Search Results (101)

Difficult, extreme operating conditions of parabolic antennas under precipitation and sub-zero temperatures require the creation of effective heating systems. The purpose of the research is to develop a multilayer coating containing two metal-ceramic layers, epoxy composite layers, carbon fabric, and an outer layer of basalt fabric, which allows for effective heating of the antenna, and to study the properties of this coating. The multilayer coating was formed on an aluminum base that was subjected to abrasive jet processing. The first and second metal-ceramic layers, Al₂O₃ + 5% Al, which were applied by high-speed multi-chamber cumulative detonation spraying (CDS), respectively, provide maximum adhesion strength to the aluminum base and high adhesion strength to the third layer of the epoxy composite containing Al₂O₃. On this not-yet-polymerized layer of epoxy composite containing Al₂O₃, a layer of carbon fabric (impregnated with epoxy resin) was formed, which serves as a resistive heating element. On top of this carbon fabric, a layer of epoxy composite containing Cr₂O₃ and SiO₂ was applied. Next, basalt fabric was applied to this still-not-yet-polymerized layer. Then, the resulting layered coating was compacted and dried. To study this multilayer coating, X-ray analysis, light and raster scanning microscopy, and transmission electron microscopy were used. The thickness of the coating layers and microhardness were measured on transverse microsections. The adhesion strength of the metal-ceramic coating layers to the aluminum base was determined by both bending testing and peeling using the adhesive method. It was established that CDS provides the formation of metal-ceramic layers with a maximum fraction of lamellae and a microhardness of 7900–10,520 MPa. In these metal-ceramic layers, a dispersed subgrain structure, a uniform distribution of nanoparticles, and a gradient-free level of dislocation density are observed. Such a structure prevents the formation of local concentrators of internal stresses, thereby increasing the level of dispersion and substructural strengthening of the metal-ceramic layers’ material. The formation of materials with a nanostructure increases their strength and crack resistance. The effectiveness of using aluminum, chromium, and silicon oxides as nanofillers in epoxy composite layers was demonstrated. The presence of structures near the surface of these nanofillers, which differ from the properties of the epoxy matrix in the coating, was established. Such zones, specifically the outer surface layers (OSL), significantly affect the properties of the epoxy composite. The results of industrial tests showed the high performance of the multilayer coating during antenna heating. Full article

In arid and semi-arid areas, soil is blown up by the wind because of its loose structure. Wind erosion causes soil quality and fertility loss, land degradation, air pollution, disruption of ecological balance, and agricultural and livestock losses. Consequently, there is an immediate imperative for methods to mitigate the impacts of wind erosion. SICP (soybean urease-induced carbonate precipitation) has emerged as a promising biogeotechnical technology in mitigating wind erosion in arid and semi-arid regions. To enhance bio-cementation efficacy and treatment efficiency of SICP, aluminum chloride (AlCl₃) was employed as an additive to strengthen the SICP process. Multiple SICP treatment cycles with AlCl₃ additive were conducted on Tengger Desert sand specimens, with the specimens treated without AlCl₃ as the control group. The potential mechanisms by which AlCl₃ enhances SICP may have two aspects: (1) its flocculation effect accelerates the salting-out of proteinaceous organic matter in the SICP solution, retaining these materials as nucleation sites within soil pores; (2) the highly charged Al³⁺ cations adsorb onto negatively charged sand particle surfaces, acting as cores to attract and coalesce free CaCO₃ in solution, thereby promoting preferential precipitation at particle surfaces and interparticle contacts. This mechanism enhances CaCO₃ cementation efficiency, as evidenced by 2.69–3.89-fold increases in penetration resistance at the optimal 0.01 M AlCl₃ concentration, without reducing CaCO₃ production. Wind erosion tests showed an 88% reduction in maximum erosion rate (from 1142.6 to 135.3 g·m⁻²·min⁻¹), directly correlated with improved microstructural density observed via SEM (spherical CaCO₃ aggregates at particle interfaces). Economic analysis revealed a 50% cost reduction due to fewer treatment cycles, validating the method’s sustainability. These findings highlight AlCl₃-modified SICP as a robust, cost-effective strategy for wind erosion control in arid zones, with broad implications for biogeotechnical applications. Full article

This study examines the morphology and development of Dobreștilor–Brusturet Cave, located in the Brusturet gorge at the western edge of the Bran–Dragoslavele Corridor, an important tourist route in the Romanian Carpathians. The research aims to analyze the geomorphological characteristics and establish the heritage value of the Dobreştilor Cave geomorphosite, supporting protection efforts for invertebrate species that led to the cave’s designation as a natural monument. The inventory of physical features prompted the Piatra Craiului National Park Scientific Council to consider including this speleological site in a thematic geotourism circuit called “The Road of Gorges and Caves in the Upper Basin of the Dâmbovițean”, integrated within protected areas. This represents the first geomorphological study of the cave. Given its ecological significance within the national park’s strict protection zone, recreational tourism is prohibited. The cave should only be used as a geotourism resource for scientific research and education. Morphogenetic analysis reveals that the cave has evolved in a vadose hydrological regime since the Pleistocene, with cavity expansion influenced by free-flowing water alternating with that under pressure during torrential episodes, concomitant with the precipitation of calcium carbonate that formed various speleothems. This research supports documentation for promotional materials and could assist local authorities in the Dâmbovicioara commune with geotourism development decisions, potentially integrating the site into a proposed “Moieciu–Fundata–Dâmbovicioara–Rucăr Geological and Geomorphological Complex”. Full article

This study systematically investigates the synergistic effects of Cu addition (0–0.7 wt.%) and 2% pre-straining on the artificial aging, natural aging (NA), and bake-hardening response (BHR) of AA6111 alloy. The results reveal that Cu significantly enhances age-hardening capacity and accelerates artificial aging kinetics. The 0.7Cu alloy achieved a 14% higher peak hardness (106.9 HV) than the Cu-free alloy (93.8 HV) while reducing peak aging time by 50% (from 10 h to 5 h). Pre-straining further promoted hardening rates, shortening peak aging times to 2 h for the 0.7Cu alloy. Natural aging (NA) severely suppressed BHR in non-pre-strained alloys, reducing paint baking (PB) increments by 75–77.5% after 14 days. However, the introduction of pre-straining not only reduces the negative effects of NA but also improves the BHR. TEM analysis demonstrated that Cu addition accelerated the precipitation of fine GP zones and β″ phases while pre-straining introduced dislocations that acted as heterogeneous nucleation sites for Q′ phases, refining precipitates and suppressing NA cluster formation. The synergistic combination of 0.7Cu and pre-straining achieved a superior BHR yield strength increment of 68.1 MPa with retained ductility, highlighting its potential for automotive applications requiring balanced formability and post-forming strength. Full article

Amid the increasing demands for ecological civilization and food security, addressing conflicts between agricultural and ecological functions has become a critical priority in spatial governance. Focusing on the Chang-Zhu-Tan Urban Cluster, this study establishes a multi-indicator evaluation framework and employs a weighted model to measure agricultural and ecological functions. The ESDA model characterizes the spatial distribution and clustering patterns of conflicts, while the RF model identifies the key drivers and underlying mechanisms. The results indicate the following: (1) Agricultural functions exhibit a “center-weak, periphery-strong” spatial pattern, with high-function zones covering over 60% of the area, whereas ecological functions are primarily concentrated in low-function zones, with high-function areas localized in the northeast. Overall, agro-ecological functionality declined from 2000 to 2020, accompanied by increased gradient differentiation. (2) High-conflict zones decreased by 7.73% during the study period, while medium-conflict and conflict-free zones expanded. Spatially, a trend of “peripheral mitigation of high conflicts and central expansion of low conflicts” emerged. (3) Natural environmental factors were the primary drivers of conflict dynamics, while land use factors gained significance over time. Elevation and slope dominated in 2000 and 2020, whereas land use economic density and crop planting area were more influential in 2010. Synergistic effects were observed, with slope–precipitation interactions providing the strongest explanatory power. This study offers empirical insights into managing agricultural–ecological conflicts, thereby contributing to enhanced spatial governance and sustainable development practices. Full article

This study systematically investigated the effects of the addition of the rare earth element yttrium (Y) on the microstructural evolution, mechanical properties, and corrosion behavior of as-extruded Al-5.6Zn-2.5Mg-1.6Cu-0.20Cr (wt.%) alloy through comprehensive characterization techniques, including X-ray diffraction (XRD), tensile testing, corrosion analysis, and electron microscopy. Microstructural characterization demonstrated that the incorporation of yttrium resulted in significant refinement of secondary phase particles within the as-extruded alloy matrix. Moreover, quantitative analysis revealed a substantial increase in low-angle grain boundary (LAGB) density, dislocation density, and the formation of subgrain structures. Notably, the volume fraction of η′ strengthening precipitates showed a marked increase, accompanied by a corresponding reduction in the width of precipitate-free zones (PFZs) along grain boundaries. Following the T74 aging treatment, the alloy with 0.1 wt.% yttrium addition exhibited a remarkable improvement in intergranular corrosion resistance, with the maximum corrosion depth reduced to 107.8 μm. However, it should be noted that the exfoliation corrosion resistance exhibited an inverse correlation with increasing yttrium content, suggesting a concentration-dependent behavior in corrosion performance. Full article

CO₂ sequestration is considered one of the main pillars in achieving the ongoing decarbonization efforts. A myriad of CO₂ sequestration projects targeted sandstone reservoirs since carbonate reservoirs appeared to be unpropitious due to their geological complexity and unfavorable mineralogy and properties. This study investigates CO₂ sequestration potential in a carbonate saline aquifer while considering various geological complexities by capitalizing on numerical simulation. A synthetic anticline reservoir model examined the optimum well location and landing zone for CO₂ sequestration. Additionally, the model evaluated the role of natural fractures in the migration path of CO₂ plume and geochemical reactions throughout the storage process. The study demonstrates that placing the injection well away from the top of the structure in a low-dip region while injecting in the bottom interval would yield the optimum design. After applying a plethora of analyses, geological complexity could impede the migration path of CO₂ but eventually produce a similar path when injected in a similar region. The geochemical interactions between the injected CO₂ and reservoir fluids and minerals reduce the free and trapped CO₂ quantities by dissolving calcite and precipitating dolomite. Furthermore, natural fractures impact the CO₂ quantities during early times only when the fractures cross the top layers. Similarly, the CO₂ migration differs due to the higher permeability within the fractures, resulting in slightly different CO₂ plumes. Consequently, the role of natural fractures should be limited in carbon storage projects, specifically if they do not cross the top of the reservoir. This study reflects a unique perspective on sequestering CO₂ while capturing the roles of natural fractures and well placement in depicting the migration path of the CO₂ plume. A similar systematic workflow and holistic approach can be utilized to optimize the subsurface storage process for potential formations. Full article

The 7000 series aluminum alloy represented by Al-Zn-Mg-Cu has good strength and toughness and is widely used in the aerospace field. However, its high Zn content results in poor corrosion resistance, limiting its application in other fields. In order to achieve the synergistic improvement of both strength and corrosion resistance, this study examines the response of strength, toughness and corrosion resistance of a high-strength aluminum alloy tail frame under aging conditions with external stresses of 135 MPa, 270 MPa and 450 MPa. The results show that with the increase in the external stress level, the strength of the alloy improves, while its corrosion resistance decreases. An optimal balance of strength, toughness and corrosion resistance is achieved at the conditions of 270 MPa-120–24 h. This phenomenon can be attributed to two main factors: first, lattice defects such as vacancy and dislocation are introduced into the stress aging process. The introduction of a vacancy makes it easier for neighboring solute atoms to migrate there. This makes the crystal precipitates more dispersed. Also, the number of precipitates in the matrix increases from 2650 to 3117, and the size is refined from 2.96 nm to 2.64 nm. At the same time, the dislocation entanglement within the crystal structure promotes the dislocation strengthening mechanism and promotes the solute atoms to have enough channels for migration. Since too many dislocations can cause the crystal to become brittle and thus reduce its strength, entangled dislocations hinder the movement of the dislocations, thereby increasing the strength of the alloy. Secondly, under the action of external force, the precipitated phase is discontinuous, which hinders the corrosion expansion at the grain boundary, thus improving the corrosion resistance of the alloy. At low-stress states, the binding force of vacancy is stronger, the precipitation free zone (PFZ) is significantly inhibited, and the intermittent distribution effect of intergranular precipitates is the most obvious. As a result, the self-corrosion current decreases from 1.508 × 10⁻⁴ A∙cm⁻² in the non-stress state to 1.999 × 10⁻⁵ A∙cm⁻², representing an order of magnitude improvement. Additionally, the maximum depth of intergranular corrosion is reduced from 274.9 μm in the non-stress state to 237.7 μm. Full article

Despite the extensive use of 7xxx aluminum alloys in aerospace, intergranular corrosion is yet to be appropriately addressed. In this work, in situ rolling friction stir welding (IRFSW) was proposed to improve the corrosion resistance of joints via microstructural design. A gradient-structured layer was successfully constructed on the surface of the joint, and the corrosion resistance was improved by in situ rolling. The intergranular corrosion depth of the IRFSW joint was reduced by 59.8% compared with conventional joints. The improved corrosion resistance was attributed to the redissolved precipitates, the disappearance of precipitate-free zones, and the discontinuous distribution of grain boundary precipitates. This study offers new insights for enhancing the corrosion resistance of aluminum alloy FSW joints. Full article

The 7085 aluminum alloy with a low Cu content is an important lightweight structural material in the aerospace field due to its advantages of low density, high specific strength, and high hardenability. However, like other high-strength Al-Zn-Mg-Cu alloys, this alloy is susceptible to stress corrosion cracking (SCC). Additionally, the lower Cu content may increase its tendency toward SCC, potentially impacting the safe use of this alloy. Therefore, this study investigated the effects of aging treatment processes on the mechanical properties and SCC resistance of 7085 aluminum alloy. And the factors affecting the properties of the alloy were analyzed by optical microscope (OM), scanning transmission electron microscope (STEM), and energy-dispersive X-ray spectroscopy (EDS) analyses. The results indicated that increasing the secondary aging temperature and adding a tertiary aging step can significantly reduce the alloy’s susceptibility to SCC while meeting the mechanical performance requirements. The reduced SCC sensitivity was mainly attributed to the increased spacing of grain boundary precipitates, a wider precipitate-free zone at the grain boundaries, and a higher Cu content in the grain boundary precipitates. Full article

Age-strengthened aluminum alloys, as important lightweight structural materials, have significantly lower fatigue properties compared to non-age-strengthened aluminum alloys. In this study, the polycrystalline models containing precipitation-free zones (PFZ) were constructed by secondary development of the traditional polycrystalline model by modifying the mesh file. Polycrystalline finite element simulations of peak age-treated Al-7.02Mg-1.98Zn alloys were carried out with this model. The results demonstrate that the PFZ’s presence markedly reduces the alloy’s yield strength and a substantial stress concentration occurs adjacent to the PFZ, generating significant compressive stresses at the PFZ. Under cyclic loading, the maximum strain energy dissipation in the model containing the PFZ far exceeds that observed in the conventional polycrystalline model, and the strain energy dissipation observed in the PFZ is significantly higher than that at other locations. This indicates that the PFZ is the main region for fatigue crack initiation. In addition, the introduction of a rotation factor to simulate the inhomogeneous rotation within the grain reveals that the additional stress concentration in the PFZ introduced by the aluminum alloy-forming process further increases the fatigue crack initiation driving force. Full article

The precipitation behavior of a novel Ni-Fe-based superalloy developed for advanced ultra-supercritical (A-USC) coal-fired power plant applications during high-temperature aging treatment was investigated. The results showed that the major precipitates in the novel alloy were randomly distributed MC carbides, M₂₃C₆ carbides at grain boundaries, and the γ′-Ni₃ (Al, Ti) phase in grain interiors after aging. MC remained relatively stable during both short-term and long-term aging. M₂₃C₆ quickly precipitated and exhibited a discrete distribution at grain boundaries during short-term aging, and partly developed into continuous films during long-term aging. After uniform precipitation, the shape of γ′ remained spherical, and the size kept increasing with aging time according to the Lifshitz–Slyozov–Wagner (LSW) model. The hardness of the novel alloy was mainly associated with the precipitation behavior of γ′; as γ′ gradually precipitated, the hardness steadily increased; after complete precipitation, as the size of γ′ increased, the hardness first increased and then decreased, reaching the peak hardness when the average radius of γ′ achieved the critical size. In addition, the novel alloy exhibited abnormal coarsening behavior at grain boundaries during both short-term and long-term aging. The coarsened grain boundaries were actually precipitate-free zones (PFZs) and the coarsened and elongated rod-like particles inside were identified as γ′ precipitates. The mechanism of strain-induced grain boundary migration and the discontinuous coarsening reaction is proposed for the formation of PFZs. Furthermore, PFZs were considered to be potential crack sources during the creep rupture test, leading to earlier failure of the material. Full article

The ecosystems in the mountainous region of Southwest China are exceptionally fragile and constitute one of the global hotspots for wildfire occurrences. Understanding the complex interactions between wildfires and their environmental and anthropogenic factors is crucial for effective wildfire modeling and management. Despite significant advancements in wildfire modeling using machine learning (ML) methods, their limited explainability remains a barrier to utilizing them for in-depth wildfire analysis. This paper employs Logistic Regression (LR), Random Forest (RF), and Extreme Gradient Boosting (XGBoost) models along with the MODIS global fire atlas dataset (2004–2020) to study the influence of meteorological, topographic, vegetation, and human factors on wildfire occurrences in the mountainous region of Southwest China. It also utilizes Shapley Additive exPlanations (SHAP) values, a method within explainable artificial intelligence (XAI), to demonstrate the influence of key controlling factors on the frequency of fire occurrences. The results indicate that wildfires in this region are primarily influenced by meteorological conditions, particularly sunshine duration, relative humidity (seasonal and daily), seasonal precipitation, and daily land surface temperature. Among local variables, altitude, proximity to roads, railways, residential areas, and population density are significant factors. All models demonstrate strong predictive capabilities with AUC values over 0.8 and prediction accuracies ranging from 76.0% to 95.0%. XGBoost outperforms LR and RF in predictive accuracy across all factor groups (climatic, local, and combinations thereof). The inclusion of topographic factors and human activities enhances model optimization to some extent. SHAP results reveal critical features that significantly influence wildfire occurrences, and the thresholds of positive or negative changes, highlighting that relative humidity, rain-free days, and land use land cover changes (LULC) are primary contributors to frequent wildfires in this region. Based on regional differences in wildfire drivers, a wildfire-risk zoning map for the mountainous region of Southwest China is created. Areas identified as high risk are predominantly located in the Northwestern and Southern parts of the study area, particularly in Yanyuan and Miyi, while areas assessed as low risk are mainly distributed in the Northeastern region. Full article

This study utilized a bobbin tool to friction stir weld aluminum 6082 workpieces under two sets of process parameters: a tool rotation speed of 280 rev/min with a weld velocity of 280 mm/min (280/280) and a tool rotation speed of 450 rev/min with a weld velocity of 450 mm/min (450/450). The weld microstructures were characterized through optical microscopy utilizing polarized light and through transmission electron microscopy (TEM) and scanning electron microscopy (SEM) coupled with chemical analysis by energy dispersive spectroscopy and electron back scatter diffraction. The microstructural studies were supplemented by hardness measurements (Vickers) performed on the same sections as the metallographic examinations. The produced weldments were free from cracks and any discontinuities. Fine, equiaxed grains that were several microns in size characterized the stir zones (SZs), and the advancing (AS) and retreating (RS) sides revealed distinct microstructural features. On the AS, the transition from the thermo-mechanically affected zone to the SZ was well defined and sharp, but on the RS, the transition appeared as a continuous, gradual change in microstructure. The lower weld energy (280/280) produced lower hardness in the stir zone than the higher energy weld (450/450), ~95 HV1 versus ~115 HV1; however, the 280/280 welds showed higher tensile strengths than the 450/450 welds, ~238 MPa as opposed to ~172 MPa. These behaviors in mechanical performance correlated with the temperature histories produced by each set of weld parameters in relation to the precipitation behavior of the alloy. The fracture characteristics of the weldments were notably different with the 450/450 sample fracturing in a quasi-brittle manner with slight plastic deformation and the 280/280 sample fracturing ductilely. A numerical simulation supported the investigation by elucidating the temperature and material flow behavior during the joining process. Full article

Research highlights: At the turn of the 21st century, there were more forest territories found disturbed by both natural processes (climate change, wildfires, insect outbreaks, permafrost thawing, etc.) and anthropogenic interferences (air pollution, clearcuts, etc.). Seed collecting, then growing seedlings in forest nurseries, and then planting seedlings over lost forest areas are the forestry measures needed to restore the forest after disturbances. Goals were to construct bioclimatic models of ranges and seed mass of major Siberian conifers (Siberian pine (Pinus sibirica Du Tour), Siberian fir (Abies sibirica Ledeb.), Siberian spruce (Picea obovata Ledeb.), Siberian larches (Larix sibirica Ledeb., L. gmelini (Rupr) Rupr, and L. cajanderi Mayr.) and Pinus sylvestris L.) and predict their potential change in a warming climate by the mid-century. Methods: Multi-year seed mass data were derived from the literature, seed station data, and were collected in the field. Climate data (January and July data and annual precipitation) were derived from published Russian reference books and websites on climate. Bioclimatic indices (growing degree-days > 5 C, negative degree-days < 0 C, and annual moisture index) were calculated from January and July temperatures and annual precipitation for both contemporary and the 2050s (2040–2060) climates using the general circulation model INM-CM5-0 and two climate change scenarios, ssp126 and ssp585, from CMIP6. Our bioclimatic range models (envelope and MaxEnt models) and regression seed mass models for major conifers were built based on these bioclimatic indices. Additionally, their ranges were limited by the permafrost border, which divided the forest area into the permafrost-free zone, where five conifers are able to grow, and the permafrost zone, where only one conifer, Dahurian larch, is able to survive. Results: Under warmed climates, the ranges of all Siberian conifers would expand 1.5-fold due to the decrease in the permafrost zone, except Dahurian larch, which would lose 5–20% of its coverage due to permafrost retreat. Conifers shifting northward would be slower than predicted only by warmed climates because permafrost would thaw slower than climates would warm. Scots pine may expand by up to 60%, covering dryer lands in the south. Future climates were found to favor seed mass increase for major Siberian conifers and for heavier seed to shift northward. Our major conifers differ by the type of seed dispersal mode: zoochoric, animal (Siberian pine) and anemochoric, and wind-dispersed (other five trees). The seed masses of the five anemochoric conifers varied within the range of 1.5–15 g of 1000 seeds, which is about 40–50-fold less than that of zoochoric Siberian pine. Site climate explained about 28–65% of the seed mass variation for the five anemochoric trees and only 11% for Siberian pine (zoochoric tree). This finding needs additional research to explain the reasons. Conclusions: Warmed climates would favor the expansion of the ranges of major Siberian conifers and their seed mass to be heavier, which would support the high-quality seed production for forest well-being and its restoration in Siberia. Full article