Search Results (20)

Dimethyl carbonate (DMC) and polyoxymethylene dimethyl ethers (PODE also known as OME) are possible diesel additives that can be produced sustainably using green methanol. DMC can be produced from CO₂ and methanol, while PODE can be produced from methanol and formaldehyde. In this study both DMC and PODE were investigated as drop-in diesel fuel additives regarding material compatibility, injection behavior, as well as particle and exhaust emissions. Both DMC and PODE are known to be incompatible with certain materials used as seals in the fuel injection system. Therefore, the material compatibility of both neat DMC and PODE as well as blends with B0 was investigated, with both PFTE and FFKM showing good compatibility. The hydraulic injection behavior of DMC–diesel and PODE–diesel blends was investigated experimentally, showing the need for compensating injection quantities for DMC and PODE blends to match neat diesel power output due to their lower calorific values. Energetic compensation can be achieved by higher injection pressures or longer injection durations. Engine tests have been conducted with both DMC–diesel and PODE–diesel blends, demonstrating the potential to mitigate the particle–NO_X trade-off. Full article

In this study, the soot formation and oxidation processes in different turbulent, pre-evaporated and partially premixed diesel surrogate flames are experimentally investigated. For this purpose, a piloted jet flame surrounded by an air co-flow is used. Starting from a defined diesel surrogate mixture, different fuel blends with increasing blending ratios of poly(oxymethylene) dimethyl ether (OME) are studied. The Reynolds number, equivalence ratio, and vaporization temperature are kept constant to ensure the comparability of the different fuel mixtures. The effects of OME addition on flame structures, soot precursors, and soot are investigated, showing soot reduction when OME is added to the diesel surrogate. Using chemiluminescence images of C₂ radicals (line of sight) and subsequent Abel-inversion, flame lengths and global flame structure are analyzed. The flame structure is visualized by means of planar laser-induced fluorescence (PLIF) of hydroxyl radicals (OH). The spatial distribution of soot precursors, such as polycyclic aromatic hydrocarbons (PAHs), is simultaneously measured by PLIF using the same excitation wavelength. In particular, aromatic compounds with several benzene rings (e.g., naphthalene or pyrene), which are known to be actively involved in soot formation and growth, have been visualized. Spatially distributed soot particles are detected by using laser-induced incandescence (LII), which allows us to study the onset of soot clouds and its structures qualitatively. Evident soot formation is observed in the pure diesel surrogate flame, whereas a significant soot reduction with changing PAH and soot structures can be identified with increasing OME addition. Full article

Clean-burning oxygenated and synthetic fuels derived from renewable power, so-called e-fuels, are a promising pathway to decarbonize compression–ignition engines. Polyoxymethylene dimethyl ethers (PODEs or OMEs) are one candidate of such fuels with good prospects. Their lack of carbon-to-carbon bonds and high concentration of chemically bound oxygen effectively negate the emergence of polycyclic aromatic hydrocarbons (PAHs) and even their precursors like acetylene (C₂H₂), enabling soot-free combustion without the soot-NO_x trade-off common for diesel engines. The differences in the spray combustion process for OMEs and diesel-like reference fuels like n-dodecane and their potential implications on engine applications include discrepancies in the observed ignition delay, the stabilized flame lift-off location, and significant deviations in high-temperature flame morphology. For CFD simulations, the accurate modeling and prediction of these differences between OMEs and n-dodecane proved challenging. This study investigates the spray combustion process of an OME_{3 − 5} mixture and n-dodecane with advanced optical diagnostics, Reynolds-Averaged Navier–Stokes (RANS), and Large-Eddy Simulations (LESs) within a constant-volume vessel. Cool-flame and high-temperature combustion were measured simultaneously via high-speed (50 kHz) imaging with formaldehyde (CH₂O) planar laser-induced fluorescence (PLIF) representing the former and line-of-sight OH* chemiluminescence the latter. Both RANS and LES simulations accurately describe the cool-flame development process with the formation of CH₂O. However, CH₂O consumption and the onset of high-temperature reactions, signaled by the rise of OH* levels, show significant deviations between RANS, LES, and experiments as well as between n-dodecane and OME. A focus is set on the quality of the simulated results compared to the experimentally observed spatial distribution of OH*, especially in OME fuel-rich regions. The influence of the turbulence modeling is investigated for the two distinct ambient temperatures of 900 K and 1200 K within the Engine Combustion Network Spray A setup. The capabilities and limitations of the RANS simulations are demonstrated with the initial cool-flame propagation and periodic oscillations of CH₂O formation/consumption during the quasi-steady combustion period captured by the LES. Full article

Polyoxymethylene dimethyl ether (PODE_n, n ≥ 1) is a promising alternative fuel to diesel with higher reactivity and low soot formation tendency. In this study, PODE_3-4 is used as a pilot ignition fuel for methane (CH₄) and the combustion characteristics of PODE_3-4/CH₄ mixtures are investigated numerically using an updated PODE_3-4 mechanism. The ignition delay time (IDT) and laminar burning velocity (LBV) of PODE_3-4/CH₄ blends were calculated at high temperature and high pressure relevant to engine conditions. It is discovered that addition of a small amount of PODE_3-4 has a dramatic promotive effect on IDT and LBV of CH₄, whereas such a promoting effect decays at higher PODE_3-4 addition. Kinetic analysis was performed to gain more insight into the reaction process of PODE_3-4/CH₄ mixtures at different conditions. In general, the promoting effect originates from the high reactivity of PODE_3-4 at low temperatures and it is further confirmed in simulations using a perfectly stirred reactor (PSR) model. The addition of PODE_3-4 significantly extends the extinction limit of CH₄ from a residence time of ~0.5 ms to that of ~0.08 ms, indicating that the flame stability is enhanced as well by PODE_3-4 addition. It is also found that NO formation is reduced in lean or rich flames; moreover, NO formation is inhibited by too short a residence time. Full article

The most effective way to reduce internal combustion engine emissions is to use a sustainable alternative fuel that contains oxygen molecules. Alternative fuels may be used to address a future global energy crisis. Different oxygenated alternative fuels have been investigated in internal combustion engines. Polyoxymethylene di-methylene ether (PODE), which contains 3–5 CH₂O groups, is currently superior in the field of oxygenated fuels due to its physical and chemical properties. Furthermore, using PODE as a fuel does not necessitate any significant engine modifications. When compared to standard diesel fuel, the use of PODE results in near stoichiometric combustion with less hazardous exhaust gas. It also significantly reduces NO_x emissions due to the lack of C-to-C bonds. Several articles in the literature were found on the manufacturing and application processes for the production of PODE. However, the current review focuses primarily on simplifying the various production technologies, the physical and chemical properties of PODEn and its advantages and disadvantages in ICEs, PODEn application in internal combustion engines and its characteristics, PODE spray analysis, and measurements of the fuel’s physical and chemical characteristics. This review emphasizes the fact that PODE can be used as a sole fuel or in conjunction with fossil fuels and advanced combustion technologies. Because C-C bonds and higher oxygen molecules are not available, the trade-off relationship between nitrogen oxides and soot production is avoided when PODEn is used as a fuel, and combustion efficiency is significantly improved. Full article

Droplet internal flow participates in liquid-phase mass transfer during multicomponent solution droplet combustion. In this work, internal flow fields in the binary droplet combustion of two polyoxymethylene dimethyl ethers (CH₃O(CH₂O)_nCH₃, n ≥ 1, abbreviated as PODE_n), i.e., PODE₂ and PODE₄, are characterized using micro-particle image velocimetry (Micro-PIV). The buoyancy-driven upward vapor flow around the droplet is found to initiate two opposite radial flows in the droplet, which form two vortex cores near the surface, while the gravitational effect and Marangoni effect resulting from the content and temperature gradients in the binary droplets can induce disturbance to the two flows. The binary droplets have comparable spatially averaged flow velocities at the stable evaporation stage to those of pure droplets, which are around 3 mm/s. The velocity curves are more fluctuant and tend to slightly increase and reach the peak values at around 250 ms, and then decrease until droplet atomization. The flow velocities in the droplet interior are generally higher than those near the droplet surface, forming a parabolic velocity profile along the horizontal radial direction. The peak velocity first increases to 5–9 mm/s as the radial flow and vortex structure start to form and then decreases to around 3 mm/s until droplet atomization. The radial flow with a spatially averaged velocity of 3 mm/s can run around one lap during the stable evaporation stage, which implies that the convection-induced mass transfer is relatively weak, and consequently, the content gradient of the binary droplet is still mainly controlled by mass diffusion. Full article

Poly(oxymethylene) dimethyl ether (OME) are a much-discussed and promising synthetic and renewable fuel for reducing soot and, if produced as e-fuel, CO₂ emissions. OME production is generally based on the platform chemical methanol as an intermediate. Thus, the OME production cost is strongly dependent on the methanol cost. This work investigates OME production from methanol. Seven routes for providing methanolic formaldehyde solutions are conceptually designed for the first time and simulated in a process simulator. They are coupled with a state-of-the-art OME synthesis to evaluate the economics of the overall production chain from methanol to OME. For a plant size of 100 kt/a, the average levelized product cost of OME is 79.08 EUR/t plus 1.31 times the cost of methanol in EUR/t. Full article

Polyoxymethylene dimethyl ether (PODE) is one of the most promising alternative fuels for diesel engines with a high cetane number, high oxygen content, and no C-C bonds. In this paper, a new spray model with a novel cavitation sub-model is adopted in order to create a numerical model suitable for engine simulation fueled with PODE/diesel blends. The effects of the blending ratio, injection timing, and EGR rate on the combustion and emission characteristics are investigated by the simulation. The simulation results show that the self-restoring oxygen properties of PODE can efficiently improve the combustion, causing a higher in-cylinder temperature, and therefore, higher NO_x emissions. Additionally, with the increase in the blending ratio, the increase in the oxidation activity of PODE/diesel blends and the improvement of atomization are conducive to reducing soot emissions. Then, the injection timing and EGR rate are optimized. The numerical results suggest that the NO_x emissions decrease initially and then increase; however, soot emissions decrease monotonically with the delay of the injection timing. When the volume blending ratio is 15%, the emission performance is best when the injection timing is between 710 °CA and 715 °CA. The increase in EGR rate can effectively reduce the in-cylinder temperature and control the NO_x emissions, but the excessive EGR rate leads to higher soot emissions and a deteriorated combustion process. Therefore, an EGR rate in the range of 0.0 to 0.2 has a better comprehensive emission performance from the perspective of controlling both the NO_x and soot emissions. Full article

On the path towards climate-neutral future mobility, the usage of synthetic fuels derived from renewable power sources, so-called e-fuels, will be necessary. Oxygenated e-fuels, which contain oxygen in their chemical structure, not only have the potential to realize a climate-neutral powertrain, but also to burn more cleanly in terms of soot formation. Polyoxymethylene dimethyl ethers (PODE or OMEs) are a frequently discussed representative of such combustibles. However, to operate compression ignition engines with these fuels achieving maximum efficiency and minimum emissions, the physical-chemical behavior of OMEs needs to be understood and quantified. Especially the detailed characterization of physical and chemical properties of the spray is of utmost importance for the optimization of the injection and the mixture formation process. The presented work aimed to develop a comprehensive CFD model to specify the differences between OMEs and dodecane, which served as a reference diesel-like fuel, with regards to spray atomization, mixing and auto-ignition for single- and multi-injection patterns. The simulation results were validated against experimental data from a high-temperature and high-pressure combustion vessel. The sprays’ liquid and vapor phase penetration were measured with Mie-scattering and schlieren-imaging as well as diffuse back illumination and Rayleigh-scattering for both fuels. To characterize the ignition process and the flame propagation, measurements of the OH* chemiluminescence of the flame were carried out. Significant differences in the ignition behavior between OMEs and dodecane could be identified in both experiments and CFD simulations. Liquid penetration as well as flame lift-off length are shown to be consistently longer for OMEs. Zones of high reaction activity differ substantially for the two fuels: Along the spray center axis for OMEs and at the shear boundary layers of fuel and ambient air for dodecane. Additionally, the transient behavior of high temperature reactions for OME is predicted to be much faster. Full article

Polyoxymethylene dimethyl ethers (PODE), as the most potential oxygenated alternative fuel for diesel engines, is widely investigated. Considering the importance of research on real driving emissions (RDE) and the few studies focus on the emission characteristics of the PODE/diesel blended fuels under real driving conditions, a portable emission measurement system (PEMS) was applied to measure the RDE of a heavy-duty tractor fueled with diesel or PODE/diesel blends. The tests were carried out in accordance with the relevant regulations of the CHINA VI emission standards. The second-by-second data from PEMS and the OBD system were utilized to construct engine transient operating maps. The results indicated that the addition of PODE can still decrease CO and PN emissions significantly under real driving conditions, although the low load conditions are still the areas of high brake specific CO and brake specific PN emissions. The NOx emissions, however, were not reduced as the results of the steady-state experiment of the same model of the engine. Fuel mass consumption raised when PODE was added, while the overall brake thermal efficiency improved, especially for the blending ratio of 30%, up to 40.3%, which is higher than 38.4% of pure diesel operation. Full article

With its high cetane number and oxygen content, polyoxymethylene dimethyl ether (PODE) can promote engine combustion and reduce particulate emissions, which has become a key research object of diesel surrogate fuel. This study further explores the effects of blending PODE on emission characteristics of a China VI diesel engine. Diesel/PODE blends with the PODE volume blending ratios of 10%, 20% and 30% have been experimentally investigated in a China VI heavy-duty diesel engine at 1900 rpm and four different loads. Furthermore, the effects of EGR rates (Exhaust Gas Recirculation) rates (0–20%) on combustion and emission characteristics have been also discussed at 1700 r/min engine speed and 50% engine load condition. An exhaust gas analyzer and a particle counter were used to collect NOx, CO and THC emissions and particulate number (PN) emissions. The results show that the CO and THC emissions can be significantly reduced with the increase in the mixing ratio of PODE. Additionally, the particle number concentration can be also reduced, especially at low and high loads. The NOx emissions can be improved by increasing EGR rates. Interestingly, there is a trade-off relationship between PN and NOx emissions. In general, blending PODE can effectively reduce NOx and PN emissions simultaneously. Full article

Polyoxymethylene dimethyl ether (PODEn) is a promising diesel additive, especially in particulate matter reduction. However, how PODEn addition affects the filtration efficiency and regeneration process of a catalytic diesel particulate filter (cDPF) is still unknown. Therefore, this experimental work investigated the size-dependent particulate number removal efficiency under various engine loads and exhaust gas recirculation (EGR) ratios when fueling with diesel (D100) and diesel/PODEn mixture (P10). In addition, the regeneration behavior of the cDPF was studied by determining the breakeven temperatures (BETs) for both tested fuels. The results showed that the cDPF had lower removal efficiencies in nucleation mode particles but higher filtration efficiencies in accumulation mode particles. In addition, the overall filtration efficiency for P10 particles was higher than that for D100 particles. Positioning the upstream cDPF, increasing the EGR ratio slightly decreased the number concentration of nucleation mode particles but greatly increased that of accumulation mode particles. However, increasing the EGR ratio decreased the removal efficiency of nanoparticles, and this effect was more apparent for the P10 case. Under the same period of soot loading, the pressure drop of P10 fuel was significantly lower than that of diesel fuel. In addition, a significantly lower BET was observed for the P10 fuel, in comparison with D100 fuel. In conclusion, adopting cDPF is beneficial for fueling with P10 in terms of the overall filtration efficiency in the particulate number and the lower input energy requirement for active regeneration. However, with the addition of EGR, the lower filtration efficiencies of nanoparticles should be concerned, especially fueling with diesel/PODEn mixture. Full article

Polyoxymethylene dimethyl ether (PODE) is a low-viscosity oxygenated fuel that can improve the volatility of blended fuels. In this work, the macroscopic and microscopic spray characteristics of diesel-PODE_3-4 under different ambient temperatures and injection pressures (IP) are studied. The studied blends consisted of pure diesel (P0), two diesel blend fuels of 20% (P20) and 50% (P50) by volume fraction of PODE_3-4. The Mie scattering and Schlieren imaging techniques are used in the experiment. The results show that with the increase in IP, the vapor phase penetration distance and the average cone angle of the three fuels increased, and the Sauter mean diameter (SMD) of the three fuels decreased. When the ambient temperature increased, the vapor phase projection area and the average vapor phase cone angle of P20 and P50 increased, and the SMD decreased, but the vapor phase projection area of pure diesel did not change significantly. The results indicate that the blended fuel with PODE_3-4 has better spray characteristics than P0 at low temperature, and the SMD hierarchy between the three fuels is P0 > P20 > P50. Through the visualization experiment, it is helpful to further understand the evaporation characteristics of different fuel properties and develop appropriate alternative diesel fuel. Full article

Polyoxymethylene dimethyl ethers (PODE) are a newly appeared promising oxygenated alternative that can greatly reduce soot emissions of diesel engines. The combustion characteristics of the PODE and diesel blends (the blending ratios of PODE are 0%, 20%, 50% and 100% by volume, respectively) are investigated based on an optical engine under the injection timings of 6, 9, 12 and 15-degree crank angles before top dead center and injection pressures of 100 MPa, 120 MPa and 140 MPa in this study. The results show that both the ignition delay and combustion duration of the fuels decrease with the increasing of PODE ratio in the blends. However, in the case of the fuel supply of the optical engine being fixed, the heat release rate, cylinder pressure and temperature of the blend fuels decrease with the PODE addition due to the low lower heating value of PODE. The addition of PODE in diesel can significantly reduce the integrated natural flame luminosity and the soot formation under all injection conditions. When the proportion of the PODE addition is 50% and 100%, the chemical properties of the blends play a leading role in soot formation, while the change of the injection conditions have an inconspicuous effect on it. When the proportion of the PODE addition is 20%, the blend shows excellent characteristics in a comprehensive evaluation of combustion and soot reduction. Full article

Emissions from diesel engines can be limited and potentially decreased by modifying the fuel chemical composition through additive insertion. One class of additives that have shown to be particularly efficient in the reduction of the particulates from the combustion of diesel fuels are oxygenated compounds. In the present study we investigate the effect of tripropylene glycol methyl ether (TPGME) and two polyoxymethylene dimethyl ethers (POMDME or OMEs) on soot formation in a laminar diesel diffusion flame. From the evaluation of soot volume fraction by laser-induced incandescence (LII) measurements we could observe that OME additives have a substantial capability (higher compared to TPGME) to decrease the particle concentration, which drops by up to 36% with respect to the pure diesel fuel. We also note a reduction in particle aggregate size, determined by wide-angle light scattering (WALS) measurements, which is more pronounced in the case of OME–diesel blends. The effects we observe can be correlated to the higher amount of oxygen content in the OME molecules. Moreover, both additives investigated seem to have almost no impact on the local soot temperature which could in turn play a key role in the production of soot particles. Full article