extraction through starting point constraint strategy and dynamic isolated noise point removal mechanism. A ray casting-based boundary-constrained Delaunay triangulation centroid calculation algorithm accurately computes centroids for arbitrary shapes, including concave profiles. An innovative convex hull centroid-driven adaptive normal iterative slicing method dynamically adjusts orientation using historical centroid data, aligning with the local member axis to minimize errors in variable or deformed regions. Experimental validation shows the method outperforms traditional fixed-direction slicing in effectiveness, parameter sensitivity, and deformation robustness, achieving sub-millimeter accuracy. Applied to monitor ultra-high-performance concrete cantilever beams at the Shanghai Grand Opera House, it produced centroid axis data consistent with total station measurements (differences within ±1.2 mm), supporting phased deformation warnings and safety assessments. This work provides a systematic, high-precision solution for extracting geometric axes from complex structural point clouds. Full article

Road defect detection is essential for traffic safety and infrastructure maintenance. Excising automated methods based on 2D image analysis lack spatial context and cannot provide accurate 3D localization required for maintenance planning. We propose a novel framework for road defect mapping from monocular video sequences by integrating differentiable Bird’s-Eye-View (BEV) mesh representation, semantic filtering, and multi-frame temporal fusion. Our differentiable mesh-based BEV representation enables efficient scene reconstruction from sparse observations through MLP-based optimization. The semantic filtering strategy leverages road surface segmentation to eliminate off-road false positives, reducing detection errors by 33.7%. Multi-frame fusion with ray-casting projection and exponential moving average update accumulates defect observations across frames while maintaining 3D geometric consistency. Experimental results demonstrate that our framework produces geometrically consistent BEV defect maps with superior accuracy compared to single-frame 2D methods, effectively handling occlusions, motion blur, and varying illumination conditions. Full article

In high-density urban environments, residential design often faces a conflict between maximizing landscape access and maintaining energy-oriented compactness. This study proposes a target-based visibility analysis framework to optimize high-rise forms under strict performance constraints. Utilizing a Quad-mesh reconstruction strategy and Inverse Targeted Ray-Casting, the method accurately quantifies visibility via the cumulative Landscape Visible Surface (LVS) on the target building and Viewpoint-Specific Surface Visibility Rate (R_v) for precise verification against specific landscape targets. The framework is applied to evaluate three morphological prototypes: Compact Tower, Dispersed Tower, and Slab–Tower Hybrid. Quantitative simulations identified the Slab–Tower Hybrid as the optimal solution, demonstrating superior “Visual Morphological Efficiency.” While maintaining a moderate Shape Coefficient (SC = 0.326) to satisfy energy standards, the Hybrid achieved a cumulative Park-View LVS approximately 1.8 times that of the Compact Tower. Furthermore, environmental simulations indicated the Hybrid fosters stable wind environments (0.4–0.7 m/s) and equitable sunlight distribution. The research concluded that through differentiated massing, high-rise architecture can achieve a synergistic balance between visual openness and physical compactness, transforming view analysis from a passive check into an active design driver. Full article

Accurate relative pose estimation between unmanned aerial vehicles (UAVs) is a key requirement for cooperative navigation, formation control, and swarm operation in GNSS-denied environments. In multi-UAV systems, monocular vision is attractive due to its low weight and power requirements; however, bearing-only measurements can lead to angular ambiguities, particularly under symmetric or planar target motion. This paper presents a geometric framework for monocular relative pose estimation using observed known motion patterns, rather than relying on complex distributed system architectures. The method exploits trajectory-induced geometric constraints by back-projecting the observed image-plane trajectory of a target UAV into three-dimensional space and tracing rays from the camera center toward a geometrically parameterized reference trajectory. Relative pose parameters are refined through nonlinear optimization using Levenberg–Marquardt, enabling accurate estimation under noisy conditions. Beyond the estimation framework, the influence of cooperative trajectory geometry on angular observability is investigated through simulation experiments. The results indicate that planar collaborative motion may induce angular ambiguity despite numerical convergence, whereas introducing modest out-of-plane excitation through three-dimensional trajectories significantly improves observability. In addition to simulation-based evaluation, a limited real-world flight experiment is conducted to qualitatively validate the observed ambiguity patterns under practical sensing conditions. In particular, three-dimensional eight-shaped trajectories are shown to significantly suppress large angular outliers and improve estimation robustness without increasing computational complexity, providing validated guidance for active trajectory design to ensure observability in vision-based aerial scenarios. Full article

This study aims to develop an electrochemical sensor based on a glassy carbon electrode (GCE) modified with Fe₃O₄ and graphene for the detection of myristicin as a characteristic compound in nutmeg plants. Electrode modification materials were prepared from a combination of graphene and magnetite, synthesized via a hydrothermal method, and further characterized using X-ray diffraction (XRD), scanning electron microscope–energy dispersive spectroscopy (SEM-EDS), and transmission electron microscopy (TEM). The two modifying materials were then optimized, and the optimum conditions were obtained at a w/w ratio of 1:2, which was applied to the GCE surface using the drop-casting technique. The electrochemical performance of the Fe₃O₄/graphene-modified electrode was evaluated under optimum experimental conditions using a Britton–Robinson buffer solution at pH 5. The scan-rate analysis of the electrode to evaluate its electrochemical performance showed an increase in surface area from 0.101 cm² for the bare GCE to 0.534 cm² for the GCE/Fe₃O₄–graphene. Electroanalytical performance was evaluated using differential pulse voltammetry (DPV), which showed a linear response over the concentration range of 1–100 µM, with a limit of detection of 0.19 µM and a limit of quantitation of 0.58 µM. The developed electrode was applied successfully to detect myristicin in nutmeg seed extract samples, and its calculated concentrations were not significantly different from those obtained with the GC-MS method. These results suggest that the developed sensor may have further potential as an alternative detection tool for characterizing electroactive compounds in nutmeg plants. Full article

Cerebral palsy (CP) is a developmental disability caused by injury to the fetal or infant brain, affecting between 1.6 to 3.7 per 1000 live births worldwide. Ambulatory patients with cerebral palsy experience various gait problems, for which they seek treatment from medical professionals. Varus foot deformities are among the most problematic for patients. Varus foot deformity is characterized by the inner border of the foot being tilted upward and the hindfoot inward, increasing weightbearing on the lateral aspect of the foot. This positioning increases weight-bearing pressure under the lateral (outside) of the foot and often under the fifth metatarsal head when walking. As such, varus foot deformity can contribute to in-toeing, make shoe and brace-wearing difficult and painful, compromise gait stability, and sometimes lead to metatarsal fractures. Current knowledge of CP etiology and classifications, as well as principles and advances in assessment and treatment decision making for varus foot deformities, are outlined in this narrative review. In younger children with flexible deformities, non-operative interventions such as bracing, botulinum toxin injection, and serial casting are effective. The literature and expert consensus suggest that, if possible, surgery should be delayed until after the age of 8 years. When surgery is indicated, soft tissue procedures are used for flexible deformities. In addition to the soft tissue procedures, bone surgery is needed for rigid deformities. Careful pre-operative foot assessment is needed, including assessment of deformity flexibility and range of motion, X-rays, and computerized gait analysis if possible. Strategies are presented for thorough assessment when gait analysis is not available or feasible. Research reports of surgical outcomes for soft tissue and bony correction are positive, but should be interpreted with caution. The quality of evidence on surgical outcomes is compromised by use of varying research design methods and selection of outcome measures, with few including measures of function or patient-reported outcomes. It is recommended that surgical outcome be assessed using standardized assessment tools, such as the Foot Posture Index, which have had their validity and reliability established. Recent advances in 3D kinematic foot model development and musculoskeletal modeling have the potential to greatly improve surgical outcomes for patients with CP. Full article

A novel membrane was synthesized in this work by grafting 1-vinyl-3-ethylimidazolium tetrafluoroborate ([C₂VIm][BF₄]) onto a polyvinylidene fluoride (PVDF) backbone, followed by the introduction of a sulfonated graphene oxide (SGO) dispersion into the polymer solution. This composite was transformed into a composite proton-conducting membrane via a solution casting process and subsequently underwent protonation. Successful grafting was confirmed using analytical techniques including Fourier Transform Infrared Spectroscopy (FTIR), ¹H Nuclear Magnetic Resonance (NMR) and X-ray Photoelectron Spectroscopy (XPS). Scanning Electron Microscopy with Energy Dispersive X-ray Spectroscopy (SEM-EDS) analysis verified the homogeneous distribution of the SGO filler. Analysis reveals that incorporating SGO as a filler substantially augments the performance of anion exchange membranes. Key enhancements include a tensile strength increase to 37.97 MPa, water uptake of 10.34%, an ion exchange capacity of 1.68 mmol/g, and the through-plane proton conductivity of 15.47 mS/cm. While vanadium permeability rose marginally to 2.02 × 10⁻⁷ cm²/min, it remains drastically lower than that of Nafion 115. The composite proton-conducting membrane also displayed robust chemical stability. The membrane was finally integrated into a vanadium redox flow battery (VRFB) for performance evaluation. At a current density of 100 mA/cm², it exhibits a satisfactory coulombic efficiency (CE) of 97.84%, excellent capacity retention, and superior cycling stability. These results demonstrate that the PVDF-g-IL/SGO-based composite proton-conducting membrane is an ideal candidate material for vanadium flow battery applications. Full article

This paper presents a novel system for estimating 3D athlete pose, boom angle, and rudder angle in Olympic dinghy sailing using onboard 360° video footage. The proposed approach integrates adaptive panorama slicing, keypoint-based rig detection, and geometric ray-casting into an end-to-end pipeline for quantitative performance analysis under real-world on-water conditions. Traditionally, restrictive International Laser Class Association (ILCA) rules have prohibited advanced sensor systems during competition. However, recent rule changes permit a single onboard camera, enabling unobtrusive and rule-compliant measurement solutions. The purpose of this study is to evaluate whether a competition-legal 360° camera combined with computer vision can provide meaningful performance-related measurements in Olympic sailing. The experimental results indicate that computer-vision-based analysis can complement traditional performance assessment and provide access to data previously limited to physical sensors or manual estimation. The system can support teams and coaches in identifying technique-related performance opportunities. Full article