Search Results (196)

This study presents a comprehensive analysis of pre- and co-seismic ionospheric disturbances associated with the 2023 Ms6.2 Jishishan earthquake by leveraging the unique observational strengths of BDS, particularly its high-orbit satellites. A multi-parameter space weather index was employed to effectively isolate seismogenic signals from geomagnetic disturbances, confirming that the main shock occurred during geomagnetically quiet conditions. Statistical analysis of 41 historical earthquakes (Mw ≥ 5.5) reveals that 47.2% were associated with detectable Total Electron Content (TEC) anomalies. An inverse correlation between earthquake magnitude and anomaly detectability within a 31-day window suggests prolonged precursor durations for larger events may produce longer-duration precursory signals, which challenge conventional detection methods. The synergistic capabilities of BDS Geostationary Earth Orbit (GEO) and Inclined Geosynchronous Orbit (IGSO) satellites were demonstrated: GEO satellites provide unprecedented temporal stability for continuous TEC monitoring, while IGSO satellites enable high-resolution spatial mapping of Co-seismic Ionospheric Disturbances (CIDs). The detected CIDs propagated at velocities below 1.6 km/s, consistent with acoustic gravity wave (AGW) mechanisms. A case study during a geomagnetically active period further reveals modulated CID propagation characteristics, indicating potential coupling between seismic forcing and space weather. Our findings validate BDS as a powerful and precise tool for ionospheric seismology and provide critical insights into Lithosphere–Atmosphere–Ionosphere Coupling (LAIC) dynamics. Full article

A series of multi-parameter, multi-layer observations was conducted to study possible electromagnetic precursors associated with the M 6.7 earthquake that struck Iburi, Hokkaido, Japan, at 18:07:59 UT on 5 September 2018. The most significant observation is seismogenic lower-ionospheric perturbations in the propagation anomalies of sub-ionospheric VLF/LF signals recorded in Japan and Russia. Other substantial observations include the GIM-TEC irregularities, the intensification of stratospheric atmospheric gravity waves (AGWs), and the satellite and ground monitoring of air temperature (T), relative humidity (RH), atmospheric chemical potential (ACP), and surface latent heat flux (SLHF). We have found that there were very remarkable VLF/LF anomalies indicative of lower-ionospheric perturbations observed on 4 and 5 September just before the EQ date and even after it from the observations in Japan and Russia. In particular, the anomaly was detected for a particular propagation path from the JJY transmitter (Fukushima) to a VLF station at Wakkanai one day before the EQ, i.e., on 4 September, and is objectively confirmed by machine/deep learning analysis. An anomaly in TEC occurred only on 5 September, but it is unclear whether it is related to a pre-EQ effect or a minor geomagnetic storm. We attempted to determine whether any seismo-related atmospheric gravity wave (AGW) activity occurred in the stratosphere. Although numerous anomalies were detected, they are most likely associated with convective weather phenomena, including a typhoon. Finally, the Earth’s surface parameters based on satellite monitoring seem to indicate some anomalies from 29 August to 3, 4, and 5 September, a few days prior to EQ data, but the ground-based observation close to the EQ epicenter has indicated a clear T/RH and ACP on 2 September with fair weather, but no significant data on subsequent days because of severe meteorological activities. By integrating multi-layer observations, the LAIC (lithosphere–atmosphere–ionosphere coupling) process for the Hokkaido earthquake appears to follow a slow diffusion-type channel, where ionospheric perturbations arise a few days after ground thermal anomalies. This study also provides integrated evidence linking concurrent lower-ionospheric, atmospheric, and surface thermal anomalies, emphasizing the diagnostic value of such multi-parameter observations in understanding EQ-associated precursor signatures. Full article

It has recently been recognized that the ionosphere is highly sensitive to pre-seismic effects, and the detection of ionospheric perturbations associated with earthquakes (EQs) is one of the most promising candidates for short-term EQ prediction. In this review, we focus on a possible use of VLF/LF (very low frequency (3–30 kHz)/low frequency (30–300 kHz)) radio sounding of seismo-ionospheric perturbations to study seismogenic effects. Because an understanding of the early history in any area will provide a lot of crucial insights to the readers (especially to young scientists) working in the field of seismo-electromagnetics, we provide a brief history (mainly results reported by a Russian group of scientists) of the initial application of subionospheric VLF/LF propagation for the study of ionospheric perturbations associated with EQs, and then we present our first convincing evidence on the ionospheric perturbation for the disastrous Kobe EQ in 1995, with a new analysis method based on the shifts in terminator times in VLF/LF diurnal variations (minima in the diurnal variations in amplitude and phase). We then summarize our latest results on further evidence of seismo-ionospheric perturbations. Firstly, we present a few statistical studies on the correlation between VLF/LF propagation anomalies and EQs based on long-term data. Secondly, we showcase studies for a few large, recent EQs (including the 2011 Tohoku EQ). Building on those EQ precursor studies, we demonstrate scientific topics and the underlying physics that can be studied using VLF/LF data, highlighting recent achievements including the revolutionary perspective of lithosphere–atmosphere–ionosphere coupling (LAIC) (or how the ionosphere is perturbed due to the lithospheric pre-EQ activity), modulation in VLF/LF data by atmospheric gravity waves (AGWs), Doppler-shift observation, satellite observation of VLF/LF transmitter signals, etc., together with the recommendation of the application of new technologies such as artificial intelligence and critical analysis to VLF/LF analysis. Finally, we want to emphasize again the essential significance of the information on lower-ionospheric perturbations within LAIC studies. Full article

In the previous research that aimed to enhance the toughness and tribological properties of silicon nitride ceramics, a lignin precursor was added to the ceramic matrix, which achieved conversion through pyrolysis and sintering, resulting in a silicon nitride-based composite ceramic containing nitrogen-doped graphene quantum dots (N-GQDs). This composite material demonstrated excellent comprehensive mechanical properties and friction-wear performance. Based on the existing experimental results, the first-principles plane wave mode conservation pseudopotential method of density functional theory was adopted in this study to build a microscopic heterostructure model of Si₃N₄-based composite ceramics containing N-GQDs. Meanwhile, the surface energy of Si₃N₄ and the system energy of the N-GQDs@Si₃N₄ heterostructure were calculated. The calculation results showed that when the distance between N-GQDs and Si₃N₄ in the heterostructure was 2.3 Å, the structural energy was the smallest and the structure was the steadiest. This is consistent with the previous experimental results and further validates the coating mechanism of N-GQDs covering the Si₃N₄ column-shaped crystals. Simultaneously, based on the results of the previous experiments, the stress of the heterostructure composed of Si₃N₄ particles coated with different numbers of layers of nitrogen quantum dots was calculated to predict the optimal lignin doping amount. It was found that when the doping amount was between 1% and 2%, the best microstructure and mechanical properties were obtained. This paper provides a new method for studying the graphene quantum dot coating structure. Full article

SiC nanowires (SiC_nw), due to their excellent dielectric properties, are promising high-temperature absorbing materials. However, the mechanism of their high-temperature absorption still requires further research. Therefore, porous SiC_nw/Si₃N₄ and SiC/Si₃N₄ ceramics with different SiC phase morphologies were fabricated using a simple precursor impregnation and pyrolysis method. The Fe impurity content of the Si₃N₄ powder raw material significantly affects the generation of SiC nanowires. When SiC exists in the form of nanowires, the excellent conductivity brought by the conductive network of the nanowires causes a significant response of the material’s permittivity to temperature. When the test temperature is room temperature, SiC_nw/Si₃N₄ has excellent absorption performance with a minimum reflection loss of −29.75 dB at 2.16 mm and an effective absorption bandwidth of 3.72 GHz at 2.54 mm. As the test temperature increases to 300 °C, the effective absorption bandwidth of SiC_nw/Si₃N₄ covers the entire X-band. The porous SiC_nw/Si₃N₄ ceramics exhibit excellent electromagnetic wave absorption performance, demonstrating significant application potential for high-temperature environments. Full article

In this study, two air pollution abatement strategies are examined, focusing on sources and sinks. These include the reduction in ozone precursors (source) and impact of nature-based solutions (sink). For the first abatement strategy (source), two waves of COVID-19 lockdown periods are leveraged as proxies for the potential abatement of air quality pollutants in Toronto, Ontario, Canada, that could occur through electric vehicle deployment. Ground level ozone (O₃) and its precursors (NO, NO₂), were examined from April to December 2020, during the first two pandemic lockdown periods in Toronto. An ozone weekend effect framework was used to evaluate changes. Results showed that ozone precursors were the lowest of any of the preceding 10 years for both weekdays and weekends; however, ozone concentrations did not have a corresponding decrease but rather had a marked increase for both weekdays and weekends. These findings reflect reduced vehicular traffic and the ozone chemistry in an NOx-saturated (VOC-limited) environment. For the second abatement strategy (sink), a comparison of surface NO₂ observations and NO₂ satellite data showed the benefits of nature-based solutions as a sink abatement strategy, with the 2020 reduction amplified at the surface. Given the lack of ozone abatement realized through source reduction, deployment of nature-based solutions as a pollutant sink may present a more effective strategy for ground-level ozone abatement. Full article

Using multiple reanalysis datasets, this study investigates the decadal variability in the relationship between Northeast Pacific Sea surface temperature (SST) and Arctic stratospheric ozone (ASO), with a focus on the role of atmospheric dynamics in mediating this connection. A significant decadal shift is identified around the year 2000, characterized by a weakening of the previously strong negative correlation between January–February SST anomalies and February–March ASO. Prior to 2000 (1980–2000), warm SST in the northeastern Pacific suppressed upward planetary wave propagation, resulting in decreased stratospheric wave activity and a weakened Brewer–Dobson circulation. The weakened BD circulation reduced poleward transport of tropical ozone and heat, yielding a colder, ozone-poor polar vortex. The strong relationship enabled skillful seasonal predictability of ASO using SST precursors in a linear regression model. However, post-2000 (2001–2022), the weakened planetary wave response to SST anomalies resulted in a breakdown of this relationship, yielding non-significant predictive skill. The findings highlight the non-stationary nature of ocean-stratosphere coupling and underscore the importance of accounting for such decadal shifts in climate models to improve projections of Arctic ozone recovery and its surface climate impacts. Full article

This study aimed to evaluate the effect of combined supplementation of MSG with glycerin, a glucogenic precursor, on ovarian function in sheep. Twenty-four ewes had estrus and follicular waves synchronized using three prostaglandin injections at 7-day intervals. The ewes were grouped: baseline TMR diet (Control; n = 8); glutamate diet (MSG; n = 8), receiving MSG (1 g/kg of body weight/day) for 16 days; and MSG plus glycerin (MSGLY; n = 8), which received MSG plus 150 mL of glycerin during the eight days prior to ovulation induction. MSG showed lower dry matter intake, while the MSGLY group showed increased heart and respiratory rates and skin temperature. Rectal temperature was higher in MSG and MSGLY. MSGLY also showed reduced triglyceride and urea levels. MSG and MSGLY exhibited decreased cholesterol and creatinine. MSGLY exhibited a higher number of large follicles and greater intraovarian blood perfusion after ovulation induction and larger corpus luteum perfusion. Ovulation rate increased by 64% in the supplemented groups vs. control. MSG supplementation led to greater SCL1A1, GRIA1, and GLUD1 genes expression. Thus, the combined supplementation of MSG and glycerin effectively enhances ovarian function in sheep, representing a viable nutritional strategy to improve reproductive outcomes. Full article

The precursor-derived ceramic route is recognized as an advanced and efficient technique for fabricating ceramic matrix composites, particularly suitable for the development and microstructural tailoring of continuous fiber-reinforced ceramic matrix composites. In this work, octamethylcyclotetrasiloxane and tetravinylcyclotetrasiloxane were employed as monomers to synthesize a branched siloxane via ring-opening polymerization. A subsequent hydrosilylation reaction led to the formation of polyvinylsiloxane with a three-dimensional crosslinked structure. The precursor exhibited excellent fluidity, adjustable viscosity, and superior thermosetting characteristics, enabling efficient impregnation and densification of reinforcements through the polymer infiltration and pyrolysis process. Upon pyrolysis, the polyvinylsiloxane gradually converted from an organic polymer to an amorphous inorganic ceramic phase, yielding silicon oxycarbide ceramics with a high ceramic yield of 81.3%. Elemental analysis indicated that the resulting ceramic mainly comprised silicon and oxygen, with a low carbon content. Furthermore, the material demonstrated a stable dielectric constant (~2.5) and low dielectric loss (<0.01), which are beneficial for enhanced thermal stability and dielectric performance. These findings offer a promising precursor system and process reference for the low-cost production of high-performance, multifunctional ceramic matrix composites with strong potential for engineering applications. Full article

This study investigates pre-seismic ionospheric anomalies preceding the 2023 Jishishan Ms6.2 earthquake using total electron content (TEC) data derived from BDS geostationary orbit (GEO) satellites. Multi-scale analysis integrating Butterworth filtering and wavelet transforms resolved TEC disturbances into three distinct frequency regimes: (1) high-frequency perturbations (0.56–3.33 mHz) showed localized disturbances (amplitude ≤ 4 TECU, range < 300 km), potentially associated with near-field acoustic waves from crustal stress adjustments; (2) mid-frequency signals (0.28–0.56 mHz) exhibited anisotropic propagation (>1200 km) with azimuth-dependent N-shaped waveforms, consistent with the characteristics of acoustic–gravity waves (AGWs); and (3) low-frequency components (0.18–0.28 mHz) demonstrated phase reversal and power-law amplitude attenuation, suggesting possible lithosphere–atmosphere–ionosphere (LAI) coupling oscillations. The stark contrast between near-field residuals and far-field weak fluctuations highlighted the dominance of large-scale atmospheric gravity waves over localized acoustic disturbances. Geometry-based velocity inversion revealed incoherent high-frequency dynamics (5–30 min) versus anisotropic mid/low-frequency traveling ionospheric disturbance (TID) propagation (30–90 min) at 175–270 m/s, aligning with theoretical AGW behavior. During concurrent G1-class geomagnetic storm activity, spatial attenuation gradients and velocity anisotropy appear primarily consistent with seismogenic sources, providing insights for precursor discrimination and contributing to understanding multi-scale coupling in seismo-ionospheric systems. Full article

This study employed a hydrothermal method to prepare V-doped MoS₂. The influence of varying filler ratios (30 wt%, 40 wt%, 50 wt%) on its absorption properties was analyzed. For annealing studies, a precursor powder with a 40 wt% filler ratio was heat-treated at 600 °C for 2 h. The results obtained through characterization and testing indicate that the unannealed 40 wt% filler sample demonstrates superior absorption performance, with minimum reflection loss (RL_min) of −32.24 dB, an effective absorption bandwidth (EAB) of 4.40 GHz, and 99.9% electromagnetic (EM) wave attenuation. However, upon subjecting the sample with a 40 wt% filling ratio to annealing treatment, a notable decrease in impedance matching degree was observed, and regions with impedance matching values close to 1 were no longer present. Consequently, it can be concluded that at a filling ratio of 40 wt%, the sample’s excellent attenuation coefficient in conjunction with its good impedance matching collectively contribute to its superior comprehensive absorption performance. Full article

With the continuous advancement of electromagnetic protection technologies, the development of lightweight electromagnetic wave-absorbing materials with excellent absorption performance has become a critical challenge in the field. In this study, commercially available hollow glass microspheres (HGMs) were employed as templates, and Ni²⁺/Co²⁺ metal ions were used to catalyze the polymerization of dopamine (PDA), forming HGM@Ni_xCo_y/PDA precursors. Subsequent high-temperature pyrolysis yielded lightweight composite absorbing materials, denoted as HGM@Ni_xCo_y/C. This material integrates dielectric loss, conductive loss, magnetic loss, and resonance absorption mechanisms, exhibiting outstanding electromagnetic wave absorption properties. The absorption performance can be effectively tuned by adjusting the Ni-to-Co ratio, with the optimal performance observed at an atomic ratio of 2:3. At a filler loading of 20 wt.%, HGM@Ni₂Co₃/C achieved an effective absorption bandwidth (EAB) of 6.83 GHz (ranging from 10.53 to 17.36 GHz) and a minimum reflection loss (RL_min) of −27.26 dB. These results demonstrate that the synergistic combination of hollow glass bubbles and carbon-based magnetic components not only significantly reduces the material density and required filler content but also enhances overall absorption performance, highlighting its great potential in the development of lightweight and high-efficiency electromagnetic wave absorbers. Full article

Thanks to several components with health-promoting properties, mushrooms are recognized as a practical functional food and a valuable source of nutrients for the food industry. Ergosterol, the major sterol in edible mushrooms and a precursor of vitamin D2 with proven pharmacological activity and nutritional value, has become a very important topic in chemical and medical research. The main objectives of this study were to determine the ergosterol content in different species of Serbian wild mushrooms and in commercial mushrooms from Korean and Serbian grocery stores using square-wave voltammetry, to compare the concentrations in different parts of white button mushrooms, and to determine a possible relationship between Zn, Cu and Fe and ergosterol contents. The ergosterol contents varied between 0.01 and 7.04 mg/g (dry mass) of the mushrooms and were generally higher in cultivated mushrooms than in wild mushrooms. In addition, the ergosterol concentration was higher in the stems than in the caps of the mushrooms examined. Iron, Zn and Cu contents varied between the mushroom species at 8.5–479.9, 13.1–149.7 and 1.62–93.03 mg/kg, respectively, and principal component analysis (PCA) extracted two factors explaining 79.14% of the total variance, suggesting a direct relationship between iron and ergosterol content. This is the first comprehensive study to analyze and evaluate ergosterol concentrations in edible mushrooms from Korea and Serbia. Full article

This study presents a straightforward hydrothermal synthesis approach to fabricate uniform and highly dispersed nanoscale Fe₃O₄ electrocatalysts for the oxygen reduction reaction (ORR). FeSO₄·7H₂O is used as the precursor, and sodium dodecyl sulfate (SDS) is incorporated as a dispersing agent to optimize particle size and dispersion. The SDS concentration plays a crucial role in controlling the particle size and distribution, with higher SDS concentrations resulting in smaller, well-dispersed particles (30–40 nm), compared to the agglomerated particles formed without SDS. The Fe₃O₄ catalyst demonstrates significant enhancement in ORR performance, with a half-wave potential of 0.091 V vs. Hg/HgO and a limiting diffusion current density of −5.50 mA cm², surpassing the performance of agglomerated Fe₃O₄ and approaching that of state-of-the-art 20% Pt/C catalysts. Additionally, the Fe₃O₄ catalyst exhibits superior stability and resistance to methanol and CO poisoning, presenting a promising alternative to platinum-based catalysts for ORR applications. This work introduces an efficient approach for the synthesis of high-performance and evenly distributed Fe₃O₄ electrocatalysts, offering a new pathway for the development of metal oxide-based ORR catalysts with enhanced activity and durability. Full article

Background: Absence epilepsy is a non-convulsive form of genetic generalized epilepsy characterized by spontaneous bilateral spike-and-wave discharges (SWDs) in EEG. In contrast to grand-mal epilepsy, absence epilepsy without greatly expressed motor and interictal EEG abnormalities is difficult to detect, especially at the early stages. The WAG/Rij rat strain is a well-validated animal model of childhood absence epilepsy. At the early, preclinical stage, precursors or immature SWDs appear. Then, with age, immature discharges gradually turn into mature ones and mature SWDs prevail at the clinical stage. Mature SWDs, with an amplitude several times higher than the background EEG, can be easily distinguished visually. However, the amplitude of immature discharges is significantly lower than that of mature SWDs and is comparable to the amplitude of sleep spindles. Therefore, it is quite a difficult problem to distinguish immature discharges from sleep spindles. The task is further complicated by the fact that absence seizures mainly appear in a state of drowsiness and slow-wave (non-REM) sleep, when a lot of sleep spindles occur. The purpose of the present study was to develop a diagnostic method that allows us to precisely distinguish immature forms of epileptic seizures from background EEG and sleep spindles. Methods: The idea of analyzing wave-train electrical activity is to investigate the wavelet spectrum, find local peculiarities in this spectrum, and estimate generalized time-frequency peculiarities of the signal in terms of the found local peculiarities. Results: The criteria for diagnosis of the immature form of epileptic discharges and sleep spindles have been developed based on the analysis of wave-train activity with the construction of AUC diagrams (area under the curve diagrams). Conclusions: The method of wave-train analysis with the construction of AUC diagrams can be used for extracting the diagnostic features necessary for the diagnosis of absence epilepsy at the early stages of the disease in people with a genetic predisposition. Full article