Search Results (247)

Accurate prediction of lithium-ion battery state of health (SOH) is crucial for improving the safety, reliability, and operational efficiency of battery management systems (BMSs). However, many data-driven methods still struggle to maintain robust forecasting performance when degradation trajectories differ across cells, especially in later-stage aging. To address this issue, this study developed a robustness-oriented SOH prediction framework, termed Ada-TL, by integrating a Transformer encoder, an LSTM regressor, and adaptive hyperparameter tuning. Cycle-level health indicators were extracted from the publicly available CALCE dataset and transformed into a compact representation for supervised learning. The Transformer module captures non-local dependencies within each input window, whereas the LSTM summarizes sequential degradation dynamics. The number of attention heads, the initial learning rate, and the L2 regularization coefficient are adaptively optimized to reduce manual trial-and-error in model configuration. Experimental results on four CS2 cells show that Ada-TL consistently outperformed BP, CNN–LSTM, and the fixed-hyperparameter baseline in overall SOH prediction accuracy, achieving RMSE values of 0.0210–0.0310, MAE values of 0.0163–0.0262, and MAPE values of 4.17–9.30%. Additional late-stage and cumulative-drift analyses further indicate that Ada-TL provided more stable post-knee tracking and better control of long-horizon bias accumulation, with late-stage RMSE reduced to 0.0169–0.0217 across the four cells. An ablation study also showed that the KPCA-based three-dimensional representation improved the overall test-set accuracy on most cells while reducing input dimensionality. These results suggest that the main value of Ada-TL lies in robustness-oriented SOH forecasting under cell-to-cell variability. Full article

As power-electronic-interfaced renewable generation displaces synchronous machines, modern power systems face coupled day-ahead challenges: net-load variability demands peak shaving, while declining inertia necessitates explicit frequency-regulation scheduling. In sequential security-constrained unit commitment (SCUC) and Security-Constrained Economic Dispatch (SCED), the reserve procured in SCUC may lose deliverability after redispatch because the same storage bandwidth is reassigned to energy service. This paper proposes a two-stage day-ahead framework that addresses both challenges for low-inertia systems with high inverter-based resource (IBR) penetration. Stage I embeds Rate-of-Change of Frequency (RoCoF), frequency nadir, and quasi-steady-state (QSS) constraints in SCUC, with a piecewise-linear outer approximation for the non-convex nadir limit. Stage II strictly inherits the SCUC commitment and reserve reservation, and it applies bandwidth deduction to prevent peak-shaving redispatch from consuming committed frequency reserve. A technology-aware partition further assigns fast-response Lithium Iron Phosphate (LFP) batteries to sub-second frequency support and long-duration Vanadium Redox Flow Batteries (VRFBs) to energy shifting. Evaluated under the adopted reduced-order frequency-response framework and disturbance representation, tests on a modified IEEE 39-bus system under an extreme-wind scenario demonstrate that explicit frequency constraints eliminate all post-contingency violations, the inheritance mechanism closes a 23.85 MW reserve gap after redispatch, and heterogeneous storage partitioning preserves essentially the same disturbance sensitivity while increasing the peak-shaving ratio to 45.85%, lowering the day-ahead cost to CNY $10.483\times {10}^6$ and reducing the average system price to 209.33 CNY/MWh. Full article

The rising global demand for lithium has led to substantial accumulation of lithium slag, a by-product of lithium carbonate production and a potential environmental contaminant. Leachates from this material contain various metal elements and may pose risks to ecosystems and organismal health. However, research on its neurotoxicity and underlying mechanisms remains limited. In this study, zebrafish embryos at 6 h post-fertilisation were exposed to varying concentrations of lithium slag leachate for 7 days. The leachate contained multiple metal ions (Li, Fe, Mn, Ni, Zn, As, Cr, Cu, Hg, Cd, Pb, etc.). Following exposure, significant metal accumulation was observed in larvae, accompanied by developmental malformations (yolk sac oedema, cardiac haemorrhage, and uninflated swim bladders). Behavioural assessment revealed reduced swimming distance and velocity, along with disrupted circadian rhythms. Biochemical analyses showed elevated Reactive oxygen species (ROS), Superoxide dismutase (SOD), Catalase (CAT), and Malondialdehyde (MDA), alongside decreased Glutathione (GSH), indicating oxidative stress. Transcriptomic analysis confirmed downregulation of core circadian genes. Neurotransmitter assays revealed decreased acetylcholine (Ach), noradrenaline (NE), and dopamine (DA), with increased gamma-aminobutyric acid (GABA) and serotonin (5-HT). These findings demonstrate that lithium slag leachate induces oxidative stress, circadian disruption, and neurobehavioural toxicity in zebrafish, providing important evidence for environmental risk assessment. Full article

This study investigates how the initial oxygen fraction in a confined space affects post-vent combustion, gas composition, and pressure hazards during thermal runaway (TR) of 58 Ah prismatic Li(Ni_0.8Co_0.1Mn_0.1)O₂ lithium-ion cells. Thermal abuse experiments were conducted in a 250 L sealed chamber under five initial oxygen fractions (20%, 15%, 10%, 5%, and 0% O₂), with synchronized measurements of cell temperature, vent-jet temperature, chamber pressure, voltage, and post-event gas composition. A first-vent event occurred reproducibly at a cell surface temperature of approximately 155 °C, followed by TR onset at about 170 °C. Although the onset temperatures were only weakly affected by ambient oxygen concentration, the post-vent hazard escalation depended strongly on oxygen availability. As the initial oxygen fraction increased from 0% to 20%, the peak vent-jet temperature increased from 353 °C to 1172 °C, and the peak chamber pressure rose from 90.7 kPa to 523.1 kPa. Gas chromatography showed that H₂, CO₂, CO, CH₄, and C₂H₄ were the dominant gaseous products. Lower oxygen fractions promoted retention of combustible species, whereas higher oxygen fractions enhanced oxidation and increased the CO₂/CO ratio. An oxygen-participation parameter, η, was introduced to quantify the fraction of initially available chamber oxygen consumed during post-vent oxidation. The increase in η was positively associated with oxygen-involved heat release and chamber overpressure. When the accessible oxygen fraction was limited to 10% or below, secondary combustion and pressure buildup were markedly suppressed, although a localized near-field thermal hazard remained significant around 10% O₂. These results provide quantitative guidance for enclosure inerting, vent management, and post-vent hazard mitigation in high-energy lithium-ion battery systems. Full article

Long-term aesthetic success in dentistry largely depends on the color stability of restorative materials. This study investigated the color changes (ΔE₀₀) of resin nanoceramic and lithium disilicate ceramic restorative materials used in computer-aided design and computer-aided manufacturing (CAD/CAM) systems following beverage immersion and after repolishing. One hundred specimens were prepared from lithium disilicate (Initial LiSi Block) and resin nanoceramic (Cerasmart), and polished. The specimens were divided into ten groups according to material and beverage type (n = 10) and immersed in distilled water, cola, tea, coffee, and turnip juice at 37 °C for 3 months. Color values were recorded at baseline, 1 week, 1 month, and 3 months, and after repolishing. ∆E₀₀ values were calculated using the CIEDE2000 color difference formula. Data were analyzed using three-way repeated measures ANOVA and post hoc Tukey and Bonferroni tests (α = 0.05). Material type, beverage type, and immersion time significantly affected color stability (p < 0.05). The highest ∆E₀₀ observed in the resin nanoceramic–tea group at 3 months (ΔE₀₀ = 11.39 ± 1.76). Lithium disilicate demonstrated better color stability. After repolishing, all ΔE₀₀ values were below the clinically acceptable limit (ΔE₀₀ ≤ 1.8). Repolishing may help maintain the long-term aesthetic success of dental restorations in the oral environment. Full article

Lithium metal batteries (LMBs) have been widely studied due to their high energy density; however, the practical implementation of LMBs is limited by issues of uncontrolled dendrite growth, continuous electrolyte decomposition, and poor Coulombic efficiency (CE). Highly concentrated electrolytes (HCEs) have emerged as a promising approach to addressing the above issues. In this work, we propose a new HCE system based on a single carbonate solvent of 2,2,2-trifluoroethyl methyl carbonate (FEMC) with a high concentration of lithium bis(fluorosulfonyl)imide (LiFSI). The resulting electrolytes exhibit enhanced anodic stability and improved compatibility with lithium metal anodes and high-voltage cathodes. The optimized 4 M LiFSI–FEMC HCE achieved the highest CE for Li plating/stripping in Li/Cu cell and lowest overpotential in Li/Li symmetric cells, outperforming both low-concentration FEMC and ethyl methyl carbonate (EMC)-based electrolytes. In full-cell configurations with LiNi_0.8Co_0.1Mn_0.1O₂ (NCM811) cathodes, the HCE demonstrates stable cycling with minimal capacity fade over 250 cycles. Importantly, the HCE enables stable operation of 4.6 V high-voltage NCM811/Li cells for more than 120 cycles with a high-capacity retention of 88.61%. Post-mortem analysis revealed a more uniform and compact solid electrolyte interphase and a thinner cathode electrolyte interphase, contributing to the enhanced cycling performance. Full article

Although halide solid electrolytes (HSEs) demonstrate a higher voltage window and superior interfacial stability toward Li-rich layered oxides (LLOs) compared to sulfide systems, HSE-based all-solid-state lithium batteries (HSE-ASSLBs) still face a fundamental trade-off between achieving high capacity and maintaining cycling stability. To resolve this issue, a rational adjustment of the depth-of-discharge (DOD) via discharge cut-off voltage control is proposed. Analysis of dQ/dV profiles and post-cycled electrodes indicates that excessive DOD (lower cut-off voltages) aggravates structural degradation and interfacial side reactions, whereas insufficient DOD (higher cut-off voltage) fails to fully utilize the compensatory capacity from low-voltage redox couples. Notably, an optimized cut-off voltage of 2.6 V activates a stable low-voltage redox reaction centered around 2.85 V, which effectively offsets high-voltage capacity loss while suppressing unfavorable interfacial evolution. As a result, the ASSLB configured with a Li_1.2Ni_0.13Mn_0.54Co_0.13O₂ cathode and a Li_2.75In_0.75Zr_0.25Cl₆ HSE delivers an initial discharge capacity of 281.6 mAh g⁻¹ at 1C and achieves significantly improved capacity retention from 71.8% to 86.1% over 300 cycles. This study confirms that DOD regulation offers a simple and effective electrochemical protocol for enabling durable high-capacity output in LLO-based ASSLBs. Full article

The West Kunlun represents one of the largest and most economically significant rare metal metallogenic belts in NW China. The newly discovered Dahongliutandong Li deposit is the first Li deposit identified within the Permian Huangyangling Group in this region, and its discovery has important implications for regional lithium exploration. In this study, whole-rock major and trace-element geochemistry and cassiterite U–Pb isotope data from both Li-poor and Li-rich pegmatites of the Dahongliutandong deposit were analyzed to constrain the mineralization age and tectonic setting. Geochemically, the pegmatites are characterized by high SiO₂ (70.57–78.50 wt%), low TiO₂, MnO, and MgO (<0.2 wt%), and strongly peraluminous signatures (A/CNK = 1.45–1.95). They exhibit coherent chondrite-normalized REE patterns with LREE enrichment and negative Eu anomalies (Eu/Eu* = 0.03–0.77), along with consistent enrichment in LILEs (e.g., Rb, U, K) and depletion in HFSEs (e.g., Nb, Ti) on primitive mantle-normalized spider diagrams, suggesting a common magmatic source or evolutionary path. Cassiterite U–Pb dating yielded consistent lower-intercept ages of 208 ± 11 Ma (MSWD = 0.86) for Li-poor pegmatites and 206 ± 5 Ma (MSWD = 1.7) for Li-rich pegmatites, both indicating Late Triassic mineralization. Combined with regional geology, these data suggest that Li mineralization was likely related to post-collisional extension following the closure of the Paleo-Tethys Ocean. This study provides new insights into regional rare metal mineralization in the West Kunlun orogenic belt. Full article

This in vitro study evaluated the fracture resistance of CAD/CAM-fabricated lithium disilicate and 3D-printed resin crowns with varying occlusal thicknesses (0.5, 1.0, and 1.5 mm) following thermomechanical aging. Sixty extracted human molars were assigned to six experimental groups (n = 10), categorized by crown material and occlusal thickness. The crowns were fabricated using CAD/CAM technology in accordance with the manufacturer’s protocol. All specimens underwent thermomechanical aging, which consisted of thermocycling between 5 and 50 °C (5500 cycles) combined with mechanical loading of 50 N at 1.6 Hz for 75,000 cycles. The fracture loads were measured using a universal testing machine, and the failure modes were assessed using scanning electron microscopy. Statistical evaluation was performed using two-way analysis of variance with Tukey’s post hoc test (α = 0.05). Both the material type and occlusal thickness had a statistically significant effect on fracture resistance (p < 0.001). Lithium disilicate crowns exhibited higher fracture loads than 3D-printed resin crowns independent of occlusal thickness. Although the fracture resistance of 3D-printed resin crowns was lower, specimens with occlusal thicknesses ≥1.0 mm exhibited fracture loads exceeding average physiological masticatory forces, suggesting that 3D-printed resin crowns may represent a clinically acceptable option for conservative posterior restorations. In contrast, crowns with an occlusal thickness of 0.5 mm demonstrated fracture resistance values below the reported functional masticatory loads. Additionally, the proportion of repairable fractures increased with increasing occlusal thickness for both materials. Overall, the findings suggest that an occlusal thickness of at least 1.0 mm may represent a reliable threshold for posterior restorations, whereas a thickness of 0.5 mm may be insufficient to withstand functional occlusal loads in molar regions. Full article

This study reports a graphite-core, multiphase gradient C–Si–N composite architecture for Si-containing graphite-based negative electrodes in lithium-ion batteries. The increase in electrode thickness is used as a practical metric of expansion-driven degradation. The composite is prepared by the simultaneous nitridation and carbonization of a graphite core–Si precursor using polyvinylpyrrolidone (PVP) as the N source. Scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy indicates a quasi-continuous radial trend in the relative N signal toward the outer shell, consistent with preferential N enrichment near the particle exterior. This spatially distributed N arrangement may spatially separate the Si-rich expansion-prone region from the carbon-rich exterior containing nitrides and other N-bearing species, thereby enabling stress partitioning. The shell architecture is designed to disperse expansion-induced stress and stabilize the electrode–electrolyte interface. During electrochemical cycling, the C–Si–N electrode with 10% PVP preserves its core–shell morphology and exhibits the smallest average electrode thickness expansion (~58% after 40 cycles, based on four independent cells). The reduced thickness growth is discussed in relation to a mechanically robust Si–N matrix (Si₃N₄-like/SiN_x-like), potential Li–N interphase species, and N-containing carbon, together with the post-mortem morphology and electrochemical impedance evolution. This study presents reduced swelling as an electrode-level trend versus nominal PVP addition, along with associated nitride-related signatures, thereby highlighting spatially graded stress buffering as an electrode-level design principle. Full article

The development of high-performance anode materials is essential to overcome the limitations associated with conventional graphite electrodes in lithium-ion batteries, and perovskite oxides emerge as promising alternatives due to their structural flexibility and defect chemistry. In this work, the potential of LaSrCoFeO₃ perovskite (LSCF) thin films as anode materials is investigated, with particular emphasis on the effect of the post-deposition annealing atmosphere. LSCF thin films were deposited by dc magnetron sputtering and then thermal-treated at 600 °C in air and vacuum. The structural, electrical and electrochemical characterizations show that vacuum annealing promotes a more efficient crystallization, leading to larger crystallites (~240 nm), and to reduced oxidation due to the formation of oxygen vacancies. This reduced state significantly reduces electrical conductivity to ~10⁻⁵ Ω·cm. When evaluated as a half-cell anode, the vacuum-annealed films exhibit a theoretical specific capacity of 121 mAh·g⁻¹, high reversibility with anodic and cathodic charge ratio Q_a/Q_c ≈ 1 and a good cyclic stability, with a loss of discharge capacity of less than 10%. Raman spectroscopy experiments confirm that the film structure remains unchanged upon the electrochemical tests, evidencing the stability of the perovskite structure. These results show that the annealing atmosphere is a determining parameter to optimize the electrochemical performance of LSCF thin films, reinforcing their potential as anodes for future lithium-ion batteries. Full article

This study presents the electrochemical characterization of a novel, binder-free, plasma-treated aluminum/carbon electrode (“Surge”) using lithium metal half-cells. The low operating potential near 0 V vs. Li/Li⁺ enables the investigation of the electrode’s charge storage mechanisms and stability limits. We compare its electrochemical behavior in coin cells (CR2032) against two reference configurations: (i) the Surge electrode with a thin copper backer (Surge + Cu-backer) and (ii) a commercial graphite electrode on an aluminum current collector (C-REF). The Surge electrode demonstrated ultra-high initial specific capacities of up to approximately 4500 mAh/g (cycle 1) with Coulombic efficiencies exceeding 85% after the formation cycle. The observed capacity significantly exceeds the theoretical value for Li-Al alloying (993 mAh/g), indicating that lithium plating within the porous carbon scaffold contributes substantially to the total charge storage. However, this high performance was limited to approximately 8 to 9 stable cycles. Post-cycling analysis via scanning electron microscopy combined with energy-dispersive X-ray spectroscopy (SEM/EDX) revealed a dominant failure mechanism: partial dissolution and consumption of the Al current collector leading to material redistribution. Quantitative EDX analysis showed a decrease in Al content from 45 at.% to 12 at.% alongside an increase in oxygen content from 8 at.% to 38 at.%, suggesting extensive Al-oxide formation. Critically, in the absence of a backer, Al-containing material deposited onto the stainless-steel cell components. The Cu backer served to redirect these deposits, improving current collection and modestly extending the short-term durability to approximately 1800 mAh/g at cycle 14 (approximately 75% capacity retention). In contrast, the C-REF control cell reached only approximately 1000 mAh/g (cycle 4) before failing within 5 to 6 cycles, underscoring the inherent instability of bare Al at low potentials. This characterization study establishes the Surge architecture as a successful proof-of-concept for ultra-high capacity charge storage and identifies Al dissolution as the dominant degradation mechanism. Future optimization must focus on stabilizing the Al substrate through protective interphases, alloying, or electrolyte engineering. Full article

Fast charging improves the usability of consumer electronics and electric vehicles (EVs) by reducing range anxiety and downtime but accelerates battery degradation and raises safety concerns. Optimizing operational conditions during fast-charging is critical to mitigating aging and ensuring safety. This study evaluated multilayer Gr/NMC811 cells under various conditions, including depths of discharge (DODs of 68%, 84%, and 100%), upper charge cutoff voltages (4.1–4.2 V), and post-charge rest periods (2–30 min), using a 20 min fast charging protocol for up to 500 cycles (up to 150,000 miles of EV use assuming 3.3 mi/kWh vehicle level energy efficiency). Surprisingly, higher DODs under fast charging improved battery life and performance compared to lower DODs. Reducing the upper charge cut-off voltage helped mitigate degradation. A brief 2 min rest period after charging further reduced aging effects. The primary aging modes were loss of lithium inventory and cathode active material. Although minor lithium plating was observed within 500 cycles, it did not affect performance significantly. These findings suggest that, with optimized conditions, cells can sustain hundreds of fast charge cycles—equivalent to over 100,000 miles of EV use—without significant adverse effects on performance or longevity. Full article

Accurate estimation of the State of Charge (SOC) for lithium-ion batteries is a core function of the Battery Management System (BMS). However, LiFePO₄ batteries present specific challenges for SOC estimation due to the characteristic plateau in their open-circuit voltage (OCV) versus SOC relationship. Moreover, data-driven estimation approaches often face significant difficulties stemming from measurement noise and interference, the highly nonlinear internal dynamics of the battery, and the time-varying nature of key battery parameters. To address these issues, this paper proposes a Long Short-Term Memory (LSTM) model integrated with feature engineering, physical constraints, and the Extended Kalman Filter (EKF). First, the model’s temporal perception of the historical charge–discharge states of the battery is enhanced through the fusion of temporal voltage information. Second, a post-processing strategy based on physical laws is designed, utilizing the Particle Swarm Optimization (PSO) algorithm to search for optimal correction factors. Finally, the SOC obtained from the previous steps serves as the observation input to EKF filtering, enabling a probabilistically weighted fusion of the data-driven model output and the EKF to improve the model’s dynamic tracking performance. When applied to SOC estimation of LiFePO₄ batteries under various operating conditions and temperatures ranging from 0 °C to 50 °C, the proposed model achieves average Mean Absolute Error (MAE) and Root Mean Square Error (RMSE) as low as 0.46% and 0.56%, respectively. These results demonstrate the model’s excellent robustness, adaptability, and dynamic tracking capability. Additionally, the proposed approach only requires derived features from existing input data without the need for additional sensors, and the model exhibits low memory usage, showing considerable potential for practical BMS implementation. Furthermore, this study offers an effective technical pathway for state estimation under a “physical information–data-driven–filter fusion” framework, enabling accurate SOC estimation of lithium-ion batteries across multiple operating scenarios. Full article

Overlay restorations offer a conservative solution for teeth with substantial loss of tooth structure, but their success depends largely on the preparation design, material type, and fabrication technique. This study aimed to assess the effects of two different preparation designs and fabrication techniques on the fracture resistance and marginal adaptation of overlays fabricated from zirconia-reinforced lithium silicate (ZLS) and 3D-printed resin. Forty extracted human molars were randomly divided into two preparation design groups: occlusal reduction (O) and occlusal reduction with a round shoulder (OS). Each group was subdivided based on the material type: ZLS or 3D-printed resin (n = 10 per subgroup). Restorations were designed using CAD and manufactured using milling (ZLS) or additive manufacturing (3D-Printed). After cementation and thermomechanical aging (5500 cycles, 5–50 °C), marginal gaps were measured at 20 predefined points using scanning electron microscopy (SEM). The fracture resistance was tested using a universal testing machine. Data were analyzed using two-way ANOVA and post hoc tests (α = 0.05). The preparation design had a significant effect on both fracture resistance and marginal adaptation (p < 0.05). Group O showed significantly smaller marginal gaps than Group OS for both materials. The ZLS overlays exhibited a significantly higher fracture resistance than the 3D-printed resin overlays. All groups demonstrated marginal gaps within the clinically acceptable range (<120 μm). The fracture resistance and marginal adaptation of overlay restorations are significantly influenced by the preparation design and material type. A simpler occlusal reduction design results in better marginal adaptation, whereas round shoulder preparations provide a higher fracture resistance. Although the 3D-printed resin showed lower fracture resistance, its marginal adaptation was comparable to that of milled restorations, suggesting its potential as a conservative and cost-effective polymer composite alternative for digitally fabricated overlay restorations. Full article