Search Results (13)

This article presents the manufacturing technology and mechanical properties of innovative pre-impregnated coatings (PCs). The base materials for PC are powders of metal oxides, non-metals, minerals and thermoplastic non-wovens. PC can be used in the manufacture of composites by methods such as vacuum infusion, autoclave curing or hand lamination. This is possible due to the novel PC structure consisting of a functional layer (FL) and a backing layer (BL). PCs are flexible so that they can be used on curved surfaces. In this work, five types of PC were subjected to a uniaxial tensile test. Depending on the powder used, failure force values ranging from 24.61 N to 28.73 N were obtained. In the next step, the pre-impregnated coatings were applied as a coating in “sandwich” composites made by vacuum infusion, which were subjected to three-point bending (3-PB) and adhesion tests. 3-PB tests proved that the coating remained integral with the substrate, even under high flexural deformation, while the adhesion achieved was in the range of 0.95 MPa to 1.57 MPa. PC can be used in many engineering products, e.g., for the coating of façade panels, roof tiles, automotive parts or rail vehicles, etc. Full article

Compared with traditional continuous plant fiber-reinforced thermoplastic composites, their 3D-printed counterparts offer distinct advantages in the rapid fabrication of complex geometries with integrated forming capabilities. However, the impregnation process of continuous plant fiber yarn with thermoplastic resin presents greater technical challenges compared to conventional synthetic fibers (e.g., carbon or glass fibers) typically employed in continuous fiber composites, owing to the yarn’s unique twisted structure. In addition, low molding pressure during 3D printing makes resin impregnation more difficult. To address the impregnation difficulty within plant fiber yarn during 3D printing, we employed two low-viscosity resins, liquid thermoplastic resin (specifically, reactive methyl methacrylate) and thermosetting epoxy resin, to pre-impregnate flax yarns, respectively. A dual-resin prepreg filament is developed for 3D printing of flax fiber-reinforced composites, involving re-coating pre-impregnated flax yarns with polylactic acid. The experimental results indicate that liquid thermoplastic resin-impregnated composites exhibit enhanced mechanical properties, surpassing the epoxy system by 39% in tensile strength and 29% in modulus, attributed to improved impregnation and better interfacial compatibility. This preparation method demonstrates the feasibility of utilizing liquid thermoplastic resin in 3D-printed continuous plant fiber composites, offering a novel approach for producing highly impregnated continuous fiber filaments. Full article

A double-layer core–shell photocatalytic coating was engineered on carbon fibers (CFb) derived from bamboo pulp precursors, employing a sequential process involving seed pre-loading, solvothermal treatment, and impregnation. XRD, SEM, and SEM-EDS analyses revealed that g-C₃N₄ and Bi₂O₃ nanosheets were co-assembled on the carbon fiber skeleton, and 50 nm MoS₂ particles were successfully loaded, resulting in the fabrication of MoS₂/g-C₃N₄/Bi₂O₃/CFb photocatalytic fibers. UV–vis spectroscopy, transient photocurrent response, and EIS tests demonstrated that the introduction of narrow-bandgap visible-light photocatalysts (g-C₃N₄ and MoS₂) enhanced light absorption and improved the separation and migration efficiency of photogenerated electron hole pairs. Photocatalytic degradation experiments of MB showed that MoS₂/g-C₃N₄/Bi₂O₃/CFb significantly outperformed g-C₃N₄/Bi₂O₃/CFb and Bi₂O₃/CFb, achieving a degradation efficiency of 92% within 60 min. Band structure calculations and analysis confirmed the formation of Z-scheme heterojunctions between g-C₃N₄ and Bi₂O₃, as well as between MoS₂ and Bi₂O₃. This dual Z-scheme heterojunction endowed MoS₂/g-C₃N₄/Bi₂O₃/CFb with enhanced redox capabilities, providing a novel strategy for developing efficient photocatalytic materials. Full article

This study designed laser engraving and resin pre-coating (RPC) treatments on an aluminum alloy (AA) surface to construct through-the-thickness “epoxy pins” for improving the bonding strength with carbon fiber reinforced polymer (CFRP). A laser engraving treatment was used to create a pitted structure on the AA surface; higher wettability was acquired and greater vertical spaces were formed to impregnate epoxy resin, resulting in stronger mechanical interlocking. The RPC technique was further used to guide high-viscosity epoxy resin into pits to form the epoxy coatings and to minimize defects between the resin and the substrate. The bonding strength of the specimen treated with both laser engraving with a unit dimension of 0.3 mm and RPC increased up to 227.1% in comparison with that of the base. The failure modes of the hybrid composites changed from the debonding failure of the AA surface to the delamination-dominated failure of the laminated CFRP composites. It was confirmed that laser engraving is a feasible and effective method when combined with RPC for treating AAs to improve the bonding strength of AA-CFRP composites, which provides a reference for preparing high-performance hybrid composites with metals. Full article

Semi-aromatic poly (hexamethylene terephthalamide) (PA6T) oligomer (prePA6T) ultrafine powder, with a diameter of <5 μm, was prepared as an emulsion sizing agent to improve the impregnation performance of CF/PA6T composites. The prePA6T hyperfine powder was acquired via the dissolution and precipitation “phase conversion” method, and the prePA6T emulsion sizing agent was acquired to continuously coat the CF bundle. The sized CF unidirectional tape was knitted into a fabric using the plain weave method, while the CF/PA6T laminated composites were obtained by laminating the plain weave fabrics with PA6T films. The interfacial shear strength (IFSS), tensile strength (TS), and interlaminar shear strength (ILSS) of prePA6T-modified CF/PA6T composites improved by 54.9%, 125.3%, and 120.9%, respectively. Compared with the commercial polyamide sizing agent product PA845H, the prePA6T sizing agent showed better interfacial properties at elevated temperatures, especially no TS loss at 75 °C. The SEM observations also indicated that the prePA6T emulsion has an excellent impregnation effect on CF, and the fracture mechanism shifted from adhesive failure mode to cohesive failure mode. In summary, a facile, heat-resistant, undamaged-to-fiber environmental coating process is proposed to continuously manufacture high-performance thermoplastic composites, which is quite promising in mass production. Full article

Currently there is gaining interest in pre-compressed foam sealing tapes to seal joints watertight between different building envelope components. Little to no information is available on the parameters affecting the resistance of these foam tapes to driving rain. On the other hand, several research studies have shown that water leakages can be expected at relatively low-pressure differences and that drainage should be provided. Therefore, a study was designed to on the one hand assess the material and installation parameters that affect the watertightness of pre-compressed polyurethane foam sealing tapes impregnated with an acrylic polymer dispersion and on the other hand evaluate the potential of providing drainage possibilities, either as a two-barrier system or by means of integrated drainage cavities. It was found that the joint width, the presence of an airtight coating, and the position of the tape relative to the exterior surface affected the watertightness of the sealed joints. Notably, 87% of the evaluated foam tapes applied as a single barrier showed water leakages at pressure differences of 600 Pa or lower. Foam tapes with integrated drainage cavities, on the other hand, resulted in watertight joints up to an average pressure difference of 825 Pa. Full article

Mild steel continues to be the most extensively used construction material in several industries and constructions. However, corrosion of mild steel in aggressive environments is a major concern. Under the tremendously increasing demand for improving the coatings strategies because of the environmental concerns due to some of the traditional coatings, silane pre-treatments have been emerging as one of the effective solutions, among other strategies. Different approaches, such as adding particles of metal oxide (such as SiO₂, ZrO₂, Al₂O₃, TiO₂ and CeO₂), incorporating plant extracts and impregnating 2D materials into the coatings, have been employed for durable corrosion resistance, including for mitigating enhanced corrosion due to the presence of bacteria. This review discusses the critical mechanistic features of silane coatings such as the role of hydrolysis and condensation in the bonding of silanes with metal surfaces. The factors that influence the performance of the silane coatings for corrosion resistance of mild steel are discussed. In particular, this review provides insight into silane coatings for mitigating microbiologically influenced corrosion (MIC) of mild steel. Full article

This paper presents the results of studies of the nanoporous silicon structure, both with different pore depths (up to 180 μm) and with layers in which a graphene-like coating was synthesized on the inner surface of the pores. The nanoporous layers were characterized by SEM as well as IR and Raman spectroscopy. Cyclic voltammetry and galvanostatic charge–discharge data in 3 M H₂SO₄ are presented as well as the results of the cyclic stability of these characteristics for the nanoporous structure. It was found that the degree of electrolyte pre-impregnation significantly affected the electrochemical processes, and the capacitance values depended on the depth (thickness) of the nanoporous layer. Increasing the thickness of the porous layer led to an increase in area-normalized pseudocapacity and was limited only by the mechanical strength of the structure. Performance improvement was also achieved by synthesis of the graphene-like layer in the volume of the nanoporous structure. The electrodes (composite materials) proposed in the work showed one of the best capacitive characteristics (87 mF/cm² with 100% capacity retention after 15,000 cycles) in comparison with the data reported in the literature at present. Full article

Nowadays, FRCM systems are increasingly used for the strengthening and retrofitting of existing masonry and reinforced concrete structures. Their effectiveness strongly depends on the bond that develops at the interface between multifilament yarns, which constitute the reinforcing fabric, and the inorganic matrix. It is well known that fabric yarns, especially when constituted by dry carbon fibers, have poor chemical-physical compatibility with inorganic matrices. For this reason, many efforts are being concentrated on trying to improve the interface compatibility by using different surface treatments on multifilament yarns. In this paper, three different surface treatments have been considered. The first two involve yarn pre-impregnation with flexible epoxy resin or nano-silica coating, while the third one involves a fiber oxidation process. Uniaxial tensile tests were carried out on single carbon yarns to evaluate tensile strength, elastic modulus and ultimate strain before and after surface treatments, and also after yarn exposure to accelerated artificial aging conditions (1000 h in saline or alkaline solutions at 40 °C), to evaluate their long-term behavior in aggressive environments. Pull-out tests on single carbon yarns embedded in a cementitious mortar were also carried out, under normal environmental conditions and after artificial exposure. Epoxy proved to be the most effective treatment, by increasing the yarn tensile strength of 34% and the pull-out load of 138%, followed by nano-silica (+9%; +40%). All surface treatments were shown to remain effective even after artificial environmental exposures, with a maximum reduction of yarn tensile strength of about 13%. Full article

The impregnation of lightweight aggregate (LWA) is an alternative method to its pre-moistening, which is used to limit the loss of fresh concrete workability due to the aggregate’s ability to absorb a great amount of mixing water. The aim of this study was to access the effectiveness, by pre-coating LWAs with cement paste, in modifying the properties of concrete composites. Two types of lightweight aggregates (Lytag and Leca) characterized with a relatively open-structure shell were selected. The other changeable parameters taken into consideration in this research were: LWA size, initial moisture of aggregate before the impregnation process and type of cement paste applied as an impregnant. Sixteen concretes prepared with pre-moistened and pre-coated lightweight aggregates were subject to a density test in different moisture conditions, a water absorption test and a compressive strength test. On the one hand, the pre-coating of LWAs with cement paste resulted in a relatively slight increase in concrete density (by up to 19%) compared to the pre-moistening of LWAs. On the other hand, it caused a very significant reduction (by up to 52%) in the composite’s water absorption and an incomparably greater growth (by up to 107%) in compressive strength. The most crucial factors determining the effectiveness of impregnation of LWAs with cement pastes in improvement of composite properties were the aggregate type and its size. The composition of impregnating slurry and the initial moisture content of LWA before pre-coating also mattered. Full article

In this paper, the reinforcement of concrete combining composite materials with carbon, glass and aramid fibers is discussed. Accordingly, cement specimens reinforced with chopped carbon fibers were manufactured via the retrofitting method and coated using various different types of fabrics (carbon, glass and aramid), and epoxy resin systems were developed and studied using compressive strength tests. In addition, polymeric matrix (epoxy resin) composite materials reinforced with different types of fabric (carbon, glass and aramid (Kevlar^® 49)) were manufactured and their shear and bending strengths were measured. Before reinforcing cement specimens, all fabrics (carbon, glass and aramid (Kevlar^® 49)) were placed in a vacuum chamber and were processed via pre-impregnation. This specific reinforcing method significantly improved the mechanical properties of cementitious structures with compressive strength values that reached 81 MPa. In a similar way, the bending and shear strengths of the materials under study were measured at 405 MPa and 33 MPa, respectively. Full article

This study consisted of developing a dressing loaded with silver (Ag) and ibuprofen (IBU) that provides a dual therapy, antibacterial and antalgic, intended for infected painful wounds. Therefore, non-woven polyethyleneterephtalate (PET) textiles nonwovens were pre-treated by cyclodextrin crosslinked with citric acid by a pad/dry/cure process. Then, textiles were impregnated in silver solution followed by a thermal treatment and were then coated by Layer-by-Layer (L-b-L) deposition of a polyelectrolyte multilayer (PEM) system consisting of anionic water-soluble poly(betacyclodextrin citrate) (PCD) and cationic chitosan. Finally, ibuprofen lysinate (IBU-L) was loaded on the PEM coating. We demonstrated the complexation of IBU with native βCD and PCD by phase solubility diagram and ¹H NMR. PEM system allowed complete IBU-L release in 6 h in PBS pH 7.4 batch (USP IV). On the other hand, microbiological tests demonstrated that loaded silver induced bacterial reduction of 4 Log₁₀ against S. aureus and E. coli and tests revealed that ibuprofen lysinate loading did not interfere with the antibacterial properties of the dressing. Full article

In this work, we studied the transport properties (thermal and electrical conductivity) of smart fabric materials treated with graphite nanomaterial stacks–acetone suspensions. An innovative and easy method to produce graphite nanomaterial stacks–acetone-based formulations, starting from a low-cost expandable graphite, is proposed. An original, economical, fast, and easy method to increase the thermal and electrical conductivity of textile materials was also employed for the first time. The proposed method allows the impregnation of smart fabric materials, avoiding pre-coating of the fibers, thus reducing costs and processing time, while obtaining a great increase in the transport properties. Two kinds of textiles, cotton and Lycra^®, were selected as they represent the most used natural and artificial fabrics, respectively. The impact of the dimensions of the produced graphite nanomaterial stacks–acetone-based suspensions on both the uniformity of the treatment and the transport properties of the selected textile materials was accurately evaluated using several experimental techniques. An empirical relationship between the two transport properties was also successfully identified. Finally, several theoretical models were applied to predict the transport properties of the developed smart fabric materials, evidencing a good agreement with the experimental data. Full article