Search Results (756)

Externally bonded carbon-fiber-reinforced polymer (CFRP) can increase the flexural capacity of steel beams, but the benefit is often limited by the performance of the adhesive interface. This study develops and validates a three-dimensional finite-element model (FEM) with an explicit cohesive-zone representation of the adhesive layer. It reproduced benchmark four-point bending tests in terms of peak load, corresponding mid-span deflection, and the transition from end/intermediate debonding to laminate rupture. A one-factor-at-a-time parametric analysis is carried out to examine the influence of (i) member geometry (beam depth; flange and web thickness), (ii) CFRP configuration (bonded length; laminate thickness), and (iii) bond quality (cohesive normal strength). Within the ranges studied, cohesive strength and bonded length are the primary variables controlling both capacity and failure mode: strengths below about 25 MPa and short plates lead to debonding-governed response. Increasing strength to around 27 MPa and bonded length to 650–700 mm delays debonding, promotes CFRP rupture, and produces the largest incremental gains in peak load, while further increases in length give smaller additional gains. Increasing laminate thickness and steel depth or flange/web thickness always raises peak load, but under baseline bond conditions failure remains debonding and the added material is only partially mobilized. When cohesive strength is increased above the threshold, additional CFRP thickness becomes more effective. A linear regression model is fitted to the FEM dataset to express peak load as a function of bonded length, cohesive strength, laminate thickness, and steel dimensions, and is complemented by a failure-mode map and a cost–capacity chart based on material quantities. Together, these results provide quantitative trends and simple relations that can support preliminary design of CFRP-strengthened steel beams for similar configurations. Full article

Wound coatings in the form of sponge plates were obtained based on hydrogels of cod collagen (CC) copolymers. The synthesis of CC copolymers with pectin was carried out in the presence of a triethylbor–hexamethylenediamine (TEB-HMDA) complex, which forms free radicals under reaction conditions, and with polyethylene glycol (PEG) during photocatalysis in the presence of RbTe_1.5W_0.5O₆ oxide under visible-light irradiation with a LED lamp. Evaluation of their effectiveness and safety for rapid healing of wounds and burn surfaces has been conducted on small animals (rats). It has shown significantly higher efficiency in comparison with commercial collagen sponges based on bovine collagen. Coatings based on cod collagen contributed to the normalization of microcirculation levels according to the results of laser Doppler flowmetry and a high rate of reduction in the area of the scalped burn wound according to planimetry. The morphological studies indicate complete epithelialization with the formation of scar tissue in all studied groups of animals. The dynamics of microcirculation parameters indicate the repair of thermal burns during local treatment with wound-healing coatings against the background of normalization of the functioning of the microcirculatory system. It is advisable to use new collagen-based polymer sponge plates to increase the effectiveness of wound treatment of various origins, shorten recovery time, and optimize the course of typical physiological reactions during the wound process in order to accelerate tissue regeneration, as well as reduce mortality. Full article

Finding efficient ways to store energy is a current topic both at the macro level and at the microscale. As silicon plates are the main platform for the integration of microelectronic devices, it is reasonable to use the silicon structures as the active materials for on-chip microcapacitors. Porous silicon (pSi) and silicon nanowires (SiNWs) are ideal candidates for planar electrodes because these layers are directly embedded into the silicon wafer. The review contains a brief summary of the formation features of pSi/SiNW and their electrochemical performance. The structural characteristics of the silicon matrix (depth and morphology) that influence capacitive electrode properties are examined comprehensively for the first time. Particular attention is given to additional coatings on the pore/wire surface. Various ways of depositing metal, carbon, and polymer layers are considered in detail. Different approaches to filling the silicon matrix are explored. Focusing on pSi/SiNWs coatings allows us to identify the effect of the structure, crystallinity, and methods of additional layer deposition on capacitance, cycling stability, and charge transport of modified electrodes. Although fabrication processes for planar microcapacitors based on pSi/SiNWs are currently underdeveloped, the specific requirements and possible challenges of on-chip integration are discussed and proposed. Full article

In response to the issue of local damage to mountainous bridges easily caused by rockfall impacts, carbon fiber cloth and steel plate strengthening methods were adopted to deeply study the impact of the width of carbon fiber cloth and steel plates on the strengthening effect. This study investigates the strengthening effectiveness of Carbon Fiber-Reinforced Polymer (CFRP) wraps and steel jackets on circular bridge piers, utilizing the ABAQUS finite element method. The analysis focuses on the effects of varying load conditions and confinement widths ranging from 100 to 200 cm, with a specific case study of a bridge pier in Nanchuan District, Chongqing. The research results show that the width of carbon fiber cloth and steel plates has a significant impact on the bridge pier’s impact resistance and damage resistance. There exists an optimal strengthening width that maximizes the strengthening effect. The stress distribution and displacement changes under different load conditions are affected by the width of the steel plate; the wider the steel plate, the better the strengthening effect, but the effect is not strictly linear. A comprehensive analysis method integrating multi-directional stress and displacement data was developed, incorporating weighting factors based on structural safety relevance. For both strengthening methods, a set of fitted formulas for widths between 100 cm and 200 cm was derived. This study provides systematic insights and practical guidance for the design of impact-resistant strengthening systems for bridge piers. Full article

Injection molding is a high-volume manufacturing process widely used for producing polymer components; however, its process parameters strongly influence residual stress, warpage, and the resulting mechanical performance. This work presents a comprehensive factorial design and ANOVA to evaluate the simultaneous effects of the injection temperature, packing pressure, packing time, and specimen orientation on the warpage, hardness, tensile, and flexural properties of polypropylene plates. The results demonstrate that the injection temperature and packing pressure are the dominant factors affecting the hardness and ultimate tensile strength, whereas warpage is mainly governed by the injection temperature and orientation. Under the tested conditions, certain combinations of injection temperature and packing pressure led to an improved mechanical performance; however, these adjustments also produced reductions in other properties, indicating that the balance among parameters depends on the targeted application rather than a single optimal set. Conversely, the parameter combination that produced the lowest warpage still yielded a significant increase in $E_{sec}$, indicating that reducing the warpage does not necessarily compromise the tensile stiffness. Interestingly, variations in the stress distribution between the tensile and bending tests suggest that the solidification-induced structure of the material influences its mechanical response, with specimens that showed a lower tensile strength exhibiting a comparatively higher resistance under bending. These findings provide new insights into the trade-offs between dimensional accuracy and mechanical performance and offer practical guidelines for optimizing polypropylene injection molding processes. Full article

Ionic polymer–metal composites (IPMCs) are promising soft actuators; however, they face challenges such as solvent evaporation, low blocking force, and complex fabrication processes. This study introduces a simplified method for fabricating ionic polymer–graphene composite (IPGC) actuators using Nafion 117 membranes and graphene powder. Graphene was directly rubbed onto the membrane surface and subjected to brief microwave irradiation to form durable electrodes, eliminating the need for solvents, multilayer casting, or expensive metal plating. The experimental results indicated that repeated fabrication cycles reduced surface resistance and enhanced bending performance, with optimal displacement achieved after three cycles. Scanning electron microscopy confirmed improved adhesion and surface uniformity following microwave treatment. A hybrid electromechanical model, combining an RC circuit with a mass–spring–damper system, was developed to accurately predict the static behavior of the actuator and achieve reliable parameter estimation. Although the bending performance of the ionic polymer actuator fabricated using the proposed method reaches approximately 75% of that of conventionally produced IPMCs, the method offers a significantly simpler and lower-cost fabrication process. Full article

An optimized extrusion process is desired for both an environmentally friendly and economically sustainable recycling process. The aim of this study is to simulate the melt conveying zone of a single-screw extruder when using contaminated polymers instead of commonly used pure materials, to optimize a mechanical recycling process, and to reduce the number of measurements needed for rheological input data by using mixing rules. Polypropylene (PP) is blended with a polyamide 12 (PA 12) grade and another PP grade to introduce polymer impurities into the material. The blends are subjected to extrusion experiments in a lab-scale single-screw extruder with pressure and temperature sensors along the barrel. An isothermal analytical simulation model is proposed using representative shear rate values and rheological mixing rules to calculate the pressure distribution along the screw channel throughout the melt conveying zone. The rheological input data for the simulation is taken from high-pressure capillary rheometric measurements, but also substituted with values derived from mixing rules. The results show that the application of the shear viscosity through mixing models yields simulated pressure values similar to those measured in the experiments. With the introduction of representative viscosity into the model, relative deviations of around 5% at certain screw speeds can be achieved. Full article

Carbon fiber-reinforced polymer (CFRP) laminates are extensively utilized in aerospace and advanced engineering fields because of their outstanding strength-to-weight ratio and superior fatigue durability. However, despite their high in-plane strength and stiffness, CFRP laminates are inherently susceptible to delamination. This weakness stems from the relatively low interlaminar strength of the resin-rich interfaces between layers compared to the much stronger in-plane fiber reinforcement. During mechanical processes such as drilling and punching, out-of-plane stresses and interlaminar shear forces develop, concentrating at these weak interfaces. This study investigates the delamination behavior of CFRP laminates with 3 to 7 plies under drilling and punching, focusing on the effects of ply count and drilling speed. Experimental tests were conducted using an 8 mm punch and drill bit at 2500, 3000, and 3500 rpm, reflecting typical workshop practices for M8 fastener holes. Scanning electron microscopy (SEM) analyses at different magnifications were used to quantify delamination extent. A three-dimensional finite element model was created in ABAQUS/Explicit, integrating the Hashin failure criterion to predict damage initiation within the plies and cohesive surfaces to simulate interlaminar delamination. The analyses show that with proper support, punching can approach the damage levels of drilling for thin CFRP plates, but drilling remains preferable for thicker laminates due to better integrity and tool longevity. Full article

Fiber-Reinforced Polymer (FRP)-laminated composite materials are increasingly recognized as a transformative solution for future structural applications, due to their exceptional properties, such as lightweight, superior fatigue life, corrosion resistance, and ease of manufacturing. These advantages make them highly suitable for innovative applications in various sectors, including aerospace, automotive, marine, energy and defense. As one of the load-carrying members, the composite laminated plate structures are widely used in aircraft structures, such as the fuselage, wing and tail. These thin-walled structures will buckle under compressive or shear loading, which is a major consideration in the structural design process. Due to their high specific strength, laminated FRP composite structures are gaining increasing attention and are widely used in advanced lightweight structures. However, to fully exploit the large post-buckling reserves of FRP structures, their damage behavior and failure modes must be well understood. In this study, a progressive failure analysis based on ANSYS finite element (FE) simulations has been carried out to predict the nonlinear response and failure characteristics of a laminated composite plate under compressive loading. The FE-based progressive failure analysis utilized shell elements based on the Classical Laminate Plate Theory (CLPT) to calculate the in-plane stresses. The failure model employed the 3D failure criterion LaRC04 for damage detection and the stiffness degradation model for damage propagation in an FRP-laminated composite plate structure. The analysis results are found in close agreement with the published simulation and experimental results. This study has proposed an efficient methodology to accurately predict the post-buckling response, i.e., failure modes and collapse loads of laminated FRP composite constructions under compressive loading. Full article

Reinforced concrete (RC) joist slabs are common in Middle Eastern buildings, where architectural needs often necessitate planting columns on shallow beams. Although such beams typically satisfy flexural and shear design requirements, their serviceability is frequently compromised by excessive deflections. This study experimentally investigated the effectiveness of polymer-bonded/bolted steel plates versus an Ultra-High-Performance Fiber-Reinforced Concrete (UHPFRC) overlay, applied to the compression face, in controlling the deflection of shallow beams with planted columns. Four half-scale beams were tested under single-point loading, including two unstrengthened specimens to be used as reference beams. The first control beam reflected typical design practice—adequate in strength but exceeding code deflection limits—while the second specimen was designed to achieve similar flexural capacity with serviceable deflection. The remaining two beams were externally strengthened using either steel plates or UHPFRC overlay. Experimental results were analyzed in terms of failure mode, peak load, and deflection response. Both strengthening methods improved bending performance, stiffness, and load capacity, with UHPFRC showing superior effectiveness. Simplified analytical equations provided reasonable predictions of deflection and ultimate load. The findings highlight the potential of compression-side strengthening, particularly using UHPFRC, to enhance the serviceability of shallow RC beams supporting planted columns. Full article

In recent years, the demand for high-strength concrete (HSC) for buildings has been steadily increasing. Continuous HSC deep beams are frequently employed in various structural applications, including high-rise buildings, bridges, and parking garages, due to their superior load capacity. Some cases require the addition of openings after the construction for passing utilities such as drainage and electricity. This study experimentally examines four two-span HSC deep beams: one control solid beam, one beam with circular openings, and two beams that utilized different strengthening schemes. The openings were asymmetrical circular openings, with one positioned in each span. This study sought to regain the full capacity of beams with openings by employing two types of strengthening schemes. The first one used bolted steel plates, while the second was a hybrid scheme that combined bolted steel plates with externally bonded fiber-reinforced polymer (FRP) sheets. Test findings demonstrated that both methods effectively restored the load capacity of the strengthened beams. The strengthened beam with steel plates achieved a load capacity of 125% compared to the solid beam. Likewise, the beam retrofitted with hybrid steel/FRP composites reached 117%. Additionally, the energy dissipation and ductility index of the strengthened beam with steel plates were 32% and 77%, respectively, compared to the strengthened beam with hybrid steel/FRP composites. The findings emphasize the effectiveness of the applied retrofitting techniques in restoring the lost capacity due to the cutting of post-construction openings in deep beams. Full article

To reduce the time of postoperative recovery and to prevent post-surgical complications, biocompatible synthetic materials with osteoconductive and osteoinductive properties are used as bone substitutes in large bone defect management. A simplified biomimetic approach to similar materials is based on the use of an inorganic filler, a polymer matrix, and a compatibilizer, mimicking the composition of the natural bone. Based on plate-like micro-sized carbonated hydroxyapatite (pCAp), we prepared compression-molded samples optionally containing an additional polyester component (poly(ε-caprolactone) PCL, poly(L-lactide) PLLA, or poly(L-methylglycolide) PLMG); syntheticblock copolymers comprising fragments of the corresponding polyester and poly(ethylene phosphoric acid) (PEPA) were also prepared and studied asa ‘two-in-one’ polymer matrix/compatibilizer. Bone regeneration experiments involving a three-month rat tibial defect model were conducted with 250–500 μm granules of the composites. Comparative studies of the introduction of the polyester-b-PEPA copolymer into composites revealed a positive effect, which manifests itself in accelerated bone regeneration, which further intensified for pCAp/PEPA-b-PLMG. The latter composite formulation was used to study the results of the introduction of cerium into the filler. One-month experiments with pCAp, CePO₄-doped pCAp, and composites of these inorganic fillers with PEPA-b-PLMG were conducted. For the first time, a positive synergistic effect of the presence of cerium and PEPA in the composite, which appeared in substitution of the implant material by two-thirds of newly formed partly matured bone, was observed four weeks after surgery. Full article

The accumulation of polyethylene terephthalate (PET) in the environment demands efficient microbial strategies for its degradation. This study evaluates the biodegradation potential of Schizophyllum commune BNT39 toward bis(2-hydroxyethyl) terephthalate (BHET), a major PET intermediate, and PET itself. Clear halos on BHET-agar plates indicated extracellular hydrolytic activity. In liquid culture, thin-layer chromatography (TLC) and high-performance liquid chromatography (HPLC) analyses revealed a three-phase degradation profile characterized by rapid BHET hydrolysis, transient dimer accumulation, and subsequent conversion to terephthalic acid (TPA). BHET was reduced by approximately 96% within seven days, while TPA accumulation reached 0.8 mg/mL after 30 days of incubation. Although PET degradation was limited, TPA was consistently detected as the principal product, with no BHET or MHET intermediates. To explore strategies for enhancing enzymatic activity, apple-derived cutin, PET, BHET, and polycaprolactone (PCL) were tested as inducers. Cutin markedly stimulated extracellular enzyme production, suggesting activation of cutinase-like enzymes. Overall, S. commune BNT39 demonstrates the ability to transform PET-related substrates, with cutin emerging as a promising natural stimulant to enhance enzymatic depolymerization. Future studies should focus on enzyme purification, activity profiling, and reaction optimization near PET’s glass transition temperature, where the polymer becomes more accessible for enzymatic attack. Full article

Metal anodes promise improvements in energy density and cost; however, their performance is determined within the first several nanometers at the interface. This review reports on how polymer-based artificial solid electrolyte interphases (SEIs) are engineered to stabilize Li and aqueous-Zn anodes, and how these designs are now evaluated against operando readouts rather than post-mortem snapshots. We group the related molecular strategies into three classes: (i) side-chain/ionomer chemistry (salt-philic, fluorinated, zwitterionic) to increase cation selectivity and manage local solvation; (ii) dynamic or covalently cross-linked networks to absorb microcracks and maintain coverage during plating/stripping; and (iii) polymer–ceramic hybrids that balance modulus, wetting, and ionic transport characteristics. We then benchmark these choices against metal-specific constraints—high reductive potential and inactive Li accumulation for Li, and pH, water activity, corrosion, and hydrogen evolution reaction (HER) for Zn—showing why a universal preparation method is unlikely. A central element is a system of design parameters and operando metrics that links material parameters to readouts collected under bias, including the nucleation overpotential (η_nuc), interfacial impedance (charge transfer resistance (R_ct)/SEI resistance (R_SEI)), morphology/roughness statistics from liquid-cell or cryogenic electron microscopy (Cryo-EM), stack swelling, and (for Li) inactive-Li inventory. By contrast, planar plating/stripping and HER suppression are primary success metrics for Zn. Finally, we outline parameters affecting these systems, including the use of lean electrolytes, the N/P ratio, high areal capacity/current density, and pouch-cell pressure uniformity, and discuss closed-loop workflows that couple molecular design with multimodal operando diagnostics. In this view, polymer artificial SEIs evolve from curated “recipes” into predictive, transferable interfaces, paving a path from coin-cell to prototype-level Li- and Zn-metal batteries. Full article

This study investigates the machining challenges of fiber-reinforced composite materials (FRCMs), focusing on carbon fiber-reinforced polymer (CFRP) plates, which exhibit high abrasiveness, delamination tendency, and accelerated tool wear. Two solid carbide helical end mills, designed for composite machining, were evaluated through helical interpolation drilling. Acoustic emission signals were continuously acquired via a piezoelectric sensor during standardized cycles, and tool wear was assessed using confocal microscopy and a digital altimeter. Signal processing played a central role, combining energy-based metrics and damage indices to identify the onset of wear and early delamination, enhancing the understanding of tool degradation and improving machining reliability. Full article