Search Results (496)

This study valorizes onion peel, an agro-industrial by-product rich in phenolic compounds and structural carbohydrates, for the development of cassava starch-based biodegradable films. The films were prepared using the solution casting method; a cassava starch matrix was mixed with a 2.5% glycerol solution and heated to 85 °C for 30 min. A separate solution of onion peel powder (OPP) in distilled water was prepared at 25 °C. The two solutions were then combined and stirred for an additional 2 min before 25 mL of the final mixture was cast to form the films. Onion peel powder (OPP) incorporation produced darker and more opaque films, suitable for packaging light-sensitive foods. Film thickness increased with OPP content (0.138–0.218 mm), while moisture content (19.2–32.6%) and solubility (24.0–25.2%) decreased. Conversely, water vapor permeability (WVP) significantly increased (1.69 × 10⁻⁹–2.77 × 10⁻⁹ g·m⁻¹·s⁻¹·Pa⁻¹; p < 0.0001), reflecting the hydrophilic nature of OPP. Thermal analysis (TGA/DSC) indicated stability up to 245 °C, supporting applications as food coatings. Morphological analysis (SEM) revealed OPP microparticles embedded in the starch matrix, with FTIR and XRD suggesting electrostatic and hydrogen–bond interactions. Mechanically, tensile strength improved (up to 2.71 MPa) while elongation decreased (14.1%), indicating stronger but less flexible films. Biodegradability assays showed slightly reduced degradation (29.0–31.8%) compared with the control (38.4%), likely due to antimicrobial phenolics inhibiting soil microbiota. Overall, OPP and cassava starch represent low-cost, abundant raw materials for the formulation of functional biopolymer films with potential in sustainable food packaging. Full article

The building sector is under increasing pressure to lower its environmental impact, prompting renewed interest in raw soil as a low-carbon and locally available material. This study investigates the mechanical and thermal properties of clay-based masonry walls through a comprehensive experimental program on earthen mortars, bricks, and their interfaces, considering both stabilized and non-stabilized formulations. Compressive, bending, and shear tests reveal that strength is strongly influenced by mortar composition, hydration time, and the soil-to-sand ratio. The addition of 5–7.5% cement yields modest gains in compressive strength but increases the carbon footprint, whereas extended pre-hydration achieves similar improvements with lower environmental costs. Thermal characterization of the studied samples (SiO₂ ≈ 61.2 wt%, Al₂O₃ ≈ 11.7 wt%, MgO ≈ 5.1 wt%) revealed that SiO₂-enriched compositions significantly enhance thermal conductivity, whereas the presence of Al₂O₃ and MgO contributes to increased heat capacity and improved moisture regulation. These findings suggest that well-optimized clay-based mortars can satisfy the structural and thermal requirements of non-load-bearing applications, offering a practical and sustainable alternative to conventional construction materials. By reducing embodied carbon, enhancing hygrothermal comfort, and relying on locally available resources, such mortars contribute to the advancement of green building practices and the transition towards low-carbon construction. Full article

Annually, about 2.4 million tons of superabsorbent polymers (SAPs) used in disposable diapers are thrown away, polluting our planet. This study aims to explore the potential for reusing SAPs removed from diapers to enhance soil water retention. To this end, the swelling and water retention properties of SAP gels from three different types of diapers were compared to those of an agricultural gel, Aquasorb. Sand was used as a model for soil. When mixed with sand, diaper gels have a swelling degree of ca. 100 g per gram of dried polymer, and a swelling pressure of 12–26 kPa, which are similar to those of Aquasorb gel. Using a synthesized poly(acrylamide-co-sodium acrylate) gel as an example, the correlation between the swelling pressure and the compression modulus of the swollen gel was demonstrated. Soil-hydrological constants were estimated from water retention curves obtained by equilibrium centrifugation of gel/sand mixtures. It was observed that adding 0.3 vol% of diaper gels to sand leads to a 3–4-fold increase in water range available to plants, which is close to that provided by agricultural gel Aquasorb. The water-holding properties were shown to be maintained during several swelling/deswelling cycles in the sand medium. The addition of diaper gels to soil had a significant positive impact on mustard (Brassica juncea L.) seed germination and seedling growth, similar to the agricultural gel Aquasorb. This suggests high potential for the reuse of SAPs from diaper waste to improve soil water retention and water accessibility to plants. This would provide both economic and environmental benefits, conserving energy and raw materials to produce new agricultural gels and limiting the amount of waste. Full article

This study systematically explores the mechanisms and application potential of biochar in remediating heavy metal-contaminated soils. Particular emphasis is placed on the role of raw materials and pyrolysis conditions in modulating key physicochemical properties of biochar, including its aromatic structure, porosity, cation exchange capacity, and ash content, which collectively enhance heavy metal immobilization. The direct remediation mechanisms are categorized into six pathways: physical adsorption, electrostatic interactions, precipitation, ion exchange, organic functional group complexation, and redox reactions, with particular emphasis on the reduction in toxic Cr⁶⁺ and the oxidation of mobile As³⁺. In addition to direct interactions, biochar indirectly facilitates remediation by enhancing soil carbon sequestration, improving soil physicochemical characteristics, stimulating microbial activity, and promoting plant growth, thereby generating synergistic effects. The study evaluates combined remediation strategies integrating biochar with phytoremediation and microbial remediation, highlighting their enhanced efficiency. Moreover, practical challenges related to the long-term stability, ecological risks, and economic feasibility in field applications are critically analyzed. By synthesizing recent theoretical advancements and practical findings, this research provides a scientific foundation for optimizing biochar-based soil remediation technologies. Full article

In the circular economy framework, municipal wastes are seen as secondary raw materials that can be used to fertilize agricultural soils. This study assessed the effect of different biowaste and green waste treatment schemes on P fertilizer value to learn about the optimal valorization of these feedstocks. The wastes were used either fresh, after composting or anaerobic digestion, or as biochars produced at various pyrolysis conditions. The fertilizer value was determined from the change in soil concentration of plant-available P (P_CAL) in incubation experiments with different soils and the temporal dynamics of fertilizer-induced growth and P accumulation of ryegrass in a pot experiment with eight harvests. The mode of waste treatment significantly influenced the P fertilizer value in the incubation and in the pot experiment. In the incubation experiment, the amendment-induced P_CAL increase varied between 22% and 33% of applied P on low-P acidic soil and between 55% and 88% of applied P on high-P acidic soil, whereby the amendment effects were mainly determined by their effects on soil pH. In the pot experiment with low-P acidic soil, the apparent P recovery in the plant biomass (APR) varied between 2% of applied P for fresh green waste and 42% for fluid digestate. The amendment effects on APR were not related to soil pH but to the P_CAL supply with the amendments and amendment effects on soil P supply. Our data show great potential for increasing the P fertilizer value of organic municipal waste materials through appropriate processing prior to application. Full article

Dioscorea nipponica is an important medicinal and edible plant in northern China, and its extract dioscin is an important raw material for the modern pharmaceutical industry. To investigate the key environmental factors influencing diosgenin accumulation in the rhizomes of D. nipponica and their action mechanism, we collected wild D. nipponica plants from 60 plots on Zhongtiao Mountain and analyzed the effects of environmental conditions on both plant growth and diosgenin synthesis. Additionally, physiological parameters of D. nipponica were investigated under different intervals of watering treatments: control (CK, 3 days), mild drought (MID, 5 days), moderate drought (MD, 8 days) and severe drought (SD, 10 days). The results showed that the water content of rhizome was the main factor affecting the diosgenin content, and soil nutrients, especially nitrogen, played an important role in the growth of D. nipponica. The results of a drought stress gradient test showed that diosgenin increased significantly under mild drought compared to the control, reaching 103.19 ± 2.63%. SD inhibited the growth of plants, and the indexes decreased by 10.08 ± 0.03–34.94 ± 5.60% compared with MID but increased the proliferation rate of rhizomes (83.33%), which is the reproductive strategy of D. nipponica when faced with drought stress. It provides a scientific basis for imitation of wild cultivation of D. nipponica. Full article

Chlorinated aliphatic hydrocarbons (CAHs) are some of the most widely distributed organic pollutants in underground environments and have high biological toxicity. This research aims to prepare an effective adsorbent comprising biochar and magnetite (MBC) to remove CAH pollution from soil. Optimization of the preparation and adsorption performance of MBC was investigated. The results of the adsorption experiment, combined with scanning electron microscopy (SEM) observations, show that the best raw material and pyrolysis temperature were coconut shell and 500 °C respectively. The Fourier transform infrared (FTIR) and X-ray diffraction (XRD) pattern characterizations, as well as the adsorption results, demonstrated the successful synthesis and enhancement effect of MBC for CAHs. The adsorption of CAHs on Fe₃O₄-loaded biochar was improved by 34.40–222.25% during pyrolysis at 500–900 °C. Additionally, MBC with a 10% Fe₃O₄ content had the best effect on three types of CAHs at low concentrations. A comparative pore analysis of MBC with different doses of Fe₃O₄ was carried out to reveal the relationship between the pore characteristics and adsorption properties. Furthermore, competitive adsorption experiments demonstrated that 4 wt% MBC addition significantly reduced the soil-bound TCE by 48.6%. Overall, these results indicated that MBC was an effective adsorbent for CAH removal from the polluted underground environment. Full article

This study’s objectives were to evaluate the life cycle of a 2 MW solar power plant in northern Poland and provide suggestions for enhancing this kind of installation’s environmental performance. Eight years of operating data were examined under the assumption that 2000 MWh of energy was produced annually on average. The evaluation took into account two waste management scenarios—landfill and recycling—and was carried out in accordance with the ReCiPe 2016 methodology. Human health and water resource usage had the most environmental effects (7.08 × 10⁵ Pt—landfill), but recycling greatly reduced these effects (−3.08 × 10⁵ Pt). Terrestrial ecosystems were negatively impacted by the turbines’ water consumption (8.94 × 10⁵ Pt—landfill), which was lessened in the recycling scenario. The water and soil environment was greatly impacted by released pollutants, such as zinc and chlorinated hydrocarbons, whose emissions were greatly decreased by material recovery. Particularly detrimental was sulfur dioxide (SO₂), which is the cause of PM 2.5 particle matter, which is dangerous to the public’s health. Recycling has helped to lower these pollutants and enhance the quality of the air. Reducing methane and other greenhouse gas emissions can help reduce CO₂ emissions, which were the most significant factor in the context of climate change (1.91 × 10⁴ Pt—landfilling). Recycling lessened these impacts and decreased the need to acquire virgin raw materials, but landfilling was linked to soil acidification and the depletion of mineral resources. According to the findings, even “green” technology, like photovoltaics, can have detrimental effects on the environment if they are not properly handled at the end of their useful lives. Recycling is turning out to be a crucial instrument for lowering negative effects on the environment, increasing resource efficiency, and safeguarding public health. Full article

Hemp (Cannabis sativa L.) is a high-yielding crop cultivated for fiber and seed production, generating substantial lignocellulosic residues such as hurds. These byproducts can be valorized through pyro-gasification, a thermochemical process that offers a sustainable alternative to combustion and produces biochar—a promising soil amendment due to its ability to enhance soil quality and mitigate drought stress. This research explores the viability of utilizing industrial hemp hurds as a direct feedstock for biochar production within the context of agricultural exploitation. The study specifically focuses on assessing the feasibility of converting raw, unprocessed hemp hurds into biochar through pyrolysis. A comprehensive characterization of the resulting biochar is conducted to evaluate its properties and potential applications in agriculture, establishing a foundational understanding for future agronomic use. Specific analysis included proximate and ultimate analysis, thermogravimetric analysis (TGA), SEM-EDS, and phytotoxicity testing. The biochar exhibited an alkaline pH (≥9), a low H/C ratio (0.37), and suitable macro- and micronutrient levels. Microstructural analysis revealed a porous architecture favorable for nutrient retention and water absorption. Germination tests with corn (Zea mays L.) showed a germination index above 90% for substrates containing 0.5–1% biochar. These findings establish a foundation for future research aimed at thoroughly exploring the agricultural potential of this material. Full article

Coal gangue, a primary solid waste by-product of coal mining and processing, constitutes approximately 10–15% of total coal output. Its accumulation poses substantial environmental challenges, including land occupation, spontaneous combustion, acid mine drainage, and heavy metal leaching. Despite its high silica and alumina content (typically exceeding 70% combined), the highly stable and crystalline structure of raw coal gangue limits its pozzolanic activity and adsorption efficiency. To address this limitation, this review emphasizes recent advances in activation strategies such as thermal (500–900 °C), mechanical (dry/wet grinding to less than 200 µm), chemical (acid/alkali treatments), microwave, and hybrid methods. The activated coal gangue resulted in an enhanced surface area (up to 55 m²/g), amorphization of kaolinite to metakaolinite, and the generation of mesoporosity under optimal conditions. This review critically examined the geotechnical applications, such as soil stabilization and mine backfill, highlighting the replacement of 50–75% of cementitious binder in backfilling and meeting the subgrade/base material strength criteria (UCS > 2 MPa). In geoenvironmental applications (adsorption of phosphate, dyes, heavy metals, and CO₂ mineralization), more than 90% of pollutant removal is attained. In construction applications, supplementary cementitious materials and sintered bricks are examined. Several critical knowledge gaps, including limited understanding of long-term durability, inconsistent activation optimization across different coal gangue sources, and insufficient assessment of environmental impacts during large-scale implementation, are clearly addressed. This review provides a roadmap for advancing sustainable coal gangue utilization and highlights emerging opportunities for cost-effective applications in the mining and construction sectors. Full article

The exponential increase in global solid waste generation poses significant environmental, economic, and social challenges, particularly in rapidly urbanizing regions. Traditional waste management methods that focus on handling and disposal have proven unsustainable because of their negative impacts on air, soil, and water quality, and their contribution to greenhouse gas emissions. In response, the concept of zero-waste cities, rooted in circular economy principles, has gained increasing attention in recent years. This study proposes a comprehensive and integrated waste management system designed to optimize resource recovery across four distinct waste streams: household, healthcare, green/organic, and inert. The system integrates four specialized facilities: a Secondary Sorting Facility, Energy Recovery Facility, Composting Facility, and Inert Processing Facility, coordinated through a central Primary Sorting Hub. By enabling interconnectivity between these processing units, the system facilitates material cascading, maximizes the reuse and recycling of secondary raw materials, and supports energy recovery and circular nutrient flow. The anticipated benefits include enhanced operational efficiency, reduced environmental degradation, and generation of multiple revenue streams. However, the implementation of such a system faces challenges related to high capital investment, technological complexity, regulatory fragmentation, and low public acceptance. Overcoming these limitations will require strategic planning, stakeholder engagement, and adaptive governance. Full article

The urgent demand for environmentally responsible construction practices has intensified interest in geopolymer concrete mixtures, which offer low-carbon alternatives to conventional Portland cement by enabling the valorization of industrial by-products. Since the large volume of waste generated by mining activities represents a significant environmental liability, this research aimed to utilize the alkali activation technique in mixtures of soil and bauxite residue, commonly known as red mud (RM), for application in green construction. All raw materials were characterized based on their physical and chemical properties. To evaluate the influence of waste content on the mechanical behavior of the geopolymers, specimens were prepared with soil contents ranging from 70% to 100% and RM dosages ranging from 0% to 30%. These mixtures underwent compaction tests using the standard Proctor energy method to determine maximum dry density and optimum moisture content. Using the optimal mixture compositions, specimens were prepared for unconfined compressive strength (UCS) tests, with NaOH at a concentration of 6 mol/L added as an activator. The experimental tests provided UCS results ranging from 2.23 MPa to 3.05 MPa. X-ray diffraction (XRD) analyses were performed on raw materials and mixtures containing 70% soil and 30% waste to assess changes in mineralogical compositions due to waste incorporation. The results confirmed the potential of alkali activation for stabilizing mixtures of soil and RM for sustainable construction. Full article

Determining constitutive model parameters from in situ tests offers several advantages, including reduced time, lower cost, and minimal soil disturbance. As part of a research project, an automated framework was developed to derive constitutive model parameters from in situ test results using a graph-based approach. Previous studies primarily focused on validating the framework’s output in terms of soil parameters by comparing them with values interpreted from laboratory tests. This study demonstrates the full capability of the framework, from importing raw in situ measurements and stratifying the soil profile to determining both soil and constitutive model parameters, and ultimately linking the results to numerical modelling. To assess the accuracy of the obtained material sets, two well-documented boundary value problems are modelled: one involving the long-term settlement behaviour of an embankment and the other addressing the failure load of shallow footings. The parameter determination framework proves particularly valuable in the early stages of geotechnical projects, offering enhanced insight and detailed soil characterisation when data is limited. Ongoing research aims to extend the framework by incorporating additional in situ tests and implementing statistical tools to better capture uncertainty and support informed decision-making. Full article

Soil warming due to climate change has a significant potential impact on crop yield and quality. Schisandra chinensis (Trucz.) Baill, a multipurpose plant disseminated in the highly climate-sensitive region of Northeast Asia, is affected by soil warming, which limits the supply and quality of raw materials. This study investigated the differential responses of biomass accumulation and bioactive ingredient production across various organs to root-zone temperature (RZT) variations, employing both physiological assessments and metabolomic profiling. Elevated root temperatures may increase plant biomass and indirectly increase photosynthetic rates by promoting root growth; however, biomass responses differ among organs. A 20 °C root temperature promoted stem and leaf growth and inhibited root development, whereas a 30 °C root temperature significantly promoted root growth but reduced leaf biomass. Schisanhenol A, a key bioactive lignan serving as a quality marker for S. chinensis, displayed synthesis dependent on temperature. Concurrently, flavonoid biosynthesis is coordinated accumulation at the naringenin nodal point. A 15 °C RZT inhibited lignan production in roots while triggering stress-responsive phenol accumulation in leaves (41.39%). Conversely, at 20 °C and 30 °C RZTs, schisanhenol synthesis was repressed in leaves but accumulated in roots (9.8–25.71%). It is worth noting that the increase in RZT significantly promoted the synthesis and accumulation of schisandrol A in the aboveground part of the plant (43.88%). This research underscores that a suitable elevation in root-zone temperature can augment the medicinal attributes of the aerial components of S. chinensis. Full article

Hemp stalk, a widely available agricultural waste, is an ideal eco-friendly raw material for biochar production. Carbonization experiments were conducted as a novel approach for the scalable and value-added utilization of hemp stalk under oxygen-exclusion conditions. The effects of feedstock types—Hibiscus cannabinus (KS), Corchorus spp. (JS), and Boehmeria spp. (RS)—and pyrolysis temperatures on biochar properties were analyzed through the measurements of X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy. The pH and electrical conductivity (EC) of biochars increased with increasing pyrolysis temperature. Notably, EC was significantly higher for RS (940–2278 μS/cm) than for KS (517–879 μS/cm) and JS (583–863 μS/cm). The C content in these three biochars increased as the temperature increased, whereas the H/C atomic ratio decreased, most notably in JS (by 0.33%). According to FTIR and XRD data, with the pyrolysis temperature increasing, the acidic oxygen-containing groups on biochar surfaces reduced. KS700, with superior aromatic structure and stability, may be able to effectively adsorb heavy metal ions. RS700, with relatively high pH and EC, was suitable for alleviating soil acidification and nutrient deficiency. The feedstock and pyrolysis temperature significantly affected the element content, pore structure, and stability of biochars derived from hemp stalk. Full article